Corrosion resistance of the layers formed on the surface of plasma-nitrided AISI 304L steel

Austenitic stainless steels have good corrosion resistance, but their low hardness and low wear resistance limit their use whenever surface hardness is required. Nitriding treatments have been successfully applied to stainless steels to improve their mechanical and tribological properties; however, at temperatures above 723 K, gas or salt bath nitriding processes decrease the corrosion resistance due to the formation of CrN and other phases within the modified layer. Chromium compounds draw chromium and nitrogen from the adjacent regions, degrading the corrosion resistance. The plasma nitriding technique permits the use of treatment temperatures as low as 623 K without promoting degradation in the corrosion resistance of stainless steel. In this work, the pulsed glow discharge (PGD) technique was used for nitriding steel (AISI304L) in order to investigate the effect of the temperature of this treatment in the morphology and, as a consequence, in the anodic behavior of the formed layers, in solution with and without chloride ions. Four different temperatures were employed (623, 673, 723, and 773 K). The samples were characterized by optical microscopy (OM), scanning electron microscopy (SEM) with energy-dispersive spectroscopy (EDS), X-ray diffraction (XRD), microhardness measurements, and electrochemical tests with potentiodynamic anodic polarization curves. The nitriding temperature alters the anodic behavior due to a displacement of the polarization curve towards higher currents, in a solution free of chloride ions. In a chloride solution, the nitriding temperature increases the pitting potential up to the oxygen evolution region.     

The thermal conductivity of AISI 304L stainless steel

A compilation and critical analysis of the thermal conductivity () of AISI 304 stainless steel (SS) between 100 and 1707 K has been given in the literature. The author represented his recommended values of by an inflection in the A versus temperature relationship between 300 and 500 K. Because a physical mechanism had not been identified that would produce such a temperature dependence in of 304 SS, interest was generated in the possible existence of an as yet undiscovered phenomenon that might cause such an inflection. Consequently, experimental verification of the inflection was sought. The present paper presents recent measurements of , the electrical resistivity, and the absolute Seebeck coefficient of 304L SS from 300 to 1000 K and of the thermal diffusivity () from 297 to 423 K. The values computed from the a measurements were within ± 1.6% of the directly measured An inflection was not observed in the temperature dependence of between 300 and 500 K. After careful evaluation and because a physical mechanism still has not been identified which would produce such an inflection, the authors conclude that the inflection in the vs T relationship reported in the literature was caused by the data analysis technique.     

Characterization of failure modes for different welding processes of AISI/SAE 304 stainless steels

Weld joints manufactured with a welding electrode type 308L and by three different arc welding processes shielded metal arc welding (SMAW), gas metal arc welding (GMAW) and flux cored arc welding (FCAW) in a AISI/SAE 304 were studied in order to compare the failure mechanisms associated with their mechanical and microstructural properties. Chemical compositions were analyzed by optical emission spectroscopy and the ferrite numbers (FN) of the welds were also identified. Relevant microstructural characteristics of the different processes were analyzed by microscopy techniques. Finally, fatigue tests were performed to study the variations in the mechanical properties of each process and to analyze their most probable failure modes by means of a fractographic study, in which the characteristic morphologies of each one (nucleation, propagation, final fracture) were identified by means of optical stereoscopy and scanning electron microscopy (SEM). Three different fracture modes were found at the welding joints that showed correlations with microstructural changes produced during the welding process. The first failure mode displayed that the nucleation of the crack was at the weld root. The second failure mode was generated at the heat affected zone (HAZ), where the crack nucleated due to a variation in the grain size produced by the process and then further propagated through the edge of the weld. The third failure mode appeared due to the presence of exogenous inclusions generated by the welding process, which acted as stress concentrators in the weld and produce the initiation and further propagation of the crack. Lastly, some welding processes presented a combination of the previous failure modes and consequently multiple sites of crack nucleation.     

Measurement of the Thermal Conductivity of Stainless Steel AISI 304L Up to 550 K

New measurements of the thermal conductivity of stainless steel AISI 304L over the temperature range 300 to 550 K are reported. To perform the measurements, the transient hot-wire technique was employed, with a new wire sensor. The sensor makes use of a soft silicone paste material and of two thin polyimide films, between the hot wires of the apparatus and the stainless steel specimen. The transient temperature rise of the wire sensor is measured in response to an electrical heating step over a period of 40 s to 2 s, allowing an absolute determination of the thermal conductivity of the solid, as well as of the polyimide film and the silicone paste. The method is based on a full theoretical model with equations solved by a two-dimensional finite-element method applied to the exact geometry. At the 95% confidence level, the standard deviation of the thermal conductivity measurements is 0.6%, while the standard uncertainty of the technique is less than 1.5%.     

Pitting corrosion failure of an AISI stainless steel pointer rod

In this study, failure analysis of a thermostatic mixing valve pointer rod made of AISI 304 stainless steel was performed. Visual examination, followed by an in-depth microstructural characterization using optical and scanning electron microscopy, was carried out for understanding the primary cause of failure. Energy dispersive X-ray, X-ray diffraction analysis and transmission electron microscopic analyses were also necessary supplements to this investigation. Finally, the obtained results infer that the combined effect of large amounts of MnS inclusions and the presence of deformation induced martensite adversely affected the pitting corrosion resistance of the pointer rod material. It is concluded that the pointer rod material was not properly investigated for defects prior to and after its fabrication.     

Bias effects on the tribological behavior of cathodic arc evaporated CrTiAlN coatings on AISI 304 stainless steel

In this study, CrTiAlN coatings were deposited on AISI 304 stainless steel by cathodic arc evaporation under a systematic variation of the substrate bias voltage. The coating morphology and properties including surface roughness, adhesion, hardness/elastic modulus (H/E) ratio, and friction behavior were analyzed to evaluate the impact of the substrate bias voltage on the coating microstructure and properties. The results suggest that for an optimized value of the substrate bias voltage, i.e. − 150 V, the CrTiAlN coatings showed increased Cr content and improved properties, such as higher adhesion strength, hardness, and elastic modulus in comparison to the coatings deposited by other substrate bias voltage. Moreover, the optimum coatings achieved a remarkable reduction in the steel friction coefficient from 0.65 to 0.45.     

Friction stir welding of AISI 304 austenitic stainless steel

The objective of this work is to demonstrate the feasibility of friction stir welding (FSW) AISI 304 austenitic stainless steels. The tool used was formed of a tungsten‐based alloy. The specimens were welded on an 11 kW vertical milling machine. Defect‐free welds were produced on 2.5 mm plates of hot‐rolled AISI 304 austenitic stainless steels at travel speeds ranging from 40 to 100 mm/min with a constant rotating speed of 1000 rpm. Tensile strengths and hardness values of the weld interface were determined and microstructure features of these samples were investigated.     

水雾化304L粉末材料的表面化学反应研究

研究了水雾化奥氏体不锈钢粉末在致密时的表面化学反应.研究发现颗粒表面和孔隙表面的化学反应受致密温度的强烈影响,材料的力学性能与表面化学反应产物及其形态和分布有关.     

Stress induced martensite transformation texture in AISI 304 austenitic stainless steel

Abstract

The phenomenological theory of martensitic transformation was applied to a tension induced martensitic transformation in an AISI 304 austenitic stainless steel in order to estimate the transformation texture. Input data were obtained from the published literature. Calculated pole figures were constructed assuming a variant selection process based on Patel and Cohen’s theory, which emphasises that a mechanical component of free energy is the driving force for martensitic transformation at temperatures above martensite start M_s. The results showed a remarkably good match between the calculated and published measured data.     

Phase formation in selected surface-roughened plasma-nitrided 304 austenite stainless steel

Direct current (DC) glow discharge plasma nitriding was carried out on three selected surface-roughened AISI 304 stainless steel samples at 833 K under 4 mbar pressures for 24 h in the presence of N₂:H₂ gas mixtures of 50 : 50 ratios. After plasma nitriding, the phase formation, case depth, surface roughness, and microhardness of a plasma-nitrided layer were evaluated by glancing angle x-ray diffractogram, optical microscope, stylus profilometer, and Vickers microhardness tester techniques. The case depth, surface hardness, and phase formation variations were observed with a variation in initial surface roughness. The diffraction patterns of the plasma-nitrided samples showed the modified intensities of the α and γ phases along with those of the CrN, Fe₄N, and Fe₃N phases. Hardness and case depth variations were observed with a variation in surface roughness. A maximum hardness of 1058 Hv and a case depth of 95 μm were achieved in least surface-roughened samples.     

Phase formation in selected surface-roughened plasma-nitrided 304 austenite stainless steel

Abstract

Direct current (DC) glow discharge plasma nitriding was carried out on three selected surface-roughened AISI 304 stainless steel samples at 833 K under 4 mbar pressures for 24 h in the presence of N₂:H₂ gas mixtures of 50 : 50 ratios. After plasma nitriding, the phase formation, case depth, surface roughness, and microhardness of a plasma-nitrided layer were evaluated by glancing angle x-ray diffractogram, optical microscope, stylus profilometer, and Vickers microhardness tester techniques. The case depth, surface hardness, and phase formation variations were observed with a variation in initial surface roughness. The diffraction patterns of the plasma-nitrided samples showed the modified intensities of the α and γ phases along with those of the CrN, Fe₄N, and Fe₃N phases. Hardness and case depth variations were observed with a variation in surface roughness. A maximum hardness of 1058 Hv and a case depth of 95 μm were achieved in least surface-roughened samples.     

Monotonic vis-à-vis cyclic fracture behaviour of AISI 304LN stainless steel

This investigation is aimed to examine the monotonic and cyclic fracture behaviour of AISI 304LN stainless steel and its weldments, in order to assess their integrity under seismic loading conditions. The monotonic fracture resistance of the steel has been determined using standard J-integral technique; whereas the cyclic fracture resistance has been evaluated using periodic unloading to different extents fixed by pre-determined R-ratio. Comparison of the fracture toughness values of the steel estimated under monotonic and cyclic loading indicates that the latter could be as low as one-fifth of the former. The observed degradation in cyclic fracture resistance has been attributed to crack tip re-sharpening during cyclic loading.     

Cyclic fracture behaviour of 304LN stainless steel under load and displacement control modes

Attempts have been made to understand cyclic fracture behaviour of AISI 304LN stainless steel used for nuclear piping materials under load vis‐à‐vis displacement controlled fracture tests; the former closely simulate the seismic loading conditions. The load controlled tests indicate that a material fails in a limited number of cycles even when the load amplitudes are sufficiently below the maximum load in a monotonic J–R test. The displacement controlled tests, on the other hand, show that the energy absorbing ability of a material gets severely reduced under cyclic loading conditions. The obtained results on standard laboratory specimens have been compared with similar available results on components in order to provide guidelines for maximum load bearing capability of engineering components under cyclic loading.     

Experimental investigation on corrosion and hardness of ion implanted AISI 316L stainless steel

The AISI 316L stainless steel has been widely used both in artificial knee and hip joints in bio-medical applications. In the present study AISI 316L SS was implanted with two different ions: nitrogen and helium at 100 keV with a dose of 1 × 10¹⁷ ions/cm² at room temperature. The crystallographic orientation and surface morphology were studied using X-ray diffraction (XRD) and scanning electron microscope (SEM). The effects of ion implantation on the corrosion performance of AISI 316L stainless steel was evaluated in 0.9% NaCl solution using electro chemical test both on the virgin and implanted samples. The subsequent Tafel analysis shows that the ion implanted specimens were more corrosion resistant when compared to the bare specimens. Microhardness was also measured by Vickers method by varying the loads. The results of the studies indicated that there was a significant improvement in both corrosion resistance and hardness of implanted samples.     

Characterization of transition joints of commercially pure titanium to 304 stainless steel

Solid-state direct bonding between commercially pure titanium and type 304 austenitic stainless steel has been carried out in the temperature range of 850–950 °C, under a uniaxial pressure of 3 MPa for 1 h. The diffusion bonds have been evaluated using light microscopy, electron probe microanalysis (EPMA), X-ray diffraction (XRD) technique and tensile testing. Light microscopy shows that different intermediate layers are formed in the reaction zone, and the width of these layers increases with an increase in bonding temperature. EPMA revealed that, at any particular bonding temperature, Ti traverses a minimum distance in the 304 stainless steel side, whereas Fe, Cr and Ni travel comparatively larger distances in the Ti side. This microanalysis also indicated different step formations in the concentration profile of Ti, Fe and Cr over different composition ranges in the diffusion zone indicating formation of intermetallic phases that were detected by XRD. Brittle intermetallic phases lower the strength and ductility of the diffusion bonded couples significantly. Best room temperature tensile strength, 217 MPa, has been obtained at 850 °C processing temperature due to minimal deleterious effects.     

Toward consistent fatigue crack initiation criteria for 304L austenitic stainless steel under multi-axial loads

In this paper, a new framework to correlate the experimental data of the 304L stainless steel under multi-axial fatigue loadings using a reference curve identified from the experimental data of standard uni-axial fatigue tests is proposed. A total of 15 available fatigue crack initiation criteria are tested on the experimental data of 225 fatigue tests collected from EDF (formerly known as Electricity of France), its partners and the literature. Based on the computational results, it appears that most of the crack initiation parameters of the 15 available criteria can be used to correlate the experimental fatigue data for the 304L stainless steel under uni-axial loadings. Under bi-axial loadings, most of these parameters appear not to be quite consistent. Two criteria are modified in order to better correlate the experimental fatigue data under bi-axial loads. A simple statistical approach to evaluate the consistency of the crack initiation criteria is also proposed. Based on the limited available experimental fagtigue data and within the new framework in this paper, the computational results show that the equivalent crack initiation parameters of the Varvani-Farahani’s criterion, the modified Lagoda–Macha–Sakane’s criterion and the modified Varvani-Farahani’s criterion can be used to correlate the experimental fatigue data under both uni-axial and bi-axial loadings for the 304L stainless steel. These criteria may be used to predict the fatigue life of the material under different loading and testing conditions by using the experimental data from the standard uni-axial fatigue tests.     

Experimental study of remaining creep life of SA-304L stainless steel using small punch creep test

In this paper, the remaining creep life of SA-304L stainless steel at elevated temperatures is studied. The small punch creep tests (SPCT) were performed on SA-304L virgin and aged materials at constant loads. Times to fracture and the minimum deflection rate in SPCTs were recorded, and the time-temperature parametric analysis was performed, based on experimental results. The constants of the Larson–Miller parameter and the Monkman–Grant relationship were obtained for different consumed creep life ratios, and eventually the equations were established to explain the variation of constants of the Larson–Miller parameter and the Monkman-Grant relationship with respect to the consumed creep life ratio.     

Critical hydrogen concentration for hydrogen-induced blistering on AISI 430 stainless steel

Effects of cold work on hydrogen diffusivity, hydrogen concentration and hydrogen trap density in AISI 430 stainless steel were investigated. Hydrogen concentration and trap density were increased with increasing cold work, but diffusivity was decreased. The increase in trap density as a result of cold work was responsible for the decrease in hydrogen diffusivity and the increase in hydrogen concentration. Trap densities varied from 10²¹ cm⁻³ for the cold-worked specimen to 10¹⁷ cm⁻³ for the annealed. The cold-worked steel was more sensitive to hydrogen-induced blistering due to its higher hydrogen concentration and trap density, but no blistering was found on annealed specimens.     

Microstructural investigation on strengthening mechanisms of AISI 304L austenitic stainless steel during cryogenic deformation

Abstract

In the present paper, microscopy techniques and mechanical tests were used to investigate in detail the strengthening mechanisms of an AISI 304L austenitic stainless steel during cryogenic deformation. The strain hardening rate–strain response of the alloy indicated three distinct regimes of hardening, being very similar to that previously reported for other low stacking fault energy alloys. The hardening rate initially decreased up to a strain of ～6% (stage I). Then, a second stage of increasing hardening rate began (stage II). At strains larger than ～25%, stage III with decreasing hardening rate followed. It was suggested that the formation of ?-martensite and α′-martensite together is responsible for the appearance of stage II. The high strain hardening values of the alloy in stage II were related to the increased fraction of α′-martensite and dislocation pile-ups behind the Lomer–Cottrell locks. The appearance of stage III was attributed to the difficulty of α′-martensite nucleation and ease of dislocation cross-slip at higher strains.     

Experimental analysis of magneto rheological abrasive flow finishing process on AISI stainless steel 316L

In this experimental study, the surface quality of AISI stainless steel 316L was improved to a nano-level surface finish by means of magneto rheological abrasive flow finishing process. In order to determine the effect of input process parameters toward the responses such as final surface roughness (SR) and material removal rate (MRR), response surface model was built up and optimal parameters were found using the desirability analysis. Based on the experimental design, 20 experiments were conducted and the minimum SR and maximum MRR obtained are 53.46?nm and 1.757?mg/s, respectively, and their optimized values are 53.10?nm and 1.817?mg/s. By using the regression equations obtained for SR and MRR as input, an evolutionary optimization algorithm called as firefly algorithm has been utilized where the required surface finish was constrained as ≤60?nm and the optimized results were confirmed by means of validation experiments. The obtained results depict that the voltage to the electromagnet plays a most significant role to produce minimum SR and maximum MRR. Moderate and least significant contributions are given by the hydraulic pressure and number of cycles, respectively, toward the responses.