MgO对贝利特-硫铝酸钡钙水泥煅烧和性能的影响

研究了MgO对贝利特-硫铝酸钡钙水泥煅烧与性能的影响.结果表明:MgO可以促进C3S在低温下形成;SO3的存在有利于MgO在贝利特-硫铝酸钡钙水泥熟料中的固溶;贝利特-硫铝酸钡钙水泥熟料具有较高的固溶MgO的能力,MgO含量达5.14%(质量分数)的贝利特-硫铝酸钡钙水泥的安定性良好,且3,28 d抗压强度分别达到49.1,81.9 MPa,展现了良好的力学性能;贝利特-硫铝酸钡钙水泥熟料较高的固溶MgO的能力,也有利于低品质高镁石灰石的应用.     

阿利特-硫铝酸钡钙水泥组成与性能的研究

用正交试验方法研究了不同硫铝酸钡钙(C2.75B1.25A3-S)矿物含量的阿利特(C3S)-硫铝酸钡钙水泥组成与性能.研究结果表明:阿利特和硫铝酸钡钙矿物可以在同一熟料体系中共存;硫铝酸钡钙矿物的最佳含量为8.0%(质量分数,下同);阿利特-硫铝酸钡钙水泥熟料最佳矿物组成为:8.0?.75B1.25A3-S,61.6?S,14.7?S,5.1?A,10.5?AF;在最佳矿物组成条件下制备的阿利特-硫铝酸钡钙水泥的1,3,28 d抗压强度分别为39.8,77.5,85.0 MPa,展现了良好的早期力学性能.借助于XRD和SEM-EDS分析,研究了阿利特-硫铝酸钡钙水泥熟料的组成和结构.     

贝利特-硫铝酸钡钙水泥的合成及力学性能

选择熟料率值和硫铝酸钡钙掺量为影响因素,采用正交试验法研究了贝利特-硫铝酸钡钙水泥熟料的合成条件和力学性能.研究结果表明,贝利特-硫铝酸钡钙水泥熟料的最佳组成为:硅率为2.9,铝率为1.1,石灰饱和系数为0.81(均为质量比),硫铝酸钡钙掺量为9%(质量分数),适宜的煅烧温度为1 380℃.在最佳条件下合成的贝利特-硫铝酸钡钙水泥的3,28,90 d抗压强度分别达到了23.8,80.9,97.4 MPa,展现了良好的力学性能.利用XRD,SEM-EDS和岩相分析等测试手段分析了该熟料的组成和结构.     

阿利特一硫铝酸钡钙水泥 CN1513786A

本发明属于水泥的技术领域，特别涉及一种由硫铝酸钡钙矿物与阿利特矿物复合的阿利特-硫铝酸钡钙水泥。本发明公开了一种阿利特-硫铝酸钡钙水泥，其水泥熟料主要是由CBAS—C3S—C2S—C3A—C4AF组成的矿相体系，各矿物的重量百分比为：硫铝酸钡钙：3％～38％，硅酸三钙：30％～60％，硅酸二钙：15％～40％，铝酸三钙：3％～20％，铁铝酸盐：3％～20％。本发明的有益效果是，比普通的硅酸盐水泥具有烧成温度低、早期强度高、硬化速度快、成本低的优点。     

SO3与SrO对阿利特硫铝酸锶钙水泥性能的影响

将硫铝酸锶钙矿物引入到硅酸盐熟料矿物体系中,合成了阿利特-硫铝酸锶钙水泥,改善了硅酸盐水泥的性能.利用X射线衍射、扫描电镜-能谱仪和岩相等测试手段,研究了过量掺加SO3和SrO对阿利特-硫铝酸锶钙水泥性能的影响.结果表明:熟料中SO3和SrO最佳过掺量分别为50％和80％(质量分数),制得的阿利特-硫铝酸锶钙水泥的1,3,28 d抗压强度分别达到32.8,66.8,126.4 MPa,具有良好的力学性能.SO3和SrO的过量掺入促进了硫铝酸锶钙矿物的形成,且有利于阿利特在低温下的形成.     

CaF2对硫铝酸锶钙水泥矿物形成及水化过程的影响

测试了掺CaF2硫铝酸锶钙水泥的抗压强度.通过热分析、X射线衍射分析和扫描电子显微镜观察,研究了CaF2对硫铝酸锶钙水泥熟料矿物形成和水化过程的影响.结果表明,当CaF2掺量为0.2%(质量分数)时,硫铝酸锶钙水泥抗压强度最高,3,28d抗压强度分别达到65.0,86.2MPa.在水泥煅烧过程中,CaF2能加速CaCO3的分解及C1.50Sr2.50A3珔S矿物的形成.此外,CaF2可以加快硫铝酸锶钙水泥的水化速率并促使水化产物CAH10转化为C3AH6.     

利用钼尾矿和赤泥烧制贝利特-硫铝酸钙水泥熟料

以钼尾矿、赤泥、石膏、石灰石和矾土为原料制备贝利特-硫铝酸钙水泥熟料。通过强度、XRD及SEM等测试手段,研究煅烧温度和原料配比对水泥熟料性能的影响。试验结果表明:以质量分数为8.59%的石膏、10.52%的钼尾矿、13.29%的赤泥、54.73%的石灰石和12.88%的矾土为原料,1350℃下煅烧可制得强度较高的贝利特-硫铝酸钙水泥熟料,矿物结构合理,XRD结果表明熟料主要矿物与硫铝酸钙水泥类似,含较多的贝利特矿物。     

高碳粉煤灰烧制高铁贝利特硫铝酸盐水泥的研究

用高碳粉煤灰及石灰石、石膏等为原料,在1250℃条件下烧成了高铁贝利特硫铝酸盐水泥,其主要矿物组成C2S为51％-55％,C4A3S为20％-30％,C4AF为12％-25％;水泥1d强度达35MPa,28d强度达66MPa。试验结果发现：熟料早期强度随C4A3S和C4AF含量的增加而增大,而C2S则更有利于后期强度的发挥;水泥强度随石膏掺量的增大而增加,但掺量不宜过多,否则反而会造成强度下降。     

硫铝酸钡钙矿物烧成若干问题的研究

本文研究了新矿物硫铝酸钡钙(3CaO·3Al_2O_3·BaSO_4)形成规律、热稳定性、杂质离子固溶情况,以及烧成温度对硫铝酸钡钙水泥强度的影响.结果表明,硫铝酸钡钙在900℃开始形成,1100℃形成速度加快,>1300℃开始缓慢分解为BaQ·Al_2O_3、C_(?2)A_2、SO_2等,但在1500℃仍可存在.硫铝酸钡钙水泥适宜的烧成温度为1300-1400℃.CaO可取代其中的BaO;Fe_2O_3可取代其中的Al_2O_3,取代极限为0.6mol Al_2O_3.     

减水剂对阿利特-硫铝酸钡钙水泥强度的影响

该文研究了不同的减水剂对阿利特-硫铝酸钡钙水泥强度的影响,研究结果表明:萘系减水剂和聚羧酸减水剂都对提高阿利特-硫铝酸钡钙水泥抗压强度有重要作用.减水剂的掺量不同,对阿利特-硫铝酸钡钙水泥性能的影响也不同,该文找出了适合于该水泥的减水剂并确定了其最佳掺量,改善了阿利特-硫铝酸钡钙水泥的性能.     

采用低品位石灰石烧制水泥熟料的研究

以低品位的石灰石为原料,通过合理的配料方案,成功制备了性能优异的水泥熟料。通过岩相观察和XRD分析结果表明,实验所用生料易烧性较好,并随温度提高而明显改善,所制备的水泥熟料的主晶相是C3S和C2S。     

石灰石对矿渣水泥水化反应的作用及特性

为节约水泥熟料,对在矿渣水泥(简称P·S)中掺用石灰石的方法进行了试验.结果表明,P·S 中C3S的早期水化反应率随石灰石粉的取代率和粉末度的增加而增加,龄期28 d的水化反应率则与P·S基本持平;C3A的水化反应率在龄期1 d内明显下降,但此后的水化反应率与P·S 中C3A的水化反应率大致相同;石灰石主要在龄期7 d内参与水化反应,且与C3A的水化反应密切相关.     

煤矸石掺力口低品位石灰石煅烧高活性混合材的研究

将未燃煤矸石掺加低品位石灰石后,在1100℃和1200℃下进行了煅烧试验。煅烧后的改性煤矸石有C2S、C3A等胶凝矿物形成,胶凝活性提高。用作水泥混合材时,活性指数可达89％。将掺加20％石灰石的煤矸石在1200℃下煅烧,应用水泥熟料煅烧热效应计算,该种改性煤矸石的理论热耗为310kJ／kg,仅为水泥熟料理论热耗的16％。     

石灰石粉对水泥混凝土性能影响的研究进展

从石灰石粉对C3S、C3A和水泥混凝土水化影响方面入手,阐述了水泥-石灰石粉胶凝体系的水化特性,并在此基础上,进一步从石灰石粉对水泥基材料流变性、强度、尺寸稳定性、耐久性的影响等方面,综述了水泥-石灰石粉胶凝材料的国内外研究现状.针对现有水泥-石灰石粉基材料研究存在的问题,探讨了全面、系统研究水泥-石灰石粉胶凝体系的重要性.     

水泥、消石灰对沥青性能影响研究

通过当量替换矿粉,对不同水泥和消石灰掺量的沥青胶浆的高低温性能进行了试验研究。研究表明,水泥等量替换后,胶浆的高低温性能均有改善,而消石灰当量替换,胶浆的高温性能有明显改善,但低温性能却也有明显的劣化。综合分析胶浆的高低温性能和可施工性能,水泥的掺量不宜超过40%,而消石灰的掺量不宜超过60%。     

Combined effect of mineral admixtures with superplasticizers on the fluidity of the blended cement paste

The new concrete often incorporates several organic and mineral admixtures which interact with the various constituents of the cements and cause some problems of hardness and workability. In the present study, limestone cement (C1) and pozzolanic cement (C2) were used to make cement paste with two types of superplasticizer; SP1 based on polynaphthalene sulphonate (PNS); and SP2 based on resins melamines (PRM). Marsh cone test was adopted to check the combined effects of the following factors on the fluidity namely the type of cement, the type and the dosage of the superplasticizer, the type and the replacement rate of the mineral admixture and the water–cement ratio (W/C). The results of this work show that limestone cement presents a high fluidity with low loss after 1 h relatively to the pozzolanic cement within the saturation proportioning. Superplasticizer SP1 constitutes an incompatibility case when it is mixed with cement containing high C₃A or alkali content such as C2 cement. Also, limestone powder is found to be the best mineral admixture when it replaces a part of cement, where more fluidity is exhibited caused by the dilution effect.     

水泥基材料在腐蚀环境中生成碳硫硅钙石的机理研究

为探索石灰石粉混凝土在低温硫酸盐环境下生成碳硫硅钙石的机理,将石灰石粉混凝土及采用硫铝酸盐水泥制备的水泥基胶凝材料分别浸泡于质量分数为10%的硫酸镁溶液和碳酸钠溶液中,进行抗压强度测试,并通过扫描电镜(SEM)、X射线衍射(XRD)及红外光谱等微观试验手段,研究并分析了碳硫硅钙石的形成原因.结果表明:低温硫酸镁溶液中的石灰石粉混凝土抗压强度随浸泡时间的延长呈现先增长后减小的趋势,表面出现膨胀剥落现象,生成大量的二水石膏,发生膨胀腐蚀;碳酸钠溶液中的硫铝酸盐水泥基胶凝材料发生了泥化现象,其抗压强度随浸泡时间延长逐渐降低,内部水化产物钙矾石随浸泡时间延长逐渐减少,发生异相结晶转换生成碳硫硅钙石.混凝土中掺加石灰石粉并不是造成碳硫硅钙石型硫酸盐腐蚀(TSA)的主要因素,水泥基胶凝材料硬化体中的钙矾石长期处于含CO2-3环境中才会生成大量烂泥状的碳硫硅钙石,造成胶凝材料破坏.     

Effects of limestone replacement ratio on the sulfate resistance of Portland limestone cement mortars exposed to extraordinary high sulfate concentrations

A comparative study has been performed on the sulfate resistance of Portland limestone cement (PLC) mortars exposed to extraordinary high sulfate concentrations (200 g/l). PLCs have been prepared by using two types of clinkers having different C₃S/C₂S ratios and interstitial phase morphologies. Blended cements have been prepared by replacing 5%, 10%, 20% and 40% of clinker with limestone. Cubic (50 × 50 × 50 mm) and prismatic (25 × 25 × 285 mm) cement mortars were prepared. After two months initial water curing, these samples were exposed to three different sulfate solutions (Na₂SO₄ at 20 °C and 5 °C, MgSO₄ at 5 °C). Solutions were not refreshed and pH values of solutions were monitored during the testing stage. The compressive strength and length changes of samples have been monitored for a period of 1 year. Additional microstructural analyses have been conducted by XRD and SEM/EDS studies. Results indicated that in general, limestone replacement ratio and low temperature negatively affect the sulfate resistance of cement mortars. Additionally, clinkers of high C₃S/C₂S ratios with dendritic interstitial phase structure were found to be more prone to sulfate attack in the presence of high amounts of limestone.From the results, it is postulated that in the absence of solution change, extraordinary high sulfate content modified the mechanism of sulfate reactions and formation of related products. At high limestone replacement ratios, XRD and SEM/EDS studies revealed that while ettringite is the main deterioration product for the samples exposed to Na₂SO₄, gypsum and thaumasite formation were dominant products of deterioration in the case of MgSO₄ attack. It can be concluded that, the difference between reaction mechanisms of Na₂SO₄ and MgSO₄ attack to limestone cement mortars strongly depends on the pH change of sulfate solutions.     

Variation of fracture toughness of asphalt concrete under low temperatures

This study presents the results of experimental evaluation on fracture toughness of asphalt concrete at various low temperatures (from −5°C to −30°C in 5°C steps). An asphalt cement, penetration grade of 85/100 and two aggregates, a granite and a limestone, were used to prepare asphalt concrete beam specimens which were conditioned using two different procedures and tested under three-point bending setup. The first procedure dealt with evaluation of fracture toughness of the asphalt concrete at a control temperature, −5°C, following conditioning at the specified temperatures. The second procedure dealt with evaluation of fracture toughness at the temperatures at which the samples were conditioned. The results showed that fracture toughness (K_IC) for both aggregate mixtures in both procedures changed in a manner that it increased by lowering temperature from −5°C to −15°C, and then decreased thereunder. An improved mechanical adhesion due to the strengthened grip of asphalt matrix resulted from differential thermal contraction (DTC) is responsible for increased resistance to the applied loads. The reduction of fracture toughness below −15°C is explained as the effect of internal damage due to DTC that is a consequence of the large difference in coefficients of thermal contraction between aggregate and asphalt cement. Granite aggregate mixture showed a slightly better resistance to fracture throughout the temperatures. Relatively good linear relations between average values of σ_f and K_IC were found from the regression analysis. Increasing flexural strength resulted in an increased fracture toughness for all mixtures. K_IC of granite mix showed more critical to the change of σ_f.     

矿物组成对低热硅酸盐水泥抗海水侵蚀性能的影响

为研究不同矿物组成对低热硅酸盐水泥抗海水侵蚀能力的影响,阐明低热硅酸盐水泥抗海水侵蚀的机理,利用分析纯化学试剂和水泥原材料分别制备硅酸二钙单矿和水泥熟料,并将具有不同矿物组成的低热硅酸盐水泥净浆试件在人工模拟海水中浸泡28d。通过强度发展规律、物相分析和综合热分析,发现硅酸二钙和铁铝酸四钙可以稳定低热硅酸盐水泥在海水中的强度发展,并阐明了海水中复杂盐离子与水泥水化产物反应的机理,建议适当提高铝酸三钙含量以增强低热硅酸盐水泥的抗海水侵蚀能力。