共查询到17条相似文献,搜索用时 46 毫秒
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用N-苯基马来酰亚胺(N-PMI)作耐热改性剂,通过悬浮聚合法合成了接枝型MCS树脂,并对其热性能进行了研究。结果表明,N-PMI成功接枝在基体树脂上,接枝改性后的MCS树脂的热性能得到了明显的改善,玻璃化温度和热分解温度明显提高。 相似文献
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采用种子乳液聚合方法制备了聚丁二烯接枝丙烯腈苯乙烯共聚物(PB g SAN),将PB g SAN共聚物与SAN树脂熔融共混获得丙烯腈丁二烯苯乙烯三元共聚物(ABS),研究了PB g SAN共聚物的接枝层厚度对ABS性能的影响。结果表明,接枝层厚度超过临界值117 nm,接枝层过厚会导致核壳改性剂粒子变硬,模量过高,从而失去了作为增韧改性剂的作用。接枝层厚度低于临界值32 nm,橡胶粒子不能被SAN接枝链完全覆盖,在SAN基体中发生聚集,导致其增韧效果降低。因此,只有改性剂的接枝层厚度介于32 nm和117 nm这两个临界值之间,才能对基体树脂起到有效的增韧作用。 相似文献
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用淀粉与甲基丙烯酸甲酯及苯乙烯单体接枝共聚合成一种新的高分子絮凝剂。共聚物红外光谱表明单体成功接枝到淀粉主链。实验研究了引发剂浓度,淀粉浓度对产物接枝效果的影响。当过氧化氢浓度为0.06 mol/L,淀粉浓度为5%(w/v),产品有较高的接枝率和接枝效率。高岭土悬浊液中的絮凝试验,验证了产品具有优良絮凝性能,并分析相关因素对其絮凝性的影响。 相似文献
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采用溶液聚合方法,以过氧化苯甲酰(BPO)为引发剂,将苯乙烯、甲基丙烯酸甲酯、甲基丙烯酸接枝到环氧树脂高分子链上后,中和、乳化制得水性环氧-苯丙接枝共聚物。并对水性环氧-苯丙接枝共聚物的亲水性、水分散稳定性和分子结构进行表征,确定了合成环氧-苯丙接枝共聚物的最佳条件:反应温度为115℃,反应时间为6 h,BPO用量为环氧树脂及接枝单体总质量的1.6%,亲水单体甲基丙烯酸用量占环氧树脂及接枝单体总质量的10%,三异丙醇胺用量占成功接技的甲基丙烯酸物质的量的95%。 相似文献
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《国际聚合物材料杂志》2012,61(4):447-459
Abstract MCS resin, formed from methyl methacrylate (MMA), styrene (St), chlorinated polyethylene (CPE), was synthesized by suspension swelling graft-copolymerization. In this paper, the synthesis conditions of MCS, the effect of different synthesis conditions on graft efficiency, the mechanical properties, rheological behavior and morphology were investigated. The graft efficiency increased with increasing CPE content. The apparent viscosity of melt increased with increasing the content of CPE. The copolymer composition was analyzed by FTS-40 Fourier transform infrared spectrometer and PE-2400 element analyzer. The fractured surface morphology of MCS resin was observed by SEM and X-ray energy dispersive spectroscopy. 相似文献
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Studies on the graft polymerizations of styrene and methyl methacrylate to hydroxyl terminated polybutadiene 总被引:1,自引:0,他引:1
Hydroxyl terminated Polybutadiene (HTPB) was grafted with styrene (St) or methyl methacrylate (MMA) by free radical solution polymerization. The graft copolymerizations were conducted in benzene at 70 °C. The initiators used were benzoyl peroxide (BPO) and azobis-isobutyronitrile (AIBN). The microstructures of theobtained graft copolymers were characterized by13C NMR measurement and the DEPT technique, as well as by IR spectrometer. The mechanism of grafting reactions was determined from the microstructures of derived graft copolymers. It showed that graft copolymer resulted when BPO was used as initiator of the vinyl monomer polymerization, but not with AIBN. It appeared that the reaction leading to graft formation was direct attack of oligomeric styrene radicals or double bonds of the HTPB. Whereas the graft copolymerization of MMA to HTPB was the same as that suggested in the literature i.e., by a hydrogen abstract reaction. 相似文献
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Siti Hajjar Che Man Azanam S. Hashim Hazizan Md. Akil 《Journal of Polymer Research》2008,15(5):357-364
The graft copolymerization of styrene/methyl methacrylate (MMA) onto deproteinized natural rubber (DPNR) latex was carried
out using ammonium peroxy disulfate (N2H8O8S2) as the initiator. The presence of the grafted polystyrene (PS) and polymethyl methacrylate (PMMA) on the rubber backbone
was confirmed by FTIR spectroscopy. The effects of monomer concentrations on curing characteristics and mechanical properties
were studied. It was found that the cure time and scorch time were increased with increasing monomer concentration whereas
the torquemax–min value was slightly decreased. It was also noted that the increase in the monomer concentration resulted in stiffer rubber
with increased modulus and reduced elongation at break. 相似文献