National Institute of Standards and Technology high-accuracy cryogenic radiometer

A high-accuracy cryogenic radiometer has been developed at the National Institute of Standards and Technology to serve as a primary standard for optical power measurements. This instrument is an electrical-substitution radiometer that can be operated at cryogenic temperatures to achieve a relative standard uncertainty of 0.021% at an optical power level of 0.8 mW. The construction and operation of the high-accuracy cryogenic radiometer and the uncertainties in optical power measurements are detailed.     

Realization of a scale of absolute spectral response using the National Institute of Standards and Technology high-accuracy cryogenic radiometer

Using the National Institute of Standards and Technology high-accuracy cryogenic radiometer (HACR), we have realized a scale of absolute spectral response between 406 and 920 nm. The HACR, an electrical-substitution radiometer operating at cryogenic temperatures, achieves a combined relative standard uncertainty of 0.021%. Silicon photodiode light-trapping detectors were calibrated against the HACR with a typical relative standard uncertainty of 0.03% at nine laser wavelengths between 406 and 920 nm. Modeling of the quantum efficiency of these detectors yields their responsivity throughout this range with comparable accuracy.     

New Program and Directions at the National Institute of Standards and Technology

The Trade Act of 1988 created the National Institute of Standards and Technology (NIST) from the National Bureau of Standards (NBS). In addition to explicitly defining and reconfirming the traditional measurement services, the law assigned new responsibilities to NIST to assist U.S. industry in capitalizing on new technologies developed in the U.S. scientific and technical community at a faster rate. This article decribes the new programs being established at NIST to comply with this mandate and the new organizational unit at NIST that brings together the traditional services and these new programs.     

Small Angle Neutron Scattering at the National Institute of Standards and Technology

The small angle neutron scattering technique is a valuable method for the characterization of morphology of various materials. It can probe inhomogeneities in the sample (whether occurring naturally or introduced through isotopic substitution) at a length scale from the atomic size (nanometers) to the macroscopic (micrometers) size. This work provides an overview of the small angle neutron scattering facilities at the National Institute of Standards and Technology and a review of the technique as it has been applied to polymer systems, biological macromolecules, ceramic, and metallic materials. Specific examples have been included.     

Developments for a New Spectral Irradiance Scale at the National Institute of Standards and Technology

Recent developments for a new spectral irradiance scale realization at the National Institute of Standards and Technology have been targeted to reduce the present relative expanded uncertainties of 0.67 % to 4.34 % (coverage factor of k = 2 and thus a 2 standard deviation estimate) in the spectral irradiance scale to 0.17 % for the range from 350 nm to 1100 nm. To accomplish this goal, a suite of filter radiometers calibrated using NIST’s high accuracy cryogenic radiometer have been used to measure the temperature of a high-temperature black-body. A comparison of the filter radiometer calibrations with the spectral irradiance scale along with an evaluation of the black-body calibration technique have been performed. With the aid of a monochromator, the calibrated filter radiometers will then be utilized to calibrate primary and secondary spectral irradiance standard lamps at NIST.     

Numeric Databases in Chemical Thermodynamics at the National Institute of Standards and Technology

During the past year the activities of the Chemical Thermodynamics Data Center and the JANAF Thermochemical Tables project have been combined to obtain an extensive collection of thermodynamic information for many chemical species, including the elements. Currently available are extensive bibliographic collections and data files of heat capacity, enthalpy, vapor pressure, phase transitions, etc. Future plans related to materials science are to improve the metallic oxide temperature dependent tabulations, upgrade the recommended values periodically, and maintain the bibliographic citations and the thermochemical data current. The recommended thermochemical information is maintained on-line, and tied to the calculational routines within the data center. Recent thermodynamic evaluations on the elements and oxides will be discussed, as well as studies in related activities at NIST.     

Interferometric analysis of reorientational nonlinear phenomena at 10.6 microm in a nematic liquid crystal

We describe an infrared interferometric technique based on a two-dimensional spatial fringe analysis Fourier method for investigating the characteristic ring diffraction pattern generated by the self-phase-modulation effect induced in nematic liquid crystals (NLCs) by an infrared laser beam and for measuring the nonlinear refractive index of the NLCs. The experimental setup employs a Mach-Zehnder interferometer with a cw CO2 laser emitting at 10.6 microm and a pyroelectric optoelectronic sensor matrix to detect the modulated ring-pattern intensity distribution formed in the far field by a nematic E7 sample. A Fourier-transform-based analysis of the interference fringe pattern allows comparison of the measurements with the theoretical ring-pattern intensity distribution. We show that accurate determination of the nonlinear refractive index can be obtained by analyzing the two-dimensional phase distribution of the modulated ring pattern.     

Bolometric Microwave Power Calibration Techniques at the National Bureau of Standards

A bolometric method of calibrating low-level microwave power measuring devices is currently employed at the National Bureau of Standards in Boulder, Colo. The technique is one of direct comparison between the standard and the unknown, and utilizes NBS working standard bolometer units and self-balancing dc bridges. In general, the unknown is calibrated to an accuracy of one per cent. The following quantities are defined and the associated errors are discussed: 1) Calibration factor of a bolometer unit in combination with a directional coupler, 2) Calibration factor of a bolometer unit, and 3) Effective efficiency of a bolometer unit.     

Realization of the National Institute of Standards and Technology detector-based spectral irradiance scale

A detector-based spectral irradiance scale has been realized at the National Institute of Standards and Technology (NIST). Unlike the previous NIST spectral irradiance scales, the new scale is generated with filter radiometers calibrated for absolute spectral power responsivity traceable to the NIST high-accuracy cryogenic radiometer instead of with the gold freezing-point blackbody. The calibrated filter radiometers are then used to establish the radiance temperature of a high-temperature blackbody (HTBB) operating near 3,000 K The spectral irradiance of the HTBB is then determined with knowledge of the geometric factors and is used to assign the spectral irradiances of a group of 1,000-W free-electron laser lamps. The detector-based spectral irradiance scale results in the reduction of the uncertainties from the previous source-based spectral irradiance scale by at least a factor of 2 in the ultraviolet and visible wavelength regions. The new detector-based spectral irradiance scale also leads to a reduction in the uncertainties in the shortwave infrared wavelength region by at least a factor of 2-10, depending on the wavelength. Following the establishment of the spectral irradiance scale in the early 1960s, the detector-based spectral irradiance scale represents a fundamental change in the way that the NIST spectral irradiance scale is realized.     

National Institute of Standards and Technology Synchrotron Radiation Facilities for Materials Science

Synchrotron Radiation Facilities, supported by the Materials Science and Engineering Laboratory of the National Institute of Standards and Technology, include beam stations at the National Synchrotron Light Source at Brookhaven National Laboratory and at the Advanced Photon Source at Argonne National Laboratory. The emphasis is on materials characterization at the microstructural and at the atomic and molecular levels, where NIST scientists, and researchers from industry, universities and government laboratories perform state-of-the-art x-ray measurements on a broad range of materials.     

Infrared responsivity of a pyroelectric detector with a single-wall carbon nanotube coating

The performance of a 10 mm diameter pyroelectric detector coated with a single-wall carbon nanotube (SWCNT) was evaluated in the 0.8 to 20 microm wavelength range. The relative spectral responsivity of this detector exhibits significant fluctuations over the wavelength range examined. This is consistent with independent absorbance measurements, which show that SWCNTs exhibit selective absorption bands in the visible and near-infrared. The performance of the detector in terms of noise equivalent power and detectivity in wavelength regions of high coating absorptivity was comparable with gold-black-coated pyroelectric detectors based on 50 microm thick LiTaO(3) crystals. The response of this detector was shown to be nonlinear for DC equivalent photocurrents >10(-9) A, and its spatial uniformity of response was comparable with other pyroelectric detectors utilizing gold-black coatings. The nonuniform spectral responsivity exhibited by the SWCNT-coated detector is expected to severely restrict the use of SWCNTs as black coatings for thermal detectors. However, the deposition of SWCNT coatings on a pyroelectric crystal followed by the study of the prominence of the spectral features in the relative spectral responsivity of the resultant pyroelectric detectors is shown to provide an effective method for quantifying the impurity content in SWCNT samples.     

Long-term temporal stability of the National Institute of Standards and Technology spectral irradiance scale determined with absolute filter radiometers

The temporal stability of the National Institute of Standards and Technology (NIST) spectral irradiance scale as measured with broadband filter radiometers calibrated for absolute spectral irradiance responsivity is described. The working standard free-electron laser (FEL) lamps and the check standard FEL lamps have been monitored with radiometers in the ultraviolet and the visible wavelength regions. The measurements made with these two radiometers reveal that the NIST spectral irradiance scale as compared with an absolute thermodynamic scale has not changed by more than 1.5% in the visible from 1993 to 1999. Similar measurements in the ultraviolet reveal that the corresponding change is less than 1.5% from 1995 to 1999. Furthermore, a check of the spectral irradiance scale by six different filter radiometers calibrated for absolute spectral irradiance responsivity based on the high-accuracy cryogenic radiometer shows that the agreement between the present scale and the detector-based scale is better than 1.3% throughout the visible to the near-infrared wavelength region. These results validate the assigned spectral irradiance of the widely disseminated NIST or NIST-traceable standard sources.     

Nonlinear and bistable reflection minima at lambda = 10.6 microm in an attenuated total reflection configuration with a highly doped n-GaAs film

n-GaAs can be so highly doped that its plasma frequency is larger than the associated frequency of a CO2 laser emission line, leading to a negative real part of the dielectric permittivity. We studied linear and nonlinear reflection properties of structures composed of such thin highly doped n-GaAs film in an attenuated total reflection (ATR) configuration. We show that deep reflection minima coincide with the excitation of Brewster-type modes of the multilayer structure. These minima feature strong nonlinear and bistable behavior and are sensitive to geometrical and material parameters. The proposed ATR configuration can be used to determine doping concentrations with an accuracy of better than 1 partper thousand and different deformation potentials of the higher-conduction bands in n-GaAs.     

Evaluation of a pyroelectric detector with a carbon multiwalled nanotube black coating in the infrared

The performance of a pyroelectric detector with a carbon multiwalled nanotube coating was evaluated in the 0.9-14 microm wavelength range. The relative spectral responsivity of this detector was shown to be flat over most of the wavelength range examined, and the spectral flatness was shown to be comparable to the best infrared black coatings currently available. This finding is promising because black coatings with spectrally flat absorbance profiles are usually associated with the highest absorbance values. The performance of the detector (in terms of noise equivalent power and specific detectivity) was limited by the very thick (250 microm thick) LiNbO3 pyroelectric crystal onto which the coating was deposited. The responsivity of this detector was shown to be linear in the 0.06-2.8 mW radiant power range, and its spatial uniformity was comparable to that of other pyroelectric detectors that use different types of black coating. The carbon nanotube coatings were reported to be much more durable than other infrared black coatings, such as metal blacks, that are commonly used to coat thermal detectors in the infrared. This, in combination with their excellent spectral flatness, suggests that carbon nanotube coatings appear extremely promising for thermal detection applications in the infrared.     

An Absolute Calibration of the National Bureau of Standards Thermal Neutron Flux

The NBS Thermal Neutron Flux has been calibrated in terms of the gold thermal neutron capture cross section. The effective thermal neutron (below cadmium cutoff energy) flux density is estimated to be 4307 ± 2 percent n/cm² sec in September 1961. This figure is in agreement with a recent value quoted by the NBS.     

Time-resolved reflectance and transmittance measurements of laser-induced free carriers in germanium, silicon, and zinc selenide at 10.6 microm

We present experimental results of reflectance and transmittance measurements of infrared radiation by high-density photogenerated free carriers in polycrystalline germanium, polycrystalline silicon, and chemical vapor deposition zinc selenide windows. Linearly polarized 1064 and 532 nm wavelength light from a Nd:YAG laser with a 130 ps pulse width were used to generate free carriers in the samples. Reflectance and transmittance were measured at a 10.6 microm wavelength using a linearly polarized CO2 laser.     

Improvements in Atomic Cesium Beam Frequency Standards at the National Bureau of Standards

The National Bureau of Standards Frequency Standard, NBS-III, a cesium beam with a 3.66-meter interaction region, has been in operation since 1963. The last published (1966) accuracy capability for NBS-III was 1.1 ? 10-12(l?). Recently, several new solid-state broad-band frequency-multiplier chains have been constructed. Reduction of the random phase noise by more than 20 dB compared to the previous state of the art has been obtained consistently. In addition, a solid-state servo system has been installed to control the frequency of the 5-MHz slave oscillator. Comparisons were made between NBS-III and one of the commercial cesium standards in the NBS clock ensemble. The relative fractional frequency stability ?(N = 2, T = 7 days, ? = 1 day) = 1 ? 10-13 was observed for nine weekly comparisons. The very-long-term frequency stability for this recently improved NBS-III system has not been evaluated fully. Due to the improvements both in electronic systems and evaluative techniques, however, an accuracy of 5 ? 10-13(1?) for a single evaluative experiment is reported. Substantial effort is being expended toward improvement of the accuracy and figure of merit (presently 10) of the NBS cesium standard. The modified system, to be called NBS-5, is expected to be in operation in the latter half of 1970 and to exhibit a figure of merit in excess of 500.