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在聚乙烯醇(PVAVA)存在下,铱与钼酸盐和罗丹明B(RB)形成离了缔合物。缔台物的最大吸收位于570nm摩尔吸光系数ε8.36×10 ̄5’L·mol ̄-1·cm ̄-1,服从比尔定率范围为0~2.75μglr/25ml。测定2.0μg铱的相对标准偏差为2.5%(n=7),检出限43n/ml(n=12)。测定铱的适宜条件为CHClO_4=0.93mol/L,C_MoO ̄2-_49.0×10~-4mol/L,C_RB=3.3×l0 ̄-5mol/L,PVAO08%。试验了30多种共存离子的影响,除形成杂多酸元素 相似文献
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利用碲钨杂多酸-罗丹明B(RB)-聚乙烯醇体系建立了分光光度测定痕量碲的新方法,确定了测定碲的适宜条件为〔H2SO4〕=1.20mol/L,〔WO2-4〕=1.2×10-4mol/L,〔RB〕=5.0×10-5mol/L和PVA0.08%。在PVA存在下碲钨杂多酸与罗丹明B形成1∶9的离子缔合物,其最大吸收位于565nm,表观摩尔吸光系数ε=1.76×107,离子缔合物至少稳定240h。测定碲的线性范围为0~0.16μg/25ml,对012μg/25ml碲测定的相对标准偏差1.3%(n=10)。考察了40多种共存离子的影响,大多数常见元素不干扰,允许500倍量Se(Ⅳ);40倍量Cu2+,Bi3+存在。本法灵敏度高,重现性和选择好,用于烟尘中碲的测定,结果与电分析法吻合。 相似文献
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本文提出了一种新的光度测定论的方法。该方法基于在聚乙烯醇(PVA)存在下,钯与钼酸盐和丁基罗丹明B(BRB)反应形成离子缔合物。缔合物的最大吸收位于580nm,摩尔吸光系数ε为3.14×10 ̄5L·mol ̄(-1)·cm ̄(-1),钯量在0~4ug/25ml范围内服从比尔定律。缔合物中pd:BRB=1:4,体系至少可稳定10h,测定钯的适宜条件是:C_(HCO4)=1.6mol/L,C_(BRB)=3.8×10 ̄(-5)mol/L,PVA0.08%。考察了30多种共存离子的影响。本法用于碳基和铝基催化剂中 相似文献
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本文提出了以新合成的试剂N-烯丙基-N'-(氨基对苯磺酸钠)硫脲(ASATu)为显色剂,光度法测定微量铜的新方法。在pH4.0的弱酸性溶液中,铜(Ⅱ)与ASATu形成配合物的最大吸收波长为3乙4nm,表观摩尔吸光系数ε_(334)=3.42×10 ̄4。铜量在10~70μg/25ml范围内呈线性关系,相关系数r=0.9999。铜(Ⅱ)和ASATu配合物的组成比为1∶3。常见离子除Fe ̄(3+)、Ag ̄+、S ̄(2-)外,均无干扰。该法简单、灵敏度高,选择性好。对合成样品、食品及生物试样的分析和回收实验,均获 相似文献
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合成了新试剂N-辛基-N’-(氨基对苯磺酸钠)硫脲(OPT),经过红外、紫外和元素分析等测试,确定了其组成和结构.并研究测定了试剂与40多种常见离子的反应及其络合物的表观摩尔吸光系数.表明它可作为Cu~2+ (m=0.015μg, c=0.50μg/mL), Au~3+(m=0.30μg, c=10μg/mL)的新鉴定试剂和光度法测定 Cu~2+(ε_301.4=1.82 X 10~5和 An~3+(ε_302.0=1.33 X 10~5的新显色剂.方法的灵敏度高,选择性好,操作简便.将该法应用于矿石样品 相似文献
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<正>Minmetals Resources acquired the world’s largest copper mine under construction for USD5.85 billion.One after another,listed companies Jien Nickle,China Molybdenum and Chihong Zinc and Germanium raised money to get involved in overseas mining projects…SOEs and private enterprises are engaged in a frenzy of overseas mine purchasing.A reporter with Economic 相似文献
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正Judging from China’s copper consumption field,the biggest consumption unit is electric power,which accounts for 47%of total consumption;it is followed by light industry sector,including household electrical appliance,machinery,durable goods and hardware etc,which accounts for 22%of total consumption;followed by transportation field, 相似文献
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《China Nonferrous Metals Monthly》2014,(10)
正In 2013,the Central Geological Prospecting Fund(CGPF)Project newly discovered 15 ore fields,including 3 large above ore fields,and 5medium sized ore fields.The reporter learned from the recently published"Annual Report of Central Geological Prospecting Fund Project(2013)"that,from 2006 to 2013 the CGPF 相似文献
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《China Nonferrous Metals Monthly》2014,(10)
正This year,the investment growth rate of real estate industry continued to slow down,sold area of commercial housing also dropped significantly,which brought huge pressure to the domestic air conditioning manufactures.In the first half of the year,by relying on high growth in national financial expenditure,along with investment in public infrastructure 相似文献
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《China Nonferrous Metals Monthly》2014,(10)
正Kang Yi,Honorary Chairman of China Nonferrous Metals Industry Association,said recently at the Forum on Development of the Non-ferrous Metals Industry in Central and Western China held in Zhengzhou that,as more and more electrolytic aluminum factories in Xinjiang came into operation,the electrolytic aluminum output of Xinjiang had reached2,275,000 tons in the first 7 months this year, 相似文献
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《China Nonferrous Metals Monthly》2014,(12)
正"Xinjiang project has been completed according to schedule,but total completion and total start of production are two different concepts,after completion it still needs a gradual process of reaching production target."On the morning of November 3,Shenhuo Coal Industry and Electricity Power told investors the above statement on the investor interaction platform. 相似文献
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正The reporter learned from Guangdong Province Precious Metal Transaction Center that in 2013the Center maintained healthy development momentum,and had become the second largest precious metal transaction platform in China in terms of market size;currently Guangdong is quickening steps of financial innovation for the Center,aiming to build a transaction center with international core competitiveness. 相似文献
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正On May 22,Baotou Rare Earth Industry Cooperation Consultation MeetingProject Agreement-signing Ceremony was held in Ningbo,nearly 40 enterprises from Ningbo,Guangdong,Hunan,and Shanxi participated in project consultation.After multi-lateral communication,agreements were signed for a total of 7 rare earth projects successfully. 相似文献