共查询到19条相似文献,搜索用时 109 毫秒
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煤直接液化技术是缓解石油供需矛盾、实现煤炭清洁高效利用的重要技术途径之一,油煤浆的黏温特性对其配制、输送、加压、预热及反应性能具有重要影响。本文从油煤浆黏温特性的变化规律、研究方法、变化机理、影响因素等方面的研究进展进行了综述。在升温过程中,油煤浆流变特性表现为非牛顿流体,具有剪切稀化特性;高温高压下黏度测定方法主要有4种;分析黏温特性变化机理:煤浆制备和升温阶段黏度变化主要由溶胀作用导致,高温阶段主要由煤裂解产生沥青质(尤其是前沥青烯)导致;从溶剂、煤的性质(煤阶、显微组分及粒径分布)、剪切速率、油煤浆浓度、催化剂和氢分压等方面分析了油煤浆黏温特性的影响因素。最后指出了未来油煤浆黏温特性的研究方向,为我国煤直接液化技术的进一步发展提供参考。 相似文献
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新疆低阶煤和重质油资源丰富,具有广阔的煤油共液化工业前景,但重质油自身流动性差,极大地限制了煤油共液化的发展。为认识重质油组成结构对油煤浆流变性能的影响,选取5种性质差异明显的重质油和2种工业循环溶剂油,探究其与上湾煤形成的油煤浆流变性能变化规律,在此基础上通过预加氢调控减压渣油的组成结构,分析重质油组成、结构与流变性能,获得重质油组成结构对油煤浆流变性能的影响规律。结果表明,重质油本身是牛顿流体,加入煤粉后转变为假塑性流体,呈现剪切稀化特征;重质油中胶质和沥青质组分含量越高,形成油煤浆的黏度越高,体系内部的触变结构越丰富,非牛顿流体特征越明显。减压渣油稠油预加氢后,形成油煤浆的黏度显著降低,其中,380℃下预加氢2 h后制成的油煤浆黏度在135℃时降至451 mPa·s,同时油煤浆的触变特性也明显减弱。预加氢促使减压渣油中的长链断裂为短链烃,胶质和沥青质组分转化为饱和分与芳香分,从而抑制胶团的生成,降低油煤浆黏度。其中,380℃下预加氢2 h后胶质含量较未处理减少约21%,重均分子量降至1 594 Da,芳香环β位的H含量增加约20%。 相似文献
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在0.5L搅拌式高压釜上开展了中温煤焦油与新疆黑山煤共处理的实验研究,考察了中温煤焦油添加量对新疆黑山煤制浆性能和液化结果的影响,探索中温煤焦油加工利用新途径.结果表明,添加中温煤焦油增加了油煤浆输送时的黏度,在油煤浆浓度为42%时,中温煤焦油添加量不高于18%.与新疆黑山煤单独液化相比,中温煤焦油与新疆黑山煤共处理具有氢耗、气产率、转化率和油产率高的特点;添加适量的中温煤焦油对新疆黑山煤液化具有正协同效应,添加量大于20%时反而对煤转化不利;最佳添加量为5%,与煤单独处理的结果相比,转化率高1.6%,油产率高1.1%;添加量大于20%时,油收率下降.因此,添加适量的中温煤焦油与新疆黑山煤共处理,既可提高煤的转化率和油收率,又可加工利用中温煤焦油,提高煤直接液化的经济效益. 相似文献
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为建立油煤浆表观黏度测定标准,实现油煤浆表观黏度的准确测量,研究了多种煤液化油煤浆在不同条件下的流变行为,考察了剪切速率、测量温度、样品放置时间、读数开始时间等因素对油煤浆表观黏度测值的影响,并确定了油煤浆表观黏度测定方法的精密度。结果表明:测定油煤浆表观黏度的最佳条件为:剪切速率100 s-1,测量温度60℃,油煤浆取样后应立即进行黏度测定,启动旋转黏度计后,第11 min开始记录读数,每隔10 s记录一次,共计30次,以测定结果的平均值为样品黏度值,修约到整数位报出。规定油煤浆表观黏度测定方法的重复性限r=0.13η100 s-1-4.30,由于试验仪器条件的限制,未对再现性做出说明。 相似文献
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Moisture readsorption and low temperature oxidation characteristics of upgraded low rank coal 总被引:1,自引:0,他引:1
Hokyung ChoiChinnasamy Thiruppathiraja Sangdo KimYoungjoon Rhim Jeonghwan LimSihyun Lee 《Fuel Processing Technology》2011,92(10):2005-2010
This study investigated the behavior of upgraded low rank coal produced by a coal-oil slurry dewatering process regarding moisture readsorption, low temperature oxidation, and spontaneous combustion. The upgraded low rank coal had higher heating values than raw coal. It also showed lower moisture readsorption than raw coal and had less susceptibility to low temperature oxidation and spontaneous combustion. This seemed to result from the coating of the asphalt on the surface of the coal, which covered fine pores and suppressed the active functional groups from reacting with moisture and oxygen in the air. The increasing upgrading pressure negatively affected the moisture readsorption, low temperature oxidation, and spontaneous combustion. 相似文献
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《分离科学与技术》2012,47(5):610-618
This paper describes the use of coal-oil agglomerates in flotation to increase the gold recovery from an ore containing fine gold particles. The effects of operating parameters on gold flotation recovery such as oil type, particle size of agglomerating material, agglomerate/ore and oil/ore ratios were investigated. The studies showed that petroleum oils are more effective than vegetable oils in oil agglomeration of Kozlu coal and coal-oil assisted gold flotation. Gold recovery can be increased using a higher amount of agglomerates in the process; however, gold grade of the flotation concentrates is reduced significantly. The use of bridging oil at high concentrations in the agglomeration process provides high-grade gold concentrates, but lower recoveries. The utilization of coarser coal particles in the coal-oil agglomeration stage leads to higher selectivity and recovery values for gold particles. 相似文献
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油煤浆输送管道弯管部位流场的数值模拟与磨损预测 总被引:1,自引:1,他引:0
针对煤液化工业中油煤浆管道,利用fluent软件对7种不同管径,8种弯径比的弯管部位的流场进行了模拟计算,得到在湍流状态下管内速度场分布。通过二次开发将磨损模型嵌入到Fluent软件中,实现了对弯管部位的磨损预测。数值计算结果表明,弯径比不同,弯管的磨损区域与磨损量有较大差异;同一管径时,随着弯径比增大,最大磨损量减小。考虑到管路经济性,弯径比取4—6是比较适宜的。 相似文献
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Grinding of coal in fuel oil for coal-oil mixtures (COM) preparation is simpler and may give better slurry properties than dry grinding followed by dispersion in oil. A 42 weight percent slurry of 600–840 μm particles of Pittsburgh coal in #2, #4, and #6 fuel oils has been ground with the novel Szego mill. Particle size distributions at different residence times are reported down to a 10 μm median size, together with energy consumption data. Low mill hold-ups and high rotational speeds enhanced the rate of grinding. 相似文献
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Single droplet combustion of coal-oil/methanol/water mixtures was investigated. A microexplosion occured during the gas-phase combustion period of emulsified fuels and caused secondary atomization of fuel droplets. The microexplosion during the combustion of a coal-oil/methanol/water mixture was the most violent of all the sample fuels and its apparent overall burning rate coefficient was maintained at the highest value over the range of ambient air temperatures used, 850–1000 °C. It was concluded that an appropriate addition of water and/or methanol could improve the combustion characteristics of coal/oil mixtures. The apparent overall burning rate coefficient of a methanol/coal/oil mixture was 2–3 times higher than that of a coal/oil mixture. However, that of a water/coal/oil mixture was 2–10 times higher than that of a coal/oil mixture. 相似文献
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神府煤内水含量高、氧碳比高,不利于湿法气化制备高性能水煤浆。选择神府同一矿区的原煤、洗煤,通过干磨湿配制浆,并对煤浆性能进行分析。结果表明,煤的可磨指数HGI与磨矿时间共同决定粉体的粒度分布,粉体粒度与煤浆的流动性及稳定性直接相关,磨矿过程应尽可能使粉体粒度偏细。粒度〉0.20 mm的粉体主要影响煤浆的稳定性,较多的大颗粒会因重力沉降作用导致煤浆性能变差;粒度〈0.076 mm的粉体主要影响煤浆的流动性,合适的质量比配能与大颗粒形成双级或多级级配。SFR、SFX制浆性能较好时粒度〈0.076 mm的粉体分别占45%、50%。 相似文献
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For the use of coal—oil mixtures as combustion fuels stable maintenance of the solid—liquid suspension is vital and for this reason the settling properties of these mixtures were studied with a system of ultrasonic sensors. The sedimentation theory of Smiles, which relies on unsteady state diffusion analogies, was applied successfully to the coal-oil mixtures and pseudo diffusion coefficients were determined. 相似文献