Investigation of timber harvesting impacts on herbaceous cover,forest floor and surface soil properties on skid road in an oak (Quercus petrea L.) stand

In this study, we investigated the timber harvesting effects on some soil properties (sand, silt, clay, pH, electrical conductivity, fine soil <2 mm, coarse soil >2 mm, root mass, organic carbon, moisture equivalent, total porosity, bulk density, moisture and compaction) at soil depths (0–5 and 5–10 cm), herbaceous cover and forest floor (unit mass, organic matter and moisture) on skid road of an oak (Quercus petrea L.) stand in Istanbul Belgrad Forest of Turkey.     

Removal of organic matter in stormwater ponds: a plug-flow model generalisation from waste stabilisation ponds to shallow rivers

ABSTRACT

This study investigates the effect of flow conditions on the organic matter concentration, removal efficiency, and reaction kinetics in a stormwater pond in Fortaleza, Brazil. As a result of unauthorized sewage discharges, BOD and COD concentrations were similar to those of combined sewer systems. The concentrations remained roughly the same during the rainy season, which was attributed to sewage network overflow. Removal efficiencies ranged from 70–90%, similar to primary facultative ponds. Fitting different hydraulic models to the field data, it was possible to obtain BOD and COD removal rates that could be described as functions of the Reynolds number. The best fit was achieved considering the plug-flow assumption, and a general BOD model including data reported in the literature for waste stabilisation ponds, stormwater ponds and shallow rivers was derived. Lastly, simulations with this general model were performed to assess the impact of remediation measures on the studied pond.     

Stormwater quality associated with a silt trap (empty and full) discharging into an urban watercourse in Scotland

The aim was to assess the influence of a full silt trap at the end of a stormwater drainage pipe on the water quality of stormwater discharged into a semi‐natural urban watercourse. For approximately eleven weeks, the water qualities of the preliminarily treated stormwater and of the receiving watercourse (Braid Burn) were studied. The mean outflow concentrations of suspended solids were 2.0 mg/l and 34.1 mg/l during dry and wet weather conditions, respectively. Suspended solids concentrations of up to 141.6 mg/l were recorded during storm events. Suspended solids values for treated stormwater were often too high compared to international secondary wastewater treatment standards of around 30 mg/l. Pollutants including heavy metals (e.g., zinc, copper and nickel) accumulated in the silt trap. However, high outflow velocities during heavy rainfall events did not result in clearly defined sediment layers due to sediment re‐suspension. Metals did not accumulate in the receiving watercourse.     

Perfluoroalkyl acids in urban stormwater runoff: Influence of land use

Perfluoroalkyl acids (PFAAs) are persistent organic pollutants in the environment and have been reported to have nonpoint sources. In this study, six PFAAs with different chain lengths were monitored in stormwater runoff from seven storm events (2009–2011) at various outfall locations corresponding to different watershed land uses. We found PFAA(s) in 100% of stormwater runoff samples. Monitoring results and statistical analysis show that PFAAs in stormwater runoff from residential areas mainly came from rainfall. On the other hand, non-atmospheric sources at both industrial and commercial areas contributed PFAAs in stormwater runoff. The mass flux of PFAAs from stormwater runoff in the Twin Cities (Minneapolis and St. Paul, MN) metropolitan area is estimated to be about 7.86 kg/year. In addition, for the first time, we monitored PFAAs on the particles/debris in stormwater runoff and found high-level PFOS on the particulate matter in runoff collected from both industrial and commercial areas; the levels were so high that the finding could not be explained by the solid–water partitioning or adsorption. PFOS on the particulate matter is suspected to have originated from industrial/commercial products, entering the waste stream as PFOS containing particles.     

Influence of organic matter on the transport of Cryptosporidium parvum oocysts in a ferric oxyhydroxide-coated quartz sand saturated porous medium

To assess the effect of organic matter on the transport of Cryptosporidium parvum oocysts in a geochemically heterogeneous saturated porous medium, we measured the breakthrough and collision efficiencies of oocysts as a function of dissolved organic matter concentration in a flow-through column containing ferric oxyhydroxide-coated sand. We characterized the surface properties of the oocysts and ferric oxyhydroxide-coated sand using microelectrophoresis and streaming potential, respectively, and the amount of organic matter adsorbed on the ferric oxyhydroxide-coated sand as a function of the concentration of dissolved organic matter (a fulvic acid isolated from Florida Everglades water). The dissolved organic matter had no significant effect on the zeta potential of the oocysts. Low concentrations of dissolved organic matter were responsible for reversing the charge of the ferric oxyhydroxide-coated sand surface from positive to negative. The charge reversal and accumulation of negative charge on the ferric oxyhydroxide-coated sand led to increases in oocyst breakthrough and decreases in oocyst collision efficiency with increasing dissolved organic matter concentration. The increase in dissolved organic matter concentration from 0 to 20 mg L⁻¹ resulted in a two-fold decrease in the collision efficiency.     

Sediment oxygen demand fractionation, kinetics and reduced chemical substances

Observations of the kinetics and fractionation of sediment oxygen demand (SOD) are reported on six cores from two shallow, freshwater lakes. These measurements were made by batch respirometry on discrete sub-cores which were handled to minimize aerial oxidation. The kinetics of oxygen uptake were measured for periods ranging from 1 to 24 h. Four parallel sediment samples were processed to differentiate oxygen uptake arising from chemical, biological and sulfidic origins. The SOD values ranged from 0.05 to 5.24 mg g⁻¹ wet sediment and the major portion of the oxygen demand resulted from chemical reactions. Reduced soluble species in sediment pore waters were calculated to account for less than 10% of the total SOD. Approx. 28% of the SOD was due to the reaction of sulfide minerals. The remainder of the demand resulted from the oxidation of organic matter and reduced metallic minerals associated with surfaces. Bulk sediment parameters (% volatile solids, organic carbon and acid-soluble sulfide) showed significant correlations with corresponding SOD fractions. Total SOD rates were adequately described by an apparent first order rate equation. Rates were found to be significantly greater in the upper 20 cm of sediment than they were in deeper samples. The relationships between sediment composition, SOD magnitude and oxygen uptake rates provide valuable insights for engineering applications of the results to dredging operations.     

Measurement and three-dimensional simulation of flow in a rectangular detention tank

There are two main ways to obtain better knowledge of the hydraulics of ponds, namely measurements and simulations. In this study, the applicability of using three-dimensional simulations as an engineering tool in stormwater pond design was investigated. To do this, three-dimensional simulations were compared with measurements of flow pattern and residence time in a large physical model of a detention tank (13 × 9 × 1 m). The agreement between measurements and simulations concerning both flow pattern and residence time distribution curves was found to be good for high flow rates.     

A washoff model for stormwater pollutants

A washoff rate equation for stormwater pollutants is presented based on linear buildup of pollutant mass in the watershed. The expression was applied to residential and open land areas that have not previously been considered even though these areas are major sources of metals, nutrients, and bacteria in stormwater runoff. The transport coefficient c was determined from the nearly constant portion of the hydrograph at the peak of each runoff event. Values of c (cm(-1)) for seven metals, i.e., Zn, Cu, Cd, Ni, Pb, Hg, and Ag (3.03+/-1.34-6.10+/-2.55 cm(-1)), TSS, BOD(5), total phosphorus (TP), E. coli, and fecal coliform (2.12+/-0.907-7.16+/-2.72 cm(-1)) were estimated using this equation. The washoff rate was developed to reflect mixed land uses based on mass deposition and effective area. The order of transport coefficients for metals is Pb>Ag>Zn>Cu>Ni>Hg>Cd reflecting decreasing particle association. For all parameters this order is TSS>fecal coliform>E. coli>Pb>BOD(5) BOD(5)>Ag>Zn>Cu>Ni>Hg>Cd>TP. The washoff rate and a related pollutant concentration model are expected to be useful for the development of best management practices for stormwater.     

Evaluation of the effects of seasonal changes in sediment characteristics on macroinvertebrate assemblage in a tropical reservoir

Osinmo Reservoir is an important water body in south‐western Nigeria. Despite being critically important, there is a lack of detailed biological studies on this reservoir. This study investigated the effect of seasonal variations on the characteristics of the sediment and the community structure of the macroinvertebrates in the reservoir between May 2012 and March 2014. The sediment was generally slightly acidic and was dominated by silty sand and sandy mud with low organic matter. Twenty‐four taxa of macroinvertebrates with a total abundance of 55,065 individuals (ind.) belonging to three phyla were recorded. Overall, the composition and the abundance of the macroinvertebrates were not significantly different (P > 0.05) in the wet and dry seasons. Seasonal variations in the sediment quality did not have a significant impact on the community metrics such as species diversity, species richness and species evenness. The dominance of sensitive species indicated a moderately clean status of the reservoir.     

Modelling the fate of organic micropollutants in stormwater ponds

Urban water managers need to estimate the potential removal of organic micropollutants (MP) in stormwater treatment systems to support MP pollution control strategies. This study documents how the potential removal of organic MP in stormwater treatment systems can be quantified by using multimedia models. The fate of four different MP in a stormwater retention pond was simulated by applying two steady-state multimedia fate models (EPI Suite and SimpleBox) commonly applied in chemical risk assessment and a dynamic multimedia fate model (Stormwater Treatment Unit Model for Micro Pollutants — STUMP). The four simulated organic stormwater MP (iodopropynyl butylcarbamate — IPBC, benzene, glyphosate and pyrene) were selected according to their different urban sources and environmental fate. This ensures that the results can be extended to other relevant stormwater pollutants. All three models use substance inherent properties to calculate MP fate but differ in their ability to represent the small physical scale and high temporal variability of stormwater treatment systems. Therefore the three models generate different results. A Global Sensitivity Analysis (GSA) highlighted that settling/resuspension of particulate matter was the most sensitive process for the dynamic model. The uncertainty of the estimated MP fluxes can be reduced by calibrating the dynamic model against total suspended solids data. This reduction in uncertainty was more significant for the substances with strong tendency to sorb, i.e. glyphosate and pyrene and less significant for substances with a smaller tendency to sorb, i.e. IPBC and benzene. The results provide support to the elaboration of MP pollution control strategies by limiting the need for extensive and complex monitoring campaigns targeting the wide range of specific organic MP found in stormwater runoff.     

Fractionation of surface sediment fines based on a coupled sieve-SPLITT (split flow thin cell) method

In traditional sediment grain-size separation using sieve technique, the bulk of the organic matter passes through the smallest mesh size (generally 38 microm) and is not further fractionated. In this study, a common sieve separation has therefore been coupled with an extra high capacity split flow thin cell fractionation (EHC-SPLITT) instrument to separate the bulk surface sediment not only into size-based sieve fractions (> 100, 63-100, 38-63 and < 38 microm) but particularly to further fractionate hydrodynamically the fine fraction (< 38 microm) using the EHC-SPLITT. Compared to the few previous studies using a smaller high capacity (HC) SPLITT cell, the EHC-SPLITT evaluated in detail here has several advantages (e.g., 23 times higher throughput and allowance for large particle diameters). First, the EHC-SPLITT was calibrated with particle standards. Then, its ability to fractionate fine surface sediments hydrodynamically was demonstrated with material from biogeochemically distinct regimes using two cutoff velocities (1 and 6 m d(-1)). The results from particle standards indicated a good agreement between theory and experiment and a satisfactory mass recovery for the sieve-SPLITT method (80-97%) was observed for sediment samples. The mass distributions revealed that particles < 38 microm were predominant (70-90%), indicating the large need for a technique such as the EHC-SPLITT to further fractionate the fine particles. There were clearly different compositions in the EHC-SPLITT-mediated sub-fractions of the sediment fines as indicated by analyses of organic and inorganic parameters (POC, Si, Fe and Al). The EHC-SPLITT technique has the potential to provide information of great utility to studies of benthic boundary layer transport and off-shelf export and how such processes fractionate geochemical signals.     

Hydrodynamic behaviour of a new permeable pavement material under high rainfall conditions

Permeable pavements are among the most effective alternative solutions for sustainable stormwater management. They decrease impervious surfaces in urban areas, reduce the risk of flooding under high rainfall conditions and protect the natural environment against stormwater pollution. In a view to ensuring sustainable stormwater management, a new eco-material has been designed for producing permeable pavements. This material is a mixture of construction wastes (crushed concrete) and organic matter (compost). The crushed concrete is the structural support and the compost is used for retention and the biological treatment of stormwater pollution. The purpose of the research work presented in this paper was to evaluate the hydrodynamic behaviour of a new permeable pavement material under high rainfall conditions. The experimental approach adopted for this research study is a temporal moment analysis. Therefore, for the experimental study, we simulated high rainfall with a return period of 10 years (Torreilles in 2001, France). The rainfall data were provided by Meteo France. The rainfall was maintained at an intensity of 126 mm/h, corresponding to a flow rate of 16 l/h at laboratory apparatus scale. Then, the flow rate was increased three times, to 25 l/h, 50 l/h and finally 100 l/h to subject the material to extreme conditions.     

Preparation of growth substrate to improve runoff quality from green roofs: physico-chemical characterization,sorption and plant-support experiments

Growth substrate plays an important role in determining the quality of runoff from green roofs. However, no systematic research has been conducted to design a substrate to improve runoff quality. Hence, the present study aimed at designing and developing a green roof substrate using low-cost and environmentally-benign materials. The inorganic fraction of the substrate includes purosil, vermiculite, sand and light-weight clay aggregates (LECA); whereas the organic fraction includes coco-peat and Sargassum wightii. Through factorial design, 13 different substrate mixes were prepared and the optimum mix (20% purosil, 30% vermiculite, 10% sand, 20% LECA, 10% coco-peat and 10% S. wightii) was found to have high water holding capacity (67.6%), air filled porosity (21%), hydraulic conductivity (5524 mm/h) and low bulk density (495 kg/m³). The substrate also provided maximum support for the growth of Portulaca oleracea. Experiments with metal-contaminated influent from the down-flow of a packed reactor revealed that the green roof substrate possesses a high sorption capacity towards various metal ions.     

Effects of molecular weight of natural organic matter on cadmium mobility in soil environments and its carbon isotope characteristics

We investigated the role of natural organic matter in cadmium mobility in soil environments. We collected the dissolved organic matter from two different types of natural waters: pond surface water, which is oxic, and deep anoxic groundwater. The collected organic matter was fractionated into four groups with molecular weights (unit: Da (Daltons)) of <1 x 10(3), 1-10 x 10(3), 10-100 x 10(3), and >100 x 10(3). The organic matter source was land plants, based on the carbon isotope ratios (delta(13)C/(12)C). The organic matter in surface water originated from presently growing land plants, based on (14)C dating, but the organic matter in deep groundwater originated from land plants that grew approximately 4000 years ago. However, some carbon was supplied by the high-molecular-weight fraction of humic substances in soil or sediments. Cadmium interacted in a system of siliceous sand, fractionated organic matter, and water. The lowest molecular weight fraction of organic matter (<1 x 10(3)) bound more cadmium than did the higher molecular weight fractions. Organic matter in deep groundwater was more strongly bound to cadmium than was organic matter in surface water. The binding behaviours of organic matter with cadmium depended on concentration, age, molecular weight, and degradation conditions of the organic matter in natural waters. Consequently, the dissolved, low-molecular-weight fraction in organic matter strongly influences cadmium migration and mobility in the environment.     

Thermal property measurements for ecoroof soils common in the western U.S.

To model the impacts of ecoroofs on building envelope heat transfer accurately, thermal property data for ecoroof soils are needed. To address this need we have measured thermal conductivity, specific heat capacity, thermal emissivity, short wave reflectivity (albedo) and density for ecoroof soil samples over a range of moisture states. To represent a wide range of commonly used ecoroof soils we created eight test samples using an aggregate (expanded shale or pumice), sand, and organic matter in varying volumetric composition ratios. The results indicate significant variability in properties as a function both of soil composition and soil wetness. Thermal conductivity ranged from 0.25 to 0.34 W/(m K) for dry samples and 0.31–0.62 W/(m K) for wet samples. Specific heat capacity ranged from 830 to 1123 J/(kg K) for dry samples and 1085–1602 J/(kg K) for wet samples. Albedo was consistently higher for dry samples (0.17–0.40) decreasing substantially (0.04–0.20) as moisture was added. Thermal emissivities were relatively constant at 0.96 ± 0.02 regardless of soil type or moisture status. These results are discussed in the context of their impacts on building energy consumption and the importance of including daily and seasonal property variation within models of the ecoroof energy balance.     

Removal of particulate matter and phosphorus in sand filters treating stormwater and drainage runoff: a case study

Runoff is often delayed and treated in wet ponds to retain particles and particulate substances. To increase the treatment efficiency, a sand filter can be placed before the outlet. The filter material is often renewed after 10–15 years due to presumed clogging by trapped particles, but often it clogs much earlier. Knowledge of how clogging develops over time is therefore important. This study has examined two filters, focusing on particle size, content and placement of particles, organic matter (OM) and phosphorus (P) retained in the filter. The study concludes that both particles and P are retained in the upper few cm’s of the filter, causing clogging after a few years, thus leaving the deeper filter material unused. Even small particles (<63 µm) are efficiently retained as long as clogging is avoided. This is preferable, as runoff is rich in small particles and as particulate P is associated with the small particles.     

Estimates of benthic fluxes of nutrients across the sediment-water interface (Guarapiranga reservoir, São Paulo, Brazil)

Concentration profiles of nutrients (dissolved organic carbon, nitrate, nitrite, ammonium and soluble reactive phosphorus) were determined in pore waters from sediment from the Guarapiranga reservoir (S?o Paulo, Brazil). Redox potential and acid volatile sulfide measurements on bulk sediment samples were determined in the field and laboratory, respectively. The sediment redox potential ranged from -170 to -220 mV at 0-1 cm and increased to somewhat higher values at 20 cm. The acid volatile sulfide (AVS) profile had a bimodal pattern with concentration peaks at 3 cm (27-55 mg kg(-1)) and 14 cm (70-110 mg kg(-1)). Dissolved organic carbon (DOC) concentrations increased from the surface (4.7-5.6 mg l(-1)) to 20 cm (values up to 12 mg l(-1)). The concentration of ammonium increased significantly with depth, with maximum concentrations occurring at 15 cm; nitrate-nitrite concentrations only increased appreciably at 10 cm. The SRP profiles increased in concentration from the surface to approximately 10-cm depth, with a maximum value of 1200 microg H2PO4- l(-1). Benthic fluxes from the sediment into the pore water ranged from 278 to 339 mg cm(-2) year(-1) for ammonium ions and from 8 to 18 mg cm(-2) year(-1) for SRP. These upward diffusive fluxes correspond to 47-70% and to 10-24% of the total deposition of N and P measured in the reservoir, respectively. The burial rates for N and P in these sediments are 30-54% and 76-89%, respectively.     

Impact of design and operation variables on the performance of vertical-flow constructed wetlands and intermittent sand filters treating pond effluent

With the aim of improving the quality of the effluent from a waste stabilization pond (WSP) different types of vertical-flow constructed wetlands (VFCWs) and intermittent sand filters (ISFs) were tested at a pilot plant in Aurignac (France). The effectiveness of each design at upgrading the pond effluent was studied over a period of 2 years. Physicochemical parameters were monitored by taking composite samples over 24 h and grab samples every week. The hydraulic behaviour of the filters was studied using (NaCl) tracer tests and monitoring the infiltration rate. This paper describes the influence on the performance of the beds of: (a) the characteristics of the medium (type of sand, depth, and presence of Phragmites); (b) feed modes; and (c) the presence of an algae clogging layer. The study demonstrates the viability of VFCWs and ISFs as means of upgrading effluent from WSPs. For hydraulic loads (HL) of up to 80 cm/day, both technologies effectively retain algae, complete organic matter degradation, and nitrify the pond effluent. The presence of plants did not significantly affect the performance of the filters although it was important in terms of maintenance. The deeper filters presented better removals for all the parameter tested, due to higher hydraulic detention times (HDTs). The dosing regime and resting period duration all affected the hydraulic performance and purification efficiency of the filters.     

轻量土击实密度模型与工程特性

为了探索软夹杂土体压实机理,指导轻量土配方设计与压实施工,基于混合土物质结构组成及土体压缩变密的物理本质,建立了击实密度模型。试验发现模型预测值与实测湿密度基本一致,绝对误差仅有0.003~0.051 g/cm³,相对误差仅有0.282%~5.267%,证明击实密度模型可以准确预测混合土不同击实条件下的湿密度。EPS颗粒压缩率、混合土湿密度随击实次数增大而增大,增大趋势逐渐变缓;混合土孔隙比随击实次数增大而减小。在击实作用下,轻量土湿密度的提高是由土体的孔隙减少和EPS颗粒软夹杂的塑性压缩共同完成的。与砂土轻量土性质相似,粘土轻量土的湿密度、无侧限抗压强度随击实次数增大而增大。=25击时,EPS颗粒压缩率范围6.13%~11.51%;=94击时,EPS颗粒压缩率范围12.80%~14.87%。证明规范规定的击实次数与击实能量适合混合土的击实,不会导致EPS颗粒消泡。考虑到击实密度模型参数测定非常繁琐,根据工程实际情况,假设压实过程中土料含水量不变与压实后土颗粒-EPS颗粒之间的孔隙近似为0,进一步提出了简化击实密度模型,并且通过试验证明了简化模型完全适用于实际工程。     

Application of probabilistic neural networks in modelling structural deterioration of stormwater pipes

In Australia, when stormwater systems were first introduced over 100 years ago, they were constructed independently of the sewer systems, and they are normally the responsibility of the third level of government, i.e., local government or city councils. Because of the increasing age of these stormwater systems and their worsening performance, there are serious concerns in a significant number of city councils regarding their deterioration. A study has been conducted on the structural deterioration of concrete pipes that make up the bulk of the stormwater pipe systems in these councils. In an attempt to look for a reliable deterioration model, a probabilistic neural network (PNN) model was developed using the data set supplied from participating councils. The PNN model was validated with snapshot-based sample data, which makes up the data set. The predictive performance of the PNN model was compared with a traditional parametric model using discriminant analysis on the same data set. Structural deterioration was hypothesised to be influenced by a set of explanatory factors, including pipe design and construction factors—such as pipe size, buried depth—and site factors—such as soil type, moisture index, tree root intrusion, etc. The results show that the PNN model has a better predictive power and uses significantly more input variables (i.e., explanatory factors) than the discriminant model. More importantly, the key factors for prediction in the PNN model are difficult to interpret, suggesting that besides prediction accuracy, model interpretation is an important issue for further investigation.