Iron salts dosage for sulfide control in sewers induces chemical phosphorus removal during wastewater treatment

Chemical phosphorus (P) removal during aerobic wastewater treatment induced by iron salt addition in sewer systems for sulfide control is investigated. Aerobic batch tests with activated sludge fed with wastewater containing iron sulfide precipitates showed that iron sulfide was rapidly reoxidised in aerobic conditions, resulting in phosphate precipitation. The amount of P removed was proportional to the amount of iron salts added, and for the sludge used, ratios of 0.44 and 0.37 mgP/mgFe were obtained for ferric and ferrous dosages, respectively. The hydraulic retention time (HRT) of iron sulfide in sewers was found to have a crucial impact on the settling of iron sulfide precipitates during primary settling, with a shorter HRT resulting in a higher concentration of iron sulfide in the primary effluent and thus enabling higher P removal. A mathematical model was developed to describe iron sulfide oxidation in aerated activated sludge and the subsequent iron phosphate precipitation. The model was used to optimise FeCl₃ dosing in a real wastewater collection and treatment system. Simulation studies revealed that, by moving FeCl₃ dosing from the WWTP, which is the current practice, to a sewer location upstream of the plant, both sulfide control and phosphate removal could be achieved with the current ferric salt consumption. This work highlights the importance of integrated management of sewer networks and wastewater treatment plants.     

Contributions of wastewater, runoff and sewer deposit erosion to wet weather pollutant loads in combined sewer systems

An observatory of urban pollutants was created in Paris for the purpose of assessing the dynamics of wastewater and wet weather flow (WW and WWF) pollutant loads within combined sewers. This observatory is composed of six urban catchments, covering land areas ranging in size from 42 ha to 2581 ha. For a wide array of parameters including total suspended solids (TSS), chemical and biochemical oxygen demand (COD and BOD₅), total organic carbon (TOC), total Kjeldahl nitrogen (TKN), heavy metals (Cu and Zn) and polycyclic aromatic hydrocarbons (PAHs), this article is intended to evaluate the contributions of wastewater, runoff and in-sewer processes to WWF pollutant loads through the use of an entry–exit mass balance approach. To achieve this objective, a total of 16 rain events were sampled on these sites between May 2003 and February 2006. This study has confirmed that at the considered catchment scale (i.e. from 42 ha to 2581 ha) the production and transfer processes associated with WWF pollutant loads do not vary with basin scale. Entry–exit chemical mass balances over all catchments and for a large number of rain events indicate that wastewater constitutes the main source of organic and nitrogenous pollution, while runoff is the predominant source of Zn. For Cu, PAHs and TSS, the calculation underscores the major role played by in-sewer processes, specifically by sediment erosion, as a source of WWF pollution. A significant loss of dissolved metals was also observed during their transfer within the sewer network, likely as a consequence of the adsorption of dissolved metals on TSS and/or on sewer deposits. Moreover, the nature of eroded particles was examined and compared to the various sewer deposits. This comparison has highlighted that such particles exhibit similar organic and PAH contents to those measured in the organic layer, thus suggesting that the deposit eroded during a wet weather period is organic and of a nature comparable to the organic layer. Despite the extent of initial field investigations, no organic deposit was observed to be present on sewer lines within the catchments, which implies that this organic deposit is probably present in another form or to be found elsewhere in the main trunks.     

A tanks-in-series bioreactor to simulate macromolecule-laden wastewater pretreatment under sewer conditions by Aspergillus niger

Sewers are typically a means of transporting wastewater to a treatment facility, with little biotransformation of the soluble polymeric organic matter by suspended biomass. In the interest of providing an effective pretreatment of wastewater in a sewer network, it is necessary to design an accurate tool simulating sewer conditions and introduce an appropriate biomass for macromolecular pollutant degradation. Such a model reactor was built using a tanks-in-series design and the degradation of a polysaccharide (starch) by Aspergillus niger MUCL 28817 was studied. Starch degradation and the accumulation of intermediates (hydrolysis fragments) in the individual reactors were quantified under transient conditions, at a mean hydraulic residence time of 17 h. Starch was degraded by 90% in this reactor system and an accumulation of oligosaccharides with molecular weight lower than 1,000 Da was observed. These results may be helpful in the development of wastewater treatment in sewers and in the alleviation of the burden on undersized wastewater treatment systems.     

Grey-box modelling of pollutant loads from a sewer system

Using a compact measuring unit with on-line meters for UV absorption and turbidity, it is possible to determine concentrations of organic load (chemical oxygen demand (COD) and suspended solids (SS)) anywhere in a sewer system. When measurements of the flow are available as well, the pollutant mass flow at the measuring point can be calculated.The measured data are used to estimate different models describing the load of pollutants in the sewer. A comparison of the models shows that a grey-box model is most informative and best in terms measured by the multiple correlation coefficient. The grey-box model is a state-space model, where the state represents the actual amount of deposition in the sewer, and the output from the model is the pollutant mass flow to the wastewater treatment plant (WWTP). The model is formulated by means of stochastic differential equations. Harmonic functions are used to describe the dry weather diurnal load profiles. It is found that the accumulation of deposits in the sewer depends on previous rain events and flows.By means of on-line use of the grey-box models, it is possible to predict the amount of pollutants in a first flush at any time, and hence from the capacity of the plant to decide if and when the available detention basin is to be used for storage of wastewater. The mass flow models comprise an important improvement of the integrated control of sewer and WWTP including control of equalisation basins in the sewer system. Further improvements are expected by the introduction of an additive model where dry weather situations and storm situations are modelled separately before addition to the resulting model.     

Evaluation of oxygen injection as a means of controlling sulfide production in a sewer system

Oxygen injection is often used to control biogenic production of hydrogen sulfide in sewers. Experiments were carried out on a laboratory system mimicking a rising main to investigate the impact of oxygen injection on anaerobic sewer biofilm activities. Oxygen injection (15-25 mg O₂/L per pump event) to the inlet of the system decreased the overall sulfide discharge levels by 65%. Oxygen was an effective chemical and biological oxidant of sulfide but did not cause a cessation in sulfide production, which continued in the deeper layers of the biofilm irrespective of the oxygen concentration in the bulk. Sulfide accumulation resumed instantaneously on depletion of the oxygen. Oxygen did not exhibit any toxic effect on sulfate reducing bacteria (SRB) in the biofilm. It further stimulated SRB growth and increased SRB activity in downstream biofilms due to increased availability of sulfate at these locations as the result of oxic conditions upstream. The oxygen uptake rate of the system increased with repeated exposure to oxygen, with concomitant consumption of organic carbon in the wastewater. These results suggest that optimization of oxygen injection is necessary for maximum effectiveness in controlling sulfide concentrations in sewers.     

大比降高速水流排水管水力计算

大比降排水管水流通常为高速水流,其水力设计已经超过排水设计规范范畴。以实际工程为例,指出该类管道不宜按照有压管路或明渠均匀流计算公式进行水力计算,应按照掺气水流计算,这为实际工程设计提供了参考依据。     

Surahammar: a case study of the impacts of installing food waste disposers in 50% of households

This paper reviews 15 years of sewage works' monitoring data to assess the effect of installing in-sink food waste disposers (FWD) and how these effects compare with the published scientific literature. For the first time, it has been possible to assess at full scale the load/cost transfer from solid-waste to wastewater management. Within a period of 10 years, 50% of households in the town of Surahammar in Sweden chose to have FWD installed as their means of managing their kitchen food waste. The drainage from the households feeds a single wastewater treatment works (WwTW) that comprises primary settlement, activated sludge, followed by chemical phosphate precipitation and mesophilic anaerobic digestion. The sewer system is separate but with overflow between foul and surface water in times of surcharge; the diameters and gradients of the sewers are unexceptional. This paper reviews the influent and biogas monitoring data for the years before installation started and the 10 years after the first peak of installations (by which time they had been installed in 30% of households). This provides a unique opportunity to verify the published research on FWD. The operational monitoring data are consistent with the already published research that FWD have little or no impact on water use, sewer blockages, vermin or wastewater treatment. The data are consistent with a hypothesis that in-sewer biological process acclimated to the change in wastewater composition and treated the dissolved and fine particulate load before it reached the WwTW. The digesters produced 46% more biogas than before FWD were installed (P=0.01). There was no significant increase in hydraulic load, or in the loading of BOD₇, COD, N or NH₄. As a result of Surahammar's overall waste strategy, not just the FWD, but the tonnage of waste to landfill from the municipality has also decreased from 3600 tonnes/year in 1996 to 1400 tonnes/year in 2007.     

Calibration of hydrodynamic model-driven sewer maintenance

Sewer performance is typically assessed using hydrodynamic models assuming the absence of in-sewer defects. As a consequence, hydraulic performance calculated by models is likely to be overestimated, while the real hydraulic performance of the sewer system remains unknown. This article introduces the concept of ‘hydraulic fingerprinting’ based on model calibration to identify in-sewer defects affecting hydraulic performance. Model calibration enables detection of changes in hydraulic properties of the sewer system. Each model calibration results in a set of model parameter values, their uncertainties and residuals. The model parameter values also incorporate the antecedent condition of the catchment of the event calibrated and are therefore less suitable to identify in-sewer defects. The residuals on the other hand, and more specifically their absolute values, statistical properties and the correlation between residuals at different monitoring locations are suitable as indicators of the occurrence of in-sewer defects. This allows the application of ‘hydraulic fingerprinting’ based on model calibration, where the ‘fingerprint’ is defined by the model parameters and the residuals. The concept of ‘fingerprinting’ is demonstrated for the combined sewer system ‘Tuindorp’ (Utrecht, the Netherlands). The results show that ‘hydraulic fingerprinting’ can be a powerful tool for directing sewer asset management actions.     

Wastewater quality and pollutant loads in combined sewers during dry weather periods

An observatory of urban pollutants was created in Paris in order to assess, at the urban catchment scale, the quality of sanitary sewage and pollutant loads during dry weather periods in the Paris combined sewer. Investigations were carried out for six urban catchments (varying from 42 to 2580 ha) focusing on a wide range of parameters, including: suspended solids (SS), chemical and biochemical oxygen demand (COD and BOD₅), total organic carbon (TOC), total Kjeldahl nitrogen (TKN), heavy metals (Cd, Cu, Pb, Zn), and aliphatic and polycyclic aromatic hydrocarbons (AHs and PAHs). Despite the marginal intra-site variability of some pollutants, which serves to reflect the impact of point sources, this work attests to the spatial homogeneity, at the physical scales considered, of wastewater quality and pollutant loads within the Paris combined sewer network. These results imply that similar production and transfer processes are occurring within sewers during dry weather periods and strongly suggest that data obtained on one specific catchment could be extrapolated to smaller or larger catchments that display quite similar land use and sewer characteristics.     

Occurrence and removal of selected organic micropollutants at mechanical, chemical and advanced wastewater treatment plants in Norway

In Norway the combined hydraulic capacity of all domestic wastewater treatment plants is relatively equally distributed between three major treatment plant types; mechanical, chemical, and combined chemical and biological. The Western coast from Lindesnes in the south to the Russian boarder in the North is dominated by mechanical treatment plants, constituting approximately 68% of the treatment capacity in that area. In the present study we report concentrations and removal efficiencies of polycyclic aromatic hydrocarbons (PAHs), nonylphenols, phthalates, polybrominated diphenyl ethers (PBDEs) and polychlorinated biphenyls (PCBs) found in five Norwegian wastewater treatment plants (WWTPs) applying different levels of treatment. Concentrations of organic micropollutants in the influents to the WWTPs were generally in the low range of what have been reported by others for domestic wastewater in Europe and North-America. More than 90% removal could be obtained for nonylphenols, PBDEs, and the more hydrophobic 4-6 ring PAHs by chemical precipitation, however, biological treatment appeared to be necessary for efficient removal of the less lipophilic 2 and 3 ring PAHs, the medium- to short-chained nonylphenol ethoxylates and diethyl phthalate. SigmaPCB(7) was removed by more than 90% by combined biological/chemical treatment, while removal efficiency by chemical treatment was not possible to estimate due to low inlet concentrations. Low or insignificant removals of PAHs, phthalates and nonylphenols with their ethoxylates were observed at the mechanical WWTP, which was in accordance with the minuscule removal of TOC.     

Illicit intrusion characterization in sewer systems

A very important aspect in sewer systems management is represented by the detection of illicit intrusions, which recently supported the development of online sensors for wastewater quality monitoring. The present paper proposes a new methodology for characterizing an illicit intrusion in a sanitary or combined sewer system, using on-line pollutant concentration measurements. The source identification is formulated as an optimization problem, solved combining the hydraulic and quality simulation tool storm water management model (SWMM) with the GALib code. The methodology, which includes a pre-screening procedure useful for complex and large systems, is applied to a literature scheme and a real test-case, showing promising results. An uncertainty analysis is also performed for checking its robustness with respect to inflow uncertainty and in the presence of measurement errors.     

Development of a model for assessing methane formation in rising main sewers

Significant methane formation in sewers has been reported recently, which may contribute significantly to the overall greenhouse gas emission from wastewater systems. The understanding of the biological conversions occurring in sewers, particularly the competition between methanogenic and sulfate-reducing populations for electron donors, is an essential step for minimising methane emissions from sewers. This work proposes an extension to the current state-of-the-art models characterising biological and physicochemical processes in sewers. This extended model includes the competitive interactions of sulfate-reducing bacteria and methanogenic archaea in sewers for various substrates available. The most relevant parameters of the model were calibrated with lab-scale experimental data. The calibrated model described field data reasonably well. The model was then used to investigate the effect of several key sewer design and operational parameters on methane formation. The simulation results showed that methane production was highly correlated with the hydraulic residence time (HRT) and pipe area to volume (A/V) ratio showing higher methane concentrations at a long HRT or a larger A/V ratio.     

Evaluation of combined sewer overflow assessment methods: case study of Cork City,Ireland

Discharges of untreated wastewater from combined sewer overflows (CSOs) present a potential threat to human health and the chemical and ecological status of receiving waters. Sewer monitoring coupled with hydraulic models are frequently applied to estimate CSO impacts and to test alternative improvement strategies, but their cost can be prohibitive. Therefore, municipal authorities must apply subjective assessment criteria to identify problematic CSOs which require immediate monitoring. In this paper, subjective assessment criteria for CSOs were reviewed and applied using a case study from Cork City, Ireland. Whilst the subjective criteria were robust in identifying nuisance CSOs (those giving rise to public complaint), the assessment of impacts on chemical and ecological status were confounded by other pollutant sources in the catchment and a lack of CSO monitoring data. A methodology was developed, using a geographical information systems (GIS) model, to prioritise monitoring of problematic CSOs on a national basis.     

A novel sulfate reduction, autotrophic denitrification, nitrification integrated (SANI) process for saline wastewater treatment

This paper reports on a lab-scale evaluation of a novel and integrated biological nitrogen removal process: the sulfate reduction, autotrophic denitrification and nitrification integrated (SANI) process that was recently proposed for saline sewage treatment. The process consisted of an up-flow anaerobic sludge bed (UASB) for sulfate reduction, an anoxic filter for autotrophic denitrification and an aerobic filter for nitrification. The experiments were conducted to evaluate the performance of the lab-scale SANI system with synthetic saline wastewater at various hydraulic retention times, nitrate concentrations, dissolved oxygen levels and recirculation ratios for over 500 days. The system successfully demonstrated 95% chemical oxygen demand (COD) and 74% nitrogen removal efficiency without excess sludge withdrawal throughout the 500 days of operation. The organic removal efficiency was dependent on the hydraulic retention time, up-flow velocity, and mixing conditions in the UASB. Maintaining a sufficient mixing condition in the UASB is important for achieving effective sulfate reduction. For a typical Hong Kong wastewater composition 80% of COD can be removed through sulfate reduction. A minimum sulfide sulfur to nitrate nitrogen ratio of 1.6 in the influent of the anoxic filter is necessary for achieving over 90% nitrate removal through autotrophic denitrifiers which forms the major contribution to the total nitrogen removal in the SANI system. Sulfur balance analyses confirmed that accumulation of elementary sulfur and loss of hydrogen sulfide in the system were negligible.     

Innovative modeling framework for combined sewer overflows prediction

Combined sewer overflows (CSOs) and street flooding are undesirable consequences of insufficient capacity of sewer networks and wastewater systems. These conditions degrade the water quality of the receiving waters, potentially damage infrastructure, and threaten public health. Significant efforts to prevent CSOs and alleviate flooding have been undertaken in Chicago, with the construction of the tunnel and reservoir plan (TARP). This study analyses the hydraulic response of the first tunnel built in Chicago “The Lawrence Avenue Tunnel” through a framework of hydrological and hydraulic models. This framework proved effective in CSO's volume, frequency and duration predictions as it yields simulation results of existing conditions that match well with available records. The findings also provide insights into the importance of system operation on CSOs occurrence and magnitude. Adaptive management of the tunnel during storm events is recommended to minimize the impact of CSOs.     

Production and transport of urban wet weather pollution in combined sewer systems: the “Marais” experimental urban catchment in Paris

An experimental catchment area was set up in the centre of Paris (France) so as to follow up the quality of wet weather flows from the entry to the exit of a combined sewer network. The distinctive characteristic of this site is its location in a town centre and the extent of the equipment used to monitor the water pollution over the whole length of its course through the catchment area. The results obtained show a change in quality between the runoff entering the sewer network and the combined storm water flow at the sewer's outlet, which cannot be explained only by the mixture with domestic wastewater. In particular, an increase was observed in the concentrations of suspended solids (SS), VSS, COD, BOD and Cu, in the proportion of pollutants linked to particles and in the characteristics of the particles. A calculation of the total masses going in and out of the sewer network during a rainfall event shows that the erosion of in-sewer pollution stocks is the main source of particles and of organic matter in wet weather flows, whereas heavy metals loads originated from roof runoff, due to the corrosion of metallic roofs. Particles eroded from the sewer sediments during rain events were found to be quite different from the particles of type A deposits and organic biofilms. Nevertheless, they have mean organic and metallic loads that are of the same order of magnitude as the particles of the organic layer at water sediment interface. A change in the chemical form of heavy metals was noticed during the transport in the sewer and it is suspected that a fraction of the dissolved metals from the runoff is adsorbed on sewer sediments.     

Methane formation in sewer systems

Methane formation and emission in sewer systems has not received as much attention as hydrogen sulphide formation. Through field measurements from two rising mains, with an average sewage temperature of 28.4 and 26.6 degrees C, respectively, at the time of sampling, this study shows that a significant amount of methane can be produced in sewer systems, and that this production is positively correlated with the hydraulic retention time of wastewater in these systems. The experimental results from a laboratory-scale sewer system fed with real sewage with a temperature of approximately 21 degrees C confirmed these field observations and further revealed that methanogenesis and sulphate reduction occur simultaneously in sewers, with methane production contributing considerably more to the loss of soluble COD in sewers than sulphate reduction. The production of methane in sewers at levels revealed by this study is a serious environmental concern as it potentially results in greenhouse emissions that is comparable to that caused by the energy consumption for the treatment of the same wastewater. Further, methane production in sewers influences sulphide production and its management due to the competition between methanogens and sulphate-reducing bacteria for potentially the same electron donors. The potential interactions between sulphate-reducing and methanogenic bacteria in sewer networks are discussed.     

计算机水力学模型在城市排水管理中的应用

本文介绍计算机水力学模型在城市排水管理领域应用的初步探索。应用实例说明 :计算机水力学模型可在排水管网数据管理、排水管网瓶颈的诊断、运行管理策略的评价、优化运行策略研究等诸方面具有实际应用价值。     

Biodegradability of organic matter associated with sewer sediments during first flush

The high pollution load in wastewater at the beginning of a rain event is commonly known to originate from the erosion of sewer sediments due to the increased flow rate under storm weather conditions. It is essential to characterize the biodegradability of organic matter during a storm event in order to quantify the effect it can have further downstream to the receiving water via discharges from Combined Sewer Overflow (CSO). The approach is to characterize the pollutograph during first flush. The pollutograph shows the variation in COD and TSS during a first flush event. These parameters measure the quantity of organic matter present. However these parameters do not indicate detailed information on the biodegradability of the organic matter. Such detailed knowledge can be obtained by dividing the total COD into fractions with different microbial properties. To do so oxygen uptake rate (OUR) measurements on batches of wastewater have shown itself to be a versatile technique. Together with a conceptual understanding of the microbial transformation taking place, OUR measurements lead to the desired fractionation of the COD. OUR results indicated that the highest biodegradability is associated with the initial part of a storm event. The information on physical and biological processes in the sewer can be used to better manage sediment in sewers which can otherwise result in depletion of dissolved oxygen in receiving waters via discharges from CSOs.     

Exfiltration in sanitary sewer systems in the US

Many municipalities throughout the US have sewer systems (separate and combined) that may experience exfiltration of untreated wastewater. A study was conducted by the US Environmental Protection Agency (USEPA) to focus on estimating the magnitude of leakage of sanitary and industrial wastewater from sewer pipes on a national basis. The method for estimating exfiltration amounts utilized groundwater table information to identify areas of the country where the hydraulic gradients of the wastewater are typically positive, i.e. the wastewater flow surface (within pipelines) is above the groundwater table. An examination of groundwater table elevations on a national basis reveals that the contiguous US comprises groundwater regions (established by the US Geological Survey) that are markedly different. Many parts of the northeastern, southeastern, and midwestern US have groundwater tables that are higher than the wastewater flow surface, resulting in inflow or infiltration. Conversely, the combination of a relatively low groundwater table and shallow sewer systems creates the potential for widespread exfiltration, a situation more commonly found in communities located in the western US.