Characteristics of wet and dry weather heavy metal discharges in the Yeongsan Watershed, Korea

A comprehensive water quality monitoring program was conducted in the Yeongsan (YS) River, Korea from 2005 to present to investigate wet and dry weather pollutant discharge in an attempt to establish point and non-point pollution management strategies. As part of this monitoring program, 11 heavy metal species were measured during dry and wet weather conditions in the YS River, where Gwangju City (GJ), a subcatchment of the YS River, was further monitored to clarify the responsibility of different metal species discharged into the mainstream. Monthly grab water samples showed that greater amounts of metals along the YS River were discharged during the wet summer months due largely to storm runoff. In addition, further monitoring results revealed that GJ, a highly urbanized area, was a significant contributor of the heavy metals being discharged into the YS River during both wet and dry weather. The most abundant metal species discharged from GJ were manganese, aluminum and iron with different contributions of wet and dry weather flows to the total discharge load. Wet weather flow was a significant contributor to the annual dissolved metal loads, accounting for 44-93% of the annual load depending on the metal species, with the exception of chromium and cadmium (9% and 27%, respectively). Mostly, metal loads during wet weather were shown to be proportional to the rainfall depth and antecedent dry period. A substantial fraction of metals were also associated with solids, suggesting that sedimentation might be an appropriate management practice for reducing the metal load generated in GJ. Overall, although dissolved metal concentrations in YS River were at an acceptable level for aquatic community protection, continual metal discharge throughout the year was considered to be a potential problem in the long-term due to gradual water quality degradation as well as continuous metal accumulation in the system.     

A survey of heavy metals in municipal wastewater in combined sewer systems during wet and dry weather periods

During wet weather, combined sewer system overflows affect the quality of water in watercourses. For planning overflows, the lowest possible load of priority substances according to Directive 2008/105/EC is crucial and the knowledge of variability in concentrations of elements in the sewer system is necessary. The behaviour of heavy metals in a sewer system was observed in the course of dry weather flow (DWF) and wet weather flow (WWF). We found, from the comparison of concentration medians for the WWF and DWF that during wet weather periods, an increase in the concentrations of As, Cr, Cd, Pb, Mn and Fe occurs in the sewer system and the effect of nonpoint sources manifests itself. Zn, Cu and Ni concentrations decreased during wet weather periods, and Hg concentrations did not significantly change. During the WWF period, a considerable nonhomogeneity of the sewage system was demonstrated.     

The vertical distribution of some heavy metals in three recent sediment cores from the Western Nigerian continental shelf

Results of trace metal analyses of three shallow sediment cores from the Nigerian continental shelf show homogeneities with respect to the vertical distributions of Pb, Ni, Cr and Cu. However, surface enrichment of heavy metals which results from human activities particularly, from Lagos city, is recognised in the uppermost few centimeters in core 12 nearest to the entrance of Lagos harbour. Sediments below this surface enrichment zone, and in the entire lengths of the other two cores which are situated farther east of Lagos port, show heavy metal contents that are more or less constant in vertical distribution with depth.     

铅锌尾矿重金属释放影响因素的探讨

铅锌尾矿废渣若不经过处理,会通过风蚀、径流对环境造成重金属污染,对尾矿废渣污染的研究一直是大家关注的方向。多年来,pH被证实是影响重金属释放的重要因素。本文通过实验,研究了浸提方法、pH和盐度对铅锌尾矿废渣重金属元素释放的影响。结果表明,Pb、Zn、Cd、As在pH值呈酸性和碱性时浸出率都较高,Cu、Ni则在pH值为碱性时浸出率更高,盐度对Pb的释放影响效果更为明显。     

北京平谷西部矿集区附近土壤重金属特征

文章以平谷西部金属矿山及矿集区为研究区,采集土壤样品169个,开展区域土壤的重金属污染研究。采用X荧光光谱法、等离子原子发射光谱法等现代测试技术,分析了土壤中重金属(As、Hg、Cd、Cr、Zn、Cu、Pb、Ni)的含量;采用ArcGIS反距离权重插值数学模型和SPSS多元统计方法对土壤重金属空间分布及污染特征进行综合研究;运用潜在生态危害指数法进行生态风险评价。结果表明,研究区域土壤中重金属含量与背景值倍数大小依次是CdPbAsZnCuHgNiCr;重金属危害程度由大到小依次为CdAsPbHgCuNiZnCr;8种重金属潜在生态危害指数RI值在52.11～32 875.38之间。综上所述,研究区域的土壤重金属存在不同程度的风险。     

The chemical phase changes in heavy metals with drying and oxidation of the lake sediments

In order to understand the effects of oxidation on heavy metal behavior in sediments, the changes in chemical phase distributions of heavy metals with oxidation of sediments from Lake Teganuma were investigated using a sequential chemical extraction procedure for heavy metals.The exposure of sediments from the lake bottom to atmosphere caused the increase of Eh and the decrease of acid volatile-S in sediments. Most of the cadmium is expected to exist as relatively stable forms such as sulfides in original reduced sediments prior to exposure to the atmosphere. With the oxidation of sediments, Cd in the sulfidic/organic fraction were transformed to forms in the exchangeable and the reducible fractions which are easily dissolved. The chemical phase changes of Cu, Pb and Zn in sediments were less drastic than the case of Cd. Cadmium distinctly affected by the change in redox potential in sediments, and its behavior in the oxidized state is most mobile. Compared to Cd, the behavior of Cu and Pb are not so remarkably affected by the change in redox condition of sediments.     

Estimation of the mass-balance of selected metals in four sanitary landfills in Western Norway, with emphasis on the heavy metal content of the deposited waste and the leachate

A worst-case simulation of the mass-balance for metals in the waste deposited during 1 year and the levels of cadmium (Cd), lead (Pb), mercury (Hg), chromium (Cr) and iron (Fe) in the leachate was calculated for four sanitary landfills in Western Norway. Estimates of the levels of metal content in mixed municipal solid waste (MSW) were found by using recent literature values calculated in a mass-balance study at a Norwegian waste incinerator plant. Leachate from the landfills were sampled and analyzed monthly during 1 year, and from these measurements the total annual discharge of the selected metals through the leachate was determined. The levels of the measured heavy metals in the leachate were low. For Cd less than 0.06%, for Pb less than 0.01% and for Hg less than 0.02% of the estimated year's deposited mass of metals were leached from the landfills during the year of investigation. The high retention of these metals are most likely due to sulfide precipitation, but also due to the immobile condition of the metals in their original deposited solid state (plastics, ceramics, etc.). The percentage of Cr leached was relatively higher, but less than 1.0% per year. The mass balance of Fe suggests that this element is more mobile under the prevailing conditions. The percentage of Fe leached varied and was estimated to be between 1.9% and 18%. The present study clearly supports the theory that MSW only to a small extent will lead to discharge of metals if deposited at well-constructed sanitary landfills with top layers.     

Constructed wetlands for stormwater management in the UK: a concise review

The use of constructed wetlands (CWs) for stormwater management is growing due to the need for sustainable water use and to prevent damage to local watercourses caused by the pollutants collected and transported by runoff. However, despite their increased use around the world, there is a lack of information regarding the use of CWs for stormwater management in the UK. This study reviews the application of CW systems for stormwater management in the UK by examining the design, treatment performance and challenges associated with their use, while drawing comparisons with the rest of the world. The review indicates that although CWs have the potential for cost-effective and efficient stormwater management in the UK, there are several challenges that must be overcome to allow their widespread implementation. These include (i) a lack of design codes and unified guidelines; (ii) ambiguities regarding drainage responsibilities and land use issues and (iii) land availability.     

Transfer of heavy metals in the food chain earthworm Black-tailed godwit (Limosa limosa): comparison of a polluted and a reference site in The Netherlands

The Black-tailed godwit (Limosa limosa) is a migratory wader that favours wet meadows for breeding. The species has a Red List status in The Netherlands, as it strongly declined in numbers since the 1960s. Intensification of agriculture and land use change resulting in habitat loss are considered major causes of this decline. In some areas the breeding habitat is contaminated with heavy metals. Adult godwits mainly feed on earthworms in the breeding season, which are known to accumulate heavy metals from the soil. In this paper we investigate the transfer of heavy metals from the soil to the Black-tailed godwit, which may have an additive negative effect on the viability of local populations. We measured heavy metal concentrations in soil, earthworms, and godwit eggs and feathers at a polluted and a reference site. The results suggest that Lead, Mercury and Cadmium are transferred from the soil to godwits even though the species spends only a few months in the breeding area during the year.     

Effect of untreated urban effluents on the accumulation of toxic metals in river sediments under tropical conditions: Funa River,Kinshasa, Democratic Republic of the Congo

The objective of the present study was to assess the status of surface sediments from Funa River. Sediment samples were characterized for physicochemical parameters, including grain size, organic matter and toxic metals. The result revealed high metal concentrations in river sediments, reaching values of 154.19, 186.00, 1105.34, 3.69, 548.02 and 5.45 mg/kg for Cr, Cu, Zn, Cd, Pb and Hg, respectively. A strong correlation was observed between analysed metals and organic matter suggesting that these contaminants could have originated from common sources with a similar transport pathway. Based on the Sediment Quality Guidelines for the Protection of Aquatic Life, Funa River is considered as highly polluted with toxic metals indicating the potential environmental and human health risk. The results of this research represent a useful tool to assess the sediment quality of urban river receiving system which can be applied to similar environment.     

Source identification of heavy metals in sewage sludge and the effect of influent characteristics: a case study from China

To advance the reclamation of sewage sludge and evaluate the potential risk during sludge application, wastewater and sludge were sampled from seven secondary wastewater treatment plants seasonally in 2016 and 2017. The influent characteristics and the accumulation of eight toxic heavy metals in sludge were analyzed. According to the results, copper, chromium, nickle and zinc were the main heavy metals constraining reclamation of sewage sludge in Shanghai and they were mainly from domestic wastewater. Influent concentration, treatment process and coexisting elements had significant effects on accumulation of heavy metals in sludge. Lead concentration in sludge from AAC plants was generally higher than that from AAO plants, but for other metals the differences were insignificant or depended on the initial concentrations. Nutrients, suspended solids and coexisting heavy metals had significant effects on heavy metal accumulation in sludge when the initial concentration was controlled.     

Quantification of stormwater runoff using a combined GIS and curve number approach: a case study for an urban watershed in the Ozark Highlands,USA

Managing stormwater runoff is crucial to preserving water quality in rapidly developing urban watersheds. The objective of this study was to develop a methodology to test existing stormwater drainage infrastructure, identify potential areas of improvement, and estimate potentially contaminated runoff by combining two widely used stormwater runoff prediction models. A watershed containing much of the University of Arkansas-Fayetteville campus was targeted for this study because stormwater from this watershed drains into a local river designated as an impaired water body due to siltation. The curve number method was used to estimate runoff for various flood-return periods and antecedent moisture conditions, while a flow-direction model integrated topography, land use, and stormwater drainage infrastructure in a GIS. The methodology developed and results generated will help stormwater planners visualise localised runoff and potentially adapt existing drainage networks to accommodate runoff, prevent flooding and erosion, and improve the stormwater quality entering nearby surfacewater bodies.     

Impact of urbanization on the quality of water in a natural reservoir: a case study with the Deepor Beel in Guwahati city,India

The Deepor Beel is a natural, freshwater wetland in the south-west corner of Guwahati, India. The Beel harbours a large number of migratory aquatic birds, especially in winter, and is a Ramsar site since 2002. The wetland provides livelihood to the people of the surrounding villages through collection and sale of fish, nymphaea nuts and flower, ornamental fish, orchids, medicinal plants, etc. The water quality of the Beel is threatened by excessive fishing, hunting of water birds, pollution from pesticides and fertilizers and infestation by water hyacinth. The present work reports on the water quality of the wetland by continuous monitoring from February to July, covering the dry, temperate period and the wet, hot and humid period. Sampling was carried out at 10 sites for physical and aggregate properties, metallic and nonmetallic constituents, organic contaminants and microbiological parameters.     

The effects of environmental factors on the patient outcomes in hospital environments:A review of literature

This study investigates the evidence supporting the impact of the built environment on the health outcomes for patients within the hospital setting. Improving the hospital environment may potentially impact the lives of millions of patients, patients' family, and staff. Prior research has suggested that the built environment can contribute to positive health outcomes. Reporting the most recent evidence may assist designers in making informed decisions. In this study, a literature review was conducted using the PICO framework within scientific databases and additional hand-searched documents. A total number of 15 articles were included. Effects of each environmental factor on patients' health outcomes were discussed in detail. Environmental factors that affect patient outcomes are (1) form, (2) unit layout, (3) floor material, (4) room features, (5) medical equipment visibility, (6) nature, (7) lighting, and (8) music. Although several studies have provided a high level of evidence, other studies have lacked a robust research design. Thus, evidence regarding several environmental factors is not conclusive. Additional studies using experimental/quasi-experimental research design have been suggested. In some studies, several environmental factors were introduced simultaneously which obscured the separate effects of each environmental factor.     

The effects of reduction of the deposited waste on short‐term landfill leachate composition of a landfill: a case study in Norway

Municipal solid waste landfill leachate was sampled over from a landfill receiving varying amounts of municipal solid waste. The investigation aimed to provide information on expected leachate changes in the short term, either after closure of an active landfill, or after a strong decline in the amount of waste deposited at smaller landfills. It was found that during a two year period following a sudden decline in the amount of waste deposited, the levels of various chemical and physical parameters all dropped sharply. The reasons for the decline in discharge levels are thought to be aerobic decomposition taking place in the municipal solid waste just after landfilling, and thus the decline in the impact of this process when there were less fresh waste masses available, and formation of preferential flow paths for the leachate as the municipal solid waste stabilized in the landfill.     

Influence of eco‐hydrological factors on aquatic plant succession in a regulated river: a case study of the Petchburi River,Thailand

Monitoring of aquatic plant biomass in the Petchburi River, a regulated river system in Thailand, was carried out together with the examination of eco‐hydrological characters and the sedimentary organic content. The surveys were performed during May, August and November of 2010 and 2011. The results indicated temporal variation in water velocity (0.08–2.51 m/s) and medium to low organic levels (0.58–4.68%) of the benthic substrates. Dominant aquatic plants were Hydrilla verticillata (L.F.) Royle and Potamogeton malaianus Miq. with the highest biomass of 70.84 and 182.72 g/m², respectively. The biomass was substantially decreased during the flood‐induced discharge period. This study indicates that Potamogeton has more adaptive potential to high water velocities than Hydrilla, while Hydrilla prefers lower water velocities. Discharge velocities of less than 0.5 m/s could provide positive growth rates of such submerged plants. Approaching the discharge control from this ecological point of view can further contribute to river habitat conservation.