陶瓷材料断裂韧性的测量标准刍议

现行的陶瓷材料断裂韧性测试方法有多种,其中常用的是单边预裂纹梁法（SEPB）和单边V型切口梁法（SVENB）。本文比较了采用SEPB法和SEVNB法测量断裂韧性的三种标准（国际标准化组织ISO 23146、美国材料与试验协会ASTM C1421和中国国家标准GB/T 23806）的异同。三种标准在试样规定、加载测试和结果计算方面差异不大,不同形状因子计算相对差值低于1%。现行国标因采用非国际基本单位mm会造成断裂韧性计算结果错误,需要经过校正系数k修订后,才能获得正确的断裂韧性值（MPa·m0.5）。     

激光切口法测量ZrB2–SiC–Graphite陶瓷的断裂韧性EI北大核心CSCD

采用纳秒激光在ZrB2-SiC-Graphite(ZSG)陶瓷材料中引入了尖锐的V型切口,切口尖端半径小于1μm。通过单边V型切口梁法测得ZSG陶瓷材料的断裂韧性为3.88MPa·m^1/2,与单边预裂纹梁法结果吻合,表明激光切口法的有效性。研究了断裂韧性与激光切口深度和试样厚度比值(a/W)的关系,对于ZSG陶瓷,试样的a/W取值范围为0.1~0.6时能获得准确的断裂韧性值。     

高红外辐射陶瓷材料的研究进展

简要概述了红外陶瓷材料的辐射机理,探讨了提高红外陶瓷材料辐射率的途径,综述了高红外辐射陶瓷材料的研究现状,并对高红外辐射陶瓷材料的应用及发展趋势进行了展望.     

基于空气耦合超声波的非金属陶瓷材料检测研究

针对非金属陶瓷材料的空气耦合超声波检测问题,建立空气耦合超声波经空气入射非金属陶瓷材料的数学模型及非金属陶瓷材料的空气耦合超声波检测有限元模型,通过matlab软件和ANSYS有限元软件联合仿真得到了非金属陶瓷材料的空气耦合超声波检测的频散曲线和各节点的接收信号,研究了空气耦合超声波在非金属陶瓷材料中的传播特性.结果表明,当频厚积小于2 MHz· mm,空气耦合超声波在非金属陶瓷材料氮化硅材料中存在A0,S0,SH0三种模态;当频厚积大于2 MHz· mm时,材料中存在较多的模态.随着声波传播距离越远,所接收到的A0模态和S0模态的信号幅值越小,且A0模态较S0模态幅值大,因此宜激发A0模态的空气耦合超声波检测和评价非金属陶瓷材料.     

金属间化合物增韧陶瓷材料的效果与机理

金属间化合物作为结构材料近几年倍受众多研究者重视,但作为第二相物质与结构陶瓷形成复合材料的研究却相对较少.本文是一篇关于金属间化合物增韧陶瓷的综述文章,对重要的金属间化合物如Ni3Al,MoSi2等的性能特点,用其增韧Al2O3,Si3N4等陶瓷材料的效果、机理作了重点分析、评述.     

基于数据库的陶瓷材料计算机辅助设计

根据已知文献的数据建立了陶瓷材料性能和组分数据库 ,开发了管理和操纵该数据库的应用程序 ,利用该程序可以查询已知陶瓷材料系统性能与组分的关系 ;建立了基于该数据库的人工神经网络预测模型 ,通过操纵陶瓷材料数据库中相关数据 ,并结合人工神经网络预测模型程序可以预测未知材料系统在给定性能条件下的各相组分 ,预测了Al2 O3 (W ,Ti)C陶瓷材料在两种目标性能下的组分 ,并计算了其预测误差 ,结果表明 ,其实验值与预测值较为吻合。     

陶瓷材料加工表面完整性及其对材料可靠性的影响

采用磨削-抛光加工、金刚石锯片切割加工、超声波加工和电火花线切割加工技术对Al2O3/TiC陶瓷材料进行加工.研究了各加工方法对陶瓷材料的加工表面完整性及其可靠性的影响.结果表明:加工方法对陶瓷材料加工表面完整性和可靠性有很大的影响.磨削-抛光加工的陶瓷试样表面粗糙度小,硬度高,抗弯强度及其可靠性最高.金刚石锯片切割加工和超声波加工次之;电火花加工陶瓷试样表面粗糙大,硬度低,抗弯强度及其可靠性最低.电火花加工陶瓷表面产生一硬度低且表面粗糙的约8μm厚的热影响层,加工表面含有大量的电火花腐蚀凹坑,随电流的增大,电火花加工陶瓷试样的抗弯强度及其可靠性降低.超声波加工陶瓷试样的表面完整性与磨料粒度有关,随磨料粒度的减小,陶瓷试样的抗弯强度及其可靠性增加.     

增硬加强堇青石陶瓷材料的研究

采用粘土、滑石、氧化铝为主要原料合成的堇青石作为基相,加入适量复合添加剂,使堇青石陶瓷材料达到致密烧结,并使其抗折强度和硬度大幅提高.     

基于分形理论的陶瓷材料显微组织模拟

利用VB开发工具,开发出基于二维和三维系统单相、复相陶瓷材料显微组织及其演变的仿真模拟软件,其主要包括三个模块:二维系统仿真模块、三维系统仿真模块和显微结构定量分析模块;可实现二维和三维的显微组织仿真图像输出,并且可方便地观察空间任意角度截面显微组织及其演变;应用分形理论、拓扑学等方法,对显微结构进行了定量分析,得到晶粒数及平均体积等参数与仿真时间MCS的变化关系。     

基于激光切割的Si3N4陶瓷断裂韧性测试方法

提出一种采用激光切割技术在Si3N4陶瓷表面预制微小切口,并结合SENB法测定陶瓷材料断裂韧性的新方法。利用连续激光束在陶瓷表面加工出切口,在三点弯曲实验前后分别运用激光共聚焦显微镜(LSCM)和扫描电镜(SEM)测量切口宽度和深度,而后计算陶瓷材料断裂韧性。在此基础上分析激光输出功率P、激光辐照光斑直径D和激光切割速率Vw与材料断裂韧性值的内在联系。结果表明:输出的激光能量密度达到陶瓷切割加工阈值后,光束在试件表面制得对应切口;切口深宽比为4.3～4.8时测得的Si3N4陶瓷断裂韧性值具有较高精度。     

Evaluation of Fracture Toughness for Ceramic Materials by a Single-Edge-Precracked-Beam Method

As a substitute for the fatigue-cracked-beam method prescribed in ASTM E399 A2, a recently devised precracking method was applied to the evaluation of fracture toughness of ceramic materials. Straight-through precracks proved to be easily introduced into rectangular beams of several ceramic materials. This method gives K_ic values almost identical with those of the fatigue-cracked-beam method. The K_ic values are almost constant over wide ranges of the pop-in precrack length and the loading rate of the three-point bend test. The test can be easily performed even at elevated temperatures although its validity should be further examined.     

Mixed-Mode Fracture Toughness of Ceramic Materials

An experimental technique whereby pure mode I, mode II, and combined mode I-mode II fracture toughness values of ceramic materials can be determined using four-point bend specimens containing sharp, through-thickness precracks is discussed. In this method, notched and fatigue-precracked specimens of brittle solids are subjected to combined mode I-mode II and pure mode II fracture under asymmetric four-point bend loading and to pure mode I under symmetric bend loading. A detailed finite element analysis of the test specimen is performed to obtain stress intensity factor calibrations for a wide range of loading states. The effectiveness of this method to provide reproducible combined mode I-mode II fracture toughness values is demonstrated with experimental results obtained for a polycrystalline Al₂O₃. Multiaxial fracture mechanics of the Al₂O₃ ceramic in combined modes I, II, and III are also described in conjunction with the recent experimental study of Suresh and Tschegg (1987). While the mode II fracture toughness of the alumina ceramic is comparable to the mode I fracture toughness K _Ic, the mode III fracture initiation toughness is 2.3 times higher than K _Ic. The predictions of fracture toughness and crack path based on various mixed-mode fracture theories are critically examined in the context of experimental observations, and possible effects of fracture abrasion on the apparent mixed-mode fracture resistance are highlighted. The significance and implications of the experimental methods used in this study are evaluated in the light of available techniques for multiaxial fracture testing of brittle solids.     

Effect of Indenter Geometry on Controlled-Surface-Flaw Fracture Toughness

Fracture toughness values obtained using both Knoop and Vickers-indentation-produced controlled surface flaws were compared as a function of indentation load for a well-characterized glass-ceramic material. At the same indentation load, Knoop cracks were larger than Vickers. As-indented K_c values calculated from fracture mechanics expressions for surface flaws were higher for Knoop flaws than Vickers, but both types gave low K_c values due to indentation residual stress effects. Analysis suggested that theoretical formalisms for indentation residual stress effects based on fracture mechanics solutions for a center-loaded penny crack in an infinite medium should apply to both indentation types. K_c values calculated using the residual stress approach were identical for Knoop and Vickers controlled surface flaws when a "calibration" value for a constant term in the expression for K_c was used for both indentation types.     

Indenter Flaw Geometry and Fracture Toughness Estimates for a Glass-Ceramic

Shapes of cracks associated with Vickers indenter flaws in a glass-ceramic were assessed by stepwise polishing and measuring surface traces as a function of depth. The cracks were of the Palmqvist type even at200-N indentation load. The toad dependence of crack lengths and fracture toughness estimates were examined in terms of relations proposed for Palmqvist and half-penny cracks. Estimates based on the half-penny crack analogy were in closer agreement with bulk fracture toughness measurements despite the Palmqvist nature of the cracks.     

压力容器材料断裂韧性值的估算方法

断裂韧性值KIC是评定材料安全性能的主要参数,寻找KIC的估算方法就显得非常有必要。利用估算方法,既能减少断裂韧性试验的费用,又能取得评价所需要的参数值。本文简述了压力容器材料在几种不同环境下的断裂韧性值的估算方法,使得一些缺陷材料在不能通过实验获得其断裂韧性值的情况下利用估算方法间接获取,为压力容器设备的安全评定提供了方便。     

Fracture Toughness Measurement of Glass and Ceramic Materials Using Chevron-Notched Specimens

Fracture toughness of several different materials was measured using chevronnotched short bar and four-point bend specimens For glass-ceramic and ceramic samples both specimens gave valid results. Fracture toughness values measured with bend specimens are 5% to 10% higher compared to those of the short bar. Consistent results for glass could be obtained only with short bar specimens. The notch width of the bend specimen affected the stability of crack growth in glass samples. Fracture toughness values measured in the present study are in good agreement with those of the previous studies.     

Measurement of the Fracture Toughness of Ceramic Materials Using a Miniaturized Disk-Bend Test

The fracture toughness of several ceramic materials has been measured using a miniaturized disk-bend test apparatus and methodology based on small disk-shaped samples 3 mm in diameter. The method involves the Vickers indentation of specimens ranging in thickness from 300 to 700 μm, and testing them in a ring-on-ring bending mode. New experiments on a glass-ceramic (GC) and Si₃N₄ have been performed to demonstrate the validity of the technique, supplementing the original work on ZnS. The fracture resistances of these materials increase with increasing crack length ( R -curve behavior). The data are analyzed using a specific model for the relationship between fracture resistance and crack length; this model enables the R -curve behavior to be treated analytically, and the fracture resistance at "infinite" crack length to be evaluated using a straightforward graphical procedure. The resulting values of the fracture toughness for ZnS, GC, and Si₃N₄ are 0.74 ± 0.02, 2.18 ± 0.09, and 4.97 ± 0.07 MPa-m^1/2, respectively, which are all in very good agreement with values obtained from conventional fracture toughness tests on large specimens. The results verify the utility of the miniaturized diskbend method for measuring the fracture toughness of brittle materials.     

Fracture Toughness of Ceramic Precracked Bend Bars

Fracture toughness was measured for four ceramic materials using precracked bend bar specimens. The effect of the precracking parameters, used for the bridge indentation method on fracture toughness values, was determined. Excellent agreement was obtained between fracture toughness values measured by this method and values obtained by other techniques.     

Effective Fracture Toughness of Microcracked Materials

Explicit analytical formulas are derived for the stress intensity factors at the tips of a main crack and of a microcrack for the two-dimensional case of a collinear microcrack. This configuration is used to derive an estimate of the toughness degradation due to microcracks linking up with an advancing main crack. The implications of this estimate for theoretical predictions of the toughening due to stress-induced micro-cracking are discussed.