共查询到19条相似文献,搜索用时 109 毫秒
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研究了天然橡胶(NR)和乙丙橡胶(EPDM)共混制备浅色胶料的力学性能、耐老化和耐臭氧性能,同时采用弹性体PNE增容NR/EPDM共混胶。结果表明:在NR中并用EPDM,随着EPDM用量的增加,NR/EPDM共混胶力学性能有所降低,耐臭氧老化性能和耐热空气老化性能提高;使用一定量增容剂PNE替代EPDM能明显改善NR/EPDM共混胶的力学性能和耐屈挠性能;通过对比不同PNE用量共混胶的SEM图像可以看出使用PNE后材料界面变得模糊,通过动态力学性能分析可知,在NR/EPDM共混胶中加入增容剂后损耗因子的两个tanδ峰值逐渐靠近,当PNE的份数为40时tanδ峰值由两个变为一个,界面的模糊和tanδ峰值的减少说明增容剂改善了两种橡胶的相容性。 相似文献
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试验研究硅烷偶联剂种类和用量以及复合材料制备方法对纳米四氧化三铁/NR复合材料物理性能的影响.结果表明,硅烷偶联剂可有效地对纳米四氧化三铁表面进行改性;透射电子显微镜、扫描电子显微镜和红外光谱分析结果表明,偶联剂Si69的改性效果较好,增强了纳米四氧化三铁/NR复合材料的界面作用,促进了纳米四氧化三铁粒子在NR中分散,改善了复合材料的结构和性能;当偶联剂Si69用量为2.25份时,纳米四氧化三铁/NR复合材料的综合物理性能最好.与机械共混法和磁流体-凝胶法相比,乳液共凝法制备纳米四氧化三铁/NR复合材料的物理性能较优. 相似文献
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制备改性煅烧高岭土/炭黑/天然橡胶(NR)/顺丁橡胶(BR)/三元乙丙橡胶(EPDM)复合材料,并对其性能进行研究。结果表明:改性煅烧高岭土对NR/BR/EPDM并用胶具有一定的补强作用,添加适量改性煅烧高岭土可使复合材料具有良好的拉伸强度、电绝缘性能和耐热老化性能;以复合材料制备的动车组车钩支撑装置具有良好的刚度和耐压性能以及较长的使用寿命。 相似文献
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采用偶联剂Si69对三氧化二钇进行表面改性,研究改性三氧化二钇对NR/BR并用胶的补强效果.红外光谱和热重分析表明,在改性三氧化二钇的表面键合了偶联剂Si69;改性三氧化二钇/NR/BR复合材料的拉伸强度和拉断伸长率比未改性三氧化二钇/NR/BR复合材料明显提高;扫描电子显微镜观察发现,改性三氧化二钇在橡胶基体中分布均匀,与橡胶的相容性很好。 相似文献
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研究了纳米SiO2加入方式及用量对NR/SBR共混胶的正硫化时间、力学性能的影响,并研究了纳米SiO2改性前后共混胶的耐热分解性能、耐热空气老化性能及微观形态结构.结果表明:纳米SiO2的加入对共混胶的正硫化时间、力学性能及耐热稳定性能有较大影响;当纳米SiO2加入量为7%(质量分数)并采用NR/SBR共混均匀后先加入纳米SiO2,再加入小料、硫磺的方式制备NR/SBR共混胶时,纳米SiO2通过使NR/SBR共混胶的分散相细化并使共混胶的整体交联密度提高,有效地提高了NR/SBR共混胶的综合力学性能和耐热稳定性能,达到了对NR/SBR共混胶良好的补强改性效果. 相似文献
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采用硫载体硫化剂4,4′-二硫化二吗啉(DTDM)对三元乙丙橡胶(EPDM)进行活性预处理,研究了活性预处理EPDM/天然橡胶(NR)并用胶的性能,并探讨了活性预处理EPDM对并用胶力学性能影响的机理。结果表明,预处理EPDM/NR并用胶的共硫化程度得到改善,并用硫化胶的力学性能提高;并用硫化胶的耐老化性能优于NR硫化胶,但比未处理EPDM/NR并用硫化胶差;并用胶只存在1个玻璃化温度的转变区,两相的相容性得到改善;在高温动态条件下,EPDM与DTDM发生活性反应,但未生成大量凝胶。 相似文献
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Changes in tensile properties, sample size, interfacial strength, and thermal conductivity of melt‐laminating layers of wood/ebonite natural rubber (NR) and expanded ethyelene–propylene diene rubber (EPDM) for polymeric roofing applications were monitored under a period of UV aging times for 60 days, the results being compared with single rubber layers of wood/NR and expanded‐EPDM. The experimental results suggested that the tensile modulus of the wood/NR‐EPDM melt‐laminating layer increased with increasing aging time. The tensile strength of the wood/NR layer decreased after prolonged UV aging, and positioned between that of the wood/NR and expanded‐EPDM layers. The sample size reduction of wood/NR layer with expanded‐EPDM top coating layer was lower than that for wood/NR single layer. The peel strength of the wood/NR‐EPDM melt‐laminating layer was found to decrease with increasing UV aging time as a result of delamination of the rubber layers. The thermal conductivity of the wood/NR‐EPDM melt‐laminating layer decreased from 0.085 to 0.070 W/m K with increasing aging times upto 40 days, but tended to increase to 0.080 W/m K at the aging time of 60 days. The experimental results in this work clearly suggested that expanded‐EPDM could be used as protecting layer, not only for moderation of photo‐oxidative degradations of wood/NR layer for roofing application, but also for minimization of dimension changes of the wood/NR‐EPDM melt‐laminating layer. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 相似文献
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用甲基丙烯酸锌原位聚合改性纳米氮化硅,再将改性纳米氮化硅填充到三元乙丙橡胶中以制备纳米橡胶复合材料,研究了复合材料的基本力学性能、耐热老化性能、耐油性能和耐磨性能等。结果表明,添加改性的纳米氮化硅在一定程度上提高了三元乙丙橡胶的撕裂强度、扯断伸长率和拉伸强度,邵尔A硬度也小幅上升。当改性纳米氮化硅的添加量为1.0份(质量)时,纳米氮化硅/三元乙丙橡胶复合材料的耐热老化性能和耐油性能有一定程度的提高,其综合性能也达到最佳。用甲基丙烯酸锌原位聚合改性可以改善纳米氮化硅与三元乙丙橡胶基质间的界面作用,提高其在三元乙丙橡胶中的分散效果。 相似文献
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<正>天然橡胶(NR)和丁苯橡胶(SBR)常用作轮胎胎面胶的主体材料,而轮胎胎侧胶是贴覆于外胎侧壁表面的覆盖胶层,起着保护帘布层免受潮湿、大气作用及机械损伤等,一般要求胎侧胶料具有耐曲挠疲劳、耐臭氧老化等性能。 相似文献
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The viscoelastic properties of the blends of chloroprene rubber (CR) with ethylene–propylene–diene monomer rubber (EPDM), polybutadiene rubber (BR), and natural rubber (NR) at different temperature were studied using rubber processing analyzer (RPA). Mooney viscosities of compounds were measured and tight milling and sheeting appearance were observed on a two‐roll mill. The results showed that Mooney viscosities and the elastic modulus of the blends decreased with the increase of the temperature from 60 to 100°C. And the decreasing trends of pure CR, pure NR, and CR/NR blend compounds were more prominent than that of pure EPDM, pure BR, CR/EPDM, and CR/BR blend compounds. For CR/EPDM blend compounds, the decreasing trend became slower with the increase of EPDM ratio in the blend. Compared with pure CR, pure NR and CR/NR blend compounds, pure EPDM, pure BR compounds, and the blend compounds of CR/EPDM and CR/BR showed less sensibility to temperature and they were less sticky to the metal surface of rolls and could be kept in elastic state at higher temperature, easy to be milled up and sheeted. At the same blend ratio and temperature, the property of tight milling of the blends decreased in the sequence of CR/EPDM, CR/BR, and CR/NR. With the increase of EPDM, BR, or NR ratio in CR blends, its property of tight milling was improved. POLYM. COMPOS., 28:667–673, 2007. © 2007 Society of Plastics Engineers 相似文献
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Comparative studies of the thermogravimetric analysis and thermo‐oxidative aging of (natural rubber)/(waste ethylene‐propylene‐diene monomer terpolymer) (NR/W‐EPDM) and (natural rubber)/(ethylene‐propylene‐diene monomer terpolymer) (NR/EPDM) blends were carried out. The blends were prepared at five different blend ratios (90/10, 80/20, 70/30, 60/40, and 50/50) on a two‐roll mill. As the pure EPDM or W‐EPDM content in the blends increased, their thermal stability also increased. The thermo‐oxidative aging of these blends was done at 100°C for 48 h. Afterwards, the NR/EPDM blends exhibited better retention of properties than the NR/W‐EPDM blends. Crosslink density measurements of the blends after thermal aging indicated that higher crosslink density was obtained from a higher content of EPDM or W‐EPDM, a result which might be due to the high rate of radical termination leading to crosslinks in the bulk of the polymer. J. VINYL ADDIT. TECHNOL., 20:99–107, 2014. © 2014 Society of Plastics Engineers 相似文献