共查询到20条相似文献,搜索用时 15 毫秒
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从五个方面综述了银在Bi-Pb-Sr-Ca-Cu-O系(BPSCCO)超导体中的作用及应用,包括:(1)银与铋系超导体的基本复合方式;(2)银与Bi-Pb-Sr-Ca-Cu-O系的物理化学作用;(3)银复合对铋系超导相生长的影响;(4)银复合对铋系超导体超导电性的影响,(5)银复合对铋系超导体材料力学性能的影响。 相似文献
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Tuo Wu Yanling Zhang Fang Yuan Zhuoqing An 《Metallurgical and Materials Transactions B》2018,49(4):1719-1731
The present study experimentally investigates the effect of Cr2O3 on the viscosity of molten slags. The viscosities of CaO-SiO2-10 pct Al2O3-Cr2O3 quaternary slags with two different binary basicities (R, basic slag with R = 1.2 and acidic slag with R = 0.8) were measured by the rotating cylindrical method from 1813 K to 1953 K (1540 °C to 1680 °C). The results showed that the viscosity of both types of slag decreased as the Cr2O3 content increased, but the viscosity of acidic slags exhibited a greater decrease. The slags showed good Newtonian behavior at such high temperatures. Cr2O3 could act as a network modifier to simplify the Si-O-Si tetrahedral structure, as verified by the Raman spectral analysis, which was consistent with the decreasing trend of viscosity. The activation energy of viscous flow decreased slightly with increasing Cr2O3, but increasing the basicity seemed to be more effective in decreasing the viscosity than adding Cr2O3. 相似文献
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研究了新显色剂 1 (8 氨基喹啉 5 偶氮 ) 8 羟基 3 ,6 萘二磺酸 (简称AQAHNA)与铜 (Ⅱ )的显色反应条件。在Tween 80存在下 ,pH5 0的乙酸 乙酸钠缓冲溶液中 ,AQAHNA与铜形成 2∶1的红紫色络合物 ,其最大的吸收峰位于5 90nm ,表观摩尔吸光系数 (ε)为 8 7× 10 4 。铜浓度在 0~ 0 4mg/L范围内遵守比尔定律。该方法用于铝合金中铜的测定 ,结果满意。 相似文献
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Y. Kaida M. Hasegawa M. Iwase Y. Kikuchi K. Wakimoto 《Metallurgical and Materials Transactions B》2005,36(1):43-51
An experimental technique was applied for simultaneous determinations of the activities of P2O5 and FexO in slags. With this technique, phosphorus-containing liquid copper was heated inside an iron crucible at temperatures below
1600 K. When copper is melted, the iron crucible dissolves into liquid copper, to a small extent, to form ternary {Cu-Fe-P}
liquid alloy, while 〈Cu-Fe-P〉 solid solutions are formed on the inner wall of the iron crucible. Slags containing tri-calcium
phosphate were then brought into equilibrium with {Cu-Fe-P} liquid alloy. By measuring the equilibrium oxygen partial pressures
with the aid of a zirconia electrolyte cell, activities of P2O5 and FexO were obtainable. Between 1553 and 1593 K, the P2O5 activities could be expressed as
The activities of P2O5 and FexO thus obtained were thermodynamically consistent with those deduced from the phase diagram. 相似文献
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Silicate slag system with additions Nb and RE formed in the utilization of REE-Nb-Fe ore deposit resources in China has industrial uses as a metallurgical slag system. The lack of a phase diagram, theoretical, and thermodynamic information for the multi-component system restrict the comprehensive utilization process. In the current work, solid phase equilibrium relations in the CaO-SiO2-Nb2O5-La2O3 quaternary system at 1273 K (1000 °C) were investigated experimentally by the high-temperature equilibrium experiment followed by X-ray diffraction, scanning electron microscope, and energy dispersive spectrometer. Six spatial independent tetrahedron fields in the CaO-SiO2-Nb2O5-La2O3 system phase diagram were determined by the Gibbs Phase Rule. The current work combines the mass fraction of equilibrium phase and corresponding geometric relation. A determinant method was deduced to calculate the mass fraction of equilibrium phase in quaternary system according to the Mass Conservation Law, the Gibbs Phase Rule, the Lever’s Rule, and the Cramer Law. 相似文献
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江阴兴澄钢铁有限公司炼钢、精炼、连铸、连轧四位一体特殊钢生产线的全套设备由德国DEMAG公司总承包,主要从德国DEMAG和SKET引进,是一整套具有90年代先进水平的全新装备,设计年产量:钢为65万t、材为60万t.主要设备有:100 t超高功率直流电弧炉、100 t LF钢包精炼炉、100 t VD真空脱气炉、5流弧形大方坯连铸机、16机架全连轧机组.整条四位一体生产线从南到北全长600 m,总投资近20亿元,主体设备总重量1 2000多吨. 相似文献
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在pH2.4~3.5的酸性介质中及加热条件下,钼(VI)与2-(3,5一二溴-2-吡啶偶氮)-5-二乙氨基苯酚(3,5-diBr-PADAP)及羟胺反应形成一种稳定的蓝色络合物,组成比为1:1:1。在十二烷基硫酸钠存在下,其最大吸收波长为6l8nm,表现摩尔吸光系数为4.8×l0 ̄4,钼含量在0~25μg/10ml时服从比尔定律。毫克量钨无干扰。铜、钴、镍、铁等高厂的干扰可通过离厂交换分离除去。本法用于测定软磁合金中的铝,获得了满意的结果。 相似文献