Retention and leaching of N in Norwegian coniferous forests

Nitrogen is brought into natural ecosystems from the atmosphere through N-fixation and deposition of NH ₄ ⁺ and NO ₃ ^- as wet and dry deposition. N is lost from terrestrial ecosystems unaffected by human activities by leaching or as gas, but the losses from different forest-and vegetation types are poorly quantified. The leaching is hampered by uptake in the vegetation and by immobilisation by soil organisms. The gas loss of N in the form of N₂O and N₂ appears to be rather small, but the loss of NO is unknown. Human activities such as those leading to the increased atmospheric dry and wet deposition of N, may affect the N-losses, but the increase in losses are likely to be very dependent on the amounts of N deposited. The present paper discusses the fate of the N deposited under the existing pollution climate in Norway where N deposition above the natural background has taken place for at least 50 years. The deposition today varies from about 15–20 kg N ha^-1 yr^-1 in the southernmost parts of the country to background values of about 2 kg ha^-1 yr^-1 in the north. Even in areas with the highest loads there are no clear indications that N-leaching in forest ecosystems has increased to unacceptable levels. The main reason for this appears to be that most of the N deposited are immobilised in forest soils and utilised by forest trees and ground cover vegetation to increased biomass production. At present therefore, no clear signs of N-saturation can be found. This is in relatively good accordance with estimates of critical loads for N in Norwegian coniferous forests. Estimates of immobilisation, gas losses, net uptake in vegetation, biological fixation as well as a figure for acceptable leaching, indicate that the long-term critical load of N might be of the order 10 to 30 kg N ha^-1 yr^-1. Most of the N deposited from the atmosphere appears therefore so far to be retained in the forests and only a small proportion seems to be lost to ground-and surface waters.     

Simulation of nitrogen in soil and winter wheat crops: Modelling nitrogen turnover through organic matter

A computer model is described that simulates leaching, organic matter turnover and nitrogen uptake by a winter wheat crop. The model is assessed against a data set from the Netherlands where winter wheat was grown in two seasons (1982–3 and 1983–4) on three different soils in two different parts of the country. The model satisfactorily simulated the growth, N uptake and production of grain. It also simulated the dynamics of indigenous soil N well but it did not always account for the fate of applied fertilizer N. Some possible reasons for this and ways of improving the model are discussed.     

Nitrogen-15 balances and nitrogen fertilizer use efficiency in upland rice

Field experiments were conducted in the 1984 and 1985 wet seasons to determine the effect of N fertilizer application method on¹⁵N balances and yield for upland rice (Oryza sativa L.) on an Udic Arguistoll in the Philippines. The test cultivars were IR43 and UPLRi-5 in 1984 and IR43 in 1985. Unrecovered¹⁵N in¹⁵N balances for 70 kg applied urea-N ha^–1, which represented N fertilizer losses as gases and movement below 0.5 m soil depth, ranged from 11–58% of the applied N. It was lowest (11–13%) for urea split applied at 30 days after seeding (DS) and at panicle initiation (PI), and highest (27–58%) for treatments receiving basal urea in the seed furrows. In all treatments with basal-applied urea, most N losses occurred before 50 DS.Heavy rainfall in 1985 before rice emergence resulted in large losses of native soil N and fertilizer N by leaching and possibly by denitrification. During the week of seeding, when rainfall was 492 mm, 91 kg nitrate-N ha^–1 disappeared from the 0.3-m soil layer in unfertilized plots. Although rainfall following the basal N application was less in 1984 than in 1985, the losses from basal applied urea-N were comparable in the two years. Daily rainfall of 20–25 mm on 3 of the 6 days following basal N application in 1984 may have created a moist soil environment favorable for ammonia volatilization.In both years, highest grain yield was obtained for urea split-applied at 30 DS and at PI. Delayed rather than basal application of N reduced losses of fertilizer N and minimized uptake of fertilizer N by weeds.     

Modelling cadmium accumulation at a regional scale in the Netherlands

The cadmium content in soils in the rural environment in the Netherlands may increase towards an exceedance of quality standards due to atmospheric deposition and the use of fertilizers and animal manure. To evaluate this problem, a simple dynamic, process-oriented model SOACAS has been developed which is aimed at predicting the accumulation of heavy metals in the topsoil in a regional context. SOACAS describes the fate of a metal in one completely mixed soil compartment using a Freundlich isotherm and analytical equations to solve the mass balance. We tested if it was possible to reconstruct the soil's present cadmium contents, using independent estimates of historical cadmium loads (hind-cast simulation). About 2500 recent point observations of cadmium contents in rural areas were available. Before comparison, a map was created to translate the point information obtained from the field data to areal average information (resolution 500 × 500 m²), required for comparison with results of SOACAS. A regression model in combination with a locally-weighted smoother within the framework of Generalized Additive Modelling (GAM) was used for this purpose. A realistic geographical pattern could be obtained with very few a priori assumptions. Comparison of the map obtained by the GAM and the map obtained by hind-cast simulation showed that, despite the large uncertainties about historical cadmium loadings, the current cadmium contents were only slightly underestimated by SOACAS. Moreover, the geographical pattern for the observed and simulated contents compared reasonably well. On this basis of this exercise we believe that the model can be used to predict trends of future metal contents as a function of emission/immission scenario's. Simulations showed that cadmium contents currently decrease in highly polluted areas around industrial plants in the South-Eastern part of the country, and still increase in arable land.     

Nitrogen leaching and soil nitrate, nitrite, and ammonium levels under irrigated wheat in Northern Mexico

Nitrate (NO⁻¹ ₃) leaching from agricultural soils can represent a substantial loss of fertilizer nitrogen (N), but a large variation in losses has been reported. We report N leaching losses under four N fertilizer treatments and two farmer's fields in the Yaqui Valley, Mexico. In these irrigated wheat systems, farmers typically apply 250 kg N ha⁻¹ as anhydrous ammonia (knifed in) or urea(broadcast), with 75% applied directly before planting and 25% at the time of the first post-planting irrigation. Over two wheat seasons, we compared typical farmer's practices to alternatives that applied less N and more closely timed fertilizer application to plant demand. Field lysimeter measurements and predictions from a water transport simulation model (called NLOSS) were used to estimate the amount of N leached over the season. Approximately 5 and 2% of the applied N leached below the root zone with the typical farmer's practice in 1995–96 and 1997–98,respectively. The alternative treatments reduced N leaching losses by 60 to95% while producing comparable economic returns to the farmer. Leaching losses from the two farmer's fields were substantially higher (about 14and26% of the applied N). Our results indicate that the typical farmer's practice leads to relatively high N leaching losses, and that alternative practices synchronizing fertilizer application with crop demand can substantially reduce these losses. This revised version was published online in August 2006 with corrections to the Cover Date.     

Studies on the effectiveness of various sulfur fertilizers under controlled conditions

Three factorial experiments with four replications were conducted in a greenhouse to examine the effectiveness of gypsum, elemental sulfur (ES powder) and three S containing N fertilizers, viz., ammonium sulfate (AS), urea + ES, and Ureas (20% AS and 80% urea). All experiments were conducted twice in different years.In the first experiment with uncropped soil, the effects of soil type, leaching rate (2.3 and 6.9 mm water per day) and urea addition on sulfate leaching losses were studied. Leaching losses decreased in the order Ureas > ammonium sulfate (AS) > gypsum urea + ES. Increasing the leaching rate greatly increased sulfate losses from both soils. Losses were greater in the sandy Typic Hapludoll than in the clayey Oxic Paleustalf. Sulfate adsorption was found to decrease strongly with rising the pH in both soils. Hydrolysis of urea temporarily raised the pH of the soil, thereby increasing the sulfate leaching losses.In the second experiment the effects of S rate (0–65 mg per kg soil), split application and leaching rate (0 and 2.3 mm per day) on sulfate leaching losses and apparent S recovery (ASR) by three successive cuts of ryegrass (Lolium perenne L.) were studied. Herbage yield more than doubled when S was applied. The effectiveness of the sulfate fertilizers was greater when S was split-applied than given all at once. With split applications the ASR decreased in the order: Ureas > AS > gypsum > urea + ES > ES powder. ES fertilizers were least effective, because the oxidation rate of ES to sulfate was clearly too slow.In the third experiment the effects of S rate (0–40 mg per kg soil) and split application on sulfate leaching losses and ASR in the grain of wheat (Triticum aestivum L.) were studied under leaching conditions (2.3 mm per day). Grain yield increased strongly due to S application. Split application greatly increased the effectiveness of the sulfate fertilizers and appeared to be an effective tool in satisfying the S need of the crop under leaching conditions. Again, ES fertilizers were least effective, because the oxidation rate of ES was too slow to meet the S demand of the crop.In all experiments leaching losses of sulfate from the ES fertilizers were smaller than from the sulfate fertilizers.     

Comparing the effectiveness of radish cover crop, oilseed rape volunteers and oilseed rape residues incorporation for reducing nitrate leaching

The soil water and N dynamics have been studied during two long fallow periods (between wheat or oilseed rape and a spring crop) in a field experiment in Châlons-en-Champagne (eastern France, 48°50 N, 2°15 E). The experiment involved frequent measurements of soil water, soil mineral N, dry matter and N uptake by cover crops. Water and N budgets were established using Ritchie's model for calculating evapotranspiration in cropped soils and a model (LIXIM) for calculating water drainage, N leaching and N mineralisation in bare soils. During the first autumn and winter, a radish cover crop (grown from September 1994 to January 1995) was compared to a bare soil. During the second period (July 1995 to April 1996), a comparison was carried out between (i) oilseed rape volunteers, (ii) bare soil with two types of oilseed rape residues incorporated into the soil (R0 and R270 residues) and (iii) bare soil without residues incorporation. R0 and R270 residues came from two preceding oilseed rape crops which received two rates of N fertilizer (0 and 270 kg N ha^-1).Soil mineral N content was markedly reduced by the presence of radish cover crop or oilseed rape volunteers during autumn. The calculated actual evapotranspiration (AET) did not differ much between treatments, meaning that the transpiration by the cover crop or volunteers was relatively low (100–150 L kg^-1 of dry matter). Consequently, nitrate leaching was reduced during the rest of the winter and spring as well as nitrate concentration in the percolating water: 45 vs. 91 mg NO₃ ^- L^-1 for radish cover crop and bare soil, respectively. The incorporation of oilseed rape residues to soil also exerted a beneficial but smaller action on reducing the nitrate content in the soil. This effect was due to extra N immobilisation which reached a maximum of about 20 kg N ha^-1 in mid-autumn for both types of residues. Nine months after the incorporation of the oilseed rape residues, and comparing to the control soil without residues incorporation, N rich residues induced a significant positive N net effect (+ 9 kg N ha^-1) corresponding to 10% of N added whereas for N poor residues no net effect was still obtained at the end of experiment (–3 kg N ha^-1, not significantly different from 0).To reduce nitrate leaching during long fallow periods, it is necessary to promote techniques leading to decrease mineral-N contents in the soil during autumn before the drainage period, such as (i) residue incorporation after harvest (without fertiliser-N) and (ii) allowing volunteers to grow or sowing a cover crop just after the harvest of the last main crop.     

1. The chemistry and biology of flooded soils in relation to the nitrogen economy in rice fields

Response of lowland rice to sources and methods of nitrogen fertilizer application were summarized for more than 100 experiments. In about 2/3 of the experiments, the yield increase per kg of fertilizer N was judged to be relatively poor with best split applications of urea. Based on frequency distribution, sulfur coated urea and urea briquets or urea supergranules deep placed more often produced satisfactory yield increases than best split urea, but even with these sources/methods the yield increases were judged to be relatively poor in about 1/2 of the experiments. There is an enormous potential to increase rice production with no further increases in inputs of fertilizer N if we could learn to match the best method/source of fertilizer with the soil-crop management complex.About 60% of the yields with no fertilizer N were in the range of 2 to 4 t/ha. Based on the average yield response to urea, this is equivalent to about 100 kg of urea N. It would appear worthwhile to study ways to improve utilization of soil nitrogen since it is already in place on the land and apparently in fairly abundant amounts in many soils.About 50 experiments with¹⁵N fertilizers were summarized. In almost all cases, the uptake of tagged fertilizer was less than the net increase in N in the above ground matter. In about 2/3 of the experiments, the addition of fertilizer N increased soil N uptake more than 20% and in 1/3 of the experiments the uptake of soil N was increased more than 40%. These results lead to much uncertainty about practical interpretation and use of¹⁵N data.     

Nitrogen leaching and uptake from calcium cyanamide in comparison to urea and calcium ammonium nitrate in an ultisol from the humid tropics

Leaching loss of N applied as calcium cyanamide (CaCN₂ — 19% N), urea and calcium ammonium nitrate (CAN — 26% N) to a coarse textured, kaolinitic ultisol profile was studied in the laboratory using undisturbed soil columns. The soil columns were leached with an amount of water equivalent to the annual rainfall of the sampling site (2420mm) using a rainfall simulator over a period of 42 days. The leachability of the three N fertilizers differed greatly and followed the order of CAN > urea > CaCN₂. Most of the N lost through leaching was in NO₃ form. Calcium cyanamide lost only 3% of applied N. Breakdown of CaCN₂ to NH₄ was incomplete (64%) and nitrification in the soil was inhibited resulting in negligible leaching loss. Nitrogen retained in the soil columns after the leaching cycle was mainly in ammoniacal form irrespective of source of N used.Effectiveness of CaCN₂ as a N source was also studied in a greenhouse experiment with maize (Zea mays) and upland rice (Oryza sativa) as testing crops. Calcium cyanamide applied one week before sowing of crops was as effective as CAN and urea under conditions of no N leaching. When applied at the time of planting and two or more weeks before planting gave lower dry matter yields and N uptake than CAN and urea.IITA Journal Paper no. 351     

N2O and NO emissions from different N sources and under a range of soil water contents

Emissions of nitrous oxide (N₂O) and nitric oxide (NO) have been identified as one of the most important sources of atmospheric pollution from grasslands. Soils are major sources for the production of N₂O and NO, which are by-products or intermediate products of microbial nitrification and denitrification processes. Some studies have tried to evaluate the importance of denitrification or nitrification in the formation of N₂O or NO but there are few that have considered emissions of both gases as affected by a wide range of different factors. In this study, the importance of a number of factors (soil moisture, fertiliser type and temperature) was determined for N₂O and NO emissions. Nitrous oxide and NO evolution in time and the possibility of using the ratio NO:N₂O as an indicator for the processes involved were also explored. Dinitrogen (N₂) and ammonia (NH₃) emissions were estimated and a mass balance for N fluxes was performed. Nitrous oxide and NO were produced by nitrification and denitrification in soils fertilised with and by denitrification in soils fertilised with . Water content in the soil was the most important factor affecting N₂O and NO emissions. Our N₂O and NO data were fitted to quadratic (r=0.8) and negative exponential (r=0.7) equations, respectively. A long lag phase was observed for the N₂O emitted from soils fertilised with (denitrification), which was not observed for the soils fertilised with (nitrification) and was possibly due to a greater inhibiting effect of low temperatures on microbial activity controlling denitrification rather than on nitrification. The use of the NO:N₂O ratio as a possible indicator of denitrification or nitrification in the formation of N₂O and NO was discounted for soils fertilised with . The N mass balance indicated that about 50 kg N ha⁻¹ was immobilised by microorganisms and/or taken up by plant roots, and that most of the losses ocurred in wet soils (WFPS >60%) as N₂ and NH₃ losses (>55%).     

Solubilization of soil organic N by alkaline-hydrolysing N fertilizers

Interactions between¹⁵N-labelled fertilizers applied at concentrations representative of the fertilizer microsite and the solubility of the nitrogenous component of soil organic matter were investigated in laboratory experiments. Soil organic N was solubilized in a-irradiated soil due to addition of NH_3(aq), and the fertilizer-induced loss of unlabelled total N in the extracted soil (TU_s) increased with increasing N fertilizer concentration and soil pH. TU_s was linearly correlated with ammoniacal-N concentration and the pH of the fertilized soil within the range of 7.5-10 (r = 0.94).Total organic N in the soil extract (OT_e) increased rapidly up to day 14 following addition of 2000 mg urea-N kg^–1 soil, but was then stable up to day 28. OT_e of a range of soils increased from between 5 and 148 to between 15 and 368 mg N kg^–1 soil after application of 1045 mg NH₃-N kg^–1 soil. While up to 25% of the organic N was solubilized by the fertilizer in nine soils, the change in total organic N in the extracts (OT_e) of three soils was not significant. The highest OT_e of 399 mg N kg^–1 soil (35.4% of soil organic N) was measured after application of 2000 mg NH₃-N kg^–1 soil.pH and OT_e decreased in the order of NH_3(aq) > urea > di-ammonium phosphate > ammonium sulphate at equivalent rates of N addition. A negative OT_e was measured following application of ammonium sulphate. OT_e was correlated with the pH of the fertilized soil but not ammoniacal-N concentration for different N fertilizer sources.     

Effect of cation exchange on the distribution and movement of cations in soils with variable charge. II. Effect of lime or phosphate on potassium and magnesium leaching

The effect of Ca(OH)₂ or Ca(H₂PO₄)₂ 2H₂O (MCP) on potassium (K) or magnesium (Mg) leaching through and out of columns of soil with predominantly variable charge was studied. Calcium hydroxide was mixed with soil from the A and B horizon to raise the pH to about 6 or 7, and MCP, equivalent to 952 mg P, was mixed with the A horizon of each soil. Various concentrations of KCl or MgCl₂ were applied as a pulse to the soil surface and leached with five pore volumes of deionised water.Calcium hydroxide or MCP addition increased leaching losses of K and Mg initially present in the soil.Liming to about pH 6 reduced leaching of applied K and Mg in all soils. This was attributed to the increase in the cation exchange capacity (CEC). Applied K leached to a greater extent at pH 7 than at pH 6 in the A horizon of each soil despite a two-fold increase in CEC. However, when Mg was applied to all soils and K applied to soil from B horizons, leaching decreased as the pH increased from 6 to about 7.The addition of MCP increased the CEC of all soils, but this had little effect on the leaching of applied K compared with the untreated soils.A proportion of applied K or Mg was displaced from the soil column for all Ca(OH)₂ or MCP treatments. In many columns, no increase in exchangeable K or Mg in the lower segments of the soil column was found. Where this occurred the activity ratio in the leachate was the same as the equilibrium activity ratio.     

Inhibition of Methane Consumption in Forest Soils by Monoterpenes

Selected monoterpenes were tested for their ability to inhibit atmospheric methane consumption by three forest soils from different vegetation types and by the cultured methanotrophic strain, Methylosinus trichosporium OB3b. Subsurface soil from coniferous (Pinus banksiana), deciduous (Populus tremuloides), and mixed hardwood (Tsuga canadensis and Prunus pensylvanica) stands was used under field-moist (bulk and intact cores) and slurry conditions. Most of the hydrocarbon monoterpenes tested significantly inhibited (40–100%) methane consumption by soils at environmentally relevant levels, with (–)--pinene being the most effective. With the exception of -myrcene, monoterpenes also strongly inhibited methane oxidation by Methylosinus trichosporium OB3b. Carbon dioxide production was stimulated in all of the soils by the monoterpenes tested. In one case, methane production was stimulated by (–)--pinene in an intact, aerobic core. Oxide and alcohol monoterpenoids stimulated methane production. Thus, monoterpenes appear to be potentially important regulators of methane consumption and carbon metabolism in forest soils.     

Mineralization of organic N originating in treated effluent used for irrigation

Reclaimed wastewater and, particularly, secondary effluent used for irrigation, may contain considerable amounts of mineral and organic N. The knowledge regarding N-transformations of effluent-originated organic N in soil is not well established. A method based on ion-exchangers (IE) was developed to remove the mineral N and other ionic species from the effluents, enabling a better follow-up of the reactions of effluent-originated organic N. Modifications of two incubation methods were used to evaluate net mineralization rates and the contributions of ammonification and nitrification of the effluent-originated organic N. A mixture of the ion-exchangers, IRN-77 (H⁺) and IRN-78 (OH^–), was found effective in removing mineral N and other ions from effluents without significantly affecting the content of organic N. In suspension-based experiments performed with a microbially active calcareous clay soil, the nitrification started after about a 1 to 4 d lag (higher lag associated with higher BOD), and the total mineral N reached plateau values after about 9 to 14 d. The time estimated for completion of ammonification of the organic N in the well-mixed and aerated suspensions was 3 to 6 d. Soil incubations were performed after adding the IE-treated effluents to small soil columns. Ammonification of both soil and effluent-originated organic N occurred concomitantly with the nitrification, making the evaluation of rates more complicated. Tracing the time differences in total mineral N between the soils irrigated with the IE-treated effluent and the blank (no added N) enabled the estimation of first order rate constants for the net mineralization of the effluent-originated organic N in: a sandy loam (0.3 wk^–1), a loess (0.4 wk^–1), and in the calcareous clay (1.1 wk^–1). About two thirds of the organic N added to the soils in the columns during the pre-incubation stage were not retained in the soils, whereas ammonium was practically not leached out. The relatively fast movement of the effluent-originated organic N in soil and its mineralization characteristics indicate that this fraction significantly affects the short (days) and middle (weeks) range transformations of N in effluent-irrigated soils.     

A study of tile drain nitrate - δ<Superscript>15</Superscript>N values as a tool for assessing nitrate sources in an agricultural region

It is important to evaluate tools which provide insight into nitrate (NO^–₃) contamination source identification in watersheds where multiple nitrogen (N) sources are applied. As nitrate-N stable isotopes have been previously used to identify contaminant sources in groundwater environments, the application of the technique to tile drainage outflow was investigated. Nitrate-N isotopic and concentration analyses of tile drain discharges from six different fields with a range of mineral fertilizer N and hog manure applications were conducted to examine general isotopic patterns and their relation to N fertilizer sources. ¹⁵N of NO^–₃ draining fields were compared to ¹⁵N source signatures through a single growing season. The objective was to determine: (a) whether tile drainage water exiting fields receiving different N sources (inorganic mineral N, organic hog manure N, or a combination of the two) had distinct ¹⁵N values, and (b) whether ¹⁵N signatures of sampled tile drain water fell within expected source ranges. Results suggest that isotopic data differed between fields in a manner consistent with differences in NO-3 sources, as fields only fertilized with mineral N had ¹⁵N values consistently lower than fields with hog manure applications. However, all fields showed isotopic values that were enriched in ¹⁵N relative to their sources during the study period. Therefore, although these fields are discharging tile drainage water with distinctive isotopic signatures, the data suggests that a quantitative evaluation of individual NO^–₃ source contributions is not possible within this watershed. Utilization of this tool in source discrimination in other tile drainage waters should only proceed if it can be demonstrated that isotopic fractionations are not altering source signatures.     

Calculating soil nutrient balances in Africa at different scales

Nutrient balances were calculated for the arable soils of 38 sub-Saharan African countries. FAO production figures and forecasts for 35 crops for the period 1982–1984 and for 2000 were used to define land use systems, further characterized by fertility input through fertilizers, manure, rain and dust, biological N-fixation, and sedimentation, and fertility output through harvest of crops and removal of residues, leaching, denitrification, and erosion. The summarized output of the study is the sum of inputs minus the sum of outputs of nitrogen, phosphorus and potassium in the root zone. The alarming annual average nutrient loss for sub-Saharan Africa was 22 kg N, 2.5 kg P, and 15 kg K in 1982–84, and will be 26 kg N, 3 kg P, and 19 kg K in 2000. As the soil nutrient pool has to offset the negative balances each year, there is gross nutrient mining in sub-Saharan Africa. The need for integrated systems of nutrient management is emphasized, manipulating all inputs and outputs in a judicious way. Future scenarios of continued mining and conservation of soil fertility are discussed.     

Phosphorus content in soil, uptake by plants and balance in three European long-term field experiments

The fate of phosphorus (P) derived from mineral fertilisers and organic manures, and the effective P balance, have been assessed in three long-term field experiments at Rothamsted (UK), Bad Lauchstaedt (Germany) and Skierniewice (Poland). This paper discusses the plant availability, uptake and overall utilisation of P over the last 30 years, based on soil test P availability indices and crop analyses determined by the standard methods used in each of the three countries. The data suggest that differences in soil type significantly influence the dynamics of P at the three locations, but most significantly between a loess Chernozem at Bad Lauchstaedt with a high organic matter content and the soils at the other two locations which have a low organic matter content. The application of P either as inorganic fertiliser or organic manure had a considerable influence on the availablity, uptake, leaching or fixing of P, but the crop recovery rate of P from mineral fertiliser did not exceed 35% with the smallest recovery (average 18%) occurring in the soil with the highest clay content at Rothamsted. At Bad Lauchstaedt and Rothamsted the most efficient utilisation of P (averages of 47% and 37%, respectively) was from soils treated with farmyard manure (FYM), with the greater quantity of P either leached or fixed (8 and 25 kg ha^-1 y^-1, respectively) occurring in soils treated with superphosphate. At Skierniewice, however, the reverse was true. Overall, the most efficient crop utilisation from mineral P (30% average) was from the loamy sand at Skierniewice. P balances for the three locations show that quantitatively, for the same P input, the amount of P either leached from or fixed in the plough layer of Broadbalk field, Rothamsted, was 2–3 times greater than at Skierniewice and 3–6 times greater than at Bad Lauchstaedt. The results suggest that differences in the soil physico-chemical properties, climate, the availability of other major nutrients, and the form in which P is applied, all influence the effectiveness of P fertilisation and P balance. The investigation highlights the importance of maintaining long-term field experiments and archived soil and crop samples on a world-wide basis for understanding nutrient cycling and fertility dynamics.     

Efficient and flexible management of nitrogen for rainfed lowland rice

Nitrogen (N) is the most limiting nutrient in the rainfed lowland rice soils of Laos. Indigenous N supply of these soils was low, ranging from 12 to 64 kg N/ha and was correlated with soil organic matter content. Resource-poor farmers and erratic rainfall are characteristic features of Lao rainfed lowland rice systems. Such climatic and economic factors influence farmers' ability to apply N at the recommended time and therefore efficient and flexible recommendations are required. Research on N management focused on the timing of N applications. Splitting the N recommendation into three equal splits at transplanting, active tillering and panicle initiation increased yields by 12% compared to a single application at transplanting. Agronomic efficiency (AE = kg increase in grain yield/kg N applied) was further increased by 9 kg/kg N if a higher proportion of the N was applied during active tillering and panicle initiation when crop N demand is high. Under conditions of suboptimal N supply, the first N application can be applied from transplanting to 30 d after transplanting without lowering grain yield or AE (for medium duration varieties transplanted 1 month after sowing). The last N application can be made between two weeks before to one week after panicle initiation without lowering yield. These findings provide the basis for an efficient (AE of 20 to 25 kg/kg N) and flexible N management strategy for Lao rainfed lowland rice under conditions of suboptimal N supply.