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1.
S. Watanabe T. Fujita K. Suga I. Nasuno 《Journal of the American Oil Chemists' Society》1983,60(9):1678-1679
Fluorination of fatty alcohols with 1,1,2,3,3,3-hexafluoropropyl di-ethylamine (PPDA) was investigated. A mixture of lauryl fluoride (yield 45%) and lauryl 2,3,3,3-tetrafluoropropionate (yield 22%) was obtained from the reaction of PPDA and lauryl alcohol. Similar results were obtained from other fatty alcohols. 相似文献
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Yuji Shimada Akio Sugihara Hirofumi Nakano Takashi Kuramoto Toshihiro Nagao Munekazu Gemba Yoshio Tominaga 《Journal of the American Oil Chemists' Society》1997,74(2):97-101
To purify docosahexaenoic acid (DHA), we attempted the selective esterification of fatty acids originating from tuna oil with
lipases. Tuna oil was hydrolyzed in NaOH-ethanol solution, and the resulting fatty acid mixture [DHA, 23.2%; named tuna-free
fatty acid (FFA)] was used as a starting material. Rhizopus delemar which acted lightly on DHA, was a suitable catalyst for the selective esterification of tuna-FFA, and lauryl alcohol was
the best substrate. The reaction proceeded most effectively when a mixture of 2.4 g lauryl alcohol/tuna-FFA (2:1, mol/mol),
0.6 g water, and 600 U Rhizopus lipase was incubated at 30°C for 20 h with stirring at 500 rpm. Under these conditions 72% of tuna-FFA was esterified, and
84% of DHA was recovered in the unesterified fatty acid fraction. The DHA content in the fatty acid fraction rose from 23
to 73% with this reaction. To further elevate the DHA content, the unesterified fatty acids were extracted, and then esterified
again under the same conditions. By this repeated esterification, DHA was purified to 89% with a recovery of 71% of its initial
content. 相似文献
5.
S. E. McGuire W. H. Chambless R. M. Owens 《Journal of the American Oil Chemists' Society》1978,55(2):300-302
Several compositional factors influence the viscosity of fatty alcohol sulfate solutions. The effects of free oil and inorganic
salts on viscosity are known by most sulfators. Each builds viscosity as its level is increased. The relation between viscosity
and alkyl sulfate homolog distribution is more subtle and often overlooked. Some synthetic alcohol manufacturers have the
flexibility within the coconut alcohol range to vary the lauryl, myristyl, and cetyl alcohol composition. Mixtures containing
high lauryl and cetyl alcohol content yielded alkyl sulfates having low viscosities. Mixtures of lauryl and myristyl alcohol
gave high viscosity alkyl sulfates. When restricted to compositions containing all three alcohols, the viscosity of the sodium
alkyl sulfate derivative was shown to be dependent on the myristyl sulfate content. Solutions having high myristyl sulfate
levels had high viscosities. A. limited solubility study of different sodium lauryl, myristyl, and cetyl alcohol sulfate solutions
was made. 相似文献
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Neeraj J. Tiwari Sudhirprakash B. Sawant 《European Journal of Lipid Science and Technology》2005,107(1):30-35
Esterification of commercial behenic acid with fatty alcohols (decanol, lauryl alcohol, myristyl alcohol and cetyl alcohol) was studied using n‐butyl benzene as solvent and tetra n‐butyl titanate (TBT) as catalyst. The effects of reaction temperature (165–185 °C) and catalyst loading (0.3–1.2%, wt/wt) on the conversion of behenic acid were studied for all the alcohols. The reaction showed first order dependence with respect to fatty alcohols and behenic acid concentration. The values of activation energy obtained for the catalyzed reaction of behenic acid with decanol, lauryl alcohol, myristyl alcohol and cetyl alcohol were found to be 68.1, 69.2, 64.5 and 67.3 kJ mol?1, respectively. The values of activation energy obtained for the uncatalyzed reaction of behenic acid with decanol, lauryl alcohol, myristyl alcohol and cetyl alcohol were found to be 86.2, 79.6, 78.6 and 87.1 kJ mol?1, respectively. Physical properties such as melting point, viscosity, specific gravity, and refractive index of these esters are reported. 相似文献
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Yuji Shimada Akio Sugihara Yumi Minamigawa Kenichi Higashiyama Kengo Akimoto Shigeaki Fujikawa Sadao Komemushi Yoshio Tominaga 《Journal of the American Oil Chemists' Society》1998,75(12):1213-1217
An attempt was made to enrich arachidonic acid (AA) from Mortierella single-cell oil, which had an AA content of 25%. The first step involved the hydrolysis of the oil with Pseudomonas sp. lipase. A mixture of 2.5 g oil, 2.5 g water, and 4000 units (U) Pseudomonas lipase was incubated at 40°C for 40 h with stirring at 500 rpm. The hydrolysis was 90% complete after 40 h, and the resulting
free fatty acids (FFA) were extracted with n-hexane (AA content, 25%; recovery of AA, 91%). The second step involved the selective esterification of the fatty acids with
lauryl alcohol and Candida rugosa lipase. A mixture of 3.5 g fatty acids/lauryl alcohol (1:1, mol/mol), 1.5 g water, and 1000 U Candida lipase was incubated at 30°C for 16 h with stirring at 500 rpm. Under these conditions, 55% of the fatty acids were esterified,
and the AA content in the FFA fraction was raised to 51% with a 92% yield. The long-chain saturated fatty acids in the FFA
fraction were eliminated as urea adducts. This procedure raised the AA content to 63%. To further elevate the AA content,
the fatty acids were esterified again in the same manner with Candida lipase. The repeated esterification raised the AA content to 75% with a recovery of 71% of its initial content. 相似文献
10.
Yuji Shimada Kazuaki Maruyama Akio Sugihara Takashi Baba Sadao Komemushi Shigeru Moriyama Yoshio Tominaga 《Journal of the American Oil Chemists' Society》1998,75(11):1565-1571
Ethyl docosahexaenoate (E-DHA) is efficiently enriched by the selective alcoholysis of ethyl esters originating from tuna
oil with lauryl alcohol using immobilized lipase. Alcoholysis of ethyl esters by immobilized Rhizopus delemar lipase raised the E-DHA content in the unreacted ethyl ester fraction from 23 to 49 mol% in 90% yield. However, the content
of ethyl eicosapentaenoate (E-EPA) was higher than the initial content. Hence we attempted to screen for a suitable lipase
to decrease the E-EPA content, and chose Rhizomucor miehei lipase. Several factors affecting the alcoholysis of ethyl esters were investigated, and the reaction conditions were determined.
When alcoholysis was performed at 30°C with shaking in a mixture containing ethyl esters/lauryl alcohol (1:3, mol/mol) and
4 wt% of the immobilized R. miehei lipase, the E-DHA content in the ethyl ester fraction was increased and the E-EPA content was decreased. By alcoholyzing
ethyl esters in which the E-DHA content was 45 mol% (E-tuna-45) for 26 h, the E-DHA content was increased to 74 mol% in 71%
yield and the E-EPA content was decreased from 12 to 6.2 mol%. To investigate the stability of the immobilized lipase, batch
reactions were carried out continually by replacing the reaction mixture with fresh E-tuna-45/lauryl alcohol (1:3, mol/mol)
every 24 h. The decrease in the alcoholysis extent was only 17% even after 100 cycles of reaction. It was found that increasing
the proportion of lauryl alcohol increased the conversion of E-EPA to lauryl-EPA. When an ethyl ester mixture in which the
E-DHA content was 60 mol% (E-tuna-60) was alcoholyzed for 24 h with 7 molar equivalents of lauryl alcohol, the E-DHA content
was raised to 93 mol% with 74% yield and the E-EPA content was reduced from 8.6 to 2.9 mol%. 相似文献
11.
The kinetics of swollen emulsion polymerization of styrene was investigated. Two types of fatty alcohol, namely, cetyl alcohol and lauryl alcohol, were used as swelling agents in the presence of sodium dodecyl sulfate as emulsifier and potassium persulfate as initiator. The polymerizations were carried out in a magnetic-drive, sealed, cylindrical polymerization reactor, in nitrogen atmosphere. The effects of emulsifier concentration and the weight ratio of emulsifier to swelling agent on the variation of total monomer conversion with the polymerization time, average particle size, and the size distribution of the latex were examined. A significant decrease in the polymerization rate was observed at especially lower emulsifier concentrations in the presence of cetyl alcohol. The maximum average diameter of the latex with the sodium dodecyl sulfate-cetyl alcohol system was obtained as 0.30 μm. Lauryl alcohol was tried as a novel swelling agent. It was found that lauryl alcohol was an effective swelling agent without using sodium dodecyl sulfate. The latexes having average diameters of 1.0 μm and 0.67 μm (highly monodisperse) were obtained using 0.6 g and 2.0 g lauryl alcohol, respectively, at 300 mL of reaction volume. If it was used together with sodium dodecyl sulfate, the presence of lauryl alcohol did not cause any significant decrease in the polymerization rate as in the case of sodium dodecyl sulfate-cetyl alcohol system, but the average diameters of the latexes obtained with different sodium dodecyl sulfate-lauryl alcohol combinations were rather small compared to the sodium dodecyl sulfate-cetyl alcohol system at the same polymerization conditions. 相似文献
12.
L. M. Smith W. L. Dunkley A. Franke T. Dairiki 《Journal of the American Oil Chemists' Society》1978,55(2):257-261
A procedure is described for gas liquid chromatographic determination of cis andtrans isomers of unsaturated fatty acids after fractionation of the saturated, monenoic, dienoic, and polyenoic fatty acid methyl
esters by argentation thin layer chromatography. To test its reliability, the procedure was used for quantitative measurement
of transisomers of unsaturated fatty acids in a known mixture of simple triglycerides containing saturated fatty acids from
4:0 to 24:0 andcis andtrans isomers of 14:1. 16:1, 18:1, and 18:2. Results of the analyses of five margarine and five butter samples are presented, together
with results of infrared spectrophotometric analyses fortrans fatty acid concentrations, ultraviolet spectrophotometric analyses for conjugated fatty acid concentrations, and enzymatic
analyses forcis-cis-methylene interrupted fatty acid concentrations. The combined argentation thin layer and gas Chromatographic procedure is
suitable for determination of the principal fatty acids in complex food lipids such as milk fat. 相似文献
13.
Yuji Shimada Akio Sugihara Yumi Minamigawa Kenichi Higashiyama Kengo Akimoto Shigeaki Fujikawa Sadao Komemushi Yoshio Tominaga 《Journal of the American Oil Chemists' Society》1998,75(9):1213-1217
An attempt was made to enrich arachidonic acid (AA) from Mortierella single-cell oil, which had an AA content of 25%. The first step involved the hydrolysis of the oil with Pseudomonas sp. lipase. A mixture of 2.5 g oil, 2.5 g water, and 4000 units (U) Pseudomonas lipase was incubated at 40°C for 40 h with stirring at 500 rpm. The hydrolysis was 90% complete after 40 h, and the resulting
free fatty acids (FFA) were extracted with n-hexane (AA content, 25%; recovery of AA, 91%). The second step involved the selective esterification of the fatty acids with
lauryl alcohol and Candida rugosa lipase. A mixture of 3.5 g fatty acids/lauryl alcohol (1:1, mol/mol), 1.5 g water, and 1000 U Candida lipase was incubated at 30°C for 16 h with stirring at 500 rpm. Under these conditions, 55% of the fatty acids were esterified,
and the AA content in the FFA fraction was raised to 51% with a 92% yield. The long-chain saturated fatty acids in the FFA
fraction were eliminated as urea adducts. This procedure raised the AA content to 63%. To further elevate the AA content,
the fatty acids were esterified again in the same manner with Candida lipase. The repeated esterification raised the AA content to 75% with a recovery of 71% of its initial content. 相似文献
14.
James H. Benedict 《Journal of the American Oil Chemists' Society》1960,37(9):415-418
A semimicro method for determining both total fatty acids and unsaponifiable matter in fats, fatty acids, and soap is presented.
The procedure involves saponification and recovery of the total fatty acids (which includes the unsaponifiables), removal
of the fatty acids with anion exchange resins, and determination of the unsaponifiable matter by weight.
The total fatty acid method was evaluated on seven samples and showed a standard deviation from the mean of 0.21%. The unsaponifiable
matter determination gives good reproducibility with a standard deviation from the mean of 0.06%. Since this ion exchange
is a direct determination of the nonionic components, the results obtained from it should be more accurate and more nearly
the true values than the macro extraction method which is empirical.
Presented at the annual spring meeting, American Oil Chemists’ Society, Dallas, Tex., April 4–6, 1960. 相似文献
15.
Analytical methods for the determination of total and water insoluble combined lactic acid in lactic acid modified fatty glycerides
are described. The acids are liberated from their esters by saponification. Lactic acid is determined by simple acid-base
titration after removal of fatty acids via liquid-liquid extraction. Water soluble constituents are extracted from a dichloro-methane
solution of the esters with 5% aqueous sodium sulfate prior to determination of water insoluble lactic acid. Methods are rapid,
simple, and suitable for use in a plant control laboratory. Extension of the procedure provides for the simultaneous determination
of fatty acid and glycerine on a single sample. 相似文献
16.
Tetramethylammonium hydroxide has been used in the extraction and pyrolysis methylation of the carboxylic acids produced by
periodate-permanganate oxidation of monounsaturated fatty acid methyl esters. This modification of the von Rudloff procedure
allows rapid determination of double-bond positions and analysis of mixtures of positional isomers of monoenoic fatty acids. 相似文献
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18.
Journal of the American Oil Chemists' Society - An analytical procedure is presented for determination of the rosin and fatty acid contents of tall oil products. Rosin acids are determined by... 相似文献
19.
A. G. Netting 《Journal of the American Oil Chemists' Society》1986,63(9):1197-1199
A simple, one-pot procedure for the saponification of fats and oils and the subsequent esterification of the resulting fatty
acid salts with pentafluorobenzyl bromide is presented. A normal phase high pressure liquid Chromatographic procedure for
the separation of these pentafluorobenzyl esters, primarily on the degree of unsaturation, is also given. Chromatographic
detection of the esters can be carried out conveniently at 254 nm, and the procedure should therefore find application in
the routine determination of the number of double bonds in fatty acids from fats and oils. 相似文献