Mg-Y-Ce稀土阻燃镁合金的高温氧化行为研究

Y和Ce的同时加入使镁合金获得了优异的阻燃效果,实现了镁合金在大气条件下的无保护熔炼。AES和XRD表面分析结果表明,Mg-Y-Ce阻燃镁合金在高温下暴露于大气中时,合金表面会生成一层以Y2O3为主的氧化膜。干燥空气中,Mg-3Y-4.5Ce合金在773, 873和973 K下氧化时,其氧化动力学曲线遵循立方规律。基于高温氧化热力学,详细分析了Mg-Y-Ce合金在高温下的选择性氧化机制,并从电化学角度探讨了Y2O3膜的半导体特性及其对镁合金基体进一步氧化的阻碍机制     

Mg-3.5Y-0.8Ca阻燃镁合金的高温氧化特性

通过Y和Ca的同时加入获得了阻燃效果优异的Mg-3.5Y-0.8Ca阻燃镁合金,实现了镁合金在大气条件下的无保护熔炼。俄歇电子能谱仪和X射线衍射表面分析结果表明:Mg-3.5Y-0.8Ca阻燃镁合金在高温下暴露于大气中时,合金表面会生成一层以Y2O3为主的氧化膜;干燥空气中,Mg-3.5Y-0.8Ca合金在773、873和973K下氧化时,其氧化动力学曲线遵循立方规律;基于高温氧化热力学分析,建立了Mg-Y合金在高温下的选择性氧化模型,并分析Ca在Mg-Y合金选择性氧化中的第三元素效应,即Ca元素加入Mg-Y合金后,同时起到“吸气剂”作用和增强Y元素表面活性的作用,因而大大降低了Y2O3发生选择性氧化所需Y含量阈值。     

Mg-3．5Y-0．8Ca阻燃镁合金的表面氧化膜结构研究

通过Y和Ca的同时加入获得了阻燃效果优异的Mg-3．5Y-0．8Ca阻燃镁合金，实现了镁合金在大气条件下的无保护熔炼。XRD，SEM和AES等表面分析结果表明，Mg-3．5Y-0．8Ca阻燃镁合金在高温下暴露于大气中时，合金表面会生成一层以Y2O3为主的氧化膜。Y2O3膜结构致密，铺展性强，在高温下为固态且不易挥发，电导率低，这些性能决定了其是一种优良的保护性氧化膜，能够阻碍镁合金基体的进一步氧化。     

N2气氛下镁合金燃点研究

采用自制试验装置研究了在静态条件下镁合金与N2之间的相互作用,特别研究了在N2气氛下Mg及镁合金的燃点情况.结果表明,添加Y、Ce、Nd和Ca都能提高Mg在N2气氛下的燃点,其中添加Ca的试验效果最好,Ca的质量分数为5.0%时燃点超过了1 030 ℃.Ce的添加使Mg-3Y合金的燃点先降后升、Mg-3Ca合金的燃点先升后降、Mg-1Nd合金的燃点显著提高,Ca的质量分数为4.5%时Mg-1Nd合金的燃点达到1 022 ℃.镁合金在N2气氛中的燃点明显高于大气中的燃点.     

稀土阻燃镁合金的高温氧化动力学研究

通过给镁中添加稀士元素Y和Ce获得了具有良好阻燃效果的Mg—Y—Ce合金，该合金能在1173K的高温下暴露于大气中0．5h而不燃烧。扫描电镜和X射线衍射分析表日月，合金表面生成了具有双层结构的复杂氧化膜：其中外层主要由Y2O3和MgO组成，内层则由大量的金属镁和极少量的MgO，Y2O3组成。高温氧化动力学研究显示，该合金在673K和773K时氧化符合抛物线一直线规律，而在873K下则遵循四方规律。     

Mg-RE合金的阻燃能力研究

主要研究了不同稀土元素对工业纯镁阻燃能力的影响,结果表明:一定量的Ce、Y、Nd、Dy稀土元素可使工业纯镁的燃点值有不同程度的提高,其中Y和Dy对阻燃能力的提高作用更为明显;观察发现Mg-Ce和Mg-Nd合金的氧化膜存在裂纹,这是他们阻燃能力较小的原因。本文还对Mg-0.5Y-Ce和Mg-0.5Y-Dy合金的阻燃能力进行了研究,发现Mg-0.5Y-5Dy合金的氧化膜致密,韧性较好,阻燃能力最强。     

Ce元素的添加对Mg-1.2Ca合金氧化行为和表面张力的影响（英文）

为了发展高性能阻燃镁合金,对工业纯镁在添加元素Ca和Ce的氧化性能进行了研究。结果表明,随着Ce含量从0%到1.5%(质量分数)的增加,Mg-1.2Ca合金的燃点不断提高,熔体表面张力不断下降。Mg-1.2Ca-1.2Ce燃点可以达到780℃,而且可在大气中不添加任何保护的情况下进行熔炼。随着Ce含量的增加,Mg-1.2Ca熔体氧化膜变得光滑而致密,可以很好地起到阻止氧化、燃烧的效果。通过检测和分析,Mg-1.2Ca-1.2Ce的氧化膜可以分成3层:外层是疏松的Mg O,中间层是MgO-CaO复合氧化膜,内层是MgO-Ce_2O_3复合氧化膜。     

稀土元素Ce与Y对JG4246A合金高温氧化行为的影响

在第二代高温合金JG4246A中分别添加不同含量的稀土元素Ce和Y,得到含0.012Ce(质量分数,%,下同)、0.017Ce、0.034Y、0.061Y四种合金铸锭,研究了在1100℃下Ce与Y对合金高温抗氧化性能的影响。采用X射线衍射仪(XRD)及扫描电镜(SEM)分析了氧化膜的物相组成以及氧化表面的形貌。结果表明,JG4246A合金在1100℃空气中恒温氧化过程中,添加稀土元素可以减少合金的氧化质量增加,氧化动力学符合抛物线规律;相对于稀土元素Y,Ce对减缓JG4246A合金的高温氧化速率的作用更显著;稀土元素的添加没有改变氧化膜的表面形貌,但是生成的尖晶石型氧化物使氧化膜更加致密,能够抑制阳离子的向外扩散,降低氧化反应速率,从而提高高温抗氧化性能。     

钇含量对Mg-Y合金组织及力学性能的影响

研究了钇(Y)含量对金属型铸造Mg-Y合金铸态组织、力学性能以及压缩变形织构的影响。结果表明:Y可以细化Mg-Y合金组织,当钇含量由w(Y)=0增加到w(Y)=3%时,合金的平均晶粒尺寸由300μm减小到55μm;随着钇含量增加,共晶相增加,并产生Mg24Y5第二相粒子; Y可以提高Mg-Y合金室温下的硬度和抗压强度,尤其能显著提高Mg-Y合金高温抗压强度;随着钇含量的增加,基面织构强度由纯镁的9. 1降至Mg-3%Y合金的3. 3。并探讨了Y弱化Mg-Y合金基面织构的机制。     

Ce元素的添加对Mg-1.2Ca合金氧化行为和表面张力的影响

摘 要：为了发展高性能阻燃镁合金,本文对工业纯镁在添加元素Ca和Ce的氧化性能进行了研究。结果表明随着Ce含量从0到1.5wt.%的增加,Mg-1.2Ca合金的燃点不断提高,熔体表面张力不断下降。Mg-1.2Ca-1.2Ce的燃点可以达到780℃,而且可以在大气中不添加任何保护的情况下进行熔炼。随着Ce含量的增加Mg-1.2Ca熔体氧化膜变得光滑而致密,可以很好地起到阻止氧化、燃烧的效果。通过检测和分析,Mg-1.2Ca-1.2Ce的氧化膜可以分成三层：外层是疏松的MgO,中间层是MgO-CaO复合氧化膜,内层是MgO-Ce2O3复合氧化膜。     

Effects of little Ce addition on as-cast microstructure and creep properties of Mg-3Sn-2Ca magnesium alloy

The effects of little Ce addition on the as-cast microstructure and creep properties of Mg-3Sn-2Ca magnesium alloy were investigated. The results indicate that adding 0.5% (mass fraction) Ce to Mg-3Sn-2Ca alloy does not cause the formation of any new phase in the alloy. However, an interesting microstructural change in the as-cast Mg-3Sn-2Ca alloy added with 0.5%Ce is observed. After adding 0.5%Ce to Mg-3Sn-2Ca alloy, not only the volume fraction of CaMgSn phase in the alloy is decreased but also the CaMgSn phases in the alloy are refined. In addition, adding 0.5%Ce to Mg-3Sn-2Ca alloy can also improve the creep-resistant properties of the alloy. After adding 0.5%Ce to Mg-3Sn-2Ca alloy, the second creep rate of the alloy at 150 °C and 70 MPa for 100 h changes from 3.28×10⁻⁸ to 1.81×10⁻⁸ s⁻¹.     

Microstructures and mechanical properties of Mg-2%Zn-0.4%RE alloys

The solidification microstructures and hardness of Mg-2%Zn (mass fraction) based alloys with addition of 0.4%Ce, 0.4%Gd, 0.4%Y or 0.4%Nd (mass fraction) were investigated, and the effects of the rare earth elements on the microstructures and mechanical properties of these alloys extruded at 310℃ were also compared. The results indicate that the trace rare earth Ce, Gd, Y or Nd in the Mg-2%Zn alloy has obviously different grain refinement effects on its solidification microstructures, and the as-cast and hot-extruded alloy with 0.4%Ce has the smallest average grain size and the highest strength. However, the extruded alloys containing 0.4%Nd or 0.4%Y with the elongation of 26.6% and 30%, respectively, show higher plasticity in spite of lower strength as compared with the alloy containing 0.4%Ce.     

Ce含量对Mg-Li-Al-Zn合金显微组织和拉伸性能的影响(英文)

制备了Mg-5Li-3Al-2Zn-xCe(x=0-2.5;质量分数,%)铸态合金,并将所得合金分别于300°C和370°C进行均匀化和固溶处理;研究固溶处理后合金显微组织和拉伸性能的变化。结果表明,合金中加入Ce后出现Al2Ce/Al3Ce析出相,此时合金主要由α-Mg、Al2Ce、Al3Ce和AlLi相组成;固溶处理后合金中AlLi和Al-Ce析出相数量减少。析出相的数量与形态对合金的力学性能十分重要,含有1.0%Ce的合金获得了优良的拉伸性能。固溶处理后Mg-5Li-3Al-2Zn-0.5Ce合金的强度和伸长率都得到了大幅度的提高,这是因为合金在固溶处理后由于基体中的溶质原子增加而获得良好的固溶强化作用。     

Effects of Ce on microstructure of semi-continuously cast Mg-1.5Zn-0.2Zr magnesium alloy ingots

Mg-1.5Zn-0.2Zr-xCe (x=0, 0.1, 0.3, 0.5, mass fraction, %) alloys were prepared by conventional semi-continuous casting. The effect of rare earth Ce on the microstructure of Mg-1.5Zn-0.2Zr-xCe alloys was studied and the distribution of Ce was analyzed by optical microscopy (OM), X-ray diffractometry (XRD) and scanning electron microscopy (SEM). The results indicate that Ce element exists in the form of Mg12Ce phase and has an obvious refining effect on the microstructure of test alloys. As the Ce content increases, the grain size reduces, the grain boundaries turn thinner, and the distribution of Mg12Ce precipitates becomes more and more dispersed. The Mg-1.5Zn-0.2Zr alloy with 0.3%Ce has the best refinement effect. From center to periphery of the ingot, the amount of granular precipitates in the grain reduces. In longitudinal section of the ingot, some relative long columnar grains appear.     

Effects of minor Ca on as-cast microstructures and mechanical properties of Mg-3Ce-1.2Mn-0.9Sc and Mg-4Y-1.2Mn-0.9Sc alloys

The effects of the addition of 0.6% Ca (mass fraction) on the as-cast microstructure and mechanical properties of the Mg-3Ce-1.2Mn-0.9Sc and Mg-4Y-1.2Mn-0.9Sc magnesium alloys were investigated and compared by optical microscopy and scanning electron microscopy, differential scanning calorimetry analysis, and tensile and creep tests. The results indicate that the addition of 0.6% Ca to the Mg-3Ce-1.2Mn-0.9Sc and Mg-4Y-1.2Mn-0.9Sc alloys can refine the grains of the two alloys. At the same time, the addition of 0.6% Ca to the Mg-3Ce-1.2Mn-0.9Sc and Mg-4Y-1.2Mn-0.9Sc alloys can effectively improve the tensile properties of the two alloys. In addition, the addition of 0.6% Ca can also improve the creep properties of the Mg-3Ce-1.2Mn-0.9Sc alloy but is not beneficial to the creep properties of the Mg-4Y-1.2Mn-0.9Sc alloy. The different effects of minor Ca on the creep properties of the Mg-3Ce-1.2Mn-0.9Sc and Mg-4Y-1.2Mn-0.9Sc alloys are possibly related to the difference in the solid solubilities of Ce and Y in Mg.     

纯Ce及Fe—Ce合金在低氧压下的氧化

研究了纯Ｃｅ和含１５％Ｃｅ（质量分数,下同）的Ｆｅ－Ｃｅ合金在６００￣８００℃低氧分压下的氧化。纯Ｃｅ氧化后形成ＣｅＯ２的外氧化。而Ｆｅ－１５Ｃｅ则产生快速Ｃｅ的内氧化,且内氧化区的显微组织保持了原始合金的显微组织,在内氧化区的前沿没有观察到Ｃｅ的贫化。     

Effects of calcium addition on as-cast microstructure and mechanical properties of Mg-5Zn-5Sn alloy

The effects of Ca addition on the as-cast microstructure and mechanical properties of the Mg-5Zn-5Sn (mass fraction,%) alloy were investigated.The results indicate that an addition of 0.5%-1.5% (mass fraction) Ca to the Mg-5Zn-5Sn alloy not only refines the as-cast microstructure of the alloy but also causes the formation of the primary and/or eutectic CaMgSn phases with high thermal stability;an increase in Ca amount from 0.5% to 1.5% (mass fraction) increases the amount and size of the CaMgSn phase.In addition,Ca addition to the Mg-5Zn-5Sn alloy improves not only the tensile properties at room temperature and 150 ℃ but also the creep properties.Among the Ca-containing Mg-5Zn-5Sn alloys,the one added 0.5% (mass fraction) Ca obtains the optimum ultimate tensile strength and elongation at room temperature and 150 ℃,however,the alloy added 1.5% (mass fraction) Ca exhibits the optimum yield strength and creep properties.     

Effects of Ce on damping capacity of AZ91D magnesium alloy

1　INTRODUCTIONThedampingcapacityisameasureoftheenergydissipatedduringmechanicalvibrationinthematerialsorcomponent .Metallicmaterialshavinghighdamp ingcapacitybecomevaluableinsuppressingmechani calvibrationandattenuatingwavepropagationforthecontrolofnoiseandthestabilizationofstructures .Takinghighdampingmetallicmaterialsasstructuralpartscouldeliminatetheneedforspecialenergyab sorbersordamperstoattenuatethevibrationandnoise ,inspiteofmostofthefrequentlyusedmetalsandalloys ,whichexhibitarela…     

微量Sc和Zr对Al-Mg-Mn合金组织与力学性能的影响

采用活性熔剂保护熔炼、水冷铜模激冷铸造制备Al-5.8Mg-0.4Mn和Al-5.8Mg-0.4Mn-0.25Sc-0.1Zr(质量分数,%)两种合金铸锭。合金铸锭经热轧中间退火冷轧成2 mm薄板;研究稳定化退火及微量Sc和Zr对Al-Mg-Mn合金组织与性能的影响。结果表明:在Al-Mg-Mn合金中加入微量Sc和Zr后形成大量弥散的Al3(Sc,Zr)粒子,这些粒子对位错和亚晶界具有强烈的钉扎作用,能明显提高合金的抗再结晶能力和室温力学性能;Al-Mg-Mn-Sc-Zr合金板材经300℃退火1 h后可获得最佳综合力学性能,其σb、σ0.2与δ分别为436 MPa、327 MPa和16.7%。