Effect of hydrogen addition using on-board alkaline electrolyser on SI engine emissions and combustion

In this study, an electrolyser was used to supply hydrogen to the SI engine. Firstly, the appropriate operation point for the electrolyser was determined by adjusting the amount of KOH in the electrolyte to 5%, 10%, 20% and 30% by mass, and applying 12 V, 16 V, 20 V, 24 V and 28 V voltages. Tests were first carried out with the gasoline without the use of an electrolyser, followed by operating the electrolyser at the appropriate point and sending obtained H₂ and O₂ to the engine in addition to the gasoline. The SI engine was operated between 2500 rpm and 3500 rpm engine speeds with and without hydrogen addition. Cylinder pressure, the amount of gasoline, H₂ and O₂ consumed by the engine and the emission data were collected from the test system at the aforementioned engine speeds. Furthermore, indicated engine torque, indicated specific energy consumption, specific emissions and HRR values were calculated. According to the results obtained, improvement in ISEC values was observed, and CO and THC values were improved by up to 21.3% and 86.1% respectively. Even though the dramatic increase in NO_x emissions cannot be averted, they can be controlled by equipment such as EGR three-way catalytic converter.     

乙醇/柴油/甲酯混合燃料的燃烧与排放特性

对燃料甲酯作为乙醇／柴油混合燃料助溶剂的可行性进行了研究,并对比了柴油机分别使用柴油、乙醇／柴油／甲酯混合燃料、乙醇／甲酯混合燃料和纯甲酯燃料时的燃烧与排放特性。结果表明,燃料甲酯可用作乙醇／柴油的助溶剂。与原机相比,含氧燃料可以大幅度降低柴油机在中高负荷时的烟度,其中E30M70燃料的烟度最小。但当使用含有乙醇的混合燃料时,着火延迟,THC排放增加,且在中高负荷时的压力升高率大,NOx排放较高。     

Investigation on combustion and emissions characteristics of a hydrogen-blended n-butanol rotary engine

In this paper, a rotary engine equipped with an n-butanol and hydrogen port-injection system was developed to investigate the combustion and emissions characteristics of a hydrogen-blended n-butanol rotary engine at part load and stoichiometric conditions. A self-developed hybrid electronic control unit was adopted to adjust the injection durations of n-butanol and hydrogen. The rotary engine was run under the conditions of 4000 rpm, a manifold absolute pressure of 35 kPa and a fixed spark timing of 45 °CA before the top dead center during the whole testing operation. The hydrogen volumetric fraction in the total intake was varied from 0% to 6.30%. The test results manifested that the brake thermal efficiency and chamber temperature were simultaneously increased with hydrogen addition. The hydrogen supplement obviously shortened flame development and propagation periods. Both chamber pressure integral heat release fraction versus crank angle were increased when the hydrogen fraction was enhanced. HC emissions were reduced by 54.5% when hydrogen volume fraction was raised from 0% to 6.30%, CO and CO₂ emissions were also reduced after increasing hydrogen blending fraction. NOx emissions were mildly elevated due to the improved chamber temperature.     

Effect of H2 addition on combustion and exhaust emissions in a heavy-duty diesel engine with EGR

The effect of the addition of hydrogen (H₂) on the combustion process and nitric oxide (NO) formation in a H₂-diesel dual fuel engine was numerically investigated. The model developed using AVL FIRE as a platform was validated against the cylinder pressure and heat release rate measured with the addition of up to 6% (vol.) H₂ into the intake mixture of a heavy-duty diesel engine with exhaust gas recirculation (EGR). The validated model was applied to further explore the effect of the addition of 6%–18% (vol.) H₂ on the combustion process and formation of NO in H₂-diesel dual fuel engines. When the engine was at N = 1200 rpm and 70% load, the simulation results showed that the addition of H₂ prolonged ignition delay, enhanced premixed combustion, and promoted diffusion combustion of the diesel fuel. The maximum peak cylinder pressure was observed with addition of 12% (vol.) H₂. In comparison, the maximum peak heat release rate was observed with the addition of 16% (vol.) H₂. The addition of H₂ was a crucial factor dominating the increased NO emissions. Meanwhile, the addition of H₂ reduced soot emissions substantially, which may be due to the reduced diesel fuel burned each cycle. Furthermore, proper combination of adding H₂ with EGR can improve combustion performance and reduce NO emissions.     

Experimental study of inlet manifold water injection on combustion and emissions of an automotive direct injection Diesel engine

This paper describes an experimental study conducted on a modern high speed common-rail automotive Diesel engine in order to evaluate the effects on combustion and pollutant emissions of water injected as a fine mist in the inlet manifold.     

Investigation on the cold start characteristics of a hydrogen-enriched methanol engine

This paper experimentally investigated the effect of hydrogen addition on the cold start performance of a methanol engine. The test was conducted on a modified four-cylinder gasoline engine. An electronically controlled hydrogen injection system was applied to realize the hydrogen port injection. The engine was started at an ambient temperature of 25 °C with two hydrogen flow rates of 0 and 189 dm³/s, respectively. The results demonstrated that hydrogen addition availed elevating the peak engine speed and cylinder pressure during the cold start. Both flame development and propagation periods are shortened after the hydrogen addition. When the hydrogen volume flow rate was raised from 0 to 189 dm³/s, HC, CO and total number of particulate emissions within 19 s from the onset of cold start were reduced by 68.7%, 75.2% and 72.4%, respectively. However, because of the enhanced in-cylinder temperature, NO_x emissions were increased after the addition of hydrogen.     

Effect of reformed biogas as a low reactivity fuel on performance and emissions of a RCCI engine with reformed biogas/diesel dual-fuel combustion

Biogas can be used as a less expensive continuance renewable fuel in internal combustion engines. However, variety in raw materials and process of biogas production results in different components and percentages of various elements, including methane. These differences make it difficult to control the combustion, effectively, in internal combustion engines. In this research, under cleaning and reforming process, biogas components were fixed. Then the effect of reformed biogas (R.BG) was investigated, numerically, on the combustion behavior, performance and emissions characteristics of a RCCI engine. A 3D-computational modeling has been performed to validate a single-cylinder compression ignition engine in conventional diesel and dual-fuel operations at 9 bar IMEP, 1300 rpm. Then, the combustion model of the RCCI engine was simulated by replacing diesel fuel with 20%, 40% and 60% of R.BG as a low reactivity fuel while remaining constant input total fuel energy per cycle. The results demonstrated that when the R.BG substitution ratio increases with a constant equivalence ratio of 0.43, the mean combustion temperature decreases to 1354 K, 1312 K, 1292 K which are about 3.5%, 6.6%, 7.9% lower than the conventional diesel combustion, respectively. The maximum in-cylinder pressure increases up to 22.63%. Instead, it results in 2.3%, 7.9%, and 14.5% engine power output losses, respectively. Also, the NOx emission, against CO, is decreased by 50%. Soot and UHC emissions were found to be slightly decreased while was used R.BG more than 40%.     

Effects of exhaust gas recirculation (EGR) on combustion and emissions during cold start of direct injection (DI) diesel engine

Through experiments conducted on a single cylinder direct injection (DI) diesel engine, effects of exhaust gas recirculatoin (EGR) on combustion and emission during cold start were investigated. Combustion of first firing cycle can be promoted significantly by introducing EGR. In experiments, when partially closed choking valve and partially or fully opened EGR valve, peak cylinder pressure of first firing cycle was about 45% higher than that under normal condition without EGR, and the start of combustion (SOC) was also much earlier. EGR also had effects on combustion stability. In the case, which kept 50% or 100% opening of EGR valve (OEV) and kept 100% opening of choking valve (OCV), more stable combustion process was achieved when common rail pressure decreased during cold start. However, excessive amount of EGR led to extreme unstable combustion and even misfiring. Opacity and NO emissions were also analyzed in detail. In the case with maximum EGR, the lowest average opacity, which was less than 4%, was achieved during initial several firing cycles of cold start. But in the later phase, excessive amount of EGR led to a great deal of white smoke emission. NO emission during initial phase of cold start is mainly affected by increase in fuel amount of injection. When combustion became stable gradually, EGR showed significant effect on NO reduction.     

Effect of hydrogen addition on combustion and emissions performance of a spark-ignited ethanol engine at idle and stoichiometric conditions

Regarding the limited fossil fuel reserves, the renewable ethanol has been considered as one of the substitutional fuels for spark ignition (SI) engines. But due to its high latent heat, ethanol is usually hard to be well evaporated to form the homogeneous fuel–air mixture at low temperatures, e.g., at idle condition. Compared with ethanol, hydrogen possesses many unique combustion and physicochemical properties that help improve combustion process. In this paper, the performance of a hydrogen-enriched SI ethanol engine under idle and stoichiometric conditions was investigated. The experiment was performed on a modified 1.6 L SI engine equipped with a hydrogen port-injection system. The ethanol was injected into the intake ports using the original engine gasoline injection system. A self-developed hybrid electronic control unit (HECU) was adopted to govern the opening and closing of hydrogen and ethanol injectors. The spark timing and idle bypass valve opening were governed by the engine original electronic control unit (OECU), so that the engine could operate under its original target idle speed for each testing point. The engine was first fueled with the pure ethanol and then hydrogen volume fraction in the total intake gas was gradually increased through increasing hydrogen injection duration. For a specified hydrogen addition level, ethanol flow rate was reduced to keep the hydrogen–ethanol–air mixture at stoichiometric condition. The test results showed that hydrogen addition was effective on reducing cyclic variations and improving indicated thermal efficiency of an ethanol engine at idle. The fuel energy flow rate was reduced by 20% when hydrogen volume fraction in the intake rose from 0% to 6.38%. Both flame development and propagation periods were shortened with the increase of hydrogen blending ratio. The heat transfer to the coolant was decreased and the degree of constant volume combustion was enhanced after hydrogen addition. HC and CO emissions were first reduced and then increased with the increase of hydrogen blending fraction. The acetaldehyde emission from the hydrogen-enriched ethanol engine is lower than that from the pure ethanol engine. However, the addition of hydrogen tended to increase NO_x emissions from the ethanol engine at idle and stoichiometric conditions.     

柴油机燃用甲醇的应用研究和进展

简单介绍了甲醇燃料在柴油机中燃烧所存在的问题及应用。并介绍了西安交通大学在此方面的一些研究进展,认为在一定的技术措施下,甲醇可以应用于柴油机,以替代或部分替代柴油;并可减少发动机的碳烟颗粒和NOx的排放,但不同的技术方法对CO和HC排放的影响不同。     

Combustion,performance and emissions of ULSD,PME and B50 fueled multi-cylinder diesel engine with naturally aspirated hydrogen

An experimental study was conducted on a diesel engine fueled with ultra-low sulfur diesel (ULSD), palm methyl ester (PME), a blended fuel containing 50% by volume each of the ULSD and PME, and naturally aspirated hydrogen, at an engine speed of 1800 rev min⁻¹ under five loads. Hydrogen was added to provide 10% and 20% of the total fuel energy. The following results are obtained with hydrogen addition. There is little change in peak in-cylinder pressure and peak heat release rate. The influence on fuel consumption and brake thermal efficiency is engine load and fuel dependent; being negative for the three liquid fuels at low engine loads but positive for ULSD and B50 and negligible for PME at medium-to-high loads. CO and CO₂ emissions decrease. HC decreases at medium-to-high loads, but increases at low loads. NO_x emission increases for PME only but NO₂ increases for the three liquid fuels. Smoke opacity, particle mass and number concentrations are all reduced for the three liquid fuels.     

The effect of HRG gas addition on diesel engine combustion characteristics and exhaust emissions

Extensive studies have been dedicated in the last decade to the possibility to use hydrogen in the dual-fuel mode to improve combustion characteristics and emissions of a diesel engine. The results of these studies, using pure hydrogen or hydrogen containing gas produced through water electrolysis, are notably different.The present investigation was conducted on a tractor diesel engine running with small amounts of the gas—provided by a water electrolyzer—aspirated in the air stream inducted in the cylinder. The engine was operated at light and medium loads and various speeds.It was found that the addition of HRG gas has a slight negative impact, up to 2%, on the engine brake thermal efficiency. Smoke is significantly reduced, up to 30%, with HRG enrichment, while NO_x concentrations vary in both senses, up to 14%, depending on the engine operation mode. A relative small amount of HRG gas can be used with favorable effects on emissions and with a small penalty in thermal efficiency.     

Experimental investigation of the effects of simultaneous hydrogen and nitrogen addition on the emissions and combustion of a diesel engine

Overcoming diesel engine emissions trade-off effects, especially NO_x and Bosch smoke number (BSN), requires investigation of novel systems which can potentially serve the automobile industry towards further emissions reduction. Enrichment of the intake charge with H₂ + N₂ containing gas mixture, obtained from diesel fuel reforming system, can lead to new generation low polluting diesel engines.     

Diesel engine development in view of reduced emission standards

Diesel engine development for use in light-, medium- and heavy-duty road vehicles is mainly driven by more and more stringent emission standards. Apart from air quality related emissions such as nitrogen oxides and particulates, also greenhouse gas (GHG) emissions are likely to become of more and more importance. Furthermore, oil-based fuel availability might become a problem due to limited reserves or due to political influences which leads to significantly increased fuel costs.     

Experimental investigation of the effects of separate hydrogen and nitrogen addition on the emissions and combustion of a diesel engine

An experimental investigation of the effects of separate hydrogen and nitrogen addition on the emissions and combustion of a diesel engine was performed and the results are presented in the current paper.     

Hydrogen effects on the diesel engine performance and emissions

In this research, effects of hydrogen addition on a diesel engine were investigated in terms of engine performance and emissions for four cylinders, water cooled diesel engine. Hydrogen was added through the intake port of the diesel engine. Hydrogen effects on the diesel engine were investigated with different amount (0.20, 0.40, 0.60 and 0.80 lpm) at different engine load (20%, 40%, 60%, 80% and 100% load) and the constant speed, 1800 rpm. When hydrogen amount is increased for all engine loads, it is observed an increase in brake specific fuel consumption and brake thermal efficiency due to mixture formation and higher flame speed of hydrogen gas according to the results. For the 0.80 lpm hydrogen addition, exhaust temperature and NOx increased at higher loads. CO, UHC and SOOT emissions significantly decreased for hydrogen gas as additional fuel at all loads. In this study, higher decrease on SOOT emissions (up to 0.80lpm) was obtained. In addition, for 0.80 lpm hydrogen addition, the dramatic increase in NOx emissions was observed.     

Investigation on the mixture formation,combustion characteristics and performance of a Diesel engine fueled with Diesel,Biodiesel B20 and hydrogen addition

An experimental and numerical study was performed to investigate the impact of Biodiesel B20 (blends 20% Rapeseed methyl ester with 80 % Diesel volumetric fraction) and different energetic fractions of hydrogen content (between 0 and 5%) on the mixture formation, combustion characteristics, engine performance and pollutant emissions formation. Experiments were carried out on a tractor Diesel engine, four-cylinders, four-stroke, 50 kW/2400 rpm, and direct injection. Simulations were conducted using the AVL codes (HYDSIM and BOOST 2013). Simulation results were validated against experimental data, by comparing the inline pressure, needle lift, in-cylinder pressure curves for Biodiesel B20 and pure Diesel fuels at 1400 rpm and 2400 rpm, respectively, under full load operating conditions. Good agreement with a maximum of 2.5% relative deviation on the peak results revealed that overall operation conditions Biodiesel B20 provides lower engine performance, efficiency, and emissions except the NOx which are slightly increased. The Biodiesel B20 has shorter ignition delay. By hydrogen addition to B20 with aspiration of the intake air flow the CO emissions, smoke, and total unburned hydrocarbon emissions THC decreased, while the NOx kept the same increasing trend for 1400 rpm and has not quite apparent trend for 2400 rpm. The enrichment by hydrogen of Diesel and B20 fuels has not a significant effect on ignition delay.     

Enhancing the performance of a spark-ignition methanol engine with hydrogen addition

This paper investigated the effect of hydrogen addition on enhancing the performance of a methanol engine at part load and lean conditions. The experiment was conducted on a modified spark-ignited engine equipped with an adjustable dual-fuel injection system. The engine was run at an engine speed of 1400 rpm with two hydrogen volume fractions in the intake of 0% and 3%. The test results illustrated that the engine cyclic variation was eased and the brake thermal efficiency was enhanced after the hydrogen blending. Besides, the hydrogen enrichment was effective on reducing the flame development and propagation periods. HC and CO emissions were generally reduced after the hydrogen blending. NOx emissions from the hydrogen-blended methanol engine could be dropped to a low level when the engine was run under high excess air ratios.     

柴油机燃用生物柴油排气氧化催化实验研究

为改善高原地区车用柴油机的排放,进行了柴油机燃用生物柴油并加装柴油机氧化催化转化器（DOC）的发动机台架试验研究。结果表明,加装DOC后,柴油机烟度、CO和HC排放显著降低,对其动力性能、经济性能和NOx排放影响则很小。     

进气道喷甲醇对柴油机性能及排放影响的研究

在增压柴油机的进气道上加装甲醇喷射系统,研究不同甲醇喷射比例对柴油机性能和排放的影响.结果表明,用甲醇替代部分柴油,在外特性试验中,甲醇的喷入扩展了发动机扭矩和功率范围,最大升高幅值分别为12.1％和12.0％.同时,柴油的消耗率降低,最大降幅为22.6％,使用经济性有所改善,费用支出率最高降幅为15.2％,但高转速高负荷时费用支出率升高了4.4％.进气道喷甲醇有效抑制了NOx的排放,最高降幅达到84.5％,碳烟的排放升高.