Comparative modeling of biological nutrient removal from landfill leachate using a circulating fluidized bed bioreactor (CFBBR)

Anaerobically digested swine wastewater contains high concentrations of phosphorus (P) and nitrogen (N). A pilot-scale experiment was carried out for nutrients removal and recovery from anaerobically digested swine wastewater by struvite crystallization. In the pilot plant, a sequencing batch reactor (SBR) and a continuous-flow reactor with struvite accumulation devices were designed and employed. The wastewater pH value was increased by CO(2) stripping, and the struvite crystallization process was performed without alkali and Mg(2+) additions. Results of the long-term operation of the system showed that, both reactors provided up to 85% P removal and recovery over wide ranges of aeration times (1.0-4.0 h), hydraulic retention times (HRT) (6.0-15.0 h) and temperatures (0-29.5°C) for an extended period of 247 d, in which approximate 30% of P was recovered by the struvite accumulation devices. However, 40-90% of NH(4)(+)-N removed was through air stripping instead of being immobilized in the recovered solids. The recovered products were detected and analyzed by scanning electron microscope (SEM), X-ray diffraction (XRD) and chemical methods, which were proved to be struvite with purity of more than 90%. This work demonstrated the feasibility and effects of nutrients removal and recovery from anaerobically digested swine wastewater by struvite crystallization without chemical additions.     

Product recovery optimization in closed-loop supply chain to improve sustainability in manufacturing

When business practices shift from a traditional open supply chain to a closed loop instead, the environmental and societal issues are efficiently integrated in business development. However, even an efficiently integrated shift introduces a number of trade-offs due to the contradictory goals that emerge from that business’s economical, environmental and social dimensions. In this paper, we propose a multi-objective mixed integer mathematical problem for a generic closed-loop supply chain (CLSC) network to rationalise how a system’s product recovery helps to improve manufacturing sustainability. The CLSC network proposed in this study consists of a hybrid manufacturing facility, warehouse, distribution centres, collection centres and a hybrid recovery facility (HRF). The proposed model determines the best location for the HRF and optimal flow of products, recovered parts and material in the network while it simultaneously maximises profit, saves activity costs, helps to decrease the harmful effects of the manufacturing process and makes a positive impact on societal development. To validate the model, a numerical illustration with the help of a case study from an electrical manufacturing industry is offered. The results authenticate the approach of the model towards the fulfilment of various environmental regulations. A sensitivity analysis, completed on demand, and the return rate also assists decision-makers to manage their decisions with a broader insight towards manufacturing sustainability.     

A model for the evaluation of environmental impact indicators for a sustainable maritime transportation systems

Maritime shipping is considered the most efficient, low-cost means for transporting large quantities of freight over significant distances. However, this process also causes negative environmental and societal impacts. Therefore, environmental sustainability is a pressing issue for maritime shipping management, given the interest in addressing important issues that affect the safety, security, and air and water quality as part of the efficient movement of freight throughout the coasts and waterways and associated port facilities worldwide. In-depth studies of maritime transportation systems (MTS) can be used to identify key environmental impact indicators within the transportation system. This paper develops a tool for decision making in complex environments; this tool will quantify and rank preferred environmental impact indicators within a MTS. Such a model will help decision-makers to achieve the goals of improved environmental sustainability. The model will also provide environmental policy-makers in the shipping industry with an analytical tool that can evaluate tradeoffs within the system and identify possible alternatives to mitigate detrimental effects on the environment.     

Energy recovery from waste incineration: economic aspects

If we consider the desirability of reducing fossil fuel consumption, together with the increasing production of combustible solid wastes, there is clearly a need for waste treatment systems which achieve both volume reduction and energy recovery. Direct incineration method is one such system. The aim of this work was to analyze the municipal solid waste incineration situated in the Province of Turin (Piedmont, North Italy), especially its economical effects in consequence of the energy recovery that can be achieved. In order to perform this analysis, two kinds of energy recovery have been studied: electric energy (electrical configuration) only, and both electric and thermal energy (cogenerative configuration). So after a reconstruction of the economic situation, by considering all the costs and revenues, for both the possible energetic configurations the correspondence between the environmental convenience (that was evaluated in a previously work) and the economic convenience has been defined. The main obtained results highlight that currently the environmental convenience corresponds to the cogenerative configuration; instead the economical convenience in the actual condition corresponds to the only electric configuration. Anyway, by working on the thermal energy price, it is possible to obtain at the same time an environmental and economic convenience.     

A prototype system for economic,environmental and sustainable optimization of a chemical complex

A prototype of a chemical complex analysis system has been developed and used to demonstrate optimization of a chemical complex. The system incorporates economic, environmental and sustainable costs, and solves a MINLP for the best configuration of plants. It was applied to expanding production of sulfuric and phosphoric acid capacities and to evaluating heat recovery options at a major chemical company, and the results were compared to the company's case study. The system selected the better of two sites for required new phosphoric and sulfuric acids production capacities and selected, sited, and sized the optional heat-recovery and power-generation facilities. System capability was demonstrated by duplicating and expanding the industrial case study. A second application of the prototype was based on an agricultural chemical complex with ten multiple plant production units as found in the Baton Rouge–New Orleans, Mississippi river corridor. The optimal configuration of units was determined based on economic, environmental and sustainable costs. A comparison of the current configuration with the optimal one was made, and sensitivity to cost and prices was analyzed. The profit increased about 7.8% from the base case to the optimal solution. Also, environmental cost declined about 17%, and sustainability costs increased about 1.5%. These results illustrated the capability of the system to select an optimum configuration of plants in an agricultural chemical complex and to incorporate economic, environmental and sustainable costs. A brief sensitivity study gave predictable results and demonstrated additional capabilities of the system. Electronic Publication     

Selection of Packaging Systems in Supply Chains from a Sustainability Perspective: The Case of Volvo

The purpose of this article is to develop an evaluation model for the selection of packaging systems in supply chains from a sustainability perspective. A theoretical evaluation model for comparing cost efficiency and the environmental impact of packaging systems in supply chains are developed from literature. The model is tested in a case study of a supply chain involving Volvo Car Corporation and Volvo Logistics Corporation, comparing the use of newly developed, one‐way packaging with the sustainability of returnable packaging. The model compares the environmental and economic impacts of two packaging systems in a specific supply chain. The criteria used in the model are (i) packaging fill rate, (ii) packaging material, (iii) transport, (iv) material handling, (v) waste handling and (vi) administration. In the case study, the one‐way packaging resulted in fewer economic and environmental impacts, thereby indicating the importance for companies to question their packaging systems. The model has been tested on one component in a case study. It provides a comparison of the packaging choices included using comparative, but not absolute, figures for the economic and environmental impacts. Managers can use the model to compare packaging systems for component supply and determine the most sustainable packaging from environmental and economic perspectives. The case study indicated that the returnable packaging system commonly used in the automotive industry is not always preferable in terms of sustainability. The article fulfils the need to evaluate the impact of packaging systems on supply chain sustainability in terms of economic and environmental criteria. Copyright © 2012 John Wiley & Sons, Ltd.     

Metallurgical recovery of metals from electronic waste: a review

Waste electric and electronic equipment, or electronic waste, has been taken into consideration not only by the government but also by the public due to their hazardous material contents. In the detailed literature survey, value distributions for different electronic waste samples were calculated. It is showed that the major economic driver for recycling of electronic waste is from the recovery of precious metals. The state of the art in recovery of precious metals from electronic waste by pyrometallurgical processing, hydrometallurgical processing, and biometallurgical processing are highlighted in the paper. Pyrometallurgical processing has been a traditional technology for recovery of precious metals from waste electronic equipment. However, state-of-the-art smelters are highly depended on investments. Recent research on recovery of energy from PC waste gives an example for using plastics in this waste stream. It indicates that thermal processing provides a feasible approach for recovery of energy from electronic waste if a comprehensive emission control system is installed. In the last decade, attentions have been removed from pyrometallurgical process to hydrometallurgical process for recovery of metals from electronic waste. In the paper, hydrometallurgical processing techniques including cyanide leaching, halide leaching, thiourea leaching, and thiosulfate leaching of precious metals are detailed. In order to develop an environmentally friendly technique for recovery of precious metals from electronic scrap, a critical comparison of main leaching methods is analyzed for both economic feasibility and environmental impact. It is believed that biotechnology has been one of the most promising technologies in metallurgical processing. Bioleaching has been used for recovery of precious metals and copper from ores for many years. However, limited research was carried out on the bioleaching of metals from electronic waste. In the review, initial researches on the topic are presented. In addition, mechanisms and models of biosorption of precious metal ions from solutions are discussed.     

聚合物基碳纤维复合材料废弃物的几种处理方法分析

从环保和可持续发展角度出发,并结合我国碳纤维(CF)生产与使用实际情况,对聚合物基碳纤维复合材料(CFRP)废弃物处理必要性作了较为详尽的阐述。根据CFRP废弃物种类,提出了机械材料再循环法、材料再循环与能量回收法、能量回收焚烧法三种可行处理方法,并从处理费用、环境影响、替代用途三方面对多种处理方案进行了合理评估。综合考虑处理环境影响、经济效益及替代物使用性能等因素,材料再循环与能量回收法为处理CFRP废弃物最合适的方法。此外,为推进其后期处理工作的顺利进行,还从内部、外部因素两方面提出相关建议。     

Multidimensional life cycle assessment on various moulded pulp production systems

Moulded pulp has been used as an alternative to plastic in certain packaging applications, but some problems in the production system lead to higher costs including energy consumption. Industry tends to operate on the basis of experience rather than through scientific evaluation and systematic design methods. The research aims at detecting the problems in the production system by a multidimensional life cycle assessment (MLCA) with transparent analysis. The MLCA measures the performance of the moulded pulp production system with regard to technical, economic and environmental aspects and produces quantitative results (in monetary units), and finally indicates the overall efficiency of the production system using a sustainability index (SI). A life cycle impact assessment method based on endpoint modelling (LIME) is mainly adopted in the MLCA. Three existing moulded pulp production systems for industrial packaging in China were assessed in this study. The results show that the main environmental impacts of the three production systems are the atmospheric emissions and landfill waste; the drying stage in the production systems, which is dominated by consumption of resources and environmental impacts, is the key to controlling costs; steam should be the first preferred heat source in the drying process for achieving sustainability in the moulded pulp production system. The optimum for the three cases is identified by calculating the newly developed SI. The MLCA approach can be used to assist in identifying potential improvements and practical new packaging designs. Copyright © 2009 John Wiley & Sons, Ltd.     

Production of green energy from co-digestion: perspectives for the Province of Cuneo, energetic balance and environmental sustainability

In Italy and many European countries, energy production from biomass is encouraged by strong economic subsidies so that biomass energy plants are getting large diffusion. Nevertheless, it is necessary to define the environmental compatibility taking into account global parameters as well as environmental impacts at regional and local scales coming from new polluting emissions. The environmental balances regarding new energy plants are of primary importance within very polluted areas such as Northern Italy where air quality limits are systematically exceeded, in particular for PM₁₀, NO₂, and ozone. The paper analyzes the renewable energy scenario relating to manure anaerobic digestion and biogas production for the Province of Cuneo, N–W Italy, and the environmental sustainability of the possible choices. The study is focused on energy producibility, heat and power, nitrogen oxides and ammonia emissions, GHG (greenhouse gases) balances dealing also with indirect releases of CH₄ and N₂O, as well as emissions due to energy crops production. The most important conclusion that can be drawn is that the production of renewable energy from anaerobic digestion could cover up to 13 % of the Province electricity consumption, but sustainability in terms of CO₂ emissions can be reached only through an overriding use of agricultural waste products (manure and by-products instead of energy crops) and cogeneration of thermal energy at disposal; the application of the best available techniques to waste gas cleaning, energy recovery, and digestate chemical–physical treatments allows positive emissive balances.     

Collaborative profitable pollution prevention: an approach for the sustainable development of complex industrial zones under uncertain information

Pollution prevention (P2) has played an integral role in the development and implementation of technologies designed to prevent the amount of waste generated at a facility. The idea of P2 was later expanded by determining minimum system material and energy requirements, thus reducing the amount of raw materials and economic investment needed. This principle, which considers environmental and economic elements, was termed profitable P2 (P3). This paper, which further expands on the principles of P2 and P3, focuses on utilizing the idea of collaborative P3 (CP3) to aid in decision-making toward sustainable development. CP3 includes a system modeling and analysis methodology, which provides industrial decision-makers with the ability to assess the industrial units’ state of sustainability, evaluate future production options, and aid in the selection of the production plan with the best possibility of working toward the sustainable development of not only a single unit, but also of the overall industrial zone. To demonstrate the efficacy of the methodology, a comprehensive study on sustainable development of an auto-manufacturing focused industrial zone is illustrated.     

Packaging's Role in Minimizing Food Loss and Waste Across the Supply Chain

This paper presents the results of Australian research that explored the role of packaging in minimizing food waste in the supply chain. The economic, social and environmental costs of food waste have been well documented elsewhere. This research contributes to the debate by identifying opportunities to reduce or recover food loss and waste through improved packaging. In the fresh produce sector, e.g. waste can be reduced through the use of packaging that improves product protection, ventilation and temperature control. Other opportunities include improved design of distribution packaging to reduce damage in transport and handling; design of primary packaging to reduce waste in the home, e.g. through appropriate portion sizes and by reducing confusion over date labels; and the use of retail‐ready packaging that minimizes handling and improves stock rotation in stores. An important conclusion of the study is that packaging can have a significant impact on reducing food waste in the food supply chain; and in some cases, a focus on reducing food waste will require more rather than less packaging. Packaging developers must therefore consider the product and its packaging as a complete system to optimize sustainability. Copyright © 2015 John Wiley & Sons, Ltd.     

政府补贴下乡村农药包装废弃物回收模式研究

针对农药包装废弃物微小利用价值以及积少成多的环境危害特点,结合政府补贴的激励机制,分别以农药生产商、农药零售商或第三方回收商作为回收主体,基于斯塔克伯格博弈分析回收主体之间的行为,分析在政府补贴下回收系统总利润的变化以及包装废弃物回收率的变化。分析结果表明:零售商回收模式在3种回收模式中为最佳的乡村农药包装废弃物的回收模式,可以同时达到回收系统总利润最优以及回收率最大,能实现经济效益与环境效益双赢。     

Biotechnological recovery of heavy metals from secondary sources—An overview

The demand for heavy metals is ever increasing with the advance of the industrialized world, whereas worldwide reserves of high-grade ores are diminishing. However, there exist large stockpiles of low and lean grade ores that are yet to be exploited. In addition, heavy metals that are present in a spectrum of waste streams including mine drainage, industrial effluents, river sediments, electronic scraps and ashes are also available for recovery and utilization. Heavy metal recovery from low and lean grade ores using conventional techniques such as pyrometallurgy, etc. chemical metallurgy encompass several inherent constraints like, high energy and capital inputs, and high risk of secondary environmental pollution. As environmental regulations become ever more stringent, particularly regarding the disposal of toxic wastes, the costs for ensuring environmental protection will continue to rise. Therefore, there is a need to utilize more efficient technologies to recover heavy metals from secondary sources in order to minimize capital outlay, environmental impact and to respond to increased demand. Biohydrometallurgy, which exploits microbiological processes to recover heavy metal ions, is regarded as one of the most promising and revolutionary biotechnologies. The products of such processes are deposited in aqueous solution thereby rendering them to be more amenable to containment, treatment and recovery. On top of this, biohydrometallurgy can be conducted under mild conditions, usually without the use of any toxic chemicals. Consequently, the application of biohydrometallurgy in recovery of heavy metals from lean grade ores, and wastes, has made it an eco-friendly biotechnology for enhanced heavy metal production.     

Recycling of solid waste rich in organic nitrogen from leather industry: mineral nutrition of rice plants

The leather industry produces a large quantity of solid waste (wet blue leather), which contains a high amount of chromium. After its removal from wet blue leather, a solid collagenic material is recovered, containing high nitrogen levels, which can be used as a nitrogen source in agriculture. In order to take more advantage of the collagen, it was enriched with mineral P and K in order to produce NPK formulations. The objective was also to evaluate the efficiency of such formulations as a nutrient supply for rice plants in an Oxisoil, under greenhouse conditions. The application of PK enriched-collagen formulations resulted in N contents in the vegetative parts and grains of rice plants which were equivalent or superior to those obtained with urea and commercial NPK formulations.     

工业余热热泵及余热网络化利用的研究现状与发展趋势

当前工业能源消耗中所排放的低品位余热量大面广,若采用高效的余热利用技术将这部分余热回收,将具有显著的节能效果。工业余热热泵技术可以实现余热品位的提升或容量的扩大,一方面可以将回收的热量应用到工业流程中,另一方面可以在区域供热及供冷方面发挥作用。本文分析了压缩式热泵、吸收式热泵与化学热泵的特点与发展趋势。目前三种热泵技术都在工质、循环以及系统创新方面得到了较大的发展,但是在容量、能效比、温升与可靠性方面存在不可兼得的瓶颈问题。此外,工业余热根据种类以及温度品位的不同,适用场合与特点也各不相同。但目前在余热回收利用的设备与系统方面,缺乏针对不同余热特点的指导性设计准则。未来的研究需要集中在发展效率高、容量大、热适应性好、稳定可靠的热泵技术,形成各余热热泵互补利用的广谱化设计准则。同时需要通过对余热的热、电、冷、储、运的网络化利用进行余热系统高质化集成,实现工业余热的高效利用。     

Using integrated process and microeconomic analyses to enable effective environmental policy for shale gas in the USA

As one of the largest consumers of energy and emitters of greenhouse gases in the world, the USA must balance energy demand and security with environmental responsibility. Recently, shale gas has emerged as a promising element toward a solution to this dilemma. Currently, shale gas production is regulated under the same rules that govern traditional oil and gas operations, without consideration for the unique environmental challenges associated with the unconventional gas extraction process. It involves small independent operators that typically utilize the most cost-effective extraction processes without necessarily prioritizing the environmental impact of their operations. As a result, opposition to shale gas extraction threatens the continuity and sustainability of the shale gas industry. The negative externalities and information asymmetry associated with this market continue to be captured in a price of natural gas which is not inclusive of the environmental costs of the extraction processes. The objective of this work is to determine the environmental policies that will lead to sustainable shale gas production. A hierarchical approach is developed to benchmark current technologies and to generate, assess and select technologies and policies that overcome market hurdles while addressing EHSS objectives. The approach analyzes the technical and microeconomic impacts of environmental remediation techniques and then takes a multipronged policy approach which supports the microeconomic, environmental, health and safety goals. To illustrate the usefulness of the proposed approach, a case study is solved for the Barnett Shale play to assess at the microeconomic and environmental implications of environmental remediation technologies for shale gas operations. Based on the results of the analysis, technology changes create both economic and environmental benefits for operators indicating a market failure resulting in the priceless favorable technologies do not reflect their impact on the environment. The market failures in the process are analyzed and four policy alternatives to the status quo are evaluated against four policy goals. The primary recommendation resulting from the analysis, the Comprehensive policy alternative, uses a phased approach to drive ongoing innovation in the shale gas industry, stimulate demand for natural gas and reduce the information asymmetry. The implementation of this policy is then applied to an economic and environmental model of a cluster of wells in the Barnett Shale to determine how the policy would be implemented.     

An integrated computer-aided system for generation and evaluation of sustainable process alternatives

This paper presents an integrated system for generation of sustainable process alternatives with respect to new process design as well as retrofit design. The generated process alternatives are evaluated through sustainability metrics, environmental impact factors as well as inherent safety factors. The process alternatives for new process design as well as retrofit design are generated through a systematic method that is simple yet effective and is based on a recently developed path flow analysis approach. According to this approach, a set of indicators are calculated in order to pinpoint unnecessary energy and material waste costs and to identify potential design (retrofit) targets that may improve the process design (in terms of operation and cost) simultaneously with the sustainability metrics, environmental impact factors and the inherent safety factors. Only steady state design data and a database with properties of compounds, including, environmental impact factor related data and safety factor related data are needed. The integrated computer-aided system generates the necessary data if actual plant or experimental data are not available. The application of the integrated system is highlighted through a number of examples including the well-known HDA process.     

Applying industrial ecosystem indicators: case of Pielinen Karelia,Finland

This paper presents an industrial ecological insight into local waste management in Pielinen Karelia, Finland. There local system is experiencing major changes because of tightening EC waste legislation including the directives on waste incineration (2000/76/EC) and landfilling of wastes (1999/31/EC). Small local landfills are closing and most of municipal wastes will be transported 120–180 km to large-scale waste management centre in Kuopio. The paper applies three industrial ecosystem indicators, based on environmental, economic and employment impacts of different waste management technologies. Environmental indicator is CO₂ equivalent emission, economic indicator is based on costs and revenues of waste management, and social (i.e. employment) indicator includes new jobs generated. The results indicate that waste incineration option in forthcoming regional cooperation could create emission savings up to 117–394 kg CO₂ eqv./ton of municipal waste when compared to local landfilling. As economic impacts, new regional cooperation and long-distance transportations will increase the costs from previous 45.6–55.2 €/ton in local landfilling to 97.4 €/ton in regional landfilling and 120.8–126.9 €/ton in regional REF-III incineration. In terms of employment, the new cooperation could create 2–6.5 new jobs. The regional cooperation results to rising operational costs but avoids investments to new local infrastructure. It also creates significant emission savings, maintains current employment in waste handling and creates new jobs in long-distance transportation.

Indicators of sustainability: assessing the suitability of a foreign technology for a developing economy

Some of the primary objectives for importing foreign technology into developing economies are to provide essential amenities like potable water, stable electrical supply, and functional communication and health facilities. It is also aimed at improving the industrial development bases in order to achieve technological advancement. However, historical trends bear witness to the fact that a majority of these efforts by the governments of developing countries have failed because such technologies are not sustainable. This paper identifies a number of indices that decision makers can use to assess the suitability of a foreign technology being considered for import into the local economy and its likely sustainability over the long term. By identifying and examining sustainability factors in relation to the socio-political contexts of a specific culture and its techno-economic level of development, and by considering such factors in the decision-making process, the selection of appropriate technologies can be greatly enhanced and the enormous waste of economic resources can be avoided.