退火处理对异种钢激光焊接头组织及性能的影响

目的 通过研究相同时间不同退火温度下304/Q345激光焊接头的组织和性能,得到优化后的退火处理制度,为制定异种钢激光焊退火工艺提供一定的理论指导和技术支撑。方法 基于前期大量试验,在激光功率和离焦量不变的情况下,调节焊接速度由15 mm/s到35 mm/s,通过改变焊接速度获得性能优异的焊接接头。由于异种钢物理化学性能差异较大,接头组织不均匀,因此还需对激光焊接头进行退火处理。结果 焊缝区显微组织由板条马氏体与残余奥氏体组成,Q345低碳钢热影响区显微组织为多面体状铁素体与黑色珠光体,其中铁素体含量更多,304奥氏体不锈钢热影响区在奥氏体晶界上析出了铁素体。不同退火温度下碳元素均由Q345低碳钢侧向焊缝迁移,在Q345低碳钢侧形成脱碳层,在焊缝中形成黑色条带状增碳层。随着退火处理温度的升高,峰值温度升高,高温停留时间变长,碳迁移强度随之增加,黑色条带状区域增碳层宽度增大。拉伸性能测试结果表明,试样均断裂于Q345母材一侧,且断口存在韧窝,属于典型韧性断裂。此外,焊缝区硬度(390HV左右)最高,热影响区硬度(300HV)次之,母材的硬度(130HV左右)最低。结论 在给定试验参数范围内,优化后的最佳退火工艺参数为550 ℃-1.5 h。     

2205双相不锈钢GTAW焊接接头组织演化

研究了ER2205不锈钢在固定焊接参数条件下的自动TIG焊接接头的两相组织演化规律。结果表明:受到原始焊道热作用的TIG焊缝具有约50%～60%的铁素体相比例,对应热影响区中的铁素体含量高达70%;随着焊接过程的进行,受到后续焊道热作用影响的焊缝和热影响区的铁素体含量持续降低;在后续焊道焊接过程中焊缝组织不断析出奥氏体相,铁素体相比例不断降低;热影响区中的铁素体含量受到自身焊道和后续一个焊道的影响比较明显;焊缝中部焊道的铁素体相比例低于打底焊道和盖面层焊道。     

13MnNiMoNbR与00Cr19Ni10异种钢焊接接头的组织与性能

首先将H309L焊丝堆焊在13MnNiMoNbR钢板坡口上,再将堆焊后的13MnNiMoNbR钢板与00Cr19Ni10钢板用H308L焊丝填充焊接,得到了13MnNiMoNbR与00Cr19Ni10异种钢焊接接头,并对接头的显微组织及硬度进行了分析。结果表明：13MnNiMoNbR钢板侧熔合线附近出现了粗大的铁素体组织,形成脱碳层,而H309L焊缝侧的奥氏体堆焊层熔合线附近出现了黑色的非常细小的碳化物析出层;由于碳化物的析出或是固溶碳,使H309L焊缝侧增碳层处的硬度明显升高。     

母材中碳进入熔池方式及其影响研究

归纳并提出了熔地母材中碳进入熔池中的方式，在此基础上，探讨了焊态下熔焊接头中脱／增碳层的形成原因，形成时期以及焊缝不均匀混合区中的碳分布特点。得出”母材中碳以机械混合唱 ，母材团，扩散混合三种方式进入熔池 态下，母材侧不完全熔化区因碳扩散鸸菜成了不明显的脱碳层，焊缝侧不均匀混合区因多为源方式而形成了碳分布不均匀的增碳层。利用异种接头金相观察和硬度测试结果。验证了所得结论的正确性。     

耐热钢焊缝中铁素体带消除的研究

研究了降低退火参数、固碳、提高平均相变点A_1等对耐热钢焊缝中的铁素体带的影响,结果表明,降低退火温度能有效地消除铁素体带,减少退火时间能细化铁素体带晶粒;引入强碳化物形成元素,能够消除铁素体带,但是对焊缝的强韧性影响复杂;提高相变点A_1温度,能够抑制铁素体带的产生,改善焊缝金属的力学性能。     

高强度贝氏体钢板不同焊接方法接头的组织和性能

利用二氧化碳保护焊、埋弧焊、手工电弧焊研究了高强度贝氏体钢板焊接接头的组织和力学性能.结果表明:二氧化碳保护焊焊后不热处理接头焊缝组织为贝氏体、少量铁素体和珠光体,热影响区为新型贝氏体组织;手工焊焊后不热处理焊缝组织主要为块状铁素体和少量珠光体,热影响区组织为新型贝氏体组织;埋弧焊焊后不热处理焊缝部分组织为针状铁素体,熔合线结合良好,组织分布均匀,晶粒细小,热影响区组织为新型贝氏体.各种焊接方法焊接接头具有良好的强韧性.     

2205双相不锈钢TIG焊接头组织及力学性能

对2205双相不锈钢进行了4组不同热输入条件下的TIG焊接实验,采用光学显微镜、扫描电镜和透射电镜对焊接接头的显微组织进行了观察与分析,并测试了焊接接头的拉伸力学性能和显微硬度。结果表明:在热影响区,随着热输入的增大,不完全再结晶区带状奥氏体宽度逐渐增大,粗晶区铁素体晶粒的粗化程度逐渐加剧、奥氏体体积分数逐渐增多;在焊缝金属中,随着热输入的增大,魏氏奥氏体逐渐减少,而块状奥氏体逐渐增多,魏氏奥氏体在高温下稳定性差,容易被相界处形成的窄条铁素体分割成块状奥氏体。随着热输入的增大,焊接接头的屈服、抗拉强度逐渐降低,断后延伸率逐渐升高。铁素体体积分数较高的热影响区显微硬度最大,焊缝金属的合金元素含量较高,因此其显微硬度高于母材。     

焊丝成分对超高强装甲钢焊接接头组织与性能的影响

利用气体保护电弧焊工艺完成了4.5 mm和9.0 mm超高强装甲钢的焊接,研究了焊丝(MG70S-6和ER307Si焊丝)成分对接头组织与性能的影响,通过光学显微镜(OM)、扫描电子显微镜(SEM)、能谱分析(EDS)、X射线衍射(XRD)等表征方法对焊接接头各区域进行微观组织和物相结构的分析,并测试了接头的硬度分布、拉伸性能和冲击韧性。结果表明,焊接接头成形质量良好,无明显未熔合、气孔、裂纹等缺陷,焊缝区组织为片状马氏体、针状铁素体和少量粒状贝氏体,完全淬火区组织为马氏体和贝氏体,不完全淬火区组织为马氏体和铁素体,回火区析出网状渗碳体。焊接接头的热影响区软化现象较为明显,接头难以达到与母材等强,断裂主要发生在焊缝区,呈现出脆性断裂特征。采用ER307Si焊丝焊接的9.0 mm装甲钢接头的焊缝室温冲击功达到94 J,完全满足使用要求。     

热输入对Q1100钢焊接接头低温韧性及耐蚀性能的影响

采用10 kJ/cm和15 kJ/cm两种焊接热输入对Q1100超高强钢进行熔化极气体保护焊,研究焊接接头的组织性能及局部腐蚀行为。结果表明：两种热输入焊接接头的焊缝组织主要为针状铁素体和少量的粒状贝氏体,粗晶区组织均为板条贝氏体,细晶区组织均为板条贝氏体和粒状贝氏体,临界相变区组织为多边形铁素体、马奥岛和碳化物的混合组织。两种热输入焊接接头中电荷转移电阻均为母材>热影响区>焊缝区,母材耐蚀性最好,热影响区次之,焊缝区耐蚀性最差。在腐蚀过程中,焊缝区作为阳极最先被腐蚀,当腐蚀一定时间后,腐蚀位置发生改变,阳极腐蚀区域转移到母材区,而焊缝区作为阴极得到保护。热输入为10 kJ/cm时,焊接接头具有更好的低温韧性和耐蚀性,其焊缝和热影响区-40℃冲击功分别为46.5 J和30.2 J。     

30CrMnSiNi2A与Q235异种钢焊接接头组织与性能分析

目的探讨30CrMnSiNi2A与Q235异种钢焊接接头的组织与性能。方法采用手工电弧焊对两者进行焊接,为了获得性能良好的焊接接头,焊前对其进行焊前预热,焊后对其进行焊后退火。通过X射线探伤检测,拉伸、冲击试验,显微硬度检测及光学显微镜金相分析等一系列工艺试验,对焊接接头进行研究。结果焊缝质量等级达到Ⅰ级;焊缝组织为先共析铁素体、针状铁素体、珠光体组织;30CrMnSiNi2A侧热影响区组织为回火索氏体,粗晶区组织片层厚度大于细晶区组织片层厚度;Q235侧热影响区由不完全重结晶区、细晶区、粗晶区组成。结论 30CrMnSiNi2A与Q235钢焊接后,获得了工艺性、力学性能良好的接头,可运用于2种材料焊接的实际生产。     

基于S35140钢的超低碳成分设计和力学性能研究

S35140钢是一种基于25Ni-20Cr的奥氏体耐热钢,为了获得高强度,通常会提高碳含量,但碳含量较高不利于高温时效稳定性和长期耐腐蚀性能.本文在S35140钢的基础上,大幅度降低碳含量,并通过调控N和Nb等微合金元素含量,以及加入Ti元素,促使析出新的强化相,弥补减少碳含量所导致的强度降低.同时引入一定量的Al元素...     

The effect of micro alloying elements (vanadium,titanium) additions on the austenite grain growth behavior in medium carbon steel containing nitrogen

The austenite grain growth behavior of microalloying elements free steel (nitrogen steel) and micro alloyed steel (V−N steel and V−Ti−N steel) was investigated. The equilibrium dissolving behavior of precipitates was calculated by thermodynamic software and the morphology was observed by tunneling electron microscope. Moreover, grain growth kinetics was analyzed through theoretical calculation. Results show that the austenite grain size of V−N steel and V−Ti−N steel are significantly refined by the undissolved precipitates compared to nitrogen steel. Due to higher dissolving temperature of (vanadium, titanium)(carbon, nitrogen), the austenite grain of V−Ti−N steel keeps fine and increases slowly from 900 °C to 1250 °C. The difference of activation energy between V−N steel and V−Ti−N steel was supposed to come from the effect of different kinds of precipitates on the austenite grain growth. Compared to the vanadium rich (vanadium, titanium)(carbon, nitrogen), the titanium rich (vanadium, titanium)(carbon, nitrogen) is larger and more stable in view of its existence at higher temperature. The decrease of pinning forces can be attributed to the decrease of volume fraction and increase of radius of (vanadium, titanium)(carbon, nitrogen). Compared with critical grain sizes, the larger experimental grain sizes lead to grain growth from 900 °C to 1250 °C.     

碳氮含量对含钒铁素体不锈钢高温性能的影响

为研究碳氮含量对其高温热拉伸及热压缩性能的影响,以含钒铁素体不锈钢为实验材料,采用Gleeble3500试验机进行热模拟实验,并对热压缩后试样的显微组织进行了金相观察和SEM检测,对析出相采用TEM分析.结果表明:钒元素的加入在一定程度上提高了材料的高温性能;在实验设计的成分范围内,较高的氮含量和低的碳含量组合能在保证材料韧塑性的前提下提高强度;热压后缓冷至室温,材料中将出现部分马氏体组织.     

Ferrite recrystallisation and characteristics of non-recrystallised ferrite grains in Ti added low carbon steels

The progress of ferrite recrystallisation in low carbon steel was slower than in ultralow carbon steel. The hardness of the non-recrystallised ferrite grains gradually decreased with increasing annealing time in ultralow carbon steel, but gradually increased with increasing annealing time in low carbon steel. The amount of Ti containing precipitates increased slightly during annealing in ultralow carbon steel, but increased remarkably with increasing annealing time in low carbon steel. These results suggest that the softening of non-recrystallised ferrite grains during annealing in ultralow carbon steel may reflect the progress of recovery and the Ostwald ripening of Ti containing precipitates formed during annealing. In contrast, the hardening of non-recrystallised ferrite grains in low carbon steel may be due to the precipitation hardening of TiC formed during annealing.     

低碳含V微合金钢析出物的双亚点阵模型热力学研究

钢中碳氮析出物通过细晶强化和析出强化方式对钢的力学性能有非常重要的作用.基于规则溶液的双亚点阵模型(其中一个为金属亚点阵,另一个为间隙原子亚点阵)建立了碳氮化钒及碳氮化钛的热力学计算模型,用以研究析出物的析出开始温度、给定温度的奥氏体成分.经计算得V(CxN1-χ)、Ti(CxN1-χ)的析出温度分别是833℃、1343℃,最大的摩尔分数为7.8×10-4.     

Copper bearing microalloyed ultrahigh strength steel on a pilot scale: Microstructure and properties

In the present study, copper bearing low carbon microalloyed ultrahigh strength steel has been produced on a pilot scale. Transformation of the aforesaid steel during continuous cooling has been evaluated. The steel sample has been thermomechanically processed followed by either air cooling or water quenching. Variation in microstructure and mechanical properties at different finish rolling temperatures has been studied. A mixture of granular bainite, bainitic ferrite and precipitation of nano-sized (Ti, Nb)C particles is the characteristic microstructural feature of air cooled steel. On the other hand, predominantly lath martensitic structure along with the similar type of microalloying precipitates of air cooled steels and Cu precipitates are obtained in case of water quenched steel. The best combination of strength (1364-1403 MPa) and ductility (11-14%) has been achieved for the selected range of finish rolling temperature of water quenched steel.     

Zr对Ti微合金化低碳钢形变奥氏体再结晶和析出相的影响

通过多道次模拟压缩实验，研究不同Zr和Ti含量的三种Ti微合金化低碳钢在950℃~1050℃形变奥氏体再结晶和析出相的变化和最佳变形温度。结果表明，Ti含量的提高和Zr的加入使Ti微合金钢形变奥氏体的再结晶和晶粒长大延迟。Zr的加入还能增加Ti微合金钢中析出相的数量、改善析出相尺寸分布的均匀性进而得到相对均匀的奥氏体组织。变形温度为1000℃时的Ti-Zr微合金钢奥氏体组织最细小均匀。     

Dissolving behaviour of second phase particles in Nb-Ti microalloyed steel

The dissolving behaviours of second phase particles in low carbon Nb-Ti microalloyed steel during isothermal holding at 1300 °C were investigated by carbon extraction replicas, TEM and EDX analysis. The experimental results indicate that there are two types of precipitates in as-forged steel: the coarsened Ti-rich precipitates originate from solidification, and the other finer Nb-rich particles attribute to strain-induced process. The strain-induced precipitates disappear after holding for 2 h at 1300 °C, while the coarsened particles from the solidification containing Nb-bearing (Nb,Ti)(C,N) still remain even holding for 48 h. With addition of Ti to the Nb-bearing microalloyed steel, the thermal stability of the carbonitrides would enhance remarkably. These results rationalize that formation and thermostability of precipitates are considerably influenced by interaction between Nb and Ti atoms.     

Formation of precipitates in multiple microalloyed pipeline steels

Abstract

An investigation has been carried out to identify the precipitates in multiple microalloyed steels. The microalloying elements and interstitials included aluminium, niobium, titanium, vanadium, carbon, and nitrogen. It was found that the precipitates are complex in nature and they were rationalised on the basis of mutual solubility probably enhanced by non-stoichiometry. The precipitate morphologies were interpreted mainly in terms of steel compositions. Steels quenched from 1250°C contained titanium rich precipitates accompanied by the evolution of new niobium rich precipitates after hot rolling and quenching. A parameter K₁ indicative of solute participation in the precipitation phenomenon was established and showed excellent correlation between steel and precipitate analyses. A sequence of precipitation in multiple microalloyed steels was achieved using solubility relationships as a premise.

MST/803     

Microstructure and mechanical properties of Fe–7Al based lightweight steel containing carbon

The effect of carbon on the microstructure and mechanical properties of lightweight steel based on Fe–7 wt-%Al produced by air induction melting with flux cover is investigated. The ingots were hot worked to plates and were characterised. Steel containing 0.02 wt-%C exhibited a single phase microstructure Fe–Al(α), whereas steel containing 0.5 and 1.0 wt-% carbon exhibited a two-phase microstructure containing significant amounts of Fe₃AlC_0.5 precipitates in Fe–Al(α) matrix. Microhardness of the matrix decreases with increasing carbon content due to depletion of aluminium from the matrix to form Fe₃AlC_0.5 carbides. The bulk hardness, room temperature strength increases and tensile elongation decreases with increasing carbon content. However, at 873 K the improvement in strength as well as creep properties with increasing carbon content is marginal.