共查询到17条相似文献,搜索用时 187 毫秒
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血液过滤用熔喷PBT非织造布紫外辐照接枝改性研究 总被引:2,自引:1,他引:2
研究了血液过滤用熔喷PBT非织造布的紫外辐照气相接枝改性方法。通过实验选择了丙烯酸(AAc)为接枝单体 ,探讨光照时间、预辐照时间、单体温度、引发剂浓度、氮气压力对接枝率和表面润湿张力的影响 ,结果得到最佳的紫外辐照接枝条件为 :室温下 ,光距 2 0cm ,预浸 10min ,二苯甲酮 (BP) 0 .0 37mol/L ,冲入单体的氮气流量 87.5h/L ,反应时间 30min。PBT非织造布AAc紫外辐照接枝后表面润湿张力可以达到 85mN/m左右 ,且表面润湿张力随接枝率的提高而增加 相似文献
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以聚丙烯(PP)熔喷非织造布和聚偏氟乙烯(PVDF)为原料,采用氧化石墨烯(GO)和AgNO3对PP熔喷非织造布进行导电改性,在其表面浇铸PVDF溶液制得具有三明治结构的PVDF/PP熔喷非织造布复合柔性薄膜。通过扫描电子显微镜、傅里叶变换红外光谱仪、数字万能表、万能试验机对熔喷非织造布及改性试样的形貌结构、表面组成、电阻率及力学性能进行分析。结果表明:PP熔喷非织造布经GO和AgNO3改性后导电效果显著,电阻率最低可达46.5Ω·m。对复合柔性薄膜的力传感性能进行测试,发现结合S型电极片时其压力传感灵敏度最好,在传感器检测显示模组100 g量程内数值稳定仅需5 s,有望在压力检测和人体运动监测领域发挥重要作用。 相似文献
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Andinet Kumella Eticha Yasin Akgul Ayben Pakolpakcil Oğuz Kagan Unlu Harun Cug Ali Kilic 《应用聚合物科学杂志》2024,141(17):e55297
Polypropylene (PP) is a semi-crystalline polymer that displays simple manufacturing, high stiffness, lightweight, chemical resistance, and inexpensive. However, PP has significant drawbacks, such as poor brittleness at low temperatures, high shrinkage ratio, and low impact resistance, which limit its development. Thermoplastic polyurethane (TPU) possesses recyclable and eco-friendly characteristics, along with the elasticity of rubber and exceptional mechanical properties. In this study, a flexible and high-filtration performance PP-TPU textile material was developed by melt-blowing for filtering PM0.3 aerosols. For the first time, a melt-blown PP-TPU nonwoven was used as an air filter. The fiber morphological studies exhibited that addition of 10 and 20 wt.% TPU into PP resulted in a fiber diameter increment from 0.94 to 1.24 μm. Also, melt-blown PP-TPU forms helical fibers, which are different from fibers noticed in melt-blown PP. Corona-charged double-layer 80PP-20TPU nonwovens have a filtration efficiency of 99.25% and quality factor (QF) of 0.13 mm H2O−1 at an air flow rate of 95 L/min. Moreover, PP's tensile strength was increased by 72.22%, and elongation was raised by 38.1% with the addition of 20 wt.% TPU. Thus, PP-TPU melt-blown composites may bring novel perspectives into the design and development of high-performance filtering materials for a variety of applications. 相似文献
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讨论了接收距离、热风速度和温度、工作区温度等工艺参数对熔喷产品拉伸强力、断裂伸长率、过滤效率和过滤阻力等性能的影响,并分析了多重因素的影响,有助于提高产品性能和质量。 相似文献
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紫外辐照接枝HEMA改性血液过滤用PBT无纺布的研究 总被引:1,自引:0,他引:1
研究了在紫外辐照条件下,以二苯甲酮(BP)为光敏剂,以甲基丙烯酸羟乙酯(HEMA)作为表面接枝物来改性血液过滤用聚对苯二甲酸丁二醇酯(PBT)无纺布,并对接枝改性后PBT进行了红外分析、扫描电镜观察、亲水性能测试.结果显示:红外图谱证实了HEMA在紫外辐照和光敏剂BP的引发条件下成功接枝到PBT 无纺布纤维表面,光敏剂... 相似文献
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Hongtao Liu Jiangang Zhou Xiuying Liu Danying Zuo Shaojin Gu Weilin Xu 《应用聚合物科学杂志》2013,130(1):631-637
Biomedical polyurethane (BPU) and silk fibroin have similarly molecular architecture in their primary and aggregate structure, both of which have amide bonds and microphase separation, and they have been employed as scaffold materials for biomedical applications. Based on this, as the featured peptide sequence of silkworm silk fibroin, GlycineAlanineGlycineAlanine (GlyAlaGlyAla) tetrapeptide was synthesized by using traditional liquid‐phase peptide synthesis method with Boc‐protected glycine and alanine as starting materials, and was transformed to its derivative with two amine‐terminated functional groups. The derivative was introduced as a chain extender into the backbone to form the hard segment of a silk‐inspired PU with urea‐linkage. Related measurements show that molecular weight of the synthesized silk‐inspired PU ranged from 13,000 to 15,000. Fourier transform infrared (FTIR) absorption bands of Amides I and II are at 1651 cm?1 and 1534 cm?1, and Raman absorption band of Amide III is at 1302 cm?1. UV‐Vis absorption peak of the silk‐inspired PU is at 266 nm. This new concept and strategy may allow the fabrication of a new class of thermoplastic polyurethane elastomers to mimic the structure and properties of silk fibroin of silkworms and spiders. Information provided by this study may be used to better understand the correlation between the natural and man‐made materials. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013 相似文献
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Jesada Chutipakdeevong Uracha Rungsardthong Ruktanonchai Pitt Supaphol 《应用聚合物科学杂志》2013,130(5):3634-3644
Considering the outstanding biocompatibility of Bombyx mori silk fibroin, this study is designed to fabricate biomimetic nanofibrous structure made of silk fibroin, which can enhance cell activities for tissue formation. The electrospinning of blend of silk fibroin with low molecular weight poly(ethylene‐oxide) (PEO) is explored with ease of preparation for high productivities. The average diameter of electrospun silk fibroin (eSF) is decreased from 414 ± 73 to 290 ± 46 nm after PEO extraction. To induce the desired cellular activity, the surface of the eSF fibers is modified with fibronectin by using the carbodiimide chemistry method. The potential use of the obtained wound healing material is assessed by indirect cytotoxicity evaluation on normal human dermal fibroblast (NHDF) in terms of their attachment and cell proliferation. The surface‐modified eSF nanofiber mats show good support for cellular adhesion and spreading as a result of fibronectin grafting on the fiber surface, especially for cell migration inside the fibrous structure. These results demonstrate a new fabrication technique of surface‐modified silk fibroin electrospun nanofibers for biomedical application; with the ability to accelerate wound healing. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 130: 3634–3644, 2013 相似文献
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