转炉留渣双渣操作生产实践

介绍了福建三安炼钢厂的转炉留渣双渣操作,以及留渣操作中安全问题的解决措施,分析了应用留渣双渣操作工艺的石灰消耗、钢铁料耗、转炉炉龄、氧耗、冶炼周期、脱磷等效果。通过优化顶底复吹转炉留渣双渣工艺制度,提高转炉前期脱磷效果,在无铁水预处理的设备条件下可以冶炼高铬铁水,满足了对钢的洁净度要求。     

转炉留渣双渣操作生产实践

介绍了福建三安炼钢厂的转炉留渣双渣操作,以及留渣操作中安全问题的解决措施,分析了应用留渣双渣操作工艺的石灰消耗、钢铁料耗、转炉炉龄、氧耗、冶炼周期、脱磷等效果。通过优化顶底复吹转炉留渣双渣工艺制度,提高转炉前期脱磷效果,在无铁水预处理的设备条件下可以冶炼高铬铁水,满足了对钢的洁净度要求。     

酒钢120t转炉留渣加双渣工艺技术研究与应用

转炉留渣加双渣工艺是利用低温有利于脱磷反应的热力学基本原理,在同一座转炉中连续脱硅、脱磷、除渣和脱碳,酒钢采用该技术在同一座转炉中进行"留渣"加"双渣法"的少渣冶炼技术,大幅度降低了石灰、白云石等消耗,总渣量可降低25%~33%。     

转炉“留渣+双渣”炼钢工艺研究

作为当下我国钢铁产品企业生产最常应用到的工艺形态,转炉“留渣+双渣”炼钢工艺的科学应用极为关键,是提升钢铁产品整体质量与产量的关键工艺类型。文章以某钢铁产业产品企业为例,就其所应用的转炉“留渣+双渣”炼钢工艺的基本流程进行了简要分析,并详细阐述了转炉“留渣+双渣”炼钢工艺的实践要点,希望能够为同行业工作者提供一些帮助。     

转炉“留渣+双渣”少渣炼钢工艺实践

介绍了鞍钢股份有限公司炼钢总厂转炉"留渣+双渣"工艺的关键技术,包括留渣及炉渣固化技术、炉渣流动性控制及高效脱磷技术、快速足量放渣及渣铁分离技术、炉渣返干控制及终渣Fe O控制技术以及"留渣+双渣"快速生产技术,采用这些技术后,吨钢成本降低12.19元。     

转炉留渣加双渣法技术研究与应用

通过对传统双渣工艺系统分析,结合冶炼过程中存在的问题,开展了终渣留渣加双渣冶炼工艺研究,并在自动化炼钢控制方面,结合留渣加双渣工艺特点,建立倒渣和留渣模型,将前期渣炉渣组分等相关信息纳入模型计算中,优化热氧平衡。根据模型在实际生产中运行效果,调整新工艺下模型的吹炼和加料模式,促进转炉终点碳和温度命中率提升至95.6%以上,提升了新工艺下炼钢自动化控制能力,为炼钢厂整体创效奠定基础。     

150t转炉双渣及留渣工艺实践

文章通过介绍双渣、留渣炼钢工艺在包钢150 t转炉运用的效果,及在实际生产中双渣工艺所遇到的难点和解决方法,得出双渣、留渣工艺有降低渣料消耗、降低钢铁料消耗的明显效果。     

对留渣和双渣转炉炼钢工艺高效脱磷技术的思考

在钢铁生产过程中,经常会出现一些磷元素,影响钢铁生产质量。传统的去磷工艺存在效率低、污染环境、成本高,以及操作复杂等缺点,无法满足现代钢铁生产的需求。留渣和双渣转炉炼钢工艺是一种高效的脱磷技术,其通过充分利用转炉熔化期后期的热量和渣子中的氧化钙含量,有效地提高脱磷效率。并且,通过控制温度和渣子的成分,进而有效控制钢水的成分和温度,提高钢水的质量和产量。因此,文章基于此,对留渣和双渣转炉炼钢工艺高效脱磷技术进行研究。通过分析传统去磷工艺的不足,以及留渣和双渣转炉炼钢工艺高效脱磷技术的优势,以此来对留渣和双渣转炉炼钢工艺的应用提供参考。     

转炉炼钢少渣冶炼技术的探索实践

介绍转炉少渣冶炼、炉渣热循环利用实践.可分两个阶段,脱碳出钢留渣、冶炼中期脱磷倒渣留渣与脱碳出钢留渣同时进行（留渣＋双渣）.脱碳留渣冶炼,通过出钢后倒渣、调渣过程控制,抑制留渣造成吹炼前期的喷溅.留渣冶炼使吨钢石灰消耗降低28.6％.“留渣＋双渣”试验,控制转炉前期炉渣碱度及全铁,选择合适脱磷渣倒炉点及温度,保证前期渣脱磷率和泡沫化,最终前期脱磷率大于60％,排渣率大于50％.“留渣＋双渣”技术,吨钢石灰消耗降低46.9％.     

120t转炉少渣炼钢的工艺实践

文章介绍了某厂120t转炉留渣操作的工艺。阐述了留渣操作对于120t转炉经济技术指标的影响,以及留渣操作的控制实践过程。     

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RH oxygen top- blowing for raising temperature should be avoided to improve the cleaniness of IF steel as far as possible, which made the end point temperature of converter higher and then dephosphorization in converter became difficult. Thermodynamics and dynamics of dephosphorization process in converter were calculated to study the relationship of phosphate partition ratio to compositions of molten steel, slag, temperature in molten steel based on slag- remaining and double slag process. Through changing the first deslagging time and the composition of slag,then serial sampling from molten steel and slag in industrial production experiments, the behavior of phosphorus in molten steel was studied and then the main measures obtaining higher phosphate partition ratio in slag- remaining and double slag process are: small- sized scrap or thin steel sheet should be used to increase FeO content in slag and prevent molten steel temperature increase when oxygen blowing in converter begins. Slag with high phosphorus content should be poured when amount of oxygen blowing reachs 40% of the total; FeO content in slag should be increased to assure the mobility of slag and then reduce rephosphorization from slag to steel when amount of oxygen blowing is greater than 40% and less than 80% of the toal; the end- point slag with 4. 0 basicity and 18 mass%-20 mass% FeO content and molten steel temperature should be controlled.     

Effect of change of slag phase on dephosphorization of ��double- slag+slag- remaining�� steelmaking technology

The microstructure and phase constituent of dephosphorization slag of ??double- slag+slag- remaining?? steelmaking technology were observed and analyzed by SEM, part of the slag were heat treatment, and the effect of the change of slag phase on dephosphorization was studied. The research results show that the phase of dephosphorization slag A1-A3 with high dephosphorization rate are composed of calcium ferrite, complex liquid silicate phase (Ca3TiFeSi3O12, Ca54MgAl2Si16O9) and 2CaO??SiO2(C2S) solid phase solution with calcium phosphate (2Ca2SiO4??Ca3(PO4)2, Ca7(PO)4(SiO4)2), the main phase of dephosphorization slag A4 with low dephosphorization rate is liquid phase, the main phases of dephosphorization slag A5 are MnFe2O4, MnV2O4, Ca12Al14O33, little phosphorus rich calcium silicate solid phase is found in both dephosphorization slag A4 and A5; the phase of dephosphorization slag A3 changes little before and after heat treatment, but the phase of dephosphorization slag A4 changes greatly after heat treatment, which changing to liquid phase and white branches like RO phase; the dephosphorization slag of ??double- slag+slag- remaining?? steelmaking technology contain many un- dissolved CaO, but little is found in decarburization slag, the formation of C2S solid phase in dephosphorization slag plays an important role to accelerate the dephosphorization reaction.     

渣系碱度对含碳球团渣相组成和渣铁分离的影响

采用煤基直接还原熔分技术和FactSage热力学分析软件以及XRD分析手段,研究了渣系碱度wCaO/wSiO2对高铁铝土矿含碳球团渣相组成和渣铁分离效果的影响。实验结果表明,渣系碱度对含碳球团的渣系组成和渣铁分离效果有重要影响。当碱度为1.0和1.5时,粒铁尺寸最大,渣铁的分离效果最好,粒铁收得率分别为91.55%和91.86%;当碱度为0.5时,粒铁尺寸较小,渣铁分离效果较差,粒铁收得率为65.43%。当碱度为2.0时;粒铁尺寸最小,渣铁分离效果最差,粒铁收得率只有44.53%。XRD分析结果表明,当渣系碱度分别为0.5、1.0、1.5和2.0时,熔分渣的主要组成分别为α-Al2O3-CaAl2Si2O8、α-Al2O3-CaO·6Al2O3-Ca2Al2SiO7、CaO·6Al2O3-Ca2SiO4-Ca2Al2SiO7、Ca2Al2SiO7-Fe2SiO4。FeAl4O7、CaAl4O7以及金属铁在熔分渣中的含量较少。     

90 t转炉留渣双渣工艺钢中残余锰含量的控制

低锰钢一般要求控制转炉终点[Mn]≤0.05%,针对传统双渣工艺熔剂消耗成本高,留渣双渣工艺去锰不稳定的问题,基于热力学、动力学分析和现场数据分析,研究了碱度炉渣（R 1.68~2.00）、温度（1340~1460℃）及渣中FeO含量（FeO）(15.5%~18.7%)对留渣双渣工艺中炉渣去锰能力的影响。通过溅渣留渣期间加入部分石灰石,吹炼开始加入少量生白云石替代部分轻烧白云石和加入少量萤石以及吹炼初期采用较高枪位,加强熔池上层炉渣搅拌加速初期锰的氧化等措施,使终点[Mn]由≤0.06%降至≤0.045%,与传统双渣法比较,减少石灰用量6.5 kg/t,减少萤石1.48 kg/t,铁皮单耗降低6.42 kg/t,明显降低冶炼熔剂成本。     

120t转炉高磷铁水冶炼高碳低磷钢生产实践

针对莱钢用高磷铁水冶炼高碳低磷钢容易出现终点碳过低和终点磷超标的问题,通过将脱磷渣碱度控制在1.5左右,实行双渣留渣工艺,提高前期底吹强度改善动力学条件,使用无氟化渣剂和增上滑板挡渣优化挡渣效果等措施,实现了高磷铁水冶炼低磷钢的高效生产。其中,终点磷质量分数可稳定控制在0.010%以下,脱磷率由89.80%提高到94.67%,终点碳质量分数控制在0.15%以上,钢水氧化性降低,钢包渣厚降低了40mm,精炼成白渣时间减少,满足了高碳低磷钢洁净度的要求,取得了良好的经济效益。     

热态炉渣循环利用技术在炼钢生产中的应用

通过对转炉终渣和精炼白渣的特性进行技术分析,转炉根据铁水硅含量采用“留渣＋单渣”法和“留渣＋双渣”法,精炼白渣采用空包热回收和出钢后热回收工艺,将转炉终渣和精炼白渣分别循环应用于转炉冶炼过程和转炉出钢过程及精炼过程.不但有利于钢水冶炼操作,降低生产成本,提高钢水质量,还减少了炉渣的排放和处理,有利于环境保护,取得了良好的经济效益和社会效益.     

有色金属冶炼废渣综合治理

本文简要叙述了葫芦岛锌厂竖罐蒸馏残渣、湿法炼锌浸出渣、煤气发生炉渣及精馏过程产出的铝铁锌渣的综合利用情况。     

Double Slag Operation Dephosphorization in BOF for Producing Low Phosphorus Steel

A study on the production of low phosphorus steel by double slag operation in 210 t converter was carried out. A phosphorus content of less than 0.005% (mass percent) was obtained before tapping. About 80% phosphorus could be removed by the first slag after 5 min. High Fe³⁺ content and high basicity in the first slag were in favor of dephosphorization. On the other hand, Fe³⁺ content had less effect on dephosphorization during second slag treatment. In the second slag period, the fraction of dephosphorization increased with the increase of basicity up to a basicity of 6. Further increase of basicity of the second slag had very little effect on dephosphorization. The tapping temperature had great impact on dephosphorization. It was impossible to get phosphorus less that 0. 005% when the tapping temperature was higher than 1 943 K. The optimum operation conditions were suggested. On the basis of these conditions, the amount of the second slag and the effect of the remaining first slag were estimated.