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炭黑-白炭黑双相粒子填充天然橡胶的硫化动力学 总被引:1,自引:0,他引:1
采用Ghoreisy’s模型和自催化反应模型研究了炭黑-白炭黑双相粒子(CSDPF)的用量及硅烷偶联剂Si 69改性CSDPF对天然橡胶(NR)硫化特性的影响。结果表明,Ghoreisy’s模型能更好地描述CSDPF及改性CSDPF填充NR的硫化过程;随着CSDPF和改性CSDPF用量的增加,NR胶料均出现硫化返原现象,但后者硫化返原现象有所减轻;随着CSDPF和改性CSDPF用量的增加,NR胶料的硫化时间变长,硫化速率下降,硫化反应级数增加;填充硅烷偶联剂Si 69改性CSDPF,胶料的硫化时间变短,硫化速率增加。 相似文献
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本文介绍了两种炭黑一白炭双相填充剂——CSDPF2000和4000,并评估了它们在轮胎胎面胶中的应用。这两种双相填充剂的主要不同之处在于白炭黑表面覆盖率。与CSDPF000系列产品相比,CSDPF4000系列产品的白炭黑表面覆盖率高得多。这主要是由于白炭黑分布于聚集体之间的缘故。CsDPF2000中的白炭黑相均匀分散于聚集体,而CSDPF4000中的白炭黑仅停留在聚集体的表面,形成壳层。在橡胶配方中,这两种双相填充剂都具有较高的聚合物与填充剂的相互作用和较低的填充剂与填充剂的相互作用。较高的聚合物与填充剂的相互作用可提高耐磨性,而较低的填充剂与填充剂相互作用可降低在高温下的滞后损失。通过提高CSDPF4000的白炭黑表面覆盖率,可提高轿车轮胎的温路面防滑性能,而CSDPF2000则可以提高载重轮胎的湿路面防滑性能。因此,通过用不同类型的CSDPF代替普通的填充剂.可以提高不同轮胎胎面胶的滚动阻力、耐磨性和湿路面防滑性能之间的综合平衡性。 相似文献
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ESBR硫化胶交联结构及动态粘弹性在拉伸疲劳过程中的变化 总被引:2,自引:0,他引:2
研究炭黑和白炭黑填充乳聚丁苯橡胶硫化胶拉伸疲劳过程中交联结构和动态粘弹性的变化。结果表明,炭黑填充胶料的拉伸性能在拉伸疲劳次数低于50万次时下降明显,而白炭黑填充胶料在50万~100万次之间下降幅度较大;随着拉伸疲劳次数的增加,两种胶料的交联密度均减小;拉伸疲劳次数达到200万次时,炭黑填充胶料的tanδ峰宽明显增大,而白炭黑填充胶料在拉伸疲劳次数50万次以上tanδ峰就明显增高、增宽;炭黑填充胶料疲劳后高弹态的tanδ变化不大,而白炭黑填充胶料tanδ显著增大;白炭黑填充胶料的Payne效应较炭黑填充胶料大,且拉伸疲劳后Payne效应明显减小。 相似文献
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研究偶联剂Si69用量对多相炭黑G10填充半钢轮胎胎面胶性能的影响,并与炭黑及炭黑/白炭黑并用填充胎面胶性能进行对比。结果表明:与炭黑填充胶料相比,炭黑/白炭黑并用填充胶料的门尼粘度较大,t90延长,t10缩短;与炭黑/白炭黑并用填充胶料相比,多相炭黑G10填充胶料的门尼粘度明显减小,t90缩短,混炼胶的Payne效应明显减弱,硫化胶的拉伸强度增大,阿克隆磨耗量和DIN磨耗量减小,压缩生热明显降低,混炼胶中炭黑分散性明显改善;随着多相炭黑G10填充胶料中偶联剂Si69用量的增大,胶料硫化特性和物理性能变化不大,损耗因子减小,其中偶联剂Si69用量为白炭黑用量8%的胶料生热较低,多相炭黑G10分散效果较好。 相似文献
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新一代补强材料——炭黑-白炭黑双相填充剂CSDPF4210因具有炭黑微区高表面活性和高白炭黑表面覆盖率的特点,可在滚动阻力、湿路面牵引性和耐磨耗性之间达到总体令人满意的均衡性能,成为极佳的备选填充剂。 相似文献
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在炭黑为主要补强材料的轮胎胎面胶行业中,人们对用白炭黑作为补强填料产生了极大的兴趣。这是因为与炭黑填充胶料相比,白炭黑填充胶料的湿路面牵引性能及雪路面牵引性能较好,而且滚动阻力较小。白炭黑在轮胎胎面胶料中的用量逐年增大,可能成为轮胎的主要填充剂。但是,白炭黑填充胶料仍存在一些问题,如未硫化胶料粘度增大,硫化速度慢等。 相似文献
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介绍了二系列白炭黑分布,白炭黑表面覆盖率和硅含量不同的炭黑-白炭黑双相填充剂CSDPF2000和CSDPF4000,并评估了其分别应用于轿车轮胎胎面胶和载重汽车轮胎胎面胶中对轮胎动态性能(滚动阻力),耐磨性和湿路面防滑性能的影响。实验证明,通过用不同类型的CSDPF代替普通的填充剂,可以改善不同轮胎胎面胶的滚动阻力,耐磨性和湿路面防滑性能之间的综合平衡性。 相似文献
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本研究论述了两种通过选择适当的填充剂材料来降低载重汽车燃油消耗的可行方法。第一种方法是采用炭黑-白炭黑双相填充剂。与普通炭黑相比,炭黑-白炭黑双相填充剂能明显降低滞后作用,进而大幅降低滚动阻力。与在胶料中采用白炭黑相比较,采用适当的双相填充剂不会明显降低耐磨耗性能。另一种方法是采用宽ASD炭黑,采用宽ASD炭黑无需在胶料中添加白炭黑就可以较小幅度地降低滞后作用。 相似文献
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Rubber compounds are reinforced with fillers such as carbon black and silica. In general, filled rubber compounds show smooth rheological behaviour in measurement of Mooney viscosity or Mooney scorch time. Variation in rheological behaviour was studied in terms of the filler composition using natural rubber compounds filled with both carbon black and silica (carbon black/silica = 60/20,40/40, and 20/60 phr). The compound filled with carbon black/silica of 60/20 phr showed normal rheological behaviour. However, the compounds filled with carbon black/silica of 40/40 and 20/60 phr showed abnormal rheological behaviour, in which the viscosity increased suddenly and then decreased at a certain point during the measurement. The abnormal behaviour was explained by the strong filler–filler interaction of silica. Moreover, the abnormal rheological behaviour was displayed more clearly as the storage time of compounds is increased. © 2003 Society of Chemical Industry 相似文献
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Jingyi Wang Hongbing Jia Lifeng Ding Xin Xiong Xuedong Gong 《Polymer Composites》2015,36(9):1721-1730
The carbon–silica dual phase filler (CSDPF) was modified by ionic liquids (ILs): 1‐allyl‐3‐methyl‐imidazolium chloride (AMI) and 1‐butlyl‐3‐methyl‐imidazolium hexafluorophosphate (BMI). The modified CSDPF was then incorporated into natural rubber (NR) through mechanical mixing. The interactions between CSDPF and ILs were investigated using differential scanning calorimetry (DSC), Fourier‐transform infrared spectroscopy (FTIR), and Raman spectroscopy. The bound rubber of NR compounds, the mechanical properties, and dynamic properties of NR vulcanizates filled with ILs modified CSDPF (ILs‐CSDPF/NR) were measured. The results showed that the AMI interacted with CSDPF through both hydrogen bonds and van der Waals forces, while the interaction between BMI and CSDPF was merely weak van der Waals force. The modification of CSDPF by ILs could improve the tensile strength, tear resistance, and fatigue life of NR vulcanizates. The AMI‐CSDPF/NR gave the superior mechanical and dynamic properties among the NR vulcanizates with the highest bound rubber content and the most homogeneous filler dispersion, which was displayed in scanning electron microscope (SEM) images. POLYM. COMPOS., 36:1721–1730, 2015. © 2014 Society of Plastics Engineers 相似文献
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Rubber compounds are reinforced with fillers such as carbon black and silica. The cure characteristics of a filled rubber compound vary with the filler type and content. The influence of the type of carbon black on the cure characteristics of carbon black filled natural rubber compounds is investigated using two types of carbon black (N220 and N550), which are different in primary size and structure. The cure time and cure rate become faster as the carbon black content increases. The crosslink density also increases and reversion resistance is improved with the increase of carbon black content. The cure time and cure rate of the compound filled with N550 are faster than those of the compound filled with N220 at the same level of bound rubber content. In addition, higher crosslink density is also observed in the compound filled with N550 compared to that of the compound filled with N220 at the same level of bound rubber content. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 98: 2282–2289, 2005 相似文献
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研究白炭黑和偶联剂Si69在工程机械轮胎胎冠胶中的应用。结果表明:与传统炭黑胎冠胶相比,用白炭黑部分替代炭黑并添加偶联剂Si69的胎冠胶加工性能、物理性能、耐磨性能、抗割口增长性能和耐老化性能提高,压缩生热降低;成品轮胎胎冠胶性能改善。 相似文献
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S. S. Bhagawan D. K. Tripathy S. K. De S. K. Sharma K. Ramamurthy 《Polymer Engineering and Science》1988,28(10):648-654
The influence of fillers like clay, silica, and carbon black on the rheological properties of 1,2 polybutadiene has been studied using a capillary rheometer. Silica filled compound exhibited the highest viscosity and clay filled compound the lowest viscosity at all shear rates. The effect of filler loading and temperature on the Theological behavior has also been studied. Smooth extrudates were obtained in most of the cases and die swell was lower for silica and carbon black filled compounds than for clay filled compounds. Rheograms of different 1,2 polybutadiene systems have been found to merge into a master curve using modified viscosity and shear rate functions that contain melt flow index as a parameter. 相似文献