Compact 50-Hz terawatt Ti:sapphire laser for x-ray and nonlinear optical spectroscopy

We report a high-repetition-rate, compact terawatt Ti:sapphire laser system. The oscillator produces an 82-MHz pulse train consisting of broad-bandwidth pulses of 0.5-nJ/pulse energy and of 9-fs pulse duration. The spectrally shaped, lambda/4 regenerative amplifier supports an 80-nm bandwidth. A single 50-Hz repetition-rate pump laser pumps both the regenerative amplifier and a multiple-pass amplifier. The final output from this laser is a 50-Hz pulse train made from pulses of 53 mJ/pulse energy and of 24-fs pulse duration. For generating ultrafast x-ray pulses, 90% of the energy from the final output of a 28-mm-diameter (1/e2) beam is focused onto an ultrafast x-ray wire target. The energy conversion efficiency from optical (800-nm central wavelength) to x-ray (characteristic lines of K(alpha) from Cu at 8 keV) pulses is estimated to be 7 x 10(-5). This laser system can also generate a lower-peak-power, dual-pulse output that can excite, simultaneously and coherently, Raman modes within an adjustable bandwidth (up to 700 cm(-1)) and at a tunable central vibrational frequency. Preliminary results for the generation of dual-pulse output and ultrafast x rays are presented.     

High-frequency overtone TCXO based on mixing of dual crystal oscillators

To implement a high-stability and high-frequency overtone temperature-compensated crystal oscillator (TCXO) conveniently, an improved design of the novel overtone TCXO is described in this paper. A 120-MHz TCXO based on mixing of dual crystal oscillators is implemented. It utilizes a 100-MHz AT-cut 5th-overtone crystal oscillator mixed with a 20-MHz AT-cut voltage-controlled crystal oscillator (VCXO). The 120-MHz mixed product is filtered to produce the output signal. The total frequency deviation of 20-MHz and 100-MHz crystal oscillators is compensated by adjusting the output frequency of the 20-MHz oscillator to produce the stable 120-MHz output frequency. In this work, verifying experimental results of the compensation are presented. The stability of the experimental 120-MHz overtone TCXO with microprocessor temperature compensation achieves +/-2 X 10(-7) over the temperature range from -30 degrees C to +70 degrees C. A phase noise level of -133 dBc/Hz at 1 kHz offset has been initially measured for the prototype TCXO. The experimental result demonstrates this approach can conveniently implement the high-frequency overtone temperature compensation with a relatively high stability, and it is available for a wider frequency range as well.     

Passively Q-Switched Diode-Pumped Continuous-Wave Nd:YAG-Cr(4+):YAG Laser with High Peak Power and High Pulse Energy

A high peak power and high pulse energy passively Q-switched diode-pumped cw Nd:YAG laser at 1.064-mum wavelength has been demonstrated with Cr(4+):YAG crystal as the saturable absorber. The average output power of 7-12 W and pulse duration of 100-250 ns was obtained with kilohertz repetition rates. The highest peak power and pulse energy obtained were 30 kW and 3.4 mJ, respectively. All the output resulted from the TEM(00) mode with M(2) < 1.1. The thermal lensing effect of the saturable absorber was investigated, demonstrating that it played an important role in optimization of the output.     

Rapidly tuning miniature transversely excited atmospheric-pressure CO2 laser

An experimental study of a rapidly tuning miniature transversely excited atmospheric-pressure CO2 laser is reported. To rapidly shift laser wavelengths over selected transitions in the 9-11 microm wavelength region, we have utilized a high-frequency stepping motor and a diffraction grating. The laser is highly automated with a monolithic microprocessor controlled laser line selection. For the achievement of stable laser output, a system of laser excitation with a voltage of 10 kV, providing effective surface corona preionization and allowing one to work at various gas pressures, is utilized. Laser operation at 59 emission lines of the CO2 molecule rotational transition is obtained and at 51 lines, the pulse energy of laser radiation exceeds 30 mJ. The system can be tuned between two different rotational lines spanning the wavelength range from 9.2 to 10.8 microm within 10 ms.     

Single-mode flashlamp-pumped dye laser oscillators

In this paper, we report single-longitudinal-mode operation in a flashlamp-pumped dye laser incorporating a multiple-prism beam expander with the grating either in a Littrow or grazing-incidence configuration. Linewidths in the 260-MHz range were obtained, using rhodamine 590 dye at output energies exceeding 60 mJ. Pulse duration for the multiple-prism Littrow dye laser oscillator was approximately 200 ns (FWHM).     

Tropospheric ozone differential-absorption lidar using stimulated Raman scattering in carbon dioxide

A UV ozone differential-absorption lidar (DIAL) utilizing a Nd:YAG laser and a single Raman cell filled with carbon dioxide (CO(2)) is designed, developed, and evaluated. The generated wavelengths are 276, 287, and 299 nm, comprising the first to third Stokes lines of the stimulated Raman scattering technique. The correction terms originated from the aerosol extinction, the backscatter, and the absorption by other gases are estimated using a model atmosphere. The experimental results demonstrate that the emitted output energies were 13 mJ/pulse at 276 nm and 287 nm and 5 mJ/pulse at 299 nm, with pump energy of 91 mJ/pulse and a CO(2) pressure of 0.7 MPa. The three Stokes lines account for 44.0% of the available energy. The use of argon or helium as a buffer gas in the Raman cell was also investigated, but this leads to a dramatic decrease in the third Stokes line, which makes this wavelength practically unusable. Our observations confirmed that 30 min of integration were sufficient to observe ozone concentration profiles up to 10 km. Aerosol extinction and backscatter correction are estimated and applied. The aerosol backscatter correction profile using 287 and 299 nm as reference wavelengths is compared with that using 355 nm. The estimated statistical error is less than 5% at 1.5 km and 10% at 2.6 km. Comparisons with the operational carbon-iodine type chemical ozonesondes demonstrate 20% overestimation of the ozone profiles by the DIAL technique.     

Temperature and pulse-duration dependence of second-harmonic generation in CdGeAs2

A detailed investigation of frequency doubling of a transversely excited atmospheric CO2 laser operating at 9.55 microm with a CdGeAs2 crystal was carried out. The temperature of the crystal was varied between 80 and 295 K to maximize the frequency-doubled energy. The temporal shape of the generated beam at 4.775 microm was monitored to calculate its peak power. High values of midwave infrared pulse energy (16.65 mJ) and peak power (92 kW) were obtained, which can be of potential use in lidar systems.     

Ho:CaF(2) solid-state saturable-absorber Q switch for the 2-µm Tm,Cr:Y(3)Al(5)O(12) laser

The holmium-doped calcium fluoride (Ho:CaF(2)) crystal was shown to be an effective solid-state saturable-absorber Q-switch for a flash-lamp-pumped Tm,Cr:Y(3)Al(5)O(12) laser at 2.017 μm. With a 1-cm-thick Ho(0.5%),Er(5%):CaP(2) saturable absorber and a 6.3% output coupler, a single Q-switched laser pulse of 51 mJ in energy and 60 ns in duration was obtained at a flash-lamp input energy of 85 J. With a 14.6% output coupler, a typical Q-switched laser pulse of 84 mJ and 82 ns was observed.     

Thermo-optic dispersion formula for AgGaS2

AgGaS(2) has been found to be 90 degrees phase matchable at 192 degrees C for sum-frequency mixing between the output of the KTP parametric oscillator at 3.2627 mum and its pump source at 1.0642 mum. The thermo-optic dispersion formula that can be used for good reproduction of the temperature-dependent phase-matching conditions thus far reported in the literature as well as our new data for second-harmonic generation of a CO(2) laser and its harmonics at 1.7652-5.2955 mum is presented.     

Development of an eye-safe solid-state tunable laser transmitter in the 1.4-1.5 microm wavelength region based on Cr4+:YAG crystal for lidar applications

An experimental optimization of the efficiency of a gain switched tunable Cr4+:YAG laser at 10 Hz is described. The thermal lensing during pulsed operation was measured. Optimal performance occurred at a crystal temperature of 34 degrees C and resulted in an output energy of approximately 7 mJ and a pulse duration of approximately 35 ns. Tunability in the range of 1350-1500 nm, spectral linewidth of approximately 200 GHz, and M2<4 are demonstrated. The main laser material parameters are estimated. Such a laser could be employed in a laboratory-based nonscanning lidar system if a narrowband birefringent filter is installed. The tunability will permit the improvement of the Cr4+:YAG transmitter for water-vapor differential absorption lidar if injection seeding is applied.     

Mid-Infrared-Wavelength Generation in 2-mum Pumped Periodically Poled Lithium Niobate

A periodically poled lithium niobate optical parametric oscillator pumped by a Tm:YAG laser at 2.0124-mum wavelength has been demonstrated. A pump pulse energy of 5.1 mJ generated 0.65 mJ of signal and idler pulse energy at a 50-Hz repetition frequency with a 27.8-mum domain-period-length grating. The lithium niobate crystal at a temperature of 180 degrees C yielded 3.61- and 4.55-mum signal and idler wavelengths, respectively. Wavelength tuning over a wide range was achieved with domain-period lengths from 25.5 to 28.2 mum and crystal temperature tuning from 50 to 180 degrees C. Signal wavelengths of 3.26-3.76 mum and idler wavelengths of 4.33-5.34 mum were generated.     

Evaluation of Nd:YAG-pumped Raman shifter as a broad-spectrum light source

We have examined the utility of a gas-filled, Nd:YAG-laser-pumped Raman shifter as a possible broad-spectrum light source. Six to nine new output frequencies with pulse energies above 1 μJ are produced when a pure-hydrogen or pure-methane Raman shifter is pumped with 40 mJ of secondharmonic, 20 mJ of third-harmonic, or 11 mJ of fourth-harmonic pump pulse energy. Optimum output occurs at pressures of approximately 10 atm for the pure-gas experiments. We also report the output frequencies and pulse energies of a mixed hydrogen-methane Raman shifter pumped by 20 mJ of the third harmonic of the laser for various proportions of the two gases at pressures up to nearly 20 atm. Depending on composition and pressure, over a dozen new output lines with pulse energies over 1 μJ can be produced. We discuss the nonlinear processes involved, the optimum operating conditions, and the suitability of the source for our application of groundwater monitoring.     

Raman spectroscopic investigation of solid samples using a low-repetition-rate pulsed Nd:YAG laser as the excitation source

We tried to investigate the possibility of using a low-repetition-rate pulsed Nd:YAG laser as an excitation source in Raman measurements for solid samples. Based on the results from the Raman spectra excited by continuous wave (CW) 532 and 325 nm lasers, we studied the influence of laser energy and irradiation time of 532 and 355 nm pulsed Nd:YAG lasers (10 Hz repetition rate) on the thermal stability of (NH4)6Mo7O(24).4H2O, NH4VO3, and Ce(NO3)(3).6H2O samples, which usually decompose at relatively low temperatures. It is observed that the heating temperature estimated at these samples caused by the irradiation of 532 nm pulsed laser with 22 mJ is no higher than 100 degrees C even for 60 min exposure. The 355 nm pulsed laser with energies below 8.0 mJ hardly causes thermal damage to hydrated (NH4)6Mo7O24 and hydrated Ce(NO3)3 SAMPLES: However, a 355 nm pulsed laser with only 2.2 mJ causes heating temperatures as high as 200 degrees C in the NH4VO3 SAMPLE: These great differences should be attributed to the electronic absorbance of the above three samples at 355 nm. We also found that a 532 nm pulsed laser with even 22 mJ and a 355 nm pulsed laser with even 8.0 mJ do not cause the phase transition of TiO2 and ZrO2, whose phase transformation easily takes place at elevated temperatures, but pulsed lasers could remove some oxygen atoms from these samples. In addition, for L-alanine and DL-beta-phenylalanine biological samples, it is surprisingly found that they are not damaged by the 355 nm pulsed laser even when the laser energy is increased to 8.0 mJ, possibly because they do not absorb the 355 nm laser. Based on these results, it is demonstrated that low-repetition-rate pulsed lasers with appropriate wavelength and energy can be employed as the excitation sources of Raman spectroscopy for characterizing some solid samples, even the thermally unstable samples.     

Solid hydrogen Raman shifter for the mid-infrared range (4.4-8 microm)

We developed a pulsed, continuously tunable laboratory laser source for the mid-infrared spectral range of 4.4-8 microm, which is characterized by the spectral linewidth of 0.4 cm(-1). The device is based on the stimulated backward Raman scattering in solid para-hydrogen at T = 4 K. It is pumped by a focused beam obtained from a commercial near-infrared optical parametric oscillator with output energy of approximately 20 mJ (7-ns pulse). Output energies range from 1.7 mJ at 4.4 microm to 120 microJ at 8 microm, which correspond to quantum efficiencies of 0.53 and 0.08, respectively. Spectra of NO, H2O, and CH4 molecules in the mid-infrared were recorded. The operation of the Raman cell pumped with 532-nm radiation was also studied.     

Development of the 2.8 microm emission doubly shifted Raman laser using stimulated Brillouin scattering in a cascaded cavity

A doubly shifted Raman laser using CH(4) gas has been developed for 2.8 microm generation, pumped by a Nd:YAG laser with 65.5 mJ at 17 ns. A dichroically coated meniscus-type lens is modified to utilize the backward stimulated Brillouin scattering and backward Stokes beams from a previous laser design [Appl. Opt.46, 5516-5521 (2007)APOPAI0003-693510.1364/AO.46.005516]. A maximum output energy of 4.76 mJ at 2.80 microm wavelength has been achieved in the cascaded resonator. A maximum conversion efficiency of 8.9% has been achieved at a CH(4) gas pressure of 600 psi. The obtained spatial beam profile is quite smooth, and its output pulse width is 10 ns.     

Complete CO oxidation over Cu2O nanoparticles supported on silica gel

We find that nearly monodisperse copper oxide nanoparticles prepared via the thermal decomposition of a Cu(I) precursor exhibit exceptional activity toward CO oxidation in CO/O2/N2 mixtures. Greater than 99.5% conversion of CO to CO2 could be achieved at temperatures less than 250 degrees C for over 12 h. In addition, the phase diagram and pathway for CO oxidation on Cu2O (100) is computed by ab initio methods and found to be in qualitative agreement with the experimental findings.     

Carbon analysis for inspecting carbonation of concrete using a TEA CO2 laser-induced plasma

It has been demonstrated that a spectrochemical analysis of carbon using the laser plasma method can be successfully applied to inspect the carbonation of concrete by detecting carbon produced in aged concrete by a chemical reaction of Ca(OH)2 with CO2 gas in environmental air, turning into CaCO3, which induces degradation of the quality of building concrete. A comparative study has been made using a TEA CO2 laser (500-1000 mJ) and a Q-switched Nd-YAG laser (50-200 mJ) to search for the optimum conditions for carbon analysis, proving the advantage of the TEA CO2 laser for this purpose. Also, it was clarified that laser irradiation with suitable defocusing conditions is a crucial point for obtaining high sensitivity in the detection of carbon. Practical experiments on the inspection of carbonation were carried out using both a concrete sample that had been intentionally carbonated by exposure to high concentrations of CO2 gas and a naturally carbonated concrete sample. As a result, good coincidence was observed between the laser method and the ordinary method, which uses the chemical indicator phenolphthalein, implying that this laser technique is applicable as an in situ quantitative method of inspection for carbonation of concrete.     

On the possibility of increasing the efficiency of sealed-off nitrogen lasers

A sealed-off nitrogen laser operating in a periodic-pulse regime at a repetition rate of 40 Hz has been experimentally studied and it is demonstrated that the laser efficiency can be increased by quasi-stationary energy pumping into the active medium (pure nitrogen or its mixtures with helium or neon). The presence of a buffer gas (helium or neon) allows the energy parameters of radiation to be increased and the laser efficiency to be controlled. A small-sized sealed-off nitrogen laser is developed, which operates at a peak output power of 160 kW and a pulse energy of 0.8 mJ with an efficiency of 0.27%.     

Near-diffraction-limited green source by frequency doubling of a diode-stack pumped Q-switched Nd:YAG slab oscillator-amplifier system

A near-diffraction-limited, stable, 18 mJ green source with a pulse width of 16.7 ns was generated at a 1 kHz repetition rate by frequency doubling of diode stacks end-pumped electro-optically Q-switched slab Nd:YAG oscillator-amplifier system. The pump to green optical conversion efficiency was 10.7%. At the output energy of 15 mJ at 532 nm, the M2 factors were 1.3 and 1.7 in the unstable and stable directions, respectively. The energy pulse stability was approximately 0.8%.     

High frame rate imaging system for limited diffraction array beam imaging with square-wave aperture weightings.

A general-purpose high frame rate (HFR) medical imaging system has been developed. This system has 128 independent linear transmitters, each of which is capable of producing an arbitrary broadband (about 0.05-10 MHz) waveform of up to +/- 144 V peak voltage on a 75-ohm resistive load using a 12-bit/40-MHz digital-to-analog converter. The system also has 128 independent, broadband (about 0.25-10 MHz), and time-variable-gain receiver channels, each of which has a 12-bit/40-MHz analog-to-digital converter and up to 512 MB of memory. The system is controlled by a personal computer (PC), and radio frequency echo data of each channel are transferred to the same PC via a standard USB 2.0 port for image reconstructions. Using the HFR imaging system, we have developed a new limited-diffraction array beam imaging method with square-wave aperture voltage weightings. With this method, in principle, only one or two transmitters are required to excite a fully populated two-dimensional (2-D) array transducer to achieve an equivalent dynamic focusing in both transmission and reception to reconstruct a high-quality three-dimensional image without the need of the time delays of traditional beam focusing and steering, potentially simplifying the transmitter subsystem of an imager. To validate the method, for simplicity, 2-D imaging experiments were performed using the system. In the in vitro experiment, a custom-made, 128-element, 0.32-mm pitch, 3.5-MHz center frequency linear array transducer with about 50% fractional bandwidth was used to reconstruct images of an ATS 539 tissue-mimicking phantom at an axial distance of 130 mm with a field of view of more than 90 degrees. In the in vivo experiment of a human heart, images with a field of view of more than 90 degrees at 120-mm axial distance were obtained with a 128-element, 2.5-MHz center frequency, 0.15-mm pitch Acuson V2 phased array. To ensure that the system was operated under the limits set by the U.S. Food and Drug Administration, the mechanical index, thermal index, and acoustic output were measured. Results show that higher-quality images can be reconstructed with the square-wave aperture weighting method due to an increased penetration depth as compared to the exact weighting method developed previously, and a frame rate of 486 per second was achieved at a pulse repetition frequency of about 5348 Hz for the human heart.