含铋层状结构陶瓷CaBi2Nb2O9的A位掺杂改性研究

利用固相反应法合成了Ca1-x(KLa)x/2Bi2Nb2O9(x=0～0.20)(xKLaCBNO)铋层状陶瓷,分析不同KLa掺杂量对CaBi2Nb2O9(CBNO)基陶瓷微观结构、介电、压电及电导性能的影响.XRD分析表明KLa的引入未改变CBNO陶瓷的单相结构.SEM和介电系数温度谱结果分别显示,KLa掺杂量的增加,细化尺寸趋于一致,而居里温度(Tc)从943℃降低至875℃,其峰值介电常数减小、峰值介电损耗增大.当掺杂量x=0.1时,样品的高温电阻率较纯CBNO显著升高,压电系数d33由5.2 pC/N提高到15.8 pC/N,居里温度高达870℃,说明A位(KLa)掺杂改性后的CBNO陶瓷在高温传感器等领域具有潜在的应用前景.     

Na0.5Bi2.5Nb2O9-Na0.5Bi4.5Ti4O15材料的微观结构及电性能

采用固相烧结法制备了铋层结构铁电材料(1-x)Na0.5Bi2.5Nb₂O₉-xNa0.5Bi4.5Ti₄O₁₅(NBNO-NBT-x)。结合XRD、SEM以及电子能谱分析推测NBNO-NBT-0.5陶瓷主要为2-4层的共生结构NaBi₇Ti₄Nb₂O₂₄,由Na0.5Bi2.5Nb₂O₉和Na0.5Bi4.5-Ti₄O₁₅沿c轴交替排列。晶格结构的不对称性增加导致晶格应力增大,而NBNO和NBT两种单体系的复合将进一步加大离子无序和结构无序,从而使该组成的陶瓷表现出不同于两种单体系的微观结构和电性能。NBNO-NBT-0.5陶瓷的晶粒长度大于20 μm,厚度小于2 μm,晶粒长径比明显高于NBNO和NBT;而相比于两种单体其居里温度TC降低,居里峰宽化,高温介电损耗增大,电导激活能减小,铁电、压电性能降低。     

Na0.5Bi0.5TiO3-K0.5Bi0.5TiO3无铅压电陶瓷的制备与性能

采用传统的干压成型法制备了Na0.5Bi0.5TiO3-K0.5Bi0.5TiO3无铅压电陶瓷,研究了不同K0.5Bi0.5TiO3含量对Na0.5Bi0.5TiO3-K0.5Bi0.5TiO3陶瓷的微观结构与电性能的影响规律.结果表明,Na0.5Bi0.5TiO3-K0.5Bi0.5TiO3无铅压电陶瓷随K0.5Bi0.5TiO3含量增加,晶格常数增大,密度减小,晶粒尺寸减小,压电常数先增大后减小,介电常数增大,介电损耗增加,机械品质因数下降,而居里温度不断升高,在200℃附近存在由铁电相向反铁电相转变的一个相变点,组分为0.84 Na0.5Bi0.5TiO3-0.16 K0.5Bi0.5TiO3的陶瓷位于准同型相界附近,具有最佳的压电性能.     

温度对Mg4Nb2O9合成的影响

Mg4Nb2O9具有与α-Al2O3相同的刚玉型晶体结构,可望成为取代氧化铝陶瓷的新一代高Q值基板陶瓷.在900～1400℃温度范围内,合成了Mg4Nb2O9化合物,采用X射线粉末衍射法进行了相结构分析.结果表明,生成物中含有Mg4Nb2O9、Mg4Nb2O6和MgO三种物相,主晶相是Mg4Nb2O9;在900～1300℃温度范围内,随着温度的升高,MgNb2O6和MgO反应生成Mg4Nb2O9相,主晶相含量线性增加,但在1300℃以上,主晶相含量随温度的升高而减小;Mg4Nb2O9相的最佳合成温度为1300℃.这些结果对研究开发Mg4Nb2O9微波基板材料有着重要的意义.     

LiSbO3含量对BiMnO3掺杂K0.5Na0.5NbO3陶瓷的结构与压电性能的影响研究

采用传统陶瓷常压烧结工艺制备(0.996–x)KNN-0.004BM-xLS(x=0、0.01、0.02、0.03、0.04、0.05、0.06)无铅压电陶瓷,着重研究了LS的含量对(0.996–x)KNN-0.004BM-xLS陶瓷相结构和压电性能的影响。结果表明,当x≤0.02时,陶瓷具有单一的正交相结构;当0.03≤x≤0.05时,陶瓷具有正交相与四方相共存的过渡结构;当x=0.06时,陶瓷具有单一的四方相结构。陶瓷的MPB成分范围在0.03≤x≤0.05。随着LS含量的增加,陶瓷材料的d33和kp均先增加后减小,当x=0.05时,均达到最大值,分别为230 pC/N和0.42;陶瓷的To-t和Tc均向低温方向移动;当x=0时,陶瓷的To-t和Tc分别为455和215℃;当x=0.02时,陶瓷的To-t和Tc分别为385和150℃;当x=0.06时,To-t和Tc分别降至370℃和75℃。     

SrBi2Nb2O9的PLD制备及其非线性光学特性

利用脉冲激光沉积(PLD)方法在MgO(100)基片上生长了SrBi2Nb2O9薄膜.XRD分析表明在MgO基片上生长的薄膜呈(115)单一取向,具有良好的结晶性;XPS数据分析得到薄膜中Sr、Bi和Nb的原子比约为122.05.利用Z扫描技术对薄膜的三阶非线性光学性质进行了测量,通过开孔(Open-aperture)和小孔(Close-aperture)的测量,计算出三阶非线性光学极化率的实部Rex(3)和虚部Imx(3)分别为4.139×10-7eSu,1.104×10-7eSu.     

聚吡咯/Ni0.5Zn0.5Fe2O4复合物的合成与表征

采用超声场下原位聚合法制备聚吡咯/Ni0.5Zn0.5Fe2O4(PPy/NZFO)复合物。分别采用X射线衍射仪(XRD)、扫描电镜(SEM)、四探针测试仪和矢量网络分析仪对其结构、形貌、电性能和吸波性能进行研究。结果表明:APS/Py摩尔比为0.75的条件下可获得团聚程度较小、粒径大小比较均匀的聚吡咯颗粒。随着超声聚合反应时间的延长,聚吡咯颗粒的粒径呈现增大趋势。PPy/NZFO复合物的电导率与PPy含量成正比。复合物的吸波性能较纯PPy有很大提高,在5~20GHz频率范围内,NZFO含量为40%(质量分数)的复合物反射损耗都在-12dB以上,在18.15GHz处具有最大的反射损耗-16.76dB,-15dB有效带宽为1.65GHz。     

Bi0.5Na0.5TiO3基A位多重复合无铅压电陶瓷的研制

针对钛酸铋钠(Bi0．5Na0．5TiO3)基复合钙钛矿压电铁电材料,发明了多种新的AB03型A位多重复合无铅压电陶瓷体系。这些新的无铅压电陶瓷具有压电铁电性能优良、铁电电滞回线矩形度高、压电铁电性能的温度特性好、工艺稳定性和重复性好等特点。所测得的一个体系(Bi0．5(Na1-x-yKxLiy)0．5TiO3)的d33达230pC／N,其kp达0．40,Pr达40μC/cm^2,矫顽场Ec则较低(小于4kV／mm);变温铁电电滞回线测试表明,在温度接近200℃时,该陶瓷还具有很好的铁电电滞回线。该体系无铅压电陶瓷性能优异,工艺性好,具有实用性。     

(Bi0.5Na0.5)TiO3系无铅压电陶瓷研究现状与展望

BNT陶瓷由于具有良好的压电性、高居里温度和烧结过程中无毒、易控制性等优点而倍受青睐.本文介绍了无铅压电陶瓷的研究概况、相变过程及其基本性质、制备工艺,根据已有的研究经验着重对BNT陶瓷掺杂改性进行了探讨,并展望了它的发展前景.     

高性能无铅压电陶瓷(Bi0.5Na0.5)0.94Ba0.06TiO3的制备与性能

采用企业的电子陶瓷工艺制备了(Bi0.5Na0.5)0.94Ba0.06TiO3(BNTBT-6)无铅压电陶瓷,研究了制备工艺对BNTBT-6陶瓷的晶相、微观结构与介电压电性能的影响.研究结果表明,烧结方式会对BNTBT-6陶瓷的晶相和性能产生一定的影响.电学性能研究结果表明,湿磨盖烧BNTBT-6陶瓷样品的压电性能优良,室温下陶瓷样品的压电常数d33达到195pC/N,机电耦合系数kp为35%,机械质量因子Qm达到130,介电损耗tgδ为0.025.     

Synthesis and electrical properties of sodium bismuth niobate Na0.5Bi2.5Nb2O9

The crystal structure of Na_0.5Bi_2.5Nb₂O₉ was refined from its powder X-ray diffraction (XRD) data. Sodium bismuth niobate at 23 °C is orthorhombic, A2₁am, with a=5.4998(3) Å, b=5.4602(2) Å, c=24.952(1) Å, and Z=4. The piezoelectric properties were investigated using the dense bulk ceramics. The electromechanical coupling coefficients (k_ij) and electrical quality factors (Q_m) are k₃₁=3.2%, k_t=10.0%, and Q_m=3800. Single crystals were also grown from stoichiometric melts using a slow cooling technique. The dielectric and ferroelectric properties of the crystal indicates that a spontaneous polarization clearly occurs in the crystallographic a-b plane.     

Bi0.5Na0.5 TiO3基无铅压电陶瓷应用的研究进展

随着人们环保意识的增强,作为环境友好型的无铅压电陶瓷典型代表Bi0.5Na0.5TiO3基压电陶瓷已成为压电陶瓷领域研发的热点材料之一.结合目前有关报道,着重介绍了近年来国内外该陶瓷在相关电子器件中的应用,并展望了BNT基无铅压电陶瓷应用的发展趋势.     

Depolarization temperature and piezoelectric properties of Na1/2Bi1/2TiO3-Na1/2Bi1/2(Zn1/3Nb2/3)O3 ceramics by two-stage calcination method

A new group of NBT-based lead-free piezoelectric ceramics, Na_1/2Bi_1/2TiO₃-Na_1/2Bi_1/2(Zn_1/3Nb_2/3)O₃, was synthesized using the two-stage calcination method and depolarization temperatures and piezoelectric properties were also investigated. The XRD analysis showed that the ceramics system had a morphotropic phase boundary (MPB) between the rhombohedral and the tetragonal structure. The highest piezoelectric properties of d ₃₃ = 97 pC/N and k _t = 0·46 were obtained near MPB compositions. Furthermore, the depolarization temperatures near MPB compositions were slightly decreased and the lowest T _d was maintained at 210°C.     

Li1.0Nb0.6Ti0.5O3陶瓷的低温烧结其微波介电性能

研究了以Li1．0Nb0．6Ti0．5O3(LNT)陶瓷为基体, B2O3-ZnO-La2O3(BZL)玻璃为烧结助剂的复合材料的低温烧结行为及微波介电特性．研究表明,BZL玻璃能有效降低LNT陶瓷的烧结温度,掺入10wt％BZL玻璃的复合材料能够在900℃烧结致密．XRD与SEM分析结果表明,添加BZL玻璃的样品烧结后含有LNT和LaNbTiO6两种晶相,其中LaNbTiO6相是LNT与BZL玻璃在烧结过程中发生化学反应的产物．在LNT陶瓷中添加BZL玻璃使材料的介电常数和品质因数下降,但有助于减小体系的谐振频率温度系数．掺入10wt％BZL玻璃的复合材料在900℃烧结2h后获得了比较满意的微波介电特性:介电常数k≈58,品质因数Q×f≈4800GHz,谐振频率温度系数τf≈11×10-6／℃．     

Sm2O3掺杂(Ba0.7Ca0.3)TiO3-Ba(Zr0.2Ti0.8)O3无铅压电陶瓷的制备与性能

采用固相合成法制备了Sm2O3掺杂的(Ba0.7Ca0.3)TiO3-Ba(Zr0.2Ti0.8)O3(BCZT)无铅压电陶瓷.借助XRD、SEM等手段对该陶瓷的显微结构与电性能进行了研究.结果表明,Sm2O3的掺杂降低了BCZT无铅压电陶瓷的烧结温度并使居里温度点Tc从85℃提高到95℃.当Sm2O3掺杂量为0.02wt%～0.1wt%时,样品具有典型ABO3型钙钛矿结构.Sm2O3掺杂量为0.02wt%时,所得陶瓷样品具有最优综合电性能,其压电常数d33、机电耦合系数kp、机械品质因子Qm、介电损耗tanδ和介电常数εr分别为590 pC/N、0.52、43、1.3%和3372.     

流延成型制备(Na0.85K0.15)0.5Bi0.5TiO3陶瓷的显微结构及性能

采用流延成型工艺制备了（Na0.85K0.15）0．5Bi0.5TiO3无铅压电陶瓷，研究了陶瓷退火前后的显微组织结构，结果表明陶瓷主晶相为钙钛矿相结构，并伴随有形貌呈针状的第二相K2Ti6O13出现；陶瓷断面和表面的晶粒形貌有差别，采用退火处理无法消除第二相K2Ti6O13，但可有效改善陶瓷断面的晶粒形貌，同时增大材料的矫顽场，并使剩余极化强度（Pr）、压电常数（d33）、介电常数（ε）与介电损耗（tanδ）变小．（Na0.85K0.15）0.5Bi0．5TiO3无铅压电陶瓷的电滞回线表现出明显铁电体的特征，其矫顽场为2680V／mm，Pr达36．6μC／cm^2，d33达113pC／N，‰为0．27，Qm达154．     

Synthesis of Na0.5Bi0.5TiO3 anisotropic particles with grain orientation by conversion of Na0.5Bi4.5Ti4O15 crystals

A novel method for synthesizing Na_0.5Bi_0.5TiO₃ (BNT) anisotropic particles with grain orientation is reported. Anisotropically shaped particles of BNT were prepared by conversion of Na_0.5Bi_4.5Ti₄O₁₅ (NBT15) single crystals. Platelet NBT15 was produced by molten-salt synthesis. They were converted to BNT by second molten-salt synthesis at 800–1200 °C. NBT15 single-crystal platelets were transformed into platelet particles of polycrystalline BNT. The reaction is topotaxial, those recrystallized BNT were oriented with (h 0 0) plane parallel to the platelet. The use of converted BNT particles as seed was confirmed by performing templated grain growth (TGG) of BNT with 5% grain-oriented, anisotropic particles of BNT.     

Properties of La-substituted Na0.5Bi4.5Ti4O15 ferroelectric thin films

Ferroelectric Na_0.5La_0.5Bi₄Ti₄O₁₅ (NaLaBTi) thin films were prepared by a chemical solution deposition method. The NaLaBTi thin films annealed at 750 °C under oxygen atmosphere were randomly oriented polycrystalline. Electrical properties of the NaLaBTi thin films were compared to Na_0.5Bi_4.5Ti₄O₁₅ thin films and better properties were observed in the NaLaBTi thin films. Remnant polarization (2P_r) and coercive electric field (2E_c) were 43 µC/cm² and 204 kV/cm at an applied electric field of 478 kV/cm, respectively. Leakage current density was 1.95 × 10^− 6 A/cm² at 100 kV/cm. Dielectric constant and dielectric loss were 805 and 0.05 at 1 kHz, respectively. Switchable polarization was suppressed by 15% after 1.44 × 10¹⁰ switching cycles.     

Synthesis of Bi2Fe4O9 via PVA sol-gel route

Bi₂Fe₄O₉ powders were synthesized by a sol-gel process using polyvinyl alcohol (PVA) as a complexing agent. Differential scanning calorimetry (DSC), thermogravimetric (TG), Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD) and Field emission scanning electron microscope (FSEM) techniques were used to characterize precursor and derived oxide powders. The effect of the ratios of positively charged valences to hydroxyl groups of PVA (Mⁿ⁺/-OH) on the formation of Bi₂Fe₄O₉ was investigated. XRD analysis showed that single-phase Bi₂Fe₄O₉ was obtained from the Mⁿ⁺/-OH = 2:1 and Mⁿ⁺/-OH = 1:1 precursors at the temperature of 700 °C. For the precursor with Mⁿ⁺/-OH = 4:1, pure Bi₂Fe₄O₉ formed at the temperature of 800 °C. Bi₂Fe₄O₉ powders clacined at 700 °C from Mⁿ⁺/-OH = 2:1 precursor shows weak ferromagnetism.