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引言工业生产中经常会遇到醇水混合物的分离问题.膜分离技术与传统的分离过程相比,具有设备简单、操作容易、能耗低和无污染等优点,因此,用经济的膜技术进行醇水混合物分离和浓缩的研究具有广阔的应用前景.其中,采用气相进料的蒸汽渗透膜技术在有机溶剂-水混合物的分离方面显示出明显的竞争优势[1-3].已报道的用于醇水混合物分离的膜以有机聚合物膜居多.有机膜虽然选择性较高,但其渗透通量却难以满足实际生产的需要.无机陶瓷膜通量大,其选择性则取决于膜孔的大小与结构.为了提高陶瓷膜的选择性,涌现出许多减小膜孔径和改善膜… 相似文献
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费托合成油水相副产物混合醇的回收多采用萃取精馏的分离方法,此方法需要配置7个精馏塔和5路循环回路。通过分析发现,流程冗长的关键因素在于混合醇中除甲醇外各个组分均与水产生共沸,而分子筛膜渗透汽化技术不受汽液平衡的限制,因此可以利用分子筛膜渗透汽化技术将混合醇中的水分先脱除,然后再利用精馏技术对混合醇各组分进行分离。本文完成了精馏-膜分离耦合工艺分离混合醇的全流程模拟,并与传统的萃取精馏工艺流程进行对比。精馏-膜分离耦合工艺大幅简化了原有萃取精馏工艺流程,整体能耗降低30%。并根据此流程在陕西延长石油(集团)有限公司建成了国内第一套膜分离-精馏耦合工艺的1000t/a低碳混合醇回收和分离的工业示范装置。 相似文献
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引 言蒸汽渗透 (vaporpermeation)是膜分离混合蒸汽的有效技术之一 ,它采用气相进料 ,过程中的浓差极化现象较弱 ,并且在分离过程中不需提供额外的热量以维持被分离物流的温度 ,避免了渗透蒸发(pervaporation)过程设备复杂的缺陷 .这使得蒸汽渗透过程可以很便利地与传统的蒸馏过程相耦联 .因而 ,利用蒸汽渗透膜技术分离有机溶剂 /水混合蒸汽的研究日益受到关注 .文献 [1,2 ]报道了γ -Al2 O3膜能有效地分离醇 /水、酮 /水混合蒸汽 .膜对有机蒸汽的吸附性能与蒸汽渗透的分离效果密切相关 ,同时也是膜传质机… 相似文献
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浊点萃取技术及其在分离过程中的应用 总被引:6,自引:0,他引:6
浊点萃取(CPE)技术是一种新型的环境友好的溶质富集和分离方法,其应用领域已经自最初的样品分析扩展到大规模的分离过程如水处理和生物产品提取.与传统的溶剂萃取技术相比,该技术具有快速、高效、简便、无需大量有机溶剂等特点.本文简要介绍了浊点萃取技术机理研究的新进展和近期报道的分离过程中的应用. 相似文献
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偏二甲肼传统的工业生产方法危险且能耗极大,渗透蒸发是一种新型的膜分离技术和清洁生产技术,受其膜材料的限制未能广泛应用,随着新型膜材料的出现打破这一瓶颈.在分析新型沸石膜用于醇/水等有机混合物脱水的应用研究基础上,讨论了将沸石膜应用于偏二甲肼脱水的可行性及待进一步研究的主要问题. 相似文献
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Zhihong YANG Guoliang ZHANG Lan LIN Danping REN Qin MENG Hongzi ZHANG 《Frontiers of Chemical Engineering in China》2009,3(1):68-72
The effects of baffles on the operation and mass-transfer characteristics in novel hollow fiber membrane contactor used in
distillation were investigated. Hollow fiber membranes, coated with a 7 μm polydimethyl-siloxane, were operated as structural
packing in the separation of ethanol-water solutions. The parallel flow mode was chosen for separation due to the stronger
driving force of the concentration difference, in which liquid flows through the lumens of the fibers and vapor flows countercurrent-wise
outside the fibers. Two baffles were installed on the shell side of the membrane contactors to enhance separation, which had
a round shape with a semi-lunar hole. The results show that both baffled and unbaffled membrane contactors gave better, more
productive separations than traditional packing in distillation, such as the excellent Sulzer Gauze BX structured packing.
The baffled membrane contactors performed better than unbaffled ones, especially at high vapor velocities. The minimal HTU
of membrane contactor with baffles could reach as low as 4.5 cm, and almost all the contactors could work well above the limit
where flooding normally occurs in conventional cases. Theoretical analysis predicted that baffles helped membrane module to
obtain a higher masstransfer coefficient and a smaller mass-transfer resistance. Finally, theoretical mass-transfer coefficient
and experimental value were compared as well as the contribution of each individual mass-transfer coefficients among liquid,
gas and membrane. 相似文献
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以乙醇/水溶液为分离对象,中空纤维PVA/PAN复合膜作为精馏填料,考察了不同膜组件的传质分离效率。实验结果表明:各种组件的分离效率均随塔釜加热功率的增加而减小;和大多数中空纤维膜接触器一样,其总传质系数Ky随中空纤维膜组件填充密度φ的增加而减少;相比于传统精馏填料而言,用中空纤维膜做精馏填料分离乙醇水溶液的分离效果更好,可以在常规填料不能操作的液泛线以上进行操作。当塔釜加热功率为120 W,45根中空纤维膜封装在内径为1.6 cm玻璃管中的传质单元高度(HTU)为5.64 cm。 相似文献
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探讨了填充密度对新型聚丙烯中空纤维膜接触器精馏过程中壳程传质的影响。中空纤维膜接触器在填充密度为4.7%、9.5%、19%时均可在远离常规填料液泛线以上的气速范围操作。低填充密度下,壳程的Sherwood数理论值大于实验值,但填充密度较高时,实验值大于理论值。高Reynolds数有利于壳程传质,低填充密度时的Sherwood数高于高填充密度时。随着F因子逐步增大,壳程气相传质阻力随之变小,且膜接触器的填充密度越高,气相传质阻力越大。3种不同填充密度膜接触器的气相总传质系数随着接触器填充密度的增大而迅速减小,由391.84×10-5 m·s-1降低为83.28×10-5 m·s-1。 相似文献
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膜接触器是一种通过膜作为两相之间的分离界面而实现相间传质的新型杂化膜过程,具体应用形式包括膜蒸馏、膜萃取、膜吸收、膜结构填料等.膜接触器使用微孔中空纤维膜将两流体分隔开,膜孔为两流体之间提供传质的场所.与传统接触分离器相比,新兴的膜接触器拥有分离效率高、工作范围宽、两相流速可单独控制以及结构紧凑等诸多独特的优点.文章着重于膜接触器及其相关过程在废水处理领域的最新研究成果和进展,具体分析比较了上述几种膜接触器的结构、工作原理和操作特点,充分展示了膜接触器在废水处理以及化工、医药、食品等领域特种分离中的广阔应用前景. 相似文献
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选用了三种不同材料的中空纤维膜(PP,PS和PES)构建新型膜接触器结构填料,并对异丙醇/水体系进行了精馏分离过程研究.在新型膜接触器中,液相和气相分别在管程和壳程进行逆向流动.实验结果表明:三种结构填料对异丙醇/水体系的分离效果依序为PES>PP>PS.不同材料的中空纤维膜作为结构填料对异丙醇/水溶液体系的分离效率均... 相似文献
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CFD Simulation and Modeling of Membrane‐Assisted Separation of Organic Compounds from Wastewater
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The extraction of volatile organic compounds (VOC) from water in porous hollow fibers was simulated with toluene, a hazardous material. The system to be simulated included a VOC stream and air as stripping gas, which were contacted using a porous hollow‐fiber membrane contactor. To model the process, the contactor was considered as three compartments, including shell side, porous membrane, and tube side. The model equations were derived and solved using computational fluid dynamics of momentum and mass transfer in all zones of the contactor. The profiles of concentration and pressure were obtained for the VOC in the hollow fibers. 相似文献
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Microporous hollow fiber gas-liquid membrane contactors have a fixed and well-defined gas-liquid interfacial area. The liquid flow through the hollow fiber is laminar, thus the liquid side hydrodynamics are well known. This allows the accurate calculation of the fiber side physical mass transfer coefficient from first principles. Moreover, in the case of gas-liquid membrane contactor, the gas-liquid exposure time can be varied easily and independently without disturbing the gas-liquid interfacial area. These features of the hollow fiber membrane contactor make it very suitable as a gas-liquid model contactor and offer numerous advantages over the conventional model contactors. The applicability and the limitations of this novel model contactor for the determination of physico-chemical properties of non-reactive and reactive gas-liquid systems are investigated in the present work. Absorption of CO2 into water and into aqueous NaOH solutions are chosen as model systems to determine the physico-chemical properties for non-reactive and reactive conditions, respectively. The experimental findings for these systems show that a hollow fiber membrane contactor can be used successfully as a model contactor for the determination of various gas-liquid physico-chemical properties. Moreover, since the membrane contactor facilitates indirect contact between the two phases, the application of hollow fiber model contactor can possibly be extended to liquid-liquid systems and/or heterogeneous catalyzed gas-liquid systems. 相似文献
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新型气液膜接触器是很多具有共同特点膜过程的总称,它使用高分子膜将两流体分隔开,膜孔为两流体提供有效传质的场所,与传统分离器相比具有许多独特的优点,日益成为分离科学研究的热点。简述膜接触器在不同气/液分离体系中的应用,针对膜吸收、膜蒸馏、膜结构填料等三种典型的气/液界面膜接触分离过程,从结构、膜材料、传质、分离效率等方面详细进行了分析和比较。着重介绍了近年来相关领域膜材料学的研究进展,如高分子膜材料、成膜方法以及膜材料的改性方法(等离子体改性法、紫外辐照法和表面涂覆改性法等)等。 相似文献
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Cristina Cardoso Pereira Jailton Ferreira Nascimento Wilson Mantovani Grava Cristiano Piacsek Borges 《应用聚合物科学杂志》2020,137(35):49013
In the present work, different poly(vinil fluoride) (PVDF) were selected for preparing membranes, based on the fact that they are able to form polymer solutions with different viscosities. This characteristic can affect spinning, as well as, mass transfer between the polymer solution and precipitation bath; therefore, each PVDF solution can differently affect membrane formation. The effect of different additives in the polymer solutions was also investigated. Flat sheet and hollow fiber membranes were characterized by Scanning Electron Microscopy analysis, contact angle, gas permeation, porosity, and membrane gas–liquid contactor tests, aiming carbon dioxide removal. The hollow fibers prepared by the polymer which formed a less viscous solution (named PVDF-I) had a faster light transmittance decay, which started around 150 s before the more viscous solution (PVDF-II). Hollow fibers obtained using PVDF-I and propionic acid, in the polymer solution, presented the best gas–liquid contactor performance. CO2 removal increased from 21 to 35.1%, for PVDF-II and PVDF-I, respectively, using aqueous diethanolamine solution, as absorbent liquid. In conclusion, even though PVDF-I and PVDF-II membranes were obtained by using the same spinning conditions and experimental methodology, the difference between the polymers properties certainly affected the final membrane morphology and transport properties. 相似文献