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通过对回收的废旧复合辊环材料进行重熔和离心铸造,制备了由耐磨WCp颗粒增强的复合层与Fe-C合金基体组成的再生复合材料辊环,并采用MMS-1G高速销-盘摩擦磨损试验机、扫描电镜(SEM),研究了在100、150和200 N载荷下滑动速度对再生复合辊环的摩擦性能的影响.结果表明,在100、150和200 N载荷条件下,随滑动速度的增加,再生复合辊环的磨损率均出现幅度很小的波动现象,而摩擦因数先降低后缓慢增加.在相同滑动速度条件下,磨损率明显随载荷的增加而增大,而摩擦因数随载荷的增加而降低.再生复合辊环在低速条件下的磨损机理主要为犁沟磨损和塑性变形,而当滑动速度较高时,表现为粘着磨损、氧化磨损和磨粒磨损. 相似文献
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为探究不同服役条件下Cf-Al2O3/Cu复合材料的摩擦磨损性能,采用QG-700型摩擦磨损试验机对其进行了在不同载荷和线速度条件下的摩擦磨损实验,分析了Cf-Al2O3/Cu复合材料的摩擦磨损性能和磨损机理。结果表明:载荷和线速度对Cf-Al2O3/Cu复合材料的摩擦磨损特性有显著影响,在实验范围内,在载荷为10 N及线速度为0.59 m/s条件下,5Cf-Al2O3/Cu复合材料的摩擦磨损性能最佳,其摩擦系数和磨损率分别为0.45和1.488×10-5 mg/m。摩擦过程中在复合材料摩擦表面产生的机械混合层有利于摩擦副之间的润滑。随着载荷增大,机械混合层减少,Cf-Al2O3/Cu复合材料的磨损加剧,基体塑性变形程度增大;随着线速度的增... 相似文献
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通过对废旧WCp/Fe-C复合材料辊环的重熔和离心铸造,获得了由外表面厚度达10~15 mm的再生复合材料层和芯部Fe-C基体材料组成的复合结构辊环.使用MMS-1G高速销盘摩擦试验机,研究了WCp/Fe-C再生复合材料层的摩擦磨损性能.试验结果表明:再生复合材料的磨损率在相同的摩擦速度下随着载荷的增加逐渐增大,而摩擦系数逐渐减小;在相同的载荷下,再生复合材料的摩擦系数随着摩擦速度的增大而减小,磨损率随着摩擦速度的增大而增加.与原复合材料相比,再生复合材料的耐磨性能略有降低,但远高于高速钢. 相似文献
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通过采用粉末冶金和原位合成技术相结合的近净成形技术制备Al-5%Si-Al2O3复合材料,并运用M一2000摩擦磨损试验机对该复合材料的摩擦磨损性能进行研究。通过单一变量比较法分析载荷和滑动速度对Al-5%Si-Al2O3复合材料摩擦磨损性能的影响,同时对长时间连续磨损下该材料的摩擦性能进行研究。通过扫描电子显微镜对Al-5%Si-Al2O3复合材料的磨损表面进行观察,并分析其磨损机制。结果表明,随着载荷的增大,试样的磨损量和摩擦因数均增加;随着滑动速度的增大,试样表面的升温使得产生氧化层的速率增加,试样的磨损量和摩擦因数均减少。在长时间的连续磨损过程中,由于初始时发生粘着磨损,试样的摩擦因数随着滑动距离的增大而增大。然后,试样表面氧化层的形成和破坏趋于动态平衡,试样表面相对稳定,其摩擦因数也随之趋于平稳。铝基复合材料的磨损机制主要为磨粒磨损、粘着磨损和氧化磨损。 相似文献
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硼酸镁晶须增强6061铝基复合材料的干摩擦磨损行为(英文) 总被引:1,自引:0,他引:1
研究搅拌铸造工艺制备的硼酸镁晶须增强6061铝基复合材料在干滑动条件下的摩擦磨损性能。复合材料的体积分数为2%,根据增强体种类,材料分别记为:Al基体、Mg2B2O5w/6061Al、ZnO/Mg2B2O5w/6061Al和CuO/Mg2B2O5w/6061Al;讨论磨损速率和摩擦因数之间的关系。结果表明:在4种材料中,ZnO/Mg2B2O5w/6061Al复合材料的磨损率最低。随着载荷和滑动速度的增大,基体和复合材料的摩擦因数和磨损率降低,摩擦磨损机制由轻微磨损机制转向严重磨损机制。 相似文献
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为研究生理盐水润滑条件下碳酸钙晶须含量、载荷大小、滑动速度因素对PEEK/CaCO3复合材料摩擦学性能的影响规律,并考察复合材料的摩擦学稳定性,在自制改性偶联剂处理晶须表面的基础上制备了PEEK/CaCO3复合材料,利用MMW1A立式万能摩擦磨损试验机对复合材料的摩擦学性能进行测试,用扫描电子显微镜(SEM)对磨损表面形貌进行扫描分析表征。结果表明,晶须含量对复合材料摩擦学性能影响明显,在0.9%的生理盐水润滑条件下PEEK/CaCO3复合材料随着晶须含量的增加,摩擦因数及比磨损率均呈现先减小后增大现象;当晶须质量分数为15%左右时,复合材料的摩擦因数达到最低值,同时比磨损量相对最低,复合材料与摩擦副的磨合过程相对平稳,具有较好的摩擦学性能,表现为粘着腐蚀磨损特征。外加载荷、滑动速度增大,材料的摩擦因数增大,比磨损率增加。 相似文献
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通过对回收的废旧复合辊环材料进行重熔和离心铸造,制备了由耐磨WCp颗粒增强的复合层与Fe-C合金墨体组成再生复合材料辊环,采用MMS-1G高速销-盘摩擦磨损试验机、扫描电镜(SEM),研完了100 N、150 N和200 N载荷下滑动速度对再生复合辊环摩擦性能的影响.结果表明,不同载荷条件下,随滑动速度的增加,再生复合辊环的磨损率均出现幅度很小的波动现象,而摩擦系数先降低后缓慢增加.在相同滑动速度条件下,磨损率明显随载荷的增加而增大,而摩擦系数随载荷的增加而降低.再生复合辊环在低速条件下的磨损机理主要为犁沟磨损和塑性变形,而当滑动速度较高时,表现为粘着磨损、氧化磨损和磨粒磨损. 相似文献
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研究了600℃时Fe-15Ce合金在H2-CO2、H2-H2S及H2-H2S-CO2 3种气氛中的腐蚀行为,Fe-15Ce合金腐蚀后发生了Ce的内氧化或形成了复杂的腐蚀产物膜,而未出现Ce的选择性氧化或硫化,这主要是合金中存在着两相及Ce在Fe中极低的溶解度的结果。Fe-15Ce合金在本实验条件下的氧化-硫化腐蚀速度低于相同温度、压力下的纯硫化。 相似文献
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M. Hoch 《Journal of Phase Equilibria》1996,17(4):290-301
We applied our model to the enthalpy of mixing data of the binary systems Na2O-SiO2, Na2O-GeO2, Na2O-B2O3, Li2O-B2O3, CaO-B2O3, SrO-B2O3, and BaO-B2O3. The most stable composition in the liquid, that is where the enthalpy of mixing is most negative, is with a metal-oxygen ratio of 4 to 3, for monovalent metals (Na and Li) and 3 to 4 for divalent metals (Ba and Ca) in liquid silicates or borates. The same applies to the CaO-SiO2, CaO-Al2O3, PbO-B2O3, PbO-SiO2, ZnO-B2O3, and ZnO-SiO2 systems. The oxygen to metal ratio, its constant value in various types of systems, reflects and describes the structure of the liquid. Using the analyzed enthalpies of mixing data and the available phase diagrams, we calculated the enthalpies of formation of the various binary compounds. The results are in excellent agreement with data in the literature that were obtained from direct solid-solid calorimetry. 相似文献
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通过热分解法制备了含IrO2-MnO2中间层Ti/RuO2-TiO2-SnO2电极,采用SEM、EDX、XRD、CV等检测方法对中间层进行表征,同时采用强化加速寿命试验对电极电化学稳定性进行表征。结果表明:450℃时前躯体完全氧化并形成固溶体,制备的中间层晶粒细小,表面结构致密,电化学孔隙率小。添加中间层使Ti/RuO2-TiO2-SnO2电极强化寿命由未加中间层的7.5h提高到995.8h,远高于国家标准20h。 相似文献
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用石墨为还原剂,将渣中La_2O_3还原入液态Sn,以测定1500℃下La_2O_3-CaF_2和La_2O_3-CaF_2-CaO-SiO_2渣中La_2O_3的活度.对La_2O_3-CaF_2系,并用Gibbs-Duhem积分法求得CaF_2的活度. 根据液态渣的离子结构模型,对上述二渣系中La_2O_3的活度数据进行了简单的讨论. 相似文献
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Jonas Botterman Koen Van den Eeckhout Ives De Baere Dirk Poelman Philippe F. Smet 《Acta Materialia》2012,60(15):5494-5500
Mechanoluminescence (ML), a general term for the phenomenon in which light emission occurs during any mechanical action on a solid, can be divided roughly into two classes: destructive ML and non-destructive ML. For practical use in high-end applications (e.g. pressure sensors), materials with non-destructive ML properties are preferred. This paper reports on the strong non-destructive ML in BaSi2O2N2:Eu. When irradiated in advance with ultraviolet or blue light, this phosphor shows intense blue-green light emission upon mechanical stimulation such as friction or pressure. The ML has an emission band peaking at 498 nm, which is ~4 nm red-shifted compared to the steady-state photoluminescence. The origin of the ML is discussed and related to the persistent luminescence of BaSi2O2N2:Eu. The same traps are responsible for both phenomena. Based on the occurrence of ML in this phosphor, we were able to show that the predominant crystallographic structure of BaSi2O2N2:Eu belongs to space group Cmc21. 相似文献
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采用第一性原理计算方法研究了Li-Mg-N-H体系贮氢材料的放氢产物Li2MgN2H2的吸氢反应过程中的过渡态、表面电子态密度和表面能。结果表明:氢分子在Li2MgN2H2低指数表面中最低能量(100)表面的Mg-Mg-Li穴位吸附位置能够形成最稳定的吸附结构并发生解离,氢分子吸附能为-0.1898eV,解离能约为0.84eV(81kJ/mol),表明该反应所需的反应活化能仍较高,吸氢反应速度缓慢。 相似文献
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The phase diagram of the CaCl2-CaF2-MgCl2-MgF2 reciprocal ternary system was calculated thermodynamically from available data on the common-ion binary subsystems and from
available data on the CaCl2-MgF2 join. This join is very nearly quasibinary and divides the system into two quasiternary systems: the CaCl2-MgF2-CaF2 system with a ternary eutectic calculated at 724 +-5 °C and the CaC2-MgF2-MgCl2 system with a ternary eutectic calculated at 561 +-5 °C. 相似文献
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The sulfidation of Fe-20% Cr-30% Mn, Fe-25%Cr-20%Mn and Fe-25% Cr was studied at 700°C in H2-H2S and the oxidation and sulfidation in H2-H2O-H2S after preoxidation in H2-H2O. The sulfidation rate is strongly increased for the Mn-containing alloys, layers of (Mn,Cr)S and (Mn,Fe)Cr2S4 are formed. Also the oxidation rate is enhanced compared to Fe-25% Cr by formation of MnCr2O4 instead of Cr2O3. The sulfidation after preoxidation leads to internal and external sulfidation of the Mn-containing alloys. With increasing oxygen pressure p(O2) = 10?26…10?22 atm. of the H2-H2O-H2S mixtures the sulfidation is suppressed, for the higher oxygen pressure 10?23 and 10?22 atm. fast oxidation prevails under formation of MnCr2O4. Manganese cannot increase the sulfidation resistance of alloys, in spite of the stability and low degree of disorder of its sulfide, since the mixed sulfide (Mn,Cr)S is formed which has a high degree of disorder, high diffusivities and high growth rate according to the doping effect of trivalent Cr3+. 相似文献
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ZHENG Chaogui LIU Hongping YE Yupu 《金属学报(英文版)》1990,3(10):284-286
Three surfaces corresponding to the primary crystallization of PrCl_3,CaCl_2 andMgCl_2 respectively,3 univariant curves related to the secondary crystallization and a ternaryeutectic(44.8 wt-% PrCl_3,31.8 wt-% CaCl_2,546℃)were found in systemPrCl_3-CaCl_2-MgCl_2 by means of DTA.A reaction occurs in this system:L=PrCl_3+CaCl_2+MgCl_2. 相似文献