共查询到20条相似文献，搜索用时 15 毫秒
1.
To describe the complex kinetics of formation and destruction mechanism of nitrogen dioxide(NO_2), there is an increasing demand for real-time and in situ analysis of NO_2 in the discharge region. Pulsed cavity ring-down spectroscopy(CRDS) provides an excellent diagnostic approach. In the present paper, CRDS has been applied in situ for time evolution measurement of NO_2 concentration which is rarely investigated in gas discharges. In pulsed direct current discharge of NO_2/Ar mixture at a pressure of 500 Pa, a peak voltage of -1300 V and a frequency of 30 Hz, for higher initial NO_2 concentration(3.05?×?10~(14)cm~(-3), 8.88?×?10~(13)cm~(-3)),the NO_2 concentration sharply decreases at the beginning of the discharge afterglow and then becomes almost constant, and the pace of decline increases with pulse duration; however, for lower initial NO_2 concentration of 1.69?×?10~(13)cm~(-3), the NO_2 concentration also decreases at the beginning of the discharge afterglow for 200 ns and 1 μs pulse durations, while it slightly increases and then declines for 2 μs pulse duration. Thus, the removal of low-level NO_2 could not be promoted by a higher mean energy input. 相似文献
2.
UV-pulsed laser cavity ringdown spectroscopy of the hydroxyl radical OH(A–X)(0–0)band in the wavelength range of 306–310 nm was employed to determine absolute number densities of OH in the atmospheric helium plasma jets generated by a 2.45 GHz microwave plasma source.The effect of the addition of molecular gases N_2 and O_2 to He plasma jets on OH generation was studied.Optical emission spectroscopy was simultaneously employed to monitor reactive plasma species.Stark broadening of the hydrogen Balmer emission line(H_β)was used to estimate the electron density nein the jets.For both He/N_2 and He/O_2 jets, newas estimated to be on the order of 10~(15)cm~(-3).The effects of plasma power and gas flow rate were also studied.With increase in N_2 and O_2 flow rates, netended to decrease.Gas temperature in the He/O_2 plasma jets was elevated compared to the temperatures in the pure He and He/N_2 plasma jets.The highest OH densities in the He/N_2 and He/O_2 plasma jets were determined to be 1.0?×10~(16)molecules/cm~3 at x?=?4 mm(from the jet orifice)and 1.8?×?10~(16)molecules/cm~3 at x=3 mm, respectively.Electron impact dissociation of water and water ion dissociative recombination were the dominant reaction pathways, respectively, for OH formation within the jet column and in the downstream and far downstream regions.The presence of strong emissions of the N_2~+ bands in both He/N_2 and He/O_2 plasma jets, as against the absence of the N_2~+ emissions in the Ar plasma jets, suggests that the Penning ionization process is a key reaction channel leading to the formation of N_2~+ in these He plasma jets. 相似文献
3.
E PANOUSIS F. CLEMENT J. F. LOISEAU N. SPYROU B. HELD J. LARRIEU F. GUERTON 《等离子体科学和技术》2007,9(6):670-673
The experimental work reported here is devoted to the study of the modifications inflicted on the surface of titanium alloy specimens by an atmospheric pressure dielectric barrier discharge（DBD） reactor in both spatial and temporal afterglow conditions. A commercially available （AcXys Technologies） modified reactor system was used for the surface treatment of the TiA6V4 titanium alloy that is widely used in the aeronautical industry. Wettability surface characterisation and XPS analyses are performed to give a macroscopic and microscopic insight to the surface modifications. Best operating conditions, at constant input energy, were obtained for a duty cycle equal to 10%. 相似文献
4.
An innovative method for coal liquefaction by using dielectric barrier discharge (DBD) plasma in a short reaction time was developed. Using tetralin as the reaction medium, DBD plasma as the energy source, and a reaction time of 10 min at 140 o C, up to 10% of coal was converted to liquid material. The results showed the feasibility of coal’s liquefaction by DBD plasma under relatively moderate conditions. Simultaneously, it was clarified that the effect of DBD plasma treatment was opposed to the thermal effect of heating. An acid plasma sheath could be formed on the coal powder surface in DBD conditions, liquefied reactions could be carried out in the absence of inorganic acid, and the products were nearly neutral and with low causticity. 相似文献
5.
In a general plane-parallel electrode system,the edge of the electrode will undermine the uniformity of the dielectric barrier discharge(DBD)because of the influence of the distorted electrical field.In this paper,the influence of the non-uniform electrical field on the edge efect of DBDs in a short-gap is investigated.We present some of the experimental results of DBDs produced by three kinds of convex-spherical electrodes.The results show that there is a dark area(the homogeneous discharge)in the central region of the electrode and a bright halo(the filamentary discharge)in the outer peripheral region,and the radius of the dark region is determined by the electrode geometry.The calculated results of the transverse(radial)field component distribution on the surface of the electrodes show that the edge efect does not come from the electrode edge,but the transverse field.The discharge has enough space to be fully developed and then format the filamentary discharge in the outer peripheral region because the streamer of the filamentary discharge is driven to move along the direction of the longer path by the transverse field.Thus,the homogeneous discharge(the Townsend DBD or a glow DBD)could not be produced in this area. 相似文献
6.
In a general plane-parallel electrode system the edge of the electrode will undermine the uniformity of the dielectric barrier discharge （DBD） because of the influence of the distorted electrical field. In this paper, the influence of the non-uniform electrical field on the edge effect of DBDs in a short-gap is investigated. We present some o.f the experimental results of DBDs produced by three kinds of convex-spherical electrodes. The results show that there is a dark area （the homogeneous discharge） in the central region of the electrode and a bright halo （the filamentary discharge） in the outer peripheral region, and the radius of the dark region is determined by the electrode geometry. The calculated results of the transverse （radial） field component distribution on the surface of the electrodes show that the edge effect does not come from the electrode edge, but the transverse field. The discharge has enough space to be fully developed and then format the filamentary discharge in the outer peripheral region because the streamer of the filamentary discharge is driven to move along the direction of the longer path by the transverse field. Thus, the homogeneous discharge （the Townsend DBD or a glow DBD） could not be produced in this area. 相似文献
7.
The experimental work reported here is devoted to the study of the luminous activity of a long dielectric barrier discharge （DBD） afterglow at atmospheric pressure. The discharge plasma is generated in a commercially available （AcXys Technologies） reactor, using a N2 flow of a few tens SL/min, whereas the luminous afterglow when channelled into a quartz tube extends at a distance of 50 cm, finishing in a luminous arrow at the tube＇s exit. The luminous activity of the afterglow is studied by means of photomultiplier scans and optical emission spectroscopy, revealing an interesting transient phase. An attempt is made to correlate this effect with the active species＇ creation and destruction mechanisms. 相似文献
8.
A new method for liquefying coal using dielectric barrier discharge plasma has been studied. By utilizing waste oil as the solvent and processing coal nanopowder in the plasma for 10 min, we have attained a liquid yield of more than 80%. The experiment shows that not only the coal nanopowder promoted the liquefaction process, but hydrogen radicals improved the liquid yield effectively. In the plasma processing, the phenomenon of the changing color of the nanopowder solution and not producing a solid residue has been obviously observed. The rational parameters that affected the liquefaction of coal nanopowder have been achieved through the experiment,and the liquefied products have been analyzed. 相似文献
9.
Feilong SONG 《等离子体科学和技术》2017,19(12):125502-125502
A highly-integrated experimental system for the plasma decomposition of fuels was built.Experiments were conducted in a flow reactor at atmospheric pressure and confirmed that n-decane could be cracked by large-gap dielectric barrier discharge under the excitation of a microsecond-pulse power supply. Alkanes and olefins with a C atom number that is smaller than10 as well as hydrogen were found in the cracked products of n-decane(n-C10 H22). The combination of preheating and plasma decomposition had strong selectivity for olefins. Under strong discharge conditions, small molecule olefins were found in the products. Moreover, there was a general tendency that small molecule olefins gradually accounted for higher percentage of products at higher temperature and discharge frequency. 相似文献
10.
Ying ZHAO Risheng YAO Yuedong MENG Jiaxing LI Yiman JIANG Longwei CHEN 《等离子体科学和技术》2017,19(3):34001-034001
To explore the feasibility of a degradation approach by non-thermal plasma and the corresponding degradation pathways,studies on the oxadiazon removal in synthetic wastewater by a dielectric barrier discharge plasma reactor were investigated.The loss of the nitro group,dechlorination and ring cleavage is mainly involved in the non-thermal plasma degradation pathways of oxadiazon in a solution based on the OES and LC-MS analysis.Detection of EC25 and the production of the chlorine ion and nitrate ion further demonstrate the feasibility and validity of the approach.The conditions with a proper applied voltage,solution flow rate,oxygen flow rate,and solution pH contribute to the plasma degradation processes with a degradation ratio of over 94％. 相似文献
11.
Yanqin LI 《等离子体科学和技术》2018,20(1):14012
The ε-Fe3N-based magnetic lubricant which is stable and high saturation magnetization has been prepared by a homemade DBD device under the atmospheric pressure. The results show that the NH3 flow rate, the applied peak-to-peak voltage and the mass ratio of surfactant and carrier lubricant have important effects on the phase structure, the magnetic properties, the size of ferroparticles and the stability of the ε-Fe3N-based magnetic lubricant. TEM images show the ε-Fe3N ferroparticles are dispersed in the carrier lubricant homogeneously, and the cluster phenomenon is not observed. The stable ε-Fe3N-based magnetic lubricant with the saturation magnetization of 50.11 mT and the mean ferroparticle size of 11 nm is prepared successfully. The main particles of the atmospheric-pressure Ar/NH3/Fe(CO)5 DBD plasma are NH, N, N+, Fe, N2, Ar, Hα, and CO; NH is a decomposition product of NH3. Fe and N active radicals are two elementary species in the preparation of the ε-Fe3N-based magnetic lubricant in the atmospheric-pressure DBD plasma. There are two discharge modes for DBD plasma, namely, multi-pulse APGD and filamentary discharge. By increasing the applied peak-to-peak voltage from 4600 to 7800 V, the discharge mode is changed from single-pulse APGD with filamentary discharge to two-pulse APGD with filamentary discharge, and the Lissajous figure also converts from a quadrilateral with one step to two steps on the right-hand side. 相似文献
12.
Dielectric barrier discharge （DBD） for SOs removal from indoor air is investigated. In order to improve the removal efficiency, two novel methods are combined in this paper, namely by applying a pulsed driving voltage with nanosecond rising time and applying a magnetic field. For SOs removal efficiency, different matches of electric field and magnetic field are discussed. And nanosecond rising edge pulsed power supply and microsecond rising edge pulsed power supply are compared. It can be concluded that a pulsed DBD with nanosecond rising edge should be adopted, and electrical field and magnetic field should be applied in an appropriate match. 相似文献
13.
In this work, the plastic of polylatic acid(PLA) film is coated by alumina(Al_2O_3)through dielectric barrier discharge plasma assisted atomic layer deposition(DBD PA-ALD) for the proposal of the barrier property enhancement. The influence of ALD Al_2O_3 thickness on properties of barrier, mechanical, optical and degradation is investigated in detail. It is obtained that the growth rate of Al_2O_3 in DBD PA-ALD is as quick as 0.12 nm/cycle. After coated～40 nm Al_2O_3, the water vapor transmission rate of PLA is reduced by two orders of magnitude.Additionally, it is noticed that the tension strength of the coated film is improved slightly,whereas the light transmission rate is decreased with the increase of Al_2O_3 thickness. The degradation test shows that Al_2O_3 coating almost does not affect the self-degradation rate of PLA film. 相似文献
14.
1 IntroductionDielectric Barrier Discharge (DBD) is a focus of low-temperature plasma research in recent years [1~4]. Gen-erally speaking, discharge intensity and ionization de-gree of gas in the gap strengthen with the increase infrequency. In practice, many DBD devices display theaforesaid characteristics only in a very small frequencyrange. When the frequency is beyond that range, thedischarge intensity will decline with the increase in fre-quency. See Fig. 1 from the top down.Resonanc… 相似文献
15.
Based on the theory of EHD (electronhydrodynamic) ,a simplified volume force model is applied to simulation to analyze the traits of plasma flow control in flow field, in which the cold plasma is generated by a DBD (dielectric-barrier-discharge) actuator. With the paraelectric action of volume force in electric field, acceleration characteristics of the plasma flow are investigated for different excitation intensities of RF(radio frequency) power for the actuator. Furthermore, the plasma acceleration leads to an asymmetric distribution of flow field, and hence induces the deflection of jet plume , then results in a significant deflection angle of 6.26o thrust-vectoring effect. It appears that the plasma flow control technology is a new tentative method for the thrust-vectoring control of a space vehicle. 相似文献
16.
Using a plexiglas plate model, the performance of peristaltic flow acceleration in- duced by multiple DBD （dielectric barrier discharge） plasma actuators was studied based on PIV （particle image velocimetry）. The asynchronous and the duty cycle pulsed actuation modes were proposed and tested. The velocity fields induced by multiple DBD plasma actuators with different phase angles and duty cycle ratios were acquired and the momentum transfer characteristics of the flow field were discussed. Consequently, the mechanism of the peristalsis-acceleration multi- ple DBD plasma actuation was analyzed. The results show that the peristaltic flow acceleration effect of multiple plasma actuators occurs mainly in paraelectric direction, and the mechanism of peristaltic flow acceleration is ejection pushing effect rather than injection pumping effect. The asynchronous and the duty cycle pulsed actuation modes can, with energy consumption increase of merely 10%, achieve 65% and 42% increase of downstream velocity, and thus are promising in velocity improvement and energy saving. 相似文献
17.
The purpose of impedance matching for a Marx generator and DBD lamp is to limit the output current of the Marx generator,provide a large discharge current at ignition,and obtain fast voltage rising/falling edges and large overshoot.In this paper,different impedance matching circuits (series inductor,parallel capacitor,and series inductor combined with parallel capacitor) are analyzed.It demonstrates that a series inductor could limit the Marx current.However,the discharge current is also limited.A parallel capacitor could provide a large discharge current,but the Marx current is also enlarged.A series inductor combined with a parallel capacitor takes full advantage of the inductor and capacitor,and avoids their shortcomings.Therefore,it is a good solution.Experimental results match the theoretical analysis well and show that both the series inductor and parallel capacitor improve the performance of the system.However,the series inductor combined with the parallel capacitor has the best performance.Compared with driving the DBD lamp with a Marx generator directly,an increase of 97.3％ in radiant power and an increase of 59.3％ in system efficiency are achieved using this matching circuit. 相似文献
18.
Gaseous naphthalene has been removed by air plasma generated by pulsed corona discharges at 100°C (LSPM) and dielectric barrier discharges (DBD) up to 250 °C (LPGP) in different reactors geometries. Naphthalene has been chosen as one of unburned hydrocarbon present in exhaust gas engine during the cold start of vehicles. The comparison between the different discharge geometries has been possible using the specific input energy (SIE) as relevant parameter for pollutant removal process control considering the differences in the electrical characteristics and the differences of gas flow. The best naphthalene degradation is obtained in the wire-to cylinder (WTC) corona discharge and the stem-to-cylinder DBD with an energy cost β respectively of 10 and 20 J L -1. The main by-products issues of the naphthalene oxidation are CO2 and CO reaching 45% in Multi-Pin-to-Plan corona discharge. We detected polyaromatic hydrocarbons in the gas phase (few ppm) and in the solid phase deposited in the reactors. The introduction of water in the discharges promotes the naphthalene degradation by OH-atom, which has better oxidising power than O-atom in dry air. 相似文献
19.
The dielectric barrier discharge(DBD) in the glow regime in neon has been investigated by experiment and two-dimensional(2D) fluid modeling.The discharge was carried out in a planar DBD system with segmented-electrodes driven by square-wave voltage.The results show that the glow DBD originates in the center of the electrode and expands outward to the electrode edge during each half cycle of the voltage,forming a radial structure.The discharge decays firstly in the inner area but sustains longer in the edge area,showing a reversed discharge area.The discharge cannot completely cover the entire electrode surface,but remains a border of non- or weak discharge.The fluid modeling shows a similar result in agreement with the experiments.The simulations indicate that the electric field in the edge area is distorted due to the boundary effect so that the electric field and charge distribution are different from that in the inner part.The distorted field reduces the longitudinal component near the edge and causes the local field to be lower than that in the center,and hence makes the discharge behindhand.It also induces a transverse field that makes the discharge extend radially outward to the edge.The boundary effect plays an important role in the glow DBD structure. 相似文献
20.
In this paper, an experimental study on SO2 removal by nanosecond rising edge pulse dielectric barrier discharge （DBD） plasma, generated by multi-needle-to-plane electrodes, is carried out. The mechanism of the effect of various factors, such as gap size between dielectric barrier and discharge needles, environmental humidity, and inlet speed of gas flow upon the removal efficiency of air purification is analyzed. The studies show that SOs removal efficiency improves with the increase in the gap size between dielectric barrier and discharge needles in the case of a fixed space between two electrodes, and also improves with the increase in the environmental humidity. For a mixed gas with a fixed concentration, there is an optimal inlet speed of gas flow, which leads to the best removal efficiency. 相似文献