Sr对AZ31B镁合金微观组织和腐蚀性能的影响

研究了Sr对AZ31B镁合金显微组织和腐蚀性能的影响。当AZ31B中加入的Sr含量大于0.3%时,合金组织中β相(Mg_(17)Al_(12))减少,分布更加弥散和均匀,并且在晶界上形成了断续网状分布的Al_4Sr相,合金组织明显细化。当AZ31B中加入的Sr含量达到0.9%时腐蚀速率下降为AZ31B的50%。但Sr含量达到1.2%时,晶界处出现共晶组织呈断续网状分布,合金晶粒再度增大。     

Sr和Y对AZ31镁合金组织与耐蚀性能的影响

研究不同含量的Sr和Y对AZ31镁合金组织与耐蚀性能的影响.结果表明:添加Sr可以明显减小AZ31合金的晶粒尺寸,使fl-Mgl7AIl2相从连续网状结构转变为弥散均匀分布颗粒状,并在AZ31-xSr合金中生成沿晶界分布的Al4Sr相.同时添加Sr和Y的晶粒细化效果好于单独添加sr的.生成晶内和沿晶界分布的Al2Y和A...     

工艺与合金元素对镁锶系合金微观组织的影响

采用"熔-浸"热还原法,制备了具有优良组织结构的镁锶系列(Mg-Sr、Mg-Sr-Y、Mg-Sr-Zn、Mg-Sr-Zn-Y)镁合金。借助OM、SEM和XRD等测试技术,研究了工艺与合金元素对镁锶系合金微观组织结构的影响。结果表明:较低温下加入SrO有助于镁锶合金中Mg17Sr2相的形成;随镁锶合金冷却速度的增大,晶界处长条状Mg17Sr2相变成颗粒状和短条状;锶、钇和锌的加入均细化了镁锶合金的显微组织,多种元素的复合效果优于添加单一元素的作用;在镁锶形成共晶组织的基础上,Mg-Sr-Y合金在枝晶内和枝晶间形成了Mg24Y5相,在Mg-Sr-Zn-Y合金中形成了Mg12YZn相。     

Sr对AZ91镁合金组织及力学性能的影响

采用光学显微镜、扫描电子显微镜和X射线衍射仪等研究Sr对AZ91镁合金组织及力学性能的影响.结果表明:添加微量Sr可以细化并离散AZ91合金的铸态共晶组织,在合金晶界处Sr与Al生成多角块状或杆状的Al4Sr高熔点相;当Sr含量为0.2%时,AZ91-0.2Sr合金的综合力学性能最优,AZ91-Sr合金的时效进程与AZ91合金相比明显被抑制.由于这些析出相及合金晶界附近Al4Sr高熔点相的强化作用,AZ91-0.2Sr合金经T6处理后的室温和高温力学性能皆优于原AZ91合金的.     

Sr,Y对AZ31镁合金显微组织与力学性能的影响

用金属型铸造法制备了不同Sr、Y含量的AZ31镁合金试样,借助光学显微镜、扫描电镜、能谱分析、XRD、力学性能测试等方法研究了Sr、Y对AZ31镁合金显微组织和力学性能的影响。结果表明,微量Sr的添加可细化AZ31镁合金的显微组织,并且在晶界处有杆状的Al4Sr形成;微量的Sr、Y复合添加可使AZ31镁合金显微组织更加细化,晶内有颗粒状的Al2Y析出,同时β-Mg17Al12相消失;合金的常温和高温力学性能随Sr、Y的添加有明显提高。     

AZ80+xSr合金的组织和Sr的存在状态

本文通过OM、XRD、SEM、EDS、DSC和拉伸试验,研究了AZ80＋xSr合金的显微组织和拉伸性能,分析了Sr元素的存在状态及其在合金中的分布,探讨了Sr元素在合金中的作用。结果表明,AZ80＋xSr合金的显微组织主要由基体α-Mg和化合物β-Mg17Al12相组成,含Sr量少的合金没有形成Mg-Sr相,而含Sr较高时可形成高温稳定相Mg17Sr2相;微量Sr元素分布在晶界上,Sr在合金中可能以两种形式存在：以固溶形式固溶在β-Mg17Al12相中,或在含量高时和Mg结合生成化合物Mg17Sr2相。Sr的加入使合金晶粒明显的细化,随Sr含量的增加沿晶分布的化合物相增多增厚;Sr含量进一步增加,化合物呈断续网状结构;加Sr后合金的抗拉强度提高20-25MPa,伸长率提高40%-100%。     

添加Bi对AZ80镁合金显微组织及力学性能的影响(英文)

研究添加Bi对AZ80镁合金铸态显微组织及力学性能的影响。结果表明:将Bi加入到AZ80镁合金中后,粗大的β-Mg17Al12离异共晶组织被细化并由连续网状分布变为断续状;晶界处和枝晶间出现具有六方D52结构的针状和颗粒状的Mg3Bi2相。力学性能测试结果表明:随着Bi含量的增加,抗拉强度和伸长率先升高再降低,AZ80-0.5%Bi合金的综合力学性能最优;当Bi含量超过1.0%(质量分数)时,针状相明显变多并粗化,加载时容易开裂而割裂基体,导致力学性能降低。     

双辊铸轧AZ31镁合金板坯的物相分析

采用双辊铸轧技术制备AZ31镁合金板坯,利用X射线衍射、金相显微镜、扫描电子显微镜以及能谱分析等技术对该板坯的物相进行分析.结果表明: 双辊铸轧AZ31镁合金板坯中的物相主要有а-Mg枝晶、枝品间富溶质а-Mg和不规则的块状Mg17(Al,Zn)12相组成的离异共晶以及弥散分布于晶内的星形细小Al8Mn5相;在双辊铸轧过程中,随着Mg液温度的降低,过饱和的Mn以Al8Mn5相的形式从Mg液中析出,而后细小的Al8Mn5相随着а-Mg初晶的长火进入枝晶胞内部;а-Mg初晶长大的同时,Al、zn等元素在枝晶问未凝固的液相中富集,最终在枝晶问形成依附于初晶的富溶质а-Mg和不规则的块状Mg17(Al,Zn)12相组成的离异共晶.     

AZ61镁合金的差热分析及凝固组织观察

通过差热分析并结合金相组织观察的方法研究了AZ61镁合金相变温度点和凝固组织的特征,并对凝固组织演变机理做了理论分析。结果表明:AZ61镁合金固液转变温度在587.10~608.43℃之间,共晶转变温度在413℃左右;AZ61镁合金在凝固过程中首先析出α-Mg树枝晶,α-Mg树枝晶间富Al的残余液体发生共晶转变,形成α-Mg+β-Mg17Al12共晶组织。共晶组织中的α-Mg相往往依附初晶α-Mg形核生长,并将β-Mg17Al12相推向α-Mg枝晶的晶界,形成离异共晶组织。     

Sr对AZ81镁合金β-Mg17Al12析出相形态及力学性能的影响

采用OM、XRD、SEM、EDS和电子拉伸试验机研究了Sr对AZ81镁合金β-Mg17Al12析出相形态及力学性能的影响.结果表明,加入0.3％的Sr时,合金中β-Mg17Al12相得到了明显细化,合金中出现颗粒状及杆状Al4Sr新相.随着Sr含量增加,β-Mg17Al12相从连续网状变为不连续网状和块状,且合金常温力学性能在Sr含量为0.6％时达到最高.当Sr含量到0.9％时,β-Mg17Al12相数量进一步减少,Al4Sr相偏聚呈断续网状.AZ81-xSr镁合金经过T6处理后,在α-Mg相晶界及晶内析出了大量层片状或针状、点状β-Mg17Al12相,合金力学性能得到显著提高.随着Sr含量增加,晶界上不连续析出的β-Mg17Al12相层片间距减小,晶内连续析出的β-Mg17A112相减少.     

Effects of Al-10Sr master alloys on grain refinement of AZ31 magnesium alloy

The effects of Al-10Sr master alloys on grain refinement of AZ31 magnesium alloy were investigated, and the refinement efficiency of different Al-10Sr master alloys （commercial, solubilized, rolled and remelted＋rapidly cooled） was compared and analyzed. The results indicate that the morphology and size of Al4Sr phases in the microstructures of different Al-10Sr master alloys, are of great difference. For the commercial Al-10Sr master alloy, the Al4Sr phases evolve from coarse block shape to relatively fine block shape after being dissolved at 500 ℃ for 4 h and followed by water quenching; but after being rolled at 300 ℃ for 50% reduction or remelted and followed by rapid cooling, the Al4Sr phases mainly exhibit fine granule and fibre shapes. In addition, the different Al-10Sr master alloys can effectively reduce the grain size of AZ31 magnesium alloy, but their refinement efficiency is different. The refinement efficiency of the Al-10Sr master alloy obtained by remelting and rapid cooling is the best, then the rolled, solubilized and commercial Al-10Sr master alloys are in turn. The difference of refinement efficiency for different Al-10Sr master alloys may be related to the dissolution rates of Al4Sr phases with different morphologies and sizes in the melt of AZ31 magnesium alloy.     

Processing Effects on Grain Refinement of AZ31 Magnesium Alloy Treated with a Commercial Al-10Sr Master Alloy

The effects of Sr amount and melt holding time on the grain refinement of AZ31 magnesium alloy treated with a commercial Al-10Sr master alloy are investigated. The effects of solutionizing, rolling, and remelting of commercial Al-10Sr master alloy on the grain refinement of AZ31 magnesium alloy are also investigated. An increase in Sr amount from 0.01 to 0.1 wt.% or melt holding time from 20 to 80 min causes the grain size of AZ31 alloy treated with the commercial Al-10Sr master alloy to gradually decrease. In addition, the solutionizing, rolling, or remelting of commercial Al-10Sr master alloy can improve the refinement efficiency of the master alloy to AZ31 alloy, and the improvement resulting from the remelting is best obvious, followed by rolling and solutionizing, respectively.     

熔体温度对AZ31B镁合金铸态组织及力学性能的影响(英文)

采用自制的电阻炉研究熔体温度对AZ31B镁合金凝固组织与拉伸性能的影响。结果表明:在温度低于850℃水冷时,金属型AZ31B镁合金铸锭等轴枝晶的尺寸随着熔体温度的升高呈直线下降,超过850℃后变化不大。组织中第二相呈现出先细化后粗化的变化规律。AZ31B镁合金试样的抗拉强度、伸长率和屈服强度随着熔体温度的提高而先快速增大后略有减小,熔体温度为850℃时试样的抗拉强度达到260MPa,屈服强度达到75.4MPa,伸长率达到27.57%,比熔体温度为750℃时的分别提高了15%、13%和61%。DSC分析表明,升高熔体温度使凝固开始点温度降低,临界晶核半径减小,从而增加了熔体中的过冷度,提高了熔体中非均匀形核率,是镁合金晶粒细化和拉伸性能提高的主要原因。     

热挤压形变对AZ31B镁合金TIG焊缝组织及断口形貌的影响

以AZ31B镁合金板用同质成分焊丝填充进行TIG对接焊,采用专门设计制作的陶瓷电加热装置在高温拉伸试验机上对接头进行热挤压形变初步试验.结果表明,焊接接头经350℃热挤压形变,可使原焊缝铸态枝晶组织转变为细球状组织,枝晶偏析得到明显改善;同时还可促使原组织中沿α-Mg基体晶界网状分布的β-Mg17Al12相转化成晶内呈弥散分布的二次析出相;通过细化焊缝晶粒、消除脆性β-Mg17Al12相对晶界的弱化作用,在晶内产生弥散强化效应,可使接头的抗拉强度达到母材金属的90%左右,塑性也在一定程度上得到改善.     

Mg对Al-Ti-B、Al-Ti-C中间合金细化铝晶粒效果的影响

试验研究了Mg对Al-5Ti-1B和Al-5Ti-0.2C两种中间合金细化铝晶粒效果的影响,分析了Mg影响两种中间合金细化铝晶粒行为的机制。结果表明,在w(Mg)=1%～7%的范围内,镁含量的增加,对两种中间合金细化铝晶粒的促进作用不显著,但对晶粒形貌有显著的影响;晶粒形貌取决于所用中间合金的种类和Mg添加量大小,相同镁含量时,用Al-5Ti-1B细化比用Al-5Ti-0.2C细化后晶粒的树枝化程度小;细化所用的中间合金相同时,随着镁含量的增加,细化晶粒的树枝化程度增大。     

不同激光功率下镁合金表面激光熔覆Ni60合金涂层的显微组织和磨损性能

为提高镁合金表面的耐磨性,利用5kW横流连续CO2激光器在AZ31B镁合金表面熔覆Ni60合金粉末,制备了无裂纹、气孔等缺陷的熔覆层。分析讨论了不同激光功率下熔覆层的显微组织和磨损性能。结果表明:熔覆层的显微组织为典型的枝晶状态,且随着激光功率的增加,枝晶尺寸增加;不同的激光功率下,熔覆层都由Mg、MgNi2、Mg2Ni3Si、Mg2Ni、Mg2Si和FeNi组成,但当激光功率增加时,Mg相含量逐渐减小,其它相含量逐渐增多。在枝晶细化和各种金属间化合物的共同作用下,熔覆层的显微硬度和耐磨性能都得到提高,且激光功率P=3 000W时,提高程度最大,即显微硬度提高了840%～1 102%,磨损失量是原始AZ31B镁合金的8.57%。     

添加Si粉对AZ91D镁合金激光表面改性

为提高镁合金的表面硬度,对预置Si粉的AZ91D进行高能CO2激光表面改性处理.采用光学显微镜、扫描电镜、电子探针微区分析和X射线衍射仪等方法研究了激光改性层的组织结构.结果表明:AZ91D表面改性层主要由α-Mg,Al12Mg17和Mg2Si组成.Si粉与镁合金完全发生反应形成金属间化合物Mg2Si,Mg2Si以树枝状分布.Al-Mn相由AZ91D基体中的团聚棒状变为激光改性层中的分散球状.激光表面改性后.由于Mg2Si相产生的强化和Mg17Al12产生的细晶强化,显微硬度从80 HV提高到324 HV.     

AZ31镁合金挤出板降温热轧的组织和织构的演变

研究AZ31镁合金挤出板坯在降温热轧过程中的组织和织构的演变规律.结果表明:退火前滑移和孪生是主要的变形机制和取向硬化机制;退火后长条晶的滑移和细小等轴晶晶界扩散迁移的共同作用成为主要的变形机制;随着压下量的增大,析出物开始破碎和分散,压下量在70%～80%之间时,基面织构组分的取向密度存在突变最大值,形成硬取向较强的{0001}基面织构,软化退火能大幅减弱硬取向;通过一道67%大压下量和一次软化退火可顺利地将AZ31镁合金轧制成厚0.5 mm的薄板.     

Comparison of corrosion behaviors of AZ31, AZ91, AM60 and ZK60 magnesium alloys

The corrosion behaviours of four kinds of rolled magnesium alloys of AZ31, AZ91, AM60 and ZK60 were studied in 1 mol/L sodium chloride solution. The results of EIS and potentiodynamic polarization show that the corrosion resistance of the four materials is ranked as ZK60＞AM60＞AZ31＞AZ91. The corrosion processes of the four magnesium alloys were also analyzed by SEM and energy dispersive spectroscopy(EDS). The results show that the corrosion patterns of the four alloys are localized corrosion and the galvanic couples formed by the second phase particles and the matrix are the main source of the localized corrosion of magnesium alloys. The corrosion resistance of the different magnesium alloys has direct relationship with the concentration of alloying elements and microstructure of magnesium alloys. The ratio of the β phase in AZ91 is higher than that in AZ31 and the β phase can form micro-galvanic cell with the alloy matrix, as a result, the corrosion resistance of AZ31 will be higher than AZ91. The manganese element in AM60 magnesium alloy can form the second phase particle of AlMnFe, which can reduce the Fe content in magnesium alloy matrix, purifying the microstructure of alloy, as a result, the corrosion resistance of AM60 is improved. However, due to the more noble galvanic couples of AlMnFe and matrix, the microscopic corrosion morphology of AM60 is more localized. The zirconium element in ZK60 magnesium alloy can refine grain, form stable compounds with Fe and Si, and purify the composition of alloy, which results in the good corrosion resistance of ZK60 magnesium alloy.     

Microstructure refinement of AZ31 alloy solidified with pulsed magnetic field

The effects of a pulsed magnetic field on the solidified microstructure of an AZ31 magnesium alloy were investigated. The experimental results show that the remarkable microstructural refinement is achieved when the pulsed magnetic field is applied to the solidification of the AZ31 alloy. The average grain size of the as-cast microstructure of the AZ31 alloy is refined to 107 μm. By quenching the AZ31 alloy, the different primary α-Mg microstructures are preserved during the course of solidification. The microstructure evolution reveals that the primary α-Mg generates and grows in globular shape with pulsed magnetic field, contrast with the dendritic shape without pulsed magnetic field. The pulsed magnetic field causes melt convection during solidification, which makes the temperature of the whole melt homogenized, and produces an undercooling zone in front of the liquid/solid interface, which makes the nucleation rate increased and big dendrites prohibited. In addition, the Joule heat effect induced in the melt also strengthens the grain refinement effect and spheroidization of dendrite arms.