～2 μm Tm3+/Yb3+-doped tellurite fibre laser

We present, for the first time, laser emission in the range 1.910–1.994 μm in Tm³⁺/Yb³⁺-doped tellurite fibre when pumped using an Yb³⁺-doped double-clad silica fibre laser operating at 1.088 μm. With this pump scheme there was strong pump excited state absorption (ESA) which caused upconversion emission at 800 nm and 480 nm due to the Tm³⁺: ³H₄ → ³H₆ and Tm³⁺: ¹G₄ → ³H₆ transitions, respectively. This strong ESA limited the maximum slope efficiency to 10% with respect to absorbed pump power, and the maximum output power to 67 mW. This is however the highest output power which has been achieved in a tellurite fibre laser so far. The lowest observed threshold was 114 mW for a 22 cm long fibre and a 90% reflective output coupler. Further power scaling was limited due to thermal damage at the pump end of the fibre. The optimum fibre length for this arrangement was around 16 cm but lasing was achieved in lengths ranging from <9 to 30 cm. Tellurite glass offers significant advantages over silicate and fluoride glasses which make it a very promising material for compact, medium power, near and mid-IR fibre lasers for range-finding, medical and atmospheric monitoring and sensing applications.     

Modelling of high-power diode-pumped erbium 3 μm fibre lasers

Abstract

We present theoretical calculations that relate to the cw operation of a high-power Er³⁺, Pr³⁺:ZBLAN double-clad fibre laser. Using the measured energy-transfer, energy-transfer-upconversion and cross-relaxation parameters relevant to Er³⁺-doped and Er³⁺, Pr³⁺-codoped ZBLAN, we compare the theoretical calculations from the model with recent experimental measurements. The model is then used to analyse the important pump and interionic processes occurring in Er³⁺, Pr³⁺:ZBLAN fibre lasers. The theoretical results indicate that energy transfer from Er³⁺ to Pr³⁺ leads to a fast depletion of the lower laser level and, due to the cw threshold condition, to low population densities in both laser levels. Thus, ground-state bleaching, pump excited-state absorption and energy-transfer upconversion amongst the Er³⁺ ions are avoided.     

Theoretical comparison of Er3+-doped crystal lasers

Abstract

The theoretical results are presented from a model that has been developed to simulate the 3 μm laser transition in Er³⁺-doped laser crystals. The rate equations for the seven lowest energy levels of Er:YAG, Er:YSGG, Er:YLF and Er:BAYF have been solved numerically for both continuous wave (cw) and pulsed (Q-switched and gain switched) laser operation with direct optical pumping into the ⁴I11/2 energy level. The dependence of slope efficiency on the Er³⁺ concentration for each laser crystal was investigated for cw operation and the relative performance of Er(15%):YLF, Er(15%):BAYF, Er(50%):YAG and Er(50%):YSGG was compared for each mode of operation. The change in the slope efficiency of Er:YLF at high Er³⁺ concentration, due to additional multi-ion processes, was calculated for a wide range of rate coefficients. It was determined that the slope efficiency could be reduced by as much as 12% by these processes and thus could explain the reduction in the slope efficiency as determined experimentally for lasers using highly doped fluoride crystals as the gain medium.     

Tm3+-doped fiber master oscillator power amplifier with broad tunability in pulse duration using an acousto-optic external modulator

ABSTRACT

We demonstrate a pulse-duration tunable Tm³⁺-doped pulsed all-fiber master oscillator power amplifier (MOPA) operating at a central wavelength of 1908 nm. By using acousto-optic(AO) external modulation, the amplified laser pulse shows a tuning range having pulse durations from 66.5 ns to 8.0 μs and a repetition rate of 100 kHz-2 MHz. The laser achieved a maximum average power of 28.1 W and a corresponding energy of 28.1 μJ at 1MHz with a 3 dB linewidth of 0.63 nm and a beam quality factor of M_x²=1.25 and M_y²=1.32. The ASE suppression ratio is 50 dB and the corresponding total amplifier gain is 27.5 dB. To the best of our knowledge, it is the highest average output power and slope efficiency (～51.0%) achieved using AO external modulation in a Tm³⁺-doped pulsed fiber amplifier.     

Thermal and photoluminescence properties of Er2S3-doped (As2Se3)90(GaSe)5Ge5 glasses

Thermal and photoluminescence characteristics of (As₂Se₃)₉₀(GaSe)₅Ge₅ glasses doped with different amounts of Er₂S₃ (Er amount from 0.1 to 3 at %) have been studied. Temperature-modulated differential scanning calorimetry measurements were used to study the glass transformation and thermal stability of these glasses. A 980-nm laser diode was used to pump the Er³⁺-doped glass samples, inducing a 1550-nm photoluminescence output signal. By appropriately pulsing the excitation, we measured the photoluminescence lifetime of the Er³⁺ state in these chalcogenide glasses.     

Properties of Er3+-doped phosphate glasses and glass fibres and efficient infrared to visible upconversion

Some thermomechanical properties such as expansion, transition temperature and high-temperature viscosity of phosphate glasses with different P₂O₅ and BaO compositions have been measured. Absorption and fluorescence spectra of the phosphate glasses with different Er³⁺ doping have also been measured. The Er³⁺ doping concentration with respect to the maximal fluorescence intensity is 0.75 mol %. The attenuation of the fibre at a wavelength of 1.53 m is 12.8 db m^–1. Upconversion of 1.064 m NdYAG laser pulses into intense green 547 and 667 nm light in the 0.75 mol % Er³⁺-doped phosphate glass fibre has been achieved. The output power of the two fluorescence signals of green 547 nm and red 667 nm are 178 and 42 W, respectively, with an upconversion efficiency of 1.78×10^–2% and 4.2×10^–3% respectively.     

Infrared-to-green up-conversion in Er3+, Yb3+-doped monoclinic KGd(WO4)2 single crystals

Optical spectroscopy of the green emission of erbium in KGd(WO₄)₂ (KGW) single crystals codoped with ytterbium ions is investigated. To do this, we firstly grew good-optical-quality KGW single crystals doped with Er³⁺ and Yb³⁺ at several dopant concentrations by the Top-seeded-solution-growth slow-cooling method (TSSG). Green photoluminescence of Er³⁺ in KGW host was studied at room temperature (RT) and low temperature (10 K) by means of Yb³⁺ sensitization after infrared excitation at 981 nm (10194 cm⁻¹). We calculated the emission and gain cross-sections and compared these with those of other known Er³⁺-doped laser materials like LiYF₄ :Er (YLF:Er) and Y₃Al₅O₁₂:Er (YAG:Er) at RT. Our study also focused on determining the optimal concentration of ions for generating the most intense green emission. We measured the lifetime of the green emission after infrared pump at several Yb³⁺ concentrations. From the low-temperature emission experiments, we determined the energy position of the sublevels of the ground state of erbium.     

Multicolor upconversion of Er3+/Tm3+/Yb3+ doped oxyfluoride glass ceramics

Er³⁺/Tm³⁺/Yb³⁺ tridoped oxyfluoride glass ceramics was synthesized in a general way. Under 980 nm LD pumping, intense red, green and blue upconversion was obtained. And with those primary colors, multicolor luminescence was observed in oxyfluoride glass ceramics with various dopant concentrations. The red and green upconversion is consistent with ⁴F_9/2 → ⁴I_15/2 and ²H_11/2, ⁴S_3/2 → ⁴I_15/2 transition of Er³⁺ respectively. While the blue upconversion originates from ¹G₄ → ³H₆ transition of Tm³⁺. This is similar to that in Er³⁺/Yb³⁺ and/or Tm³⁺/Yb³⁺ codoped glass ceramics. However the upconversion of Tm³⁺ is enhanced by the energy transfer between Er³⁺ and Tm³⁺.     

Phase transition of Er3+-doped Al2O3 powders prepared by the non-aqueous sol–gel method

The Er³⁺-doped Al₂O₃ powders have been prepared by the non-aqueous sol–gel method using the aluminum isopropoxide as precursor, acetylacetone as chelating agent, nitric acid as catalyzer, and hydrated erbium nitrate, as dopant under isopropanol environment. The phase structure and phase transition of the Er³⁺-doped Al₂O₃ powders were investigated by using thermogravimetry/differential thermal analysis (TG/DTA), Fourier transform infrared spectroscopy (FT-IR), and X-ray diffraction (XRD). The phase contents diagram for the Er-doped Al–O system with the doping concentration up to 5 mol% was described at the sintering temperature from 550 to 1250 °C. There were the three crystalline types of Er³⁺-doped Al₂O₃ phases, γ-, θ- and α-(Al, Er)₂O₃, and the two relative stoichiometric compounds composed of Al, Er, and O, ErAlO₃ and Al₁₀Er₆O₂₄ phases in the Er–Al–O phase contents diagram. The Er³⁺ doping suppressed crystallization of the γ and θ phases and delayed phase transition of the γ → θ and θ → α. The increased Er³⁺ doping concentration and the elevated sintering temperature enhanced the precipitation of the ErAlO₃ and Al₁₀Er₆O₂₄ phases. The preparation procedure for the Er³⁺-doped Al₂O₃ powders in the non-aqueous sol–gel process, including chelating, hydrolysis, peptization, doping and gelation, has a significant effect on the phase formation and its transition for the Er³⁺-doped Al₂O₃ powders.     

Luminescence in various classes of Er<Superscript>3+</Superscript>-doped inorganic compounds under IR excitation

We have studied the luminescence of various classes of Er³⁺-doped inorganic phosphors under IR excitation. The highest IR Stokes luminescence efficiency in the range 1.5–1.6 μm is offered by Yb_0.99Er_0.01PO₄ (xenotime structure). This efficient IR phosphor has been commercialized under the name AM-1500M-1. It is of considerable practical interest for security and authentication applications and also as a gain medium for mid-IR lasers operating in the spectral range 1.5–1.6 μm, safe to the human eye.     

Comparative study of Er3+ and Tm3+ co-doped YOF and Y2O3 powders as red spectrally pure upconverters

We prepared Er³⁺ and Tm³⁺ co-doped yttrium oxyfluoride (YOF) powder by combustion synthesis and we observed that under near-infrared (λ = 980 nm) laser excitation the characteristic green (²H_11/2, ⁴S_3/2 → ⁴I_15/2) emission of Er³⁺ was suppressed by energy transfer (ET) mechanisms between Tm³⁺ and Er³⁺. The ET process observed in YOF was much more efficient than that observed in standard Y₂O₃ powder prepared under similar conditions. YOF combines the superior mechanical and thermal properties of oxides with low phonon energy of fluorides. Our results show that this material is a serious candidate for use as a red upconversion phosphor.     

Efficient upconversion-pumped continuous wave Er3+:LiLuF4 lasers

We report on detailed spectroscopic investigations and efficient visible upconversion laser operation of Er³⁺:LiLuF₄. This material allows for efficient resonant excited-state-absorption (ESA) pumping at 974 nm. Under spectroscopic conditions without external feedback, ESA at the laser wavelength of 552 nm prevails stimulated emission. Under lasing conditions in a resonant cavity, the high intracavity photon density bleaches the ESA at 552 nm, allowing for efficient cw laser operation.We obtained the highest output power of any room-temperature crystalline upconversion laser. The laser achieves a cw output power of 774 mW at a slope efficiency of 19% with respect to the incident pump power delivered by an optically-pumped semiconductor laser. The absorption efficiency of the pump radiation is estimated to be below 50%.To exploit the high confinement in waveguides for this laser, we employed femtosecond-laser pulses to inscribe a cladding of parallel tracks of modified material into Er³⁺:LiLuF₄ crystals. The core material allows for low-loss waveguiding at pump and laser wavelengths. Under Ti:sapphire pumping at 974 nm, the first crystalline upconversion waveguide laser has been realized. We obtained waveguide-laser operation with up to 10 mW of output power at 553 nm.     

Diode-cladding-pumped Yb3+, Ho(3+)-doped silica fiber laser operating at 2.1-microm

The characteristics of the performance of a diode-cladding-pumped Yb3+, Ho(3+)-doped silica fiber laser are presented. To our knowledge this in the first demonstration of a Yb3+, Ho(3+)-doped fiber laser, and a maximum output power of 0.85 W was achieved for a launched pump power of 10.9 W. For launched pump powers < 7 W, the slope efficiency was approximately 12.5%. Visible fluorescence emission with peaks at approximately 485, approximately 550, and approximately 660 nm measured at the output from the laser suggests that excited-state absorption and energy-transfer upconversion losses may impair the functioning of the laser. Increasing the Yb3+ and Ho3+ concentrations and the Yb3+:Ho3+ concentration ratio may lead to an improvement in the overall efficiency of the device.     

Hydrothermal trivalent lanthanide doped Lu2O3 nanorods: Evaluation of the influence of the surface in optical emission properties

Tm³⁺-doped and Yb³⁺, Er³⁺/Tm³⁺-codoped Lu₂O₃ rods of ∼90 nm of diameter have been prepared through a soft hydrothermal procedure. A body/surface model has been proposed to describe the dynamics exhibited by fluorescence decays of ³H₄ and ³F₄ Tm³⁺ multiplets in Tm-Lu₂O₃ nanorods as well as the new features of the near infrared to visible upconverted emissions of Er³⁺ and Tm³⁺ in Yb³⁺-codoped Lu₂O₃ nanorods.     

Spectroscopic properties of Yb3+-doped PbWO4 single crystal

Yb³⁺-doped PbWO₄ single crystal was grown using modified vertical Bridgman method. X-ray diffraction (XRD) analysis, optical absorption spectra, X-ray excited luminescence (XEL), fluorescence of ²F_5/2→²F_7/2 and its lifetime at room temperature were investigated. PWO:Yb³⁺ shows the broad absorption of Yb³⁺ (850–1050 nm) and efficient emission (950–1100 nm). Annealing exerts a distinct influence on the PWO:Yb³⁺ crystal, e.g. disappearance of color and annihilation of the absorption in the region around 450–750 nm, meanwhile the absorption of Yb³⁺ ions was enhanced by the annealing treatment. A novel luminescence band on the X-ray excited luminescence spectra of PWO:Yb³⁺ centered at about 500 nm was observed overlapped on that of PWO host.     

Synthesis of Er<Superscript>3+</Superscript> and Er<Superscript>3+</Superscript> : Yb<Subscript>3+</Subscript> doped sol-gel derived silica glass and studies on their optical properties

Er₃₊ and Er₃₊ : Yb₃₊ doped optical quality, crack and bubble free glasses for possible use in making laser material have been prepared successfully through sol-gel route. The thermal and optical, including UV-visible absorption, FTIR etc characterizations were undertaken on the samples. The absorption characteristics of Er₃₊ doped samples clearly revealed the absorption due to Er₃₊ ions. On the other hand Yb₃₊ : Er₃₊ doped samples showed enhanced absorption due to² F _7/2 →² F _5/2 transition. The absorption and emission cross-section for² F _7/2 ↔² F _5/2 of Yb³⁺ were estimated. FTIR absorption spectra have clearly shown the reduction of the absorption peak intensity with heat treatment in the range 3700–2900 cm⁻¹. The 960 cm^-1 band also showed progressive decrease in the absorption band peak intensity with heat treatment. The result of the investigations with essential discussions and conclusions have been reported in this paper.     

Design and achieving mechanism of upconversion white emission based on Yb/Tm/Er tri-doped KY3F10 nanocrystals

KY₃F₁₀:Yb³⁺/Tm³⁺/Er³⁺ upconversion nanocrystals are synthesized via a simple hydrothermal procedure. The nanocrystals emit the near equal energy white light with high brightness and favorable color balance when excited using a 980 nm continuous wave diode laser. The research of upconversion mechanism indicates that in addition to the energy transfer processes from Yb³⁺ to Tm³⁺ and Er³⁺, respectively, there exists a new process ¹G₄ (Tm³⁺) + ⁴I_11/2 (Er³⁺) → ³H₄ (Tm³⁺) + ⁴S_3/2 (Er³⁺).     

Polarized spectral properties and 1.5–1.6 μm laser operation of Er:Sr3Yb2(BO3)4 crystal

Undoped and Er³⁺-doped Sr₃Yb₂(BO₃)₄ crystals were grown by the Czochralski method. Room temperature polarized spectral properties of the Er:Sr₃Yb₂(BO₃)₄ crystal were investigated. The efficiency of the energy transfer from Yb³⁺ to Er³⁺ ions in this crystal was calculated to be about 95%. End-pumped by a diode laser at 970 nm in a hemispherical cavity, a 0.75 W quasi-CW laser at 1.5–1.6 μm with a slope efficiency of 7% and an absorbed pump threshold of 3.8 W was achieved in a 0.5-mm-thick Z-cut crystal glued on a 5-mm-thick pure YAG crystal with UV-curable adhesive.     

Bright white upconversion luminescence from Er-Tm-Yb doped CaSnO3 powders

Bright white upconversion luminescence from Er³⁺-Tm³⁺-Yb³⁺ doped CaSnO₃ powders is obtained under the diode laser excitation of 980 nm. It is composed of three primary colors of red, green and blue emissions, which originate from the transitions of ⁴F_9/2 → ⁴I_15/2, (²H_11/2, ⁴S_3/2) → ⁴I_15/2 of Er³⁺ ions and ¹G₄ → ³H₆ of Tm³⁺ ions, respectively. The efficient upconversion emission is attributed to the energy transfer between Yb³⁺ and Er³⁺ or Tm³⁺ions. Moreover, it is observed that Tm³⁺ acts as the quenching center for the green upconversion luminescence from Er³⁺ ions, and the sensitizer for the red and blue luminescence when the Tm³⁺ doping content is less than 0.3 mol%. This is interpreted in terms of the efficient energy transfer between Tm³⁺ and Er³⁺ ions. The calculated color coordinates fall within the white region in the standard 1931 CIE chromaticity diagram, indicating the potential applications of Er³⁺-Tm³⁺-Yb³⁺ doped CaSnO₃ in the field of displaying and lasers, etc.     

Pulsed pumped Yb3+-doped double-cladding fiber amplifier

A pulsed pumped Yb³⁺-doped double-cladding fiber (DCF) amplifier is reported, Seeded by a passive mode-locked Yb³⁺-doped fiber laser, the fiber amplifier can generate 200 W peak-power and 120 ps duration pulses at 100 Hz repetition rate. Because of the pulsed pump approach, the amplified spontaneous emission (ASE) and the spurious lasing between pulses are well avoided.