Passive‐matrix polymer light‐emitting displays

Abstract— Organic light‐emitting device research focuses on the use of small‐molecule and polymer materials to make organic electroluminescent displays, with both passive‐ and active‐matrix technologies. This paper will focus on the characteristics of red, green, and blue electroluminescent polymers suitable for fabricating monochrome and full‐color passive‐matrix displays. The stability of polymer OLEDs, and the use of ink‐jet printing for direct high‐resolution patterning of the light‐emitting polymers will also be discussed. It will be shown that the performance of light‐emitting polymers is at the brink of being acceptable for practical applications.     

A single‐substrate multicolor cholesteric liquid‐crystal display prepared through ink‐jet printing

Abstract— Ink‐jet printing was used to prepare a single‐substrate multicolor cholesteric liquid‐crystal (Ch‐LC) display incorporating three Ch‐LCs exhibiting different reflective wavelengths. A room‐temperature low‐vacuum chemical‐vapor‐deposition process was developed for coating a thin polymer film onto the Ch‐LC so that the top electrode could be coated onto the Ch‐LC layer. Herein, the successful operation of such a 10.4‐in. QVGA Ch‐LC display at 40 V will be described.     

LED packaging by ink‐jet microdeposition of high‐viscosity resin and phosphor dispersion

Abstract— An ink‐jet‐printing method applied to the microdeposition of high‐viscosity resin, including optimization of phosphor dispersion for light‐emitting‐diode (LED) packaging was examined for the first time. An ultrasonic ink‐jet‐printing method was used, in which ink droplets are ejected by a focused ultrasonic beam from a nozzle‐less printhead. To fabricate white LEDs, high‐viscosity phosphor‐dispersed resin was deposited to form an encapsulant dome. Two types of methods to control phosphor sedimentation for color uniformity were examined; one is heating the lead frame during the resin deposition, and the other is hydrophobic surface treatment of the lead frame base enabling the fabrication of a small encapsulant dome. For light direction control, a silicone micro lens was deposited on an encapsulant dome using the ink‐jet method. The results show that ultrasonic ink‐jet printing is an applicable technique to optimize and modify on‐demand optical characteristics of LED devices.     

Single‐layered multi‐color electrowetting display by using ink‐jet‐printing technology and fluid‐motion prediction with simulation

Abstract— This paper describes a single‐layered multi‐color electrowetting display (EWD) by using ink‐jet‐printing (IJP) technology and comparing different pattern electrodes with the use of the numerical investigations of ANSYS FLUENT®. This work consists of two parts: the first describes the design of implementing a single‐layered multi‐color EWD and the second demonstrates the application of ANSYS FLUENT® simulation in different pattern electrodes settings on the proposed EWD. The single‐layered multi‐color EW device was evaluated by using various colored oils without adopting a color filter. The single‐layered multi‐color EWD at a driving voltage of 25 V can achieve a maximum aperture ratio and reflectivity of 80% and 38.5%, respectively. The colored saturation of R, G, B oils can increase to 50% (NTSC: 13.3–27.8%). In addition, a radiate electrode at the required viewable area condition of 85% and force 5 * F^k, which results in ink stable contraction and a shorter response time of 50% (radiate vs. square), was proposed. The experimental results and simulation demonstrate that ink‐jet‐printing (IJP) technology along with the use of radiate electrodes can result in a single‐layered multi‐color EWD with a shorter response time.     

A scalable manufacturing process for flexible active‐matrix e‐paper displays

Abstract— A scalable manufacturing process for fabricating active‐matrix backplanes on low‐cost flexible substrates, a key enabler for electronic‐paper displays, is presented. This process is based on solution processing, ink‐jet printing, and laser patterning. A multilayer architecture is employed to enable high aperture ratio and array performance. These backplanes were combined with E Ink electrophoretic media to create high‐performance displays that have high contrast, are bistable, and can be flexed repeatedly to a radius of curvature of 5 mm.     

Low‐cost display assembly and interconnect using ink‐jet printing technology

Ink‐jet printing methods may be utilized for efficient micro‐deposition of solder bumps, spacer balls, and adhesive sealant/bond lines, as well as liquid‐crystal and color‐filter droplets, in the manufacture of display panels. Advantages realized by this approach include data‐driven low‐cost high‐speed non‐contact environmentally friendly processing.     

Towards large‐area full‐color active‐matrix printed polymer OLED television

Abstract— We have developed a new multi‐head polymer OLED ink‐jet‐printing technology to make large‐screen OLED television displays. This printer is used to make a 13‐in.‐diagonal 16:9‐format polymer‐OLED prototype driven by an LTPS active matrix with a pixel circuit which compensates for TFT threshold‐voltage variations. A novel scrolling‐bar addressing scheme is used to reduce motion artifacts and to make sparkling images with a high local peak brightness. The scalability of the polymer‐OLED technology to larger sizes for television applications is discussed.     

Printing of polymer thin‐film transistors for active‐matrix‐display applications

Abstract— We present a process for active‐matrix flat‐panel‐display manufacture based on solution processing and printing of polymer thin‐film transistors. In this process, transistors are fabricated using soluble semiconducting, conducting, and dielectric polymer materials. Accurate definition of the transistor channel and other circuit components are achieved by direct ink‐jet printing combined with surface‐energy patterning. We have used this process to create 4800‐pixel 50‐dpi active‐matrix backplanes. These backplanes were combined with polymer‐dispersed liquid crystal to create the first ink‐jet‐printed active‐matrix displays. Our process is, in principle, environmentally friendly, low temperature, compatible with flexible substrates, cost effective, and advantageous for short‐run length and large display sizes. As well as polymer‐dispersed liquid crystal, this technology is applicable to conventional liquid‐crystal and electrophoretic display effects.     

Super‐high‐resolution transfer printing for full‐color OLED display patterning

Abstract— A transfer‐printing method for the patterning of thin polymer layers is described. A hard stamp with a raised feature is brought into contact with a spin‐coated organic film under elevated pressure and temperature to break the films. The patterned film is then transfer printed onto the devices. This method is used to print red/green/blue subpixel arrays with a pattern size as small as 12 μm at a resolution of 530 ppi to demonstrate its ability for full‐color organic light‐emitting‐display fabrication. Devices with printed organic layers have similar performance to spin‐coated controls under optimized printing temperature and pressure settings. The critical physical parameters include a soft intermediate plate for the sharp breaking of edge patterns, control of surface energies, and printing at moderate temperature and pressure to achieve intimate contact between the printed layer and the underlying substrate.     

Digital lithographic processing for large‐area electronics

Abstract— A non‐contact jet‐printed mask‐patterning process is described. By combining digital imaging with jet printing, digital lithography was used to pattern a‐Si:H‐based electronics on glass and plastic substrates in place of conventional photolithography. This digital lithographic process is capable of layer‐to‐layer registration of ±5 μm using electronic mask files that are directly jet printed onto a surface. Aminimum feature size of 50 μm was used to create 180 × 180 element backplanes having 75‐dpi resolution for display and image‐sensor applications. By using a secondary mask process, the minimum feature size can be reduced down to ～15 μm for fabrication of short‐channel thin‐film transistors. The same process was also used to pattern black‐matrix wells in fabricating color‐filter top plates in LCD panels.     

Fabrication of pinhole/micro‐lens array for improving resolution of integral imaging 3‐D display

In this paper, we present a new fabrication of micro‐lens array (MLA) with pinhole array—pinhole/micro‐lens array (P/MLA) for integral imaging 3‐D display (II), which combine lithography and ink‐jet printing. A black circular groove array (BCGA) is used as pinhole array, and laser 3‐D microscope and a homemade setup have been used for the characterization of P/MLA. The results show that high‐precision P/MLA can be obtained using BCGA as templates. By controlling the driving voltage at different steps, the distance between nozzle and substrate, as well as the number of liquid droplets, P/MLA with smooth morphology, different sizes, good repeatability of geometry parameters, great uniformity of focusing, and good converging performance can be achieved. For demonstration, P/MLA with curvature, focal length, numerical aperture, and F‐number of 815.8 μm, 1.60 mm, 0.1311, and 3.8 are applied for the reconstruction in II, exhibiting good reconstruction performance with high resolution, and BCGA reduces the influence of stray light on II and improves the quality of the reconstructed image.     

A 5.8‐in. phosphorescent color AMOLED display fabricated by ink‐jet printing on plastic substrate

Abstract— A flexible phosphorescent color active‐matrix organic light‐emitting‐diode (AMOLED) display on a plastic substrate has been fabricated. Phosphorescent polymer materials are used for the emitting layer, which is patterned using ink‐jet printing. A mixed solvent system with a high‐viscosity solvent is used for ink formulation to obtain jetting reliability. The effects of evaporation and the baking condition on the film profile and OLED performances were investigated. An organic thin‐film‐transistor (OTFT) backplane, fabricated using pentacene, is used to drive the OLEDs. The OTFT exhibited a current on/off ratio of 10⁶ and a mobility of 0.1 cm²/V‐sec. Color moving images were successfully shown on the fabricated display.     

Novel application of ink‐jet‐printing technology in multi‐domain alignment liquid‐crystal displays

Abstract— Based on the drop‐on‐demand characteristics of ink‐jet printing, the multi‐domain alignment liquid‐crystal display (LCD) could be achieved by using patterned polyimide materials. These polyimide ink locations with different alignment procedures could be defined in a single pixel, depending on the designer 's setting. In this paper, we combined the electro‐optical design, polyimide ink formulation, and ink‐jetting technology to demonstrate the application of multi‐domain alignment liquid‐crystal display manufactory. The first one was a multi‐domain vertical‐alignment LCD. After the horizontal alignment material pattern on the vertical alignment film, the viewing angle would reach 150° without compensation film. The second one was a single‐cell‐gap transflective LCD within integrating the horizontal alignment in the transmissive region and hybrid alignment in the reflective one in the same pixel. In addition, this transflective LCD was also demonstrated in the form of a 2.4‐in. 170‐ppi prototype.     

Requirements for large‐sized high‐resolution TFT‐LCDs

Abstract— A 22‐in. prototype TFT‐LCD with a resolution of 200 pixels per inch and wide‐viewing‐angle capability has been developed and its requirements in terms of screen quality and technology will be discussed. An in‐plane‐switching mode with dual‐domain structure, post‐spacers, and high‐resolution process were implemented to achieve superior front‐of‐screen quality. And, also, in order to improve reliability and productivity, we developed a new injection method for liquid crystals which enabled us to eliminate injection holes.     

A new wettability‐control technique for fabricating color OLED panels by an ink‐jet‐printing method

Abstract— The fabrication technique for color OLED panels by means of wettability‐controllable hole‐injection material (HIM) and a photocatalytic lithography method achieves both precise ink‐jet printing and long‐lifetime devices. The technique enables us to selectively change the non‐wetting surface of a hole‐injection layer (HIL) of metal‐oxide nanoparticles (MONPs) into a wetting surface without damage to the device performance. Wetting patterns formed by this method with photocatalyst‐coated photomasks made it possible to print emission material with patterns of precisely 98‐μm widths on the hole‐injection layer. A fluorescent green‐emitting device fabricated with an HIM of MONPs by the photocatalytic treatment exhibited a long lifetime of 365 hours at30,000 cd/m², which can be extrapolated to a lifetime of more than 110,000 hours at 1000 cd/m², assuming an acceleration coefficient of 1.7. A two‐color device and a monochrome passive‐matrix panel were also successfully fabricated. The two‐color device emitted light without the mixing of colors. The monochrome panel displayed alphabetical characters with good uniformity and no flaws.     

Three‐dimensional printing technologies for terahertz applications: A review

Three‐dimensional (3D) printing technologies enables fast prototyping of complex 3D objects with ever improving printing qualities. To date, 3D printing has been found useful in areas such as manufacturing, industrial design, aerospace, dental and medical industries, and many others. In this article, we review recent advances of 3D printing technologies for terahertz (THz) applications. Different 3D printing technologies and printable materials are first discussed and compared. 3D‐printed THz components and devices, which are categorized as waveguides/fibers, antennas, and quasi‐optical components, are further demonstrated. It is found that the performances and functionalities of 3D‐printed THz devices have been greatly enhanced, while the operating frequencies have been increased from the lower end of THz range to over 1 THz region. With further development of novel materials and printing techniques, it is believed that 3D printing technologies will play an important role in the realization of THz components for efficient control and manipulation of THz waves.     

All‐additive ink‐jet‐printed display backplanes: Materials development and integration

Abstract— Methods used to deposit and integrate solution‐processed materials to fabricate TFT backplanes by ink‐jet printing are discussed. Thematerials studied allow the development of an all‐additive process in which materials are deposited only where their functionality is required. The metal layer and semiconductor are printed, and the solution‐processed dielectric is spin‐coated. Silver nanoparticles are used as gate and datametals, the semiconductor used is a polythiophene derivative (PQT‐12), and the gate dielectric is an epoxy‐based photopolymer. The maximum processing temperature used is 150°C, making the process compatible with flexible substrates. The I_ON/I_OFF ratio was found to be about 10⁵?10⁶, and TFT mobilities of 0.04 cm²/V‐sec were obtained. The influence of surface treatments on the size and shape of printed features is presented. It is shown that coffee‐stain effects can be controlled with ink formulation and that devices show the expected pixel response.     

Video processing for active‐matrix polymer OLED TV

Abstract— Active‐matrix OLED panels have inherent features that allow a higher‐quality image reproduction than LCD panels, i.e., high‐contrast, fast response time, and the capability to produce locally high peak luminance levels. We demonstrated a 13‐in.‐ink‐jet‐printed active‐matrix polymer‐OLED prototype for TV applications at SID 2004. This prototype is used as a carrier for studying video‐processing algorithms that take full advantage of the specific characteristics of OLEDs. Addressing schemes, gamut conversion, histogram‐based brightness control, and sparkle processing will be discussed.     

A study of roll‐printing technology for TFT‐LCD fabrication

Abstract— Recently, potential breakthrough technologies for low‐cost processing of TFT‐LCDs and new process developments for flexible‐display fabrication have been widely studied. A roll‐printing process using etch‐resist material as a replacement for photolithographic patterning was investigated. The characterization of the properties of patterns formed in roll printing, a method to fabricate cliché plates for fine patterns, and the design of a new formulation for resist printing ink is reported. The pattern position accuracy, which is one of the most important issues for the successful application of printing processes in display manufacturing was studied and how it can be improved by optimizing the blanket roll structure is explained. New design rules for the layout of the thin‐film‐transistor array was derived to improve the compatibility of roll printing. As a result, a prototype 15‐in.‐XGA TFT‐LCD panel was fabricated by using printing processes to replace all the photolithographic patterning steps conventionally used.     

Spatial gamut mapping algorithms for cross‐display color reproduction

Abstract— Owing to the fast developments of computer networks and color imaging technologies, there is a tendency towards remote proofing in the printing or textile industries. More cases such as cross‐display color matching will occur in the future information society. The problems of color mismatching we usually find in cross‐display devices have been widely discussed today. In this paper, to achieve equivalent color matching between a sRGB monitor and an Adobe RGB monitor, the spatial gamut mapping algorithm (SGMA), which introduces sigmoidal tone mapping, multi‐mapping paths, and unsharp mask (USM) operation into a sRGB color‐management system, is proposed. According to the designs of USM locations, this proposed SGMA can be further developed into pre‐USM, post‐USM, and double‐USM types. Besides, two critical image characteristics, edge map and color histogram, are investigated to establish the relationship between image content and SGMA. The psychophysical experimental results show that double‐USM SGMA obtains better color matching than the other spatial types.