A study on the performance of multi-stage condensation heat pumpsEtude sur la performance des pompes à chaleur à condensation en plusieurs étages

In this study, computer simulation programs were developed for multi-stage condensation heat pumps and their performance was examined for CFC11, HCFC123, HCFC141b under the same condition. The results showed that the coefficient of performance (COP) of an optimized ‘non-split type’ three-stage condensation heat pump was 25–42% higher than that of a conventional single-stage heat pump. The increase in COP differed among the fluids examined. The improvement in COP was due largely to the decrease in average temperature difference between the refrigerant and water in the condensers, which resulted in a decrease in thermodynamic irreversibility. For the three-stage heat pump, the highest COP was achieved when the total condenser area was evenly distributed to the three condensers. For the two-stage heat pump, however, the optimum distribution of total condenser area varied with working fluids. For the three-stage system, splitting the condenser cooling water for the use of intermediate and high pressure subcoolers helped increase the COP further. When the individual cooling water for the intermediate and high pressure subcoolers was roughly 10% of the total condenser cooling water, the optimum COP was achieved showing an additional 11% increase in COP as compared to that of the ‘non-split type’ for the three-stage heat pump system.     

A study on the performance of multi-stage heat pumps using mixturesEtude sur la performance de pompes à chaleur multi-étagées utilisant des mélanges

Multi-stage heat pumps composed of a condenser, evaporator, compressor, suction line heat exchanger, and low and/or high stage economizers are studied by computer simulation. Their thermodynamic performance and design options are examined for various working fluids. In the simulation, HCFC22/HCFC142b and HFC134a are studied as an interim and long term alternatives for CFC12 while HFC32/HFC134a and HFC125/HFC134a are studied as long term alternatives for HCFC22. The results indicate that the three-stage super heat pump with appropriate mixtures is up to 27.3% more energy efficient than the conventional single-stage system with pure fluids. While many factors contribute to the performance increase of a super heat pump, the most important factor is found to be the temperature matching between the secondary heat transfer fluid and refrigerant mixture, which is followed by the use of a low stage economizer and suction line heat exchanger. The contribution resulting from the use of a high stage economizer, however, is not significant. With the suction line heat exchanger, the system efficiency increases more with the fluids of larger molar liquid specific heats. From the view point of volumetric capacity and energy efficiency, a 40%HCFC22/60%HCFC142b mixture is proposed as an interim alternative for CFC12 while a 25%HFC32/75%HFC134a mixture is proposed as a long term alternative for HCFC22.     

The impact of work input to sorption cyclesImpact de l'apport en énergie sur les cycles à sorption

In recent years the interest in cooling machines or heat pumps combining the principles of compression and sorption technology is increasing. The reason is that both technologies have specific drawbacks which can be overcome by the combination. Our discussion is centred around absorption cycles which use a compressor, and, consequently, an input of a significant amount of mechanical work in addition to heat. In most publications cycles of this kind are discussed in terms of one single COP as usual in the refrigeration industry. This, however, is wrong from a thermodynamic, and misleading from a technical and economical point of view. In order to highlight the need for a strict thermodynamic approach, a fundamental difference between distinct kinds of work input, namely “recoverable work”, “dissipative work” and “heat transformation work” is discussed in the first part of the paper. In the second part it is shown how the input of both work and heat into a energy conversion system has to be handled with both mechanical and thermal COP. The method is thermodynamically sound and straightforward, technically feasible and easy to apply, and most quickly transferred into economical terms. In the third part, a practical example of a compression–absorption hybrid is investigated.     

A 1-D analysis of ejector performanceAnalyse unidimensionnelle de la performance d'un éjecteur

A 1-D analysis for the prediction of ejector performance at critical-mode operation is carried out in the present study. Constant-pressure mixing is assumed to occur inside the constant-area section of the ejector and the entrained flow at choking condition is analyzed. We also carried out an experiment using 11 ejectors and R141b as the working fluid to verify the analytical results. The test results are used to determine the coefficients, η_p, η_s, φ_p and φ_m defined in the 1-D model by matching the test data with the analytical results. It is shown that the1-D analysis using the empirical coefficients can accurately predict the performance of the ejectors.     

Empirical correlation for ejector designCorrélation empirique pour la conception des éjecteurs

In the present study, two empirical correlations from the test results of 15 ejectors are derived for the performance prediction of ejectors using R141b as the working fluid. The ratio of the hypothetical throat area of the entrained flow to the nozzle throat area A_e/A_t, the geometric design parameter of the ejector A₃/A_t, and the pressure ratios P_g/P_e and P_c*/P_e are used to correlate the performance of the ejector. The prediction of the entrainment ratio ω using the correlations is within ±10% error. A method of calculation for the ejector design using the correlations is also developed. R141b is shown in the present study to be a good working fluid for an ejector. The measured ω for the ejectors used in the present study can reach as high as 0.54 at P_g=0.465 MPa (84°C), P_c^*=0.087 MPa (28°C) and P_e=0.040 MPa (8°C). For P_g=0.538 MPa (90°C), P_c^*=0.101 MPa (32°C) and P_e=0.040 MPa (8°C), ω reaches 0.45.

Résumé

Dans cette étude, on a établi deux corrélations empiriques à partir des résultats expérimentaux obtenus utilisant 15 éjecteurs; ces corrélations ont été utilisées ensuite pour prédire la performance d'éjecteurs utilisant le R141b comme fluide frigorigène. Les rapports A_e/A_t (section de passage du fluide entraîné rapporté à la section théorique du col de l'éjecteur), et A₃/A_t (section de sortie de l'éjecteur rapporté à la section théorique du col de l'éjecteur) et les relations entre pressions P_g/P_e et P_c*/P_e sont utilisés pour trouver la corrélation de la performance de l'éjecteur. La prévision du taux d'entraînement à partir des corrélations est précise à la hauteur de ±10%. Les auteurs ont également développé une méthode de calcul permettant de concevoir des éjecteurs à partir des corrélations. On a montré dans cette étude que le R141b s'avère être un fluide actif efficace pour cette utilisation. Le ω mesuré des éjecteurs utilisés dans cette étude peuvent atteindre 0.54 à P_g=0.465 MPa (84°C), P_c^*=0.087 MPa (28°C) et P_e=0.040 MPa (8°C). Pour P_g=0.538 MPa (90°C), P_c^*=0.101 MPa (32°C) et P_e=0.040 MPa (8°C), ω atteint 0.45.     

Energetic efficiency of cogeneration systems for combined heat, cold and power productionEfficacité énergétique des systèmes de cogénération utilisés pour produire simultanément de la chaleur, du froid et de la puissance électrique

This paper deals with the problem of energetic efficiency evaluation of cogeneration systems for combined heat, cold and power production. Cogeneration systems have a large potential for energy saving, especially when they simultaneously produce heat, cold and power as useful energy flows. Various cogeneration systems for combined heat, cold and power production are designed by means of computer simulation to minimize consumption of the primary energy. Equations of energetic efficiency of this combined cogeneration systems are presented, that relate the primary energy rate (PER) and comparative primary energy saving (Δq_p) to energy parameters of designed systems. Comparison of energetic efficiency of combined cogeneration systems with contemporary conventional separate production of heat, cold and power shows a large potential for energy saving by designed combined cogeneration systems.     

Effect of strip location on the air-side pressure drop and heat transfer in strip fin-and-tube heat exchangerEffet de la localisation des gaufrures d’ailettes sur la chute de pression de l''air et sur le transfert de chaleur dans un échangeur à tubes à ailettes

This work discusses about the pressure drop and heat transfer characteristics of a plain fin, a strip fin and combinations thereof in the fin-and-tube heat exchanger. Experimental apparatus and test algorithm using scale-up model fin geometry are discussed. The present work uses the electric heaters inside of the tube as the heating source to simulate the hot water loop in the wind tunnel test. The test results of the plain and strip fins are compared with the existing correlation and experimental data. It was found that a hybrid fin, plain fin at front row and strip fin at rear row, was more effective to enhance the heat transfer than that of the whole strip fin at the same fan power.

Résumé

Dans l’article, on traite des caractéristiques de la chute de pression et du transfert de chaleur d’une ailette lisse, d’une ailette gaufrée et de combinaisons de ces deux types d’ailettes dans un échangeur de chaleur à tubes ailetés. Le dispositif expérimental et l’algorithme utilisant une géométrie des ailettes échelonnées sont présentés. On utilise des équipements de chauffage électriques à l’intérieur du tube, comme source de chaleur, pour simuler la boucle d’eau chaude dans le tunnel expérimental. Les résultats expérimentaux concernant les ailettes lisses et les ailettes gaufrées sont comparés avec la corrélation existante et les données expérimentales. On a observé que des ailettes hybrides, c’est-à-dire lisses à la rangée frontale et gaufrées à la rangée arrière, étaient plus efficaces pour intensifier le transfert de chaleur que des ailettes entièrement gaufrées, à la même puissance du ventilateur.     

Evaluation of metal hydride machines for heat pumping and cooling applications: Evaluation des machines à hydrure métallique dans les applications de pompes à chaleur et de refroidissement

Three different schemes of metal hydride solid sorption devices for heat pumping and cooling applications are presented and compared based on theoretical evaluations. Key parameters obtained from experimental and simulation results from coupled metal hydride reaction beds have been used for the theoretical evaluation. The single (HS) and double stage (HD) devices show reasonable performances, but they require many moving parts. Using high performance reaction beds, e.g. a capillary tube bundle reaction bed, cycle times of about 5–10 min can be obtained with these devices. This corresponds to a specific power output of 100–200 W kg⁻¹ (HS) or 150–300 W kg⁻¹ (HD), referred to the total hydride inventory of the machine. The multi-hydride-thermal-wave (HW) system has a lower specific power output, but it offers significant advantages like modest hardware effort, low pumping power and a very wide operating temperature range.     

Carbon dioxide as a working fluid in drying heat pumpsLe dioxyde de carbone comme fluide actif dans des séchoirs à pompe à chaleur

Carbon dioxide as a working fluid in refrigeration and heat pump systems is increasingly important in view of the CFC substitution problem. It is both under ecological and economical aspects an attractive alternative to the HFC working fluids at present in practical use. The thermophysical properties and characteristics of carbon dioxide are quite different from those of refrigerants used in conventional vapour compression cycles. Its application in conventional vapour compression refrigerating systems is limited by its critical parameters (t_c=31.1°C and p_c=73.8 bar). The possibility to use carbon dioxide also beyond these limits in high temperature processes, e.g. heat pumps, is given by the application of a trans-critical process. The design and construction of a commercial drying heat pump system (batch type cabinet dryer with 12 kW heating capacity and closed air circuit) using the natural working fluid carbon dioxide is shown and experimental results of investigations carried out are presented. Energy savings are given compared to manufacturer's data of energy consumption.     

Zeolite heat pump — adsorption of methanol in synthetic zeolites 13X, 4A and 5A

The adsorption isotherms for methanol adsorption in synthetic zeolites 13X, 4A and 5A were measured gravimetrically at various temperatures. The model of Langmuir and the potential theory were used for correlating the equilibrium data. The monolayer capacity was calculated using these two models. A small deviation at elevated temperatures was observed. The differential heat of adsorption was measured calorimetrically for all three zeolites. The isosteric heat of adsorption was calculated for zeolite 13X using measured equilibrium data. The log p, 1/T equilibrium diagram for zeolite 13X was computed using the Langmuir equation.     

Performance characteristics correlation for round tube and plate finned heat exchangers: Equations relatives aux performances d'échangeurs de chaleur constitués de tubes ronds et de plaques à ailettes

A number of correlation equations describing the performance characteristics of round tube and plate fin have been published in the open literature. However, many of these correlations are restricted to flat finned heat exchangers and a limited number of geometrical configurations. In this study, 28 heat exchanger samples were tested in an open circuit thermal wind tunnel over a velocity range of 1 to 20 m/s for a number of geometries. The geometrical variations include the number of tube rows, fin thickness and the spacing between fins, rows and tubes. Both flat and corrugated fins were tested and the results were correlated in terms of j and f factors as a function of Reynolds number and the geometrical parameters of the heat exchangers. An important feature of this correlation is the novel way in which the geometric parameters are expressed in the correlation. Ratios of these parameters are derived from consideration of the physics of the flow and heat transfer in the heat exchangers. This results in a more accurate and physically meaningful correlation which can be applied to a broader range of geometries. The correlation was validated against test data in the literature for round tube and plate fin with good agreement. It was found that the fin type affects the heat transfer and friction factor, and that the number of tube rows has a negligible effect on the friction factor. The number of tube rows effect was found to be influenced by the fin and tube geometries as well as the Reynolds number.Un certain nombre d'équations pour des caractéristiques du rendement des échangeurs de chaleur à tubes ronds plaques à ailettes ont été publiés dans le littérature. Cependant, dans bien des cas, ces corrélations se limitent aux échangeurs à ailette plate dans un nombre limité de configurations géométriques. Dans cette étude, 28 échangeurs de chaleur ont été testés utilisant une soufflerie à circuit ouvert avec une vitesse d'air de 1 à 20 m/s pour plusieurs formes géométriques. Les variations géométriques portaient sur le nombre de rangées de tubes, l'épaisseur des ailettes et la distance séparant des ailettes, des rangées et des tubes. Les ailettes plates et ondulées ont été testées et les corrélations en termes de facteurs j et f en fonction du nombre de Reynolds et les paramètres géométriques des échangeurs de chaleur. Un aspect important de cette corrélation est le façon originale d'exprimer des paramètres géométriques. Les rapports de ces paramètres sont obtenus à partir des flux et transferts de chaleur dans des échangeurs de chaleur. Ce procedé permet d'obtenir une corrélation plus précise et utilé qui s'applique à une gamme de formes géomátriques plus large. La corrélation a été validée en fonction des données concernant des échangeurs à tube et à plaque à ailettes dans la littérature: les données expérimentales et théoriques concordent bien. On a montré que le type d'ailette exerce une influence sur le transfert de chaleur et le facteur de frottement. Cependant, le nombre de rangées de tubes a un effet negligeable sur le coéfficient de frottement. On a démontré que l'effet nombre de rangées de tube est influencé par les géométries des ailettes et des tubes ainsi que par le nombre de Reynolds.     

Experimental correlation of combined heat and mass transfer for NH3–H2O falling film absorptionCorrélation expérimentale entre le transfert de chaleur et de masse pour de l'absorption au NH3–H2O à film tombant

In this article, experimental analysis was performed for ammonia–water falling film absorption process in a plate heat exchanger with enhanced surfaces such as offset strip fin. This article examined the effects of liquid and vapor flow characteristics, inlet subcooling of the liquid flow and inlet concentration difference on heat and mass transfer performance. The inlet liquid concentration was selected as 5%, 10% and 15% of ammonia by mass while the inlet vapor concentration was varied from 64.7% to 79.7%. It was found that before absorption started, there was a rectification process at the top of the test section by the inlet subcooling effect. Water desorption phenomenon was found near the bottom of the test section. It was found that the lower inlet liquid temperature and the higher inlet vapor temperature, the higher Nusselt and Sherwood numbers are obtained. Nusselt and Sherwood number correlations were developed as functions of falling film Reynolds Re₁, vapor Reynolds number Re_v, inlet subcooling and inlet concentration difference with ±15% and ±20% error bands, respectively.     

A contribution to the evaluation of the economic perspectives of absorption chillers: Contribution à l'évaluation des perspectives économiques des refroidisseurs à adsorption

The development of new working pairs and cycles extends the field of application of absorption systems with corresponding environmental benefits. The performance of standard cycles can be enhanced, e.g. by multi-staging. For each application the suitable working pair and cycle can be chosen regarding thermodynamical and economical aspects. Still, the performance strongly depends on the given external conditions. In this paper, basic thermodynamic constraints stemming from those conditions and valid for all sorption cycles are derived using the concept of endo-reversibility. Fundamental economic conclusions can be drawn. Subsequently, real machines are analysed. A comparison with manufacturers data and experimental data is made. The working pairs lithium bromide/water and binary hydroxide solution/water are discussed.     

Study on adsorption refrigeration cycle utilizing activated carbon fibers. Part 1. Adsorption characteristics

Thermal heat driven adsorption systems using natural refrigerants have been focused on the recent energy utilization trend. However, the drawbacks of these adsorption systems are their poor performance in terms of system cooling capacity and coefficient of performance (COP). The objective of this paper is to improve the performance of thermally powered adsorption cooling system by selecting new adsorbent–refrigerant pair. Adsorption capacity of adsorbent–refrigerant pair depends on the thermophysical properties (pore size, pore volume and pore diameter) of adsorbent and isothermal characteristics of the pair. In this paper, the thermophysical properties of two PAN types of activated carbon fibers (FX-400 and KF-1000) are determined from the nitrogen adsorption isotherms. The standard nitrogen gas adsorption/desorption measurements on various adsorbents at liquid nitrogen of temperature 77.3 K were performed. Surface area of each adsorbent was determined by the Brunauer, Emmett and Teller (BET) plot of nitrogen adsorption data. Pore size distribution was measured by the Horvath and Kawazoe (HK) method. As of the adsorption/desorption isotherms, FX-400 shows very small hysteresis when the value of P/P_o exceeds 0.4, while KF-1000 has no hysteresis in the whole range of P/P_o. The adsorption capacity of FX-400 is about 30% higher than that of KF-1000. The adsorption equilibrium data of activated carbon fiber (ACF)-methanol are presented and correlated with simple equations. The adsorption equilibrium data of ACF (KF-1000)-water also presented in order to facilitate comparison with those of ACFs-methanol pair. The results will contribute significantly in designing the adsorber/desorber heat exchanger for thermally driven adsorption cooling system.     

Selective water sorbent for solid sorption chiller: experimental results and modelling

In this paper the experimental results of a lab-scale chilling module working with the composite sorbent SWS-1L (mesoporous silica gel impregnated with CaCl₂) are presented. The interesting sorption properties of this material yield a high COP=0.6 that gives a promising alternative to the common zeolite or silica gel for application in solid sorption units driven by low temperature heat (T 100 °C). The measured low specific power of the device is a result of not optimised geometry of the adsorber and of the pelletised shape of the adsorbent. Heat transfer optimisation is currently under progress to increase the specific power. The experimental results are compared with those of a mathematic model able to describe the dynamic behaviour of the system. The model is used to study the influence of the main operating parameters on the system performance.     

Performances of adsorption systems for ambient heating and air conditioning: Performances de systèmes à adsorption pour le chauffage et le conditionnement d'air d'ambiance

Two adsorption systems are considered: zeolite–water and activated carbon–methanol, both consisting of two ‘uniform temperature' adsorbent beds operating with internal heat recovery by a heat carrier circuit. Regarding the zeolite–water system, the performance obtained with a new adsorbent bed, with good heat transfer properties, is compared with a traditional tube and fin exchanger embedded with zeolite pellets. The performances were calculated by using a dynamic model developed and validated previously. Results show that the system based on the new adsorber has a higher specific power and the same Coefficient of Performance. Results of simulation for adsorbers consisting of finned tube heat exchangers and utilising the activated carbon–methanol pair are also presented.     

Thermodynamic based comparison of sorption systems for cooling and heat pumping: Comparaison des performances thermodynamique des systèmes de pompes à chaleur à sorption dans des applications de refroidissement et de chauffage

A comparison of thermodynamic performances of sorption systems (liquid absorption, adsorption, ammonia salts and metal hydrides) is carried out for typical applications (deep-freezing, ice making, air-conditioning and heat pumping) with either air-cooled or water-cooled heat sink. The results are given in terms of cooling coefficient of performance (COP) (heating COP or coefficient of amplification (COA) for the heat pump), cooling (heating) power versus reactor volume or weight and thermodynamic efficiency. LiBr–water systems show the best results for air-conditioning except when small units are required (metal hydride systems lead to more compact units). Other systems, however, show better results for other applications (chemical reaction with ammonia salts for deep-freezing, adsorption for heat pumping).     

A phenomenological theory of polycomponent interactions in non-ideal mixtures. Application to NH3/H2O and other working pairsInteractions entre les composants de mélanges non-idéaux : théorie et application au fluide actif NH3 / H2O et à d'autres fluides actifs

The paper proposes an original linear phenomenological theory (Ph T) of evolution physical mono-, bi- and particular polycomponent gas–liquid interactions with non-ideal mixture. The expressions of the phenomenological factors (entropy source, force, coefficient and coupled heat and mass transfer currents) are deduced. The theory is particularized to the NH₃/H₂O and other gas–liquid systems used in the thermal absorption technology. The work's conclusions are listed next. The paper raises the problem of ammonia bubble absorption which is difficult to answer with current theory of interface mass transfer and absorption as a surface phenomenon. The heat and mass transfer at the gas–liquid interface is governed by the thermodynamic force, which applies also to solid–liquid, solid–gas, or liquid–liquid, gas–gas type interactions and continuous or discontinuous media. The paper mentions a postulate referring to the force behavior approaching an ideal point, previously formulated by the author. According to its consequence, the mass and heat currents suffer an ideal point approaching (i.p.a.) effect, not mentioned so far in the specialized literature, consisting in a continuous increase of their absolute value by several percent (for a pure component), to several hundred times (for a binary system) when the interacting system approaches an ideal state, as compared to the values of states which are far from the same ideal point. In this way, “far from equilibrium” becomes synonymous to “low interaction”. The classic assessment of the interface mass transfer by analogy with heat transfer lacks basic physics. The (Ph T) satisfactorily explains the problem of ammonia bubble absorption. Absorption is a mass phenomenon, not a surface one. An intensive way of improving absorption is emphasized, which seeks to promote the i.p.a. effect appearance rather than the extensive way currently used, based on increasing gas–liquid interaction area. To this extent, the bubble absorber is hereby proposed for efficient absorption. The i.p.a. effect existence offers an additional chance for a satisfactory explanation of the Marangoni effect.     

Simulation d'une machine frigorifique à absorption fonctionnant avec des mélanges d'alcanes

We propose in this article an absorption chiller operating with binary alkane mixtures as an alternative to compression machines. It is an installation using low-level energy at a temperature below 150 °C (waste heat or solar energy) and operating with environmentally friendly fluids. Ten mixtures are considered and compared with two cooling mediums of the condenser and the absorber: the ambient air at 35 °C and the water at 25 °C. For an air-cooled chiller, the COP reaches 0.37 for the n-butane/octane system. This value remains 27% lower than that of an ammonia/water installation operating under the same conditions. For a water-cooling chiller, the n-butane/octane and propane/octane systems give a COP of about 0.63, which is comparable to that of the ammonia/water system. When n-butane is used as refrigerant, the machine works at a pressure under 5 bars, which is an advantage compared with machines working with ammonia/water mixtures.     

Irreversible refrigerators with isothermal heat exchanges: Réfrigérateurs irréversibles avecéchanges thermiques isotherms

A maximum for the coefficient of performance (COP_f) is verified for a temperature difference between reservoirs and the hot isotherm of a closed irreversible cyclical refrigerator working at steady-state conditions. A maximum also exists when the COP_f is considered as a function only of a parameter depending on the thermal characteristics of the heat exchangers. The influence of the parameter and entropy generation on the COP_f maxima is described.