PⅢ方法制备的TiN膜的性能

用一种新型的等离子体浸没式离子注入技术(PⅢ)，在Cr12MoV钢基体上制备了TiN膜，经XPS分析发现，膜中的组织为TiN、TiO2和Ti2O3。对有与无TiN膜的Cr12MoV钢试样进行对比，测定了维氏硬度，耐磨性以及磨痕。结果表明：TiN膜具有高的硬度和优良的抗摩擦性能。     

热处理工艺对SDC90新型冷作模具钢组织与性能的影响

为了确定SDC90新型高强韧冷作模具钢的热处理工艺,采用光学显微镜、洛氏硬度计和冲击试验机等对其显微组织、硬度和冲击性能进行了研究,并与Cr12MoV钢进行了对比。结果表明:SDC90钢中的莱氏体、碳化物比Cr12MoV钢的更细小、分布更均匀;经1 040℃淬火和210℃回火后,其硬度与Cr12MoV钢的相当,而冲击功却是它的2倍;该钢经1 080℃淬火和540℃回火后,其硬度和冲击功均高于Cr12MoV钢的;该钢的高硬度与良好的强韧性配合可大大提高模具的使用寿命。     

不同齿轮材料离子镀膜处理及其结合强度的研究

对常用的氮化齿轮材料 40Cr、20CrMo、32Cr2MoV,在不同的表面粗糙度下进行了离子氮化和TiN复合镀膜处理,并测定了膜层厚度和镀膜后的结合强度。结果表明,相同镀膜条件下的膜层厚度没有明显差异;但随着表面粗糙度的下降,膜层的结合强度上升;含有较多Cr、V的 32Cr2MoV通过复合处理之后其硬度梯度分布更为合理,比 40Cr、20CrMo涂层结合强度更好,膜层性能优越。     

Cr12MoV模具钢TiN涂层的力学性能

本文对Cr12MoV模具钢TiN涂层的力学性能进行了研究。用XRD等仪器测定了TiN涂层的组织结构和显微硬度、耐磨附着力等性能。     

冷处理对Cr12MoV钢硬度的影响

通过测定不同热处理条件下Cr12MoV钢的硬度值和残余奥氏体量,并通过金相和透射电镜观察发现．钢中的列余奥氏体和下贝氏体组织对冷作模具钢的耐磨性能有不利的影响．采用冷处理工艺可以抑制下贝氏体转变．显著提高Cr12MoV钢的硬度和耐磨性能．     

W9Mo3Cr4V钢在织针模具中的应用

Cr12MoV模具钢是目前普遍应用的织针模具材料。在冲裁过程中,由Cr12MoV钢制造的模具刃磨寿命低,影响织针的尺寸精度、尺寸一致性以及织针生产成本,相比Cr12MoV模具钢,W9Mo3Cr4V钢热处理后具有更高的硬度和耐磨性,同时具有高热硬性、高淬透性、足够的塑性和韧性。对Cr12MoV钢和W9Mo3Cr4V钢织针模具的磨损量和刃磨寿命进行研究结果表明,W9Mo3Cr4V钢模具比Cr12MoV钢模具的正常磨损阶段更长,模具的平均刃磨寿命可延长40%,具有明显的优越性。     

深冷处理对三角材质Cr12MoV钢性能的影响

对淬火后的Cr12MoV钢采用不同时间深冷处理,经回火处理后,对其进行金相组织分析和力学性能测试。试验结果表明,1 050℃淬火＋550℃回火后,Cr12MoV钢的冲击功可达4.5J,淬火后的深冷处理时间〉4h后细化晶相的效果明显,超过12h的深冷处理可将Cr12MoV钢的硬度提升至65.5HRC,耐连续磨损性能提高2倍,可以有效改进三角的使用工况并延长使用寿命。     

Cr12MoV钢低温淬火试验和应用

Cr12MoV钢广泛用于制造高性能的冷作模具,要求淬火至高硬度(HRC>60)的常规工艺规定的淬火温度是1020～1040℃。为了充分发挥Cr12MoV钢的性能潜力和工艺的适用性,我们试验了Cr12MoV钢的低温淬火,该工艺能在获得高的淬火硬度的基础上提高钢的强度和韧性,改善某些工模具的使用寿命,同时有利于减小淬火变形和扩大淬火加热工艺的适用性,     

Cr12MoV钢表面磁控溅射TiB2-TiN薄膜的摩擦磨损性能

采用磁控溅射技术在淬火态Cr12MoV表面制备SiC/TiN、SiC/TiB2-TiN薄膜(SiC为中间层),研究TiN、TiB2-TiN薄膜的组织结构和摩擦磨损性能。结果表明,SiC薄膜与基材和TiN、TiB2-TiN薄膜间都具有明显的且呈梯度的元素扩散,界面结合良好。在水润滑条件下与钢球对摩时(载荷0.5 N,时间0.5 h),TiN薄膜、TiB2-TiN薄膜具有良好摩擦磨损性能,其平均摩擦因数分别为0.33、0.31,低于淬火态Cr12MoV的0.45,磨损速率分别为2.0×10-8和1.5×10-8mm3/(N.m),低于淬火态Cr12MoV的8.66×10-7mm3/(N.m),其中在水润滑条件下TiB2-TiN薄膜比TiN薄膜具有更好的摩擦磨损性能。     

Cr12MoV钢模具的热处理

阐述了Cr12MoV钢在制造模具过程中热处理的重要性,通过对Cr12MoV钢的锻造、锻造后的热处理及热处理前的预处理、最终热处理等方面介绍了Cr12MoV钢在制造模具时在热处理方面应注意的问题和经验,以保证Cr12MoV钢制造的模具,特别是容易变形、要求精度较高的模具热处理后能够满足模具图纸及技术需求。     

TiN、CrN的环境摩擦磨损对比研究

采用直流叠加脉冲偏压电弧离子镀技术在45钢表面沉积了TiN、CrN薄膜。用显微硬度计测试了薄膜的硬度,用划痕仪测量了薄膜的膜基结合力,用球-盘式摩擦磨损试验机评价了不同介质条件下（干摩擦、水润滑、油润滑）TiN、CrN薄膜的摩擦学特性,用表面轮廓仪测试了薄膜磨痕处的磨损轮廓,用扫描电镜（SEM）观察了薄膜磨痕形貌。结果表明,相对于干摩擦条件下,在水润滑和油润滑条件下TiN和CrN薄膜的摩擦因数和磨痕深度都有所降低。在相同的介质条件下,CrN薄膜的摩擦因数和磨痕深度始终小于TiN薄膜。     

高速钢表面镀覆薄膜的腐蚀机理研究

利用AIP-01型多弧离子镀膜机在高速钢基体上制备了TiN及(Ti，Cr)N复合薄膜，对制得的薄膜进行盐水全浸泡试验，研究了带有宏观熔滴颗粒的TiN及(Ti，Cr)N复合薄膜的腐蚀机理。结果表明：高速钢表面镀覆薄膜后耐腐蚀性能显著提高，复合薄膜中随Cr含量的增大，薄膜耐腐蚀性能提高，薄膜的腐蚀包括小孔腐蚀和电偶腐蚀。     

Characteristic evaluation of friction and wear in the C-N and TiN coated gear

C-N films were deposited on the 20CrMo alloy steel substrate by the Plasma Source Ion Implantation (PSII) method and TiN films were coated on the same material by the Physical Vapor Deposition (PVD) method. It was found that friction coefficient of C-N coating were relatively lower than TiN coating. And with the load increased, the friction coefficients of C-N coating and TiN coating were both decreased. Then the author puts forward the test rig, working under the conditions of 1,800 rpm, 20 N·m for 100 h. The observations by microscope showed the wear reduced. The antiwearing performance enhanced prominently. But the TiN coated gear had a more serious friction phenomenon than C-N coated gear. This is caused by that coating of TiN, which was made at a high temperature about 500°C. The high temperature led to the substrate intenerated and the surface hardness had decreased from 850 HV to 630 HV. PSII method eliminates the tempering problem of the coating of C-N films, which had better wear resistance than TiN films. The friction and wear resistance of gears which coated by C-N films ameliorated significantly.     

A comparative study on the microstructure and tribological properties of Si3N4 and TiN films produced by the IBED method

The tribological properties of Si₃N₄ and TiN thin films produced by ion beam enhanced deposition (IBED) were compared on a SRV friction and wear testing machine. The friction coefficient of all thin films shows a descending tendency with increase in load, and is lower than that of 52100 steel. All the IBED films show a much better wear resistance than 52100 steel, especially in the higher load and frequency ranges; it can reach six times that of the latter. In order to understand the reasons for their excellent properties, the microstructure, microhardness and bonding strength with the substrate were analysed by SEM, X-ray diffraction, Knoop hardness and scratching test methods separately. The results show that the TiN(1) film exhibits the best tribological properties, which are closely related with its greater hardness and bonding strength.     

大气环境下Au/TiN复合薄膜的滑动摩擦磨损性能

以30CrMnSi钢为基体,用磁控溅射法制备出Au/TiN复合薄膜材料,研究了薄膜在大气环境中的滑动摩擦磨损性能。结果表明:该复合薄膜材料与9Cr18钢球构成的滑动摩擦副,在接触压力不大于1.0GPa条件下,摩擦系数小于0.15,摩擦次数超过3×105;在较宽的温度、湿度和磁场范围内,薄膜的摩擦磨损性能保持稳定。当接触压力增大至3.0GPa时,薄膜的摩擦系数增大,耐磨寿命减小。该薄膜可用于大气环境下长寿命低载荷精密摩擦副的润滑。     

Tribological properties of plasma nitrided stainless steel against SAE52100 steel under ionic liquid lubrication condition

1Cr18Ni9Ti stainless steel was modified by plasma nitriding. The phase composition of the plasma nitrided layer was examined by means of X-ray diffraction. The friction and wear properties of the modified and unmodified 1Cr18Ni9Ti stainless steel specimens sliding against SAE52100 steel under the lubrication of ionic liquid of 1-ethyl-3-hexylimidazolium hexafluorophosphate (L-P308) and poly α-olefin (PAO) were investigated on an Optimol SRV oscillating friction and wear tester, with the interactions among the modified surface layer and the ionic liquids and PAO to be focused on. The morphologies of the worn surfaces were observed using a scanning electron microscope. The chemical states of several typical elements on the worn surfaces of the modified steel surfaces were examined by means of X-ray photoelectron spectroscopy. Results showed that the modified sample had better anti-wear abilities than the unmodified one, but the modified sample had a slightly higher friction coefficient than the untreated one. This was partly attributed to the change in the hardness and phase composition of the stainless steel surfaces after plasma nitriding and tribochemical reactions between the steel and the lubricant. The resultant surface protective films composed of various tribochemical products together with the adsorbed boundary lubricating film contributed to reduce the friction and wear.