CSP工艺钛微合金碳钢中的碳氮化钛析出相

 应用透射电镜、高分辨电镜等方法观察分析了薄板坯连铸连轧EAF-CSP工艺生产的微钛低碳钢热轧板的含钛析出相,实验钢的成分为(mass%）：C：0.04~0.07%、Si：0.6%、Mn：0.6%、Ti：0.06~0.14 %。电解萃取及X射线衍射分析结果表明：钢中存在不同碳氮比的碳氮化钛析出相,这些碳氮化物的C/N比值的差异是由各个析出相的形成温度及析出时钛和氮、碳元素在钢中的过饱和度不同而造成的。实验钢萃取粉末（包括各种析出相）的质量分数约占钢的0.305%。其中五分之四左右为渗碳体,另外五分之一主要是钛的碳化物、氮化物和碳氮化物,还有少量的硫化物和氧化物。 在薄板坯连铸连轧工艺的连铸坯及热轧板中均观察到了由相间沉淀方式形成的碳氮化物粒子列。本文讨论了相间沉淀的形成机制。与传统连铸连轧工艺生产的同类钢相比,CSP工艺低碳钢中微量钛的加入明显增加了细小析出相的数量。     

CSP工艺钛微合金钢中的碳氮化钛析出相

应用TEM、HREM、X射线衍射等方法分析了薄板坯连铸连轧EAF-CSP工艺生产的钛微合金钢热轧板的含钛析出相,钢的化学成分(质量分数,%)为:C 0.04~0.07、Si≤0.6、Mn≤0.6、Ti 0.06~0.14。结果表明:试验钢中存在不同碳氮比的碳氮化钛,其C/N比值之差是由各析出相的形成温度及析出时钛和氮、碳在钢中的过饱和度不同造成的。试验钢萃取粉末的质量分数约占钢的0.305%。其中70%以上为渗碳体,其余的主要是钛的碳化物、氮化物和碳氮化物以及少量硫化物和氧化物。添加钛明显增加了细小析出相的数量。在CSP工艺连铸坯及热轧板中均观察到由相间沉淀方式形成的碳氮化物粒子列。讨论了相间沉淀的形成机制。     

Analysis on Microstructure Characteristics and Precipitation Behavior of Automobile Beam Steels Produced by Compact Strip Production

 The microstructure characteristics and precipitation behavior of automobile beam steels produced by Compact Strip Production (CSP) were investigated by use of scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X-ray energy dispersive spectroscopy. The result shows that the final microstructure is mainly of polygonal ferrite and small amount of pearlite, the average ferrite grain size is about 3～6μm. Small amount addition Ti to aluminium-killed steel can help to refine the microstructure and improve the mechanical properties. A large number of fine precipitates have been observed in automobile beam steels. The mean particle size is about 10～30nm. Remarkable strengthening and grain refinement can be obtained by these nano-particles.     

Analysis of Microstructure Characteristics and Precipitation Behavior of Automobile Beam Steels Produced by Compact Strip Production

The microstructure characteristics and precipitation behavior of automobile beam steels produced by compact strip production (CSP) were investigated by use of scanning electron microscopy (SEM),transmission electron microscopy (TEM) and X-ray energy dispersive spectroscopy. The result shows that the final microstructure is mainly composed of polygonal ferrite and small amount of pearlite,and the average ferrite grain size is about 3-6μm. Small amount addition Ti to aluminium-killed steel can help to refine the microstructure and improve the mechanical properties. A large number of fine precipitates have been observed in automobile beam steels. The mean particle size is about 10-30nm. Remarkable strengthening and grain refinement can be obtained by these nano-particles.     

CSP生产无取向电工钢的组织和性能

 研究了采用CSP流程生产的无取向电工钢的金相组织、第二相粒子分布、磁性能。结果表明,采用CSP流程生产的无取向电工钢热轧板成品均为均匀粗大的等轴晶;热轧板中第二相粒子平均尺寸在150 nm左右,且随(Si+Al)含量的增加,第二相粒子的类型发生明显的变化;CSP流程生产的无取向电工钢磁性能得到明显的提高。     

CSP生产的钒氮微合金钢的组织细化和析出物研究

 紧凑式带钢工艺（CSP）生产的钒氮微合金钢屈服强度超过600 MPa,韧性良好。采用扫描电镜和透射电镜观察发现,铁素体平均晶粒直径在3 μm左右,在铁素体晶粒内部分布着数十纳米和几纳米的两类V(C,N)析出物。细晶强化是主要的强化方式,在铁素体中析出的V(C,N)粒子起到了沉淀强化作用。分析了超细晶组织形成的主要原因。     

Analysis on the Microstructure and Performance Evolvement of Alloyed Tool Steel Hot Rolling Strip Produced by CSP Technology

This thesis determinates the microstructure and inclusions of the alloyed tool steel by CSP processing with the help of SEM.The results show that the slab microstructures are the fine branched crystalline grains and the branch width has little disparity from the surface to the central region.For the product,the grain microstructures are fine pearlites and few ferrites with the pearlite space 0.4μm to 0.2μm.     

CSP生产Ti微合金化高强钢中纳米碳化物

采用光学金相、电子显微术和化学相分析的方法并结合热力学计算,分析了紧凑式带钢生产(CSP)的Ti微合金化高强钢中的析出物及其析出规律.研究发现:高强钢中存在微米尺寸的立方TiN析出和大量纳米尺寸的析出物粒子;钢中MX相(M=Ti,Mo,Cr;X=C,N)的质量分数为0.0927%,其中10 nm以下的析出物占26.9%;均热之前和均热过程TiN已基本全部析出,连轧前TiC不具备析出的热力学条件;降低钢中N和S含量、严格控制卷取温度可增加TiC的体积分数,降低γ→α相变温度可以阻止细小碳化物长大.结果表明,析出物总的沉淀强化效果约为156 MPa,并能通过化学成分和工艺的控制进一步增强.     

CSP生产的微钛低碳高强度钢中的纳米级析出物

对CSP生产的低碳微钛高强度钢进行了化学相分析和高分辨率透射电镜的观察.发现钢中纳米级M3C型颗粒的数量要比MC型颗粒多2个数量级,其中＜18 nm的M3C有0.024%,而＜18 nm的MC只有0.000 9%.高分辨率电镜观察的结果表明,纳米级析出物主要有3类,第1类主要含Ti、Fe、C、O、N,第2类含Fe、C、O,第3类只含Fe、O.     

CSP流程试制50W270高牌号无取向硅钢织构的演变

研究了CSP流程试制50W270高牌号无取向硅钢热轧→常化→冷轧→退火过程中织构的演变.利用电子背散射衍射技术对全流程织构进行测量和分析.发现热轧板织构在厚度方向上存在较大差异,表层主要为铜型、黄铜和高斯织构,1/4层存在微弱的高斯织构和旋转立方织构,中心层以γ纤维织构和旋转立方织构为主,还含有较弱的α纤维织构.与热轧板相比,常化板表层和1/4层织构变化不大,中心层旋转立方织构和α纤维织构增强.冷轧板各层均具有α纤维织构和γ纤维织构.与冷轧板相比,成品板各层中α纤维织构基本消失,还出现了立方织构和高斯织构.     

Nb在CSP生产管线钢中的应用

针对薄板坯连铸连轧的工艺特点,根据Nb在钢中的析出规律和作用机理,包钢合理选择微合金化元素Nb及其添加量,并通过严格的冶炼和轧制工艺控制,成功地开发出管线钢等系列产品,对钢中的组织进行了研究,探讨了薄板坯连铸连轧条件下含铌微合金钢的强韧化机理。     

CSP工艺试制汽车用高强度热轧板中的析出

利用透射电镜研究了珠钢CSP工艺试生产的汽车用高强度热轧板中的析出颗粒形貌与分布；利用Ashby-Orowan的弥散强化模型讨论了析出物颗粒尺寸及体积分数与屈服强度的关系。结果表明，在ZJ510L—B热轧板的铁素体晶界、晶内及位错上有大量细小的析出物，析出以TiC颗粒为主，细小弥散的析出颗粒产生的强化增量约40MPa，CSP工艺规程充分发挥了微合金元素的潜力。     

Calculation of AlN and MnS Precipitation in Non-Oriented Electrical Steel Produced by CSP Process

Combining with the study of analogue experiments and test analysis, the kinetics of precipitation and growth of AlN and MnS in non-oriented electrical steel produced by the CSP process is calculated. The results show that the precipitate phase particles of AlN and MnS in typical non-oriented electrical steel grades produced by the CSP process have grown to some extent in the soaking stage, but the precipitation contents are less than 20% of the total contents of nitride and sulfide. The precipitate phase particles of AlN and MnS have precipitated almost after the hot rolling process. The precipitation contents are more than 80% of the total contents of nitride and sulfide, but it is very late for the precipitate phase particles to grow at the end of the hot rolling process.     

Calculation of AIN and MnS Precipitation in Non-Oriented Electrical Steel Produced by CSP Process

Combining with the study of analogue experiments and test analysis,the kinetics of precipitation and growth of AIN and MnS in non-oriented electrical steel produced by the CSP process is calculated.The results show that the precipitate phase particles of AIN and MnS in typical non-oriented electrical steel grades produced by the CSP process have grown to some extent in the soaking stage,but the precipitation contents are less than 20% of the total contents of nitride and sulfide.The precipitate phase particles of AIN and MnS have precipitated almost after the hot roiling process.The precipitation contents are more than 80% of the total contents of nitride and sulfide,but it is very late for the precipitate phase particles to grow at the end of the hot rolling process.     

CSP工艺生产SPA-H钢的宏观偏析

针对目前珠江钢铁有限责任公司薄板坯连铸连轧生产线(CSP)生产的集装箱板用钢SPA-H铸坯的宏观偏析进行了分析研究,从导致铸坯宏观中心偏析的各影响因素入手,对问题进行全面的分析与阐述,提出了进一步提高薄板坯连铸生产SPA-H钢质量的一些建议和技术措施.     

薄板坯连铸连轧生产Ti微合金化钢的强化机理

为了阐明薄板坯连铸连轧生产Ti微合金化钢的强化机理,通过电镜和化学相分析等实验手段对Ti含量不同的集装箱板进行了研究,结果表明,连轧前钢中尺寸为几十纳米的方形TiN粒子已基本析出,连轧及其后的低温阶段钢中形成纳米尺寸的弥散的TiC析出物,降低了Fe3C的质量分数.小于10 nm的TiC粒子是Ti微合金化钢屈服强度显著提高的主要原因.     

薄板坯连铸连轧CSP生产低碳钢板的组织特征

对珠钢CSP线生产的低碳钢（ZJ400）连铸坯及轧后的组织特征观察和硬度测定表明：CSP线生产的连铸坯铸态组织为较细的树枝晶,枝晶宽度为几微米到30um,靠近表面层的枝晶宽度与中心区域差别很小,经第一道次50％变形后,板坯组织明显细化,具有局部“树枝晶”特征,“枝晶”宽度约5um,中心区域硬度降低,成品薄板的晶粒尺寸平均为5um,大多呈尖角型。变形区位力,应变及温度分布的有限元模拟分析结果与实际组织分析结果吻合。     

CSP工艺生产的低碳钢中纳米尺寸硫化物

用电子显微镜和X射线能谱分析等技术对薄板坯连铸连轧CSP工艺生产的低碳钢进行了系统研究,在钢中发现了大量尺寸在30-200nm范围的纳米级硫化物。在实验研究基础上对硫化物在CSP工艺加速冷却条件下的析出行为进行了讨论,提出了低碳钢中纳米尺寸硫化物的固态析出机制。结果表明：降低钢中的碳含量、控制硫含量、加快铸坯的凝固速度和冷却速度,控制硫化物在奥氏体相区析出等是影响纳米尺寸硫化物形成的重要因素。     

轧制工艺对CSP线热轧汽车用高强钢板组织特征的影响

研究了薄板坯连铸连轧(CSP)工艺生产高强度汽车用大梁板的工艺控制参数与力学性能和显微组织间的关系.根据柔性工艺控制的指导思想,在珠钢电炉CSP流程下实现了生产不同级别高强度钢板的柔性轧制工艺.利用扫描电镜和透射电镜研究了其组织和强度差异产生的原因.研究表明,钢板最终组织为多边形铁素体和少量珠光体组成,平均铁素体晶粒尺寸约为3.7~5.6μm;当降低卷取温度,部分渗碳体已破碎成细小的碳化物粒子分布于铁素体基体上,钢板中有少量贝氏体出现.     

邯钢CSP工艺过程钢中夹杂物热力学分析与研究

通过对邯钢低碳铝镇静钢中夹杂物的形成热力学进行计算和分析，取样后经非水溶液电解法分离得到邯钢工艺过程钢中夹杂物，验证了非水电解的可行性和热力学计算的准确性，初步提出了改进邯钢精炼工艺的有效措施，并对硫化物的形成机理进行了初步分析。