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New hybrid auxetic chiral mechanical metamaterial are designed and fabricated via multi‐material 3D printing. Due to the chirality‐induced rotation, the material have unique sequential cell‐opening mechanisms. Mechanical experiments on the 3D printed prototypes and systematic FE simulations show that the effective stiffness, the Poisson's ratio and the cell‐opening mechanisms of the new design can be tuned in a very wide range by tailoring two non‐dimensional parameters: the cell size ratio and stiffness ratio of component materials. As example applications, sequential particle release mechanisms and color changing mechanisms of the new designs are also systematically explored. The present new design concepts can be used to develop new multi‐functional smart composites, sensors and/or actuators which are responsive to external load and/or environmental conditions for applications in drug delivery and color changing for camouflage.
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For artificial materials, desired properties often conflict. For example, engineering materials often achieve high energy dissipation by sacrificing resilience and vice versa, or desired auxeticity by losing their isotropy, which limits their performance and applications. To solve these conflicts, a strategy is proposed to create novel mechanical metamaterial via 3D space filling tiles with engaging key-channel pairs, exemplified via auxetic 3D keyed-octahedron–cuboctahedron metamaterials. This metamaterial shows high resilience while achieving large mechanical hysteresis synergistically under large compressive strain. Especially, this metamaterial exhibits ideal isotropy approaching the theoretical limit of isotropic Poisson's ratio, -1, as rarely seen in existing 3D mechanical metamaterials. In addition, the new class of metamaterials provides wide tunability on mechanical properties and behaviors, including an unusual coupled auxeticity and twisting behavior under normal compression. The designing methodology is illustrated by the integral of numerical modeling, theoretical analysis, and experimental characterization. The new mechanical metamaterials have broad applications in actuators and dampers, soft robotics, biomedical materials, and engineering materials/systems for energy dissipation.  相似文献   

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三维超材料是具有三维空间特定排布的亚波长人工周期结构,具有自然材料不具备的超常规物理性能。本文以三维超材料的电磁调控技术为线索,简要论述了近年来三维超材料在基础研究和制造工艺方面的研究现状;梳理了目前三维超材料的制造方法,包含印刷电路板及组装的方法、机械加工方法、3D打印技术、微纳制造工艺;选取电磁隐身罩、透镜天线、吸波器、柔性超材料等代表性应用类别,简述了三维超材料器件的电磁调控方法与实现手段,所涉及的超材料种类包括左手超材料、渐变折射率超材料、智能超材料等。基于目前三维超材料研究领域待解决的问题,对今后三维超材料的发展趋势进行了探讨。

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Protective armors are widespread in nature and often consist of periodic arrays of tile‐like building blocks that articulate with each other through undulating interfaces. To investigate the mechanical consequences of these wavy tessellations, especially in instances where the amplitude of the undulations is near the scale of the constituent tiles as is found in the seedcoats of many plant species, an approach that integrates parametric modeling and finite element simulations with direct mechanical testing on their 3D‐printed multi‐material structural analogues is presented. Results from these studies demonstrate that these tiled arrays of largely isotropic star‐like unit cells exhibit an unusual combination of mechanical properties including auxeticity and mutually amplified strength and toughness which can be systematically tuned by varying the waviness of the sutural tessellation.  相似文献   

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于相龙  周济 《材料工程》2016,(7):119-128
本文以智能超材料关键技术为主线,基础研究和新产品研发为辅,简要论述近年来智能超材料的发展现状和趋势。根据智能超材料所调控激元的不同,可分为智能电磁超材料,智能机械超材料,智能热学超材料,智能耦合超材料,此外两项关键技术为智能超材料新型设计与仿真技术和材料制备技术与材料基因工程。这些智能超材料在科学基础研究方面涉及超材料中多物理场耦合机制,新型人工原子与人工分子设计,超材料与自然材料的融合,超材料可调性探索和新型传感型超材料机制探求。基础研发和技术拓展将推进智能超材料施展到更加广泛的应用领域,如微型天线及无线互联,光电磁隐身,医学图像上用的完美成像,航空航天和交通车辆所用的智能蒙皮,精密仪器制程与片上实验室集成型超材料等。基于上述国内外智能超材料研究的发展趋势,本文进行了系统性的分类厘清,并分析了其研究现状,给出了我国智能超材料发展的美好愿景。  相似文献   

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准零刚度隔振器作为国内外主流的非线性隔振器,凭借其高静态刚度和低动态刚度力学特性,在机械工程领域应用较多,但近零刚度范围窄、后期组装繁琐等问题限制了其隔振的应用范围,通过结构设计使近零刚度范围增大,且能通过一体化成型技术快速制备方面的研究仍较稀缺。本文基于能量屏蔽理论设计了一种新型零刚度单元结构,通过将外界输入能量循环于超材料内部,从而屏蔽外界对隔振对象的能量输入,达到隔振效果。该研究首先设计出具有优化潜力的初始结构,然后使用机器学习与有限元分析结合的方法对初始结构进行优化,自动搜索出最优的超材料结构参数,且最优结构满足零刚度性能设计要求,之后使用3D打印对最优结构单元及2×2阵列结构进行一体化制造。并对样件进行静态实验验证,实验结果表明:在静态压缩过程中,该结构的等效刚度在大范围内近似于0。又对阵列结构进行动态振动实验,结果得出,阵列结构在23 mm振幅下0.1~100 Hz范围内,9.2 kg载荷隔振性能最优,最小传递率可达−61 dB,载荷越接近9.2 kg隔振性能越好。该结构具有结构简单、一体化成型等优势,可应用于列车座椅、康复医疗设备、精密仪器保护及微重力环境等领域下的隔振。  相似文献   

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316L and Cu-based inks are developed to 3D-printed tetrachiral auxetic structures. The main objectives of the work are to study the effects of powders composition and powder:binder volume ratio on rheological properties and printability of the inks. Following these results, customized Gcode is developed using FullControl Gcode Designer open-source software to 3D print intricate tetrachiral auxetic structures. The results reported in this work show how powder composition (316L versus Cu) has less effect on the inks’ rheological behavior than powder size distribution and powders:binder volume ratio. In terms of rheological parameters, the zero-shear rate viscosity mainly affects the capability of the printed ink to retain its shape after printing, while the yield stress affects the printability. The printed and sintered auxetic structures achieve the intended lattice-geometry design.  相似文献   

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The scattering characteristics of a cylindrical reflector coated with a chiral material and embedded in a double-negative metamaterial have been studied using numerical simulation. The effects of double-negative metamaterial background media and chiral admittances of a chiral coating layer upon the co- and cross-polarized echo widths have been investigated. It is shown that a double-negative metamaterial background with relatively larger negative values of the permittivity and the permeability enhances the co-polarized echo width in the forward scattering direction and reduces this echo width in the backward scattering direction as compared to the free space background. It is further shown that by increasing the chiral admittance of a chiral-coated cylindrical reflector embedded in a double-negative metamaterial with fixed background parameters increases the co-polarized echo width in the forward and the backward scattering directions as compared to an achiral-coated cylindrical reflector embedded in the same double-negative metamaterial background.  相似文献   

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Architected materials with nano/microscale orders can provide superior mechanical properties; however, reproducing such levels of ordering in complex structures has remained challenging. Inspired by Bouligand structures in nature, here, 3D printing of complex geometries with guided long-order radially twisted chiral hierarchy, using cellulose nanocrystals (CNC)-based inks is presented. Detailed rheological measurements, in situ flow analysis, polarized optical microscopy (POM), and director field analysis are employed to evaluate the chiral assembly over the printing process. It is demonstrated that shear flow forces inside the 3D printer's nozzle orient individual CNC particles forming a pseudo-nematic phase that relaxes to uniformly aligned concentric chiral nematic structures after the flow cessation. Acrylamide, a photo-curable monomer, is incorporated to arrest the concentric chiral arrangements within the printed filaments. The time series POM snapshots show that adding the photo-curable monomer at the optimized concentrations does not interfere with chiral self-assemblies and instead increases the chiral relaxation rate. Due to the liquid-like nature of the as-printed inks, optimized Carbopol microgels are used to support printed filaments before photo-polymerization. By paving the path towards developing bio-inspired materials with nanoscale hierarchies in larger-scale printed constructs, this biomimetic approach expands 3D printing materials beyond what has been realized so far.  相似文献   

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The ability to manufacture 3D metallic architectures with microscale resolution is greatly pursued because of their diverse applications in microelectromechanical systems (MEMS) including microelectronics, mechanical metamaterials, and biomedical devices. However, the well-developed photolithography and emerging metal additive manufacturing technologies have limited abilities in manufacturing micro-scaled metallic structures with freeform 3D geometries. Here, for the first time, the high-fidelity fabrication of arbitrary metallic motifs with sub-10 µm resolution is achieved by employing an embedded-writing embedded-sintering (EWES) process. A paraffin wax-based supporting matrix with high thermal stability is developed, which permits the printed silver nanoparticle ink to be pre-sintered at 175 °C to form metallic green bodies. Via carefully regulating the matrix components, the printing resolution is tuned down to ≈7 µm. The green bodies are then embedded in a supporting salt bath and further sintered to realize freeform 3D silver motifs with great structure fidelity. 3D printing of various micro-scaled silver architectures is demonstrated such as micro-spring arrays, BCC lattices, horn antenna, and rotatable windmills. This method can be extended to the high-fidelity 3D printing of other metals and metal oxides which require high-temperature sintering, providing the pathways toward the design and fabrication of 3D MEMS with complex geometries and functions.  相似文献   

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Thermally cured thermoset polymers such as epoxies are widely used in industry and manufacturing due to their thermal, chemical, and electrical resistance, and mechanical strength and toughness. However, it can be challenging to 3D print thermally cured thermosets without rheological modification because they tend to flow and not hold their shape when extruded due to cure times of minutes to hours. 3D printing inside a support bath addresses this by allowing the liquid polymer to be held in place until the thermoset is fully cured and expands the structures that can be printed as extrusion is not limited to layer-by-layer. Here, the use of Freeform Reversible Embedding (FRE) to 3D print off-the-shelf thermoset epoxy into lattice structures using nonplanar extrusion is reported. To do this, the authors investigate how extrusion direction in 3D space impacts epoxy filament morphology and fusion at filament intersections. Furthermore, the advantages of this approach are shown by using nonplanar printing to produce lattice geometries that show ≈ four times greater specific modulus compared with lattice structures printed using other materials and printing techniques.  相似文献   

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将3D打印技术引入到纺织技术应用领域,生产三维立体打印织物。利用自主设计的3D打印机,通过Solidworks三维建模、模型分层处理、生成扫描路径逐层打印堆积成型的过程试织了平纹结构的三维立体织物试样,并从经向方向测试了其拉伸力学性能。试验结果表明:三维立体打印织物与普通织物类似,试样在拉伸初始阶段属于力学高模量区,经向伸长缓慢。三维立体打印织物的拉伸破坏过程不是同时发生,首先在织物熔融凝结固着点的最弱处断裂,应力集中后结构遭到破坏,试样断裂。  相似文献   

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