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钛酸酯偶联剂改性的无机填料应用于聚丙烯复合材料,可以改善材料性能,扩大应用领域。概述了钛酸酯偶联剂改性的无机填料在不同种类的聚丙烯复合材料中的应用,以及对复合材料力学性能和阻燃性的影响。 相似文献
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《合成材料老化与应用》2016,(2)
按照增强材料和填充材料的不同,对聚丙烯复合材料的研究进展进行综述,主要介绍了玻纤增强聚丙烯复合材料、天然纤维/聚丙烯复合材料和无机填料/聚丙烯复合材料。 相似文献
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采用无机填料制备电镀级聚丙烯树脂,通过对填料的颗粒形状,粒径大小,分布及填料量进行合理调控,使改性后的聚丙烯树脂具有可电镀性,镀层外观平坦光亮,剥离强度符合GB5933标准第2.6款。 相似文献
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PP/mPE/无机填料三元复合材料的形态结构和力学性能 总被引:6,自引:1,他引:6
采用刚性无机填料对茂金属聚乙烯(mPE)弹性体增韧聚丙烯(PP)二元共混体系进行增强,从而制得PP/mPE无机填料三元复合材料。分别探讨了CaCO3用量对复合材料拉伸性能和低温冲击性能影响,并考察了不同填料的增强效果。实验结果表明,由于弹性体的存在,无机填料的增强作用减弱;共混物的低温冲击强度也因填料的加入而大幅度下降,但经过表面处理的高岭土体系的冲击强度反而提高。SEM断裂形貌显示,未经表面处理的填料和基体的界面结合较弱,而改性高岭土则以层状结构分散于基体中,并呈现牢固的界面结合。 相似文献
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Wattanaphon Cheewawuttipong Shuichi Tanoue Hideyuki Uematsu Yoshiyuki Iemoto 《Polymer Composites》2016,37(3):936-942
High thermal conductivity fillers of boron nitride (BN) and vapor‐grown carbon fiber (VGCF) were used alone or incorporate to prepare polypropylene (PP) composites. The effects of filler content, particle size and shape, and single vs. hybrid BN/VGCF fillers were investigated with respect to the thermal conductivity of the PP composites. The thermal conductivity of PP/BN composites depended upon the content and particle size of the BN. Increased content and length of VGCF had the effect of increasing the thermal conductivity of the PP composites. Hybrid fillers were created with a mixture of medium‐sized BN and long‐length VGCF; hybrid BN/VGCF fillers enhanced the thermal conductivity of PP composites with a lower total content compared with PP composites containing only medium‐sized BN particles. POLYM. COMPOS., 37:936–942, 2016. © 2014 Society of Plastics Engineers 相似文献
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Composites consisting of carbon fibers (CF) and carbon particles (CP) in polypropylene (PP) matrix were melt-compounded. Composites
were analyzed for their mechanical, electrical and thermal properties. Results indicate that the addition of these fillers
improved the mechanical properties of the composites. Thermal conductivity was enhanced as the concentration of fillers was
increased. Carbon fibers render the composites electrically conductive so we observed a percolation threshold near 10 wt.%
of CF for PP/CF (PP and CF composite) and near 25 wt.% of CP for PP/CP (PP and carbon particle composite). All the results
indicated that carbon fibers are more effective in improving the properties as compare to the carbon particles. 相似文献
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高抗冲高刚性EPDM改性聚丙烯的研究 总被引:2,自引:0,他引:2
加入超细改性无机刚性粒子提高三元乙丙橡胶(EPDM)的硬度,再与聚丙烯(PP)进行共混。研究了超细改性无机刚性粒子用量对EPDM硬度及流动性的影响,比较了PP与不同硬度EPDM的共混物在力学性能上的差异。结果表明:随着EPDM硬度的增加,共混物不仅韧性提高,弯曲模量也大幅度上升。选择合适的硬度,可制得高抗冲高刚性的EPDM改性PP共混材料。 相似文献
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Comparative study on electrical properties of copper nanowire/polypropylene and carbon nanotube/polypropylene composites
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Nanocomposites using copper nanowires (CuNWs) or carbon nanotubes (CNTs) as fillers with polypropylene (PP) as matrix were prepared by miscible solution mixing and precipitation method. Comparative studies on electrical conductivity and electromagnetic interference shielding properties were reported. On the conductivity curve, a plateau was found for both CuNW/PP composite and CNT/PP composite. The plateaus are located at a different concentration range for each composite type: for CuNW/PP composite, it is between 0.8 and 1.7 vol %, while for CNT/PP composite the plateau occurs in a narrower range between 0.4 and 0.6 vol %. The shielding effectiveness (SE) increases with increased concentration of fillers. CNT/PP composite has higher SE at concentrations less than 2 vol %; the two curves cross near 10 dB at this point and at concentrations higher than 2 vol %, CuNW/PP composite has higher SE. © 2014 American Institute of Chemical Engineers AIChE J, 61: 296–303, 2015 相似文献
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The thermal and viscoelastic properties of polypropylene (PP)/cellulose as well as PP/Xylan composites were investigated
by differential scanning calorimetry (DSC) and dynamic mechanical thermoanalysis (DMTA). Morphological aspects were available
by using polarizing light microscopy and scanning electron microscopy (SEM). Three types of fillers were incorporated in PP:
xylan fillers (XL), cellulose microfibers (CM) and short fibers of spun cellulose (CS). The compatibilizer maleic anhydride
modified PP (MAPP) was added to the composites. The crystallization temperature and crystallinity of PP apparently increased
in the presence of all fiber types. The cellulose fiber surfaces act as nucleating agents for PP, resulting in the formation
of transcrystalline regions around the fibers. The DMTA spectra of PP/filler composites revealed a significant increase in
the stiffness and a remarkable decrease of the damping values. This effect was stronger for PP/CS than for the other composites.
The results verify that improved compatibility and interfacial adhesion between fiber and matrix markedly contribute to an
improvement of the mechanical properties.
Received: 30 October 1997/Revised version: 11 December 1997/Accepted: 12 December 1997 相似文献
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通过动态硫化工艺制备了溴化丁基橡胶(BIIR)/聚丙烯(PP)热塑性弹性体,研究了加工时间、填料、硫化剂对弹性体力学性能的影响。结果表明,动态硫化制备热塑性弹性体的时间约为13 min;使用炭黑N330/白炭黑双相填料的热塑性弹性体具有较好的力学性能;在氧化锌、硫磺、溴化辛基酚醛树脂及硫磺/溴化辛基酚醛树脂并用硫化体系中,溴化辛基酚醛树脂硫化的热塑性弹性体力学性能最佳。 相似文献
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Y. W. Leong M. B. Abu Bakar Z. A. Mohd. Ishak A. Ariffin B. Pukanszky 《应用聚合物科学杂志》2004,91(5):3315-3326
Three types of mineral fillers—talc, calcium carbonate (CaCO3), and kaolin (10–40 wt % filler loadings)—were compounded with polypropylene (PP) with a twin‐screw extruder. The composites were injection‐molded, and the effects of the filler loading on the mechanical, flow, and thermal properties for the three different types of filled composites were investigated. The aim was to compare their properties and to deduce prospective filler combinations that would yield hybrid PP composites in following studies. The results showed that in most cases, the strength and stiffness of the talc‐filled PP composites was significantly higher than those of the CaCO3‐ and kaolin‐filled PP composites. However, CaCO3, being a nonreactive filler, increased the toughness of PP. The kaolin‐filled PP composites also showed some improvement in terms of strength and stiffness, although the increases in these properties were not as significant as those of the talc‐filled PP composites. The effects of interfacial interactions between the fillers and PP on the mechanical properties were also evaluated with semiempirical equations. The nucleating ability of all three fillers was studied with differential scanning calorimetry, and the strongest nucleating agent of the three was talc, followed by CaCO3 and kaolin. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 91: 3315–3326, 2004 相似文献