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1.
Felib Y. Iskander 《Journal of the American Oil Chemists' Society》1993,70(8):803-805
Instrumental neutron activation analysis was used to determine the concentration of As, Ba, Ce, Co, Cr, Cs, Eu, Fe, Hg, K,
Na, Rb, Sb, Sc, Se, Sr and Zn in almond, sunflower, peanut, sesame, linseed, soy, corn and olive oils, as well as in three
margarine brands. The concentration of As, Ba, Ce, Cs, Eu, Hg, Rb, Se and Sr were below the system detection limit under the
experiment conditions. Chromium was detected only in one of the margarine samples (171 μg/g); Sb only in corn oil (18 ng/g)
and Sc only in linseed oil (19 ng/g). Cobalt, Fe, K, Na and Zn were detected in all oil and margarine samples investigated.
The concentration ranges for Co, Fe, K, Na and Zn in oils were: 0.016–0.053; 4.45–19.1; 5.93–47.2; 2.44–12.9 and 0.48–1.54
μg/g, respectively. For margarine, the concentration ranges for Co, Fe, K, Na and Zn were 0.09–0.012; 4.53–10.6; 58.3–1140;
13.2–9870 and 0.38–0.47 μg/g, respectively. The elemental contents of the analyzed samples are within the ranges reported
in the literature for edible oils and fats. 相似文献
2.
The purpose of this study was to measure oxygen and nitrogen in coals using instrumental neutron activation analysis. For six U.S. coals total oxygen ranged from 9.4 to 28.7% and total nitrogen varied from 0.72 to 1.61%. To obtain values of organic oxygen and nitrogen either a low-temperature-ashing method or an acid-treatment method was suitable for bituminous coals. The mean difference of the experimentally determined values (Odmmf)LTA ? (Odmmf)AT = ?0.82, s = 0.51, was found to be statistically significant at the 95% confidence level, but the comparable difference for nitrogen was not. By the LTA method oxygen and nitrogen on the dmmf basis for bituminous coals showed no statistically significant difference with calculated dmmf values. Nitrogen was detected in all the LTAs varying from 0.38 to 1.67%. Formation of insoluble CaF2 in the acid-treatment method caused an interference in the nitrogen determination due to the 19F (n, 2n) 18F reaction but was correctable. In addition, recoil proton reactions on C and O leading to the formation of 13N must be accounted for in all nitrogen determinations in the coal matrix. 相似文献
3.
Analysis of arsenic and bromine in marine and terrestrial oils 总被引:2,自引:0,他引:2
Gulbrand Lunde 《Journal of the American Oil Chemists' Society》1972,49(1):44-47
Samples of marine and terrestrial oils of both plant and animal origin have been analyzed for arsenic and bromine content.
Two oil samples (cod liver oil and oil extracted from mackerel fillets) were fractionated on silica gel columns and bromine
was determined in the different fractions. The results obtained indicate that lipid soluble bromine and arseno organic compounds
are characteristic components of marine animal and marine plant oils (seaweed). The results also show that the bromine is
not localized in any particular compound or type of compounds. The bromine-containing compounds seem to be relatively stable,
but the arseno-containing compounds are not. When oils containing arsenic and bromine were saponified, some of the arsenic
and bromine compounds were found in the fatty acid fraction while others appeared in the water soluble fraction. 相似文献
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Junichi Kaneko Chushiro Yonezawa Yoshimi Kasugai Hitoshi Sumiya Takeo Nishitani 《Diamond and Related Materials》2000,9(12):2019-2023
Metallic impurities in high-purity type IIa and conventional type Ib diamond single crystals grown by high-pressure and high-temperature (HPHT) synthesis were determined by neutron activation analysis using thermal neutrons. Metallic impurities of Fe, Co, Cr and other minor elements were detected in the high-purity type IIa diamond crystal. The typical quantities of these metallic impurities were a few ppb. The influence of these metallic impurities on the electrical properties of the type IIa diamond crystal was practically negligible compared with nitrogen and boron impurities behaving as a donor and an acceptor, respectively. In addition to the impurities detected in the type IIa diamond crystal, Ni impurities of several hundreds of ppb were detected in conventional type Ib diamond crystals. A difference in molten metal solvents used in the synthesis of each diamond crystal resulted in the difference in metallic impurities. 相似文献
8.
Yasuhiro Ando Toru Ota Yukiko Matsuhira Kazunaga Yazawa 《Journal of the American Oil Chemists' Society》1996,73(4):483-487
This paper presents the positional distribution of fatty acids in docosahexaenoic acid (22∶6n-3)-rich fish oil triacyl-sn-glycerols (TG). Stereospecific analysis of TG was carried out by a nonenzymatic method. The TG of bonito head oil, obtained
after a winterization process, contained 22∶6n-3 at concentrations of 28,7, and 49 mole % in thesn-1,sn-2, andsn-3 positions, respectively. In the TG of oil before the winterization process, 22∶6n-3 was concentrated in thesn-3 position, followed evenly by thesn-1 andsn-2 positions. Tuna orbital oil, obtained after winterization, showed the preferential association of 22∶6n-3 to thesn-3 position, followed by thesn-1 position. This distribution pattern was similar to that observed for seal oil TG rather than sardine oil TG. The bonito
head and tuna orbital oils are useful as fish oils with characteristics different from those of common fish oils, such as
menhaden, sardine, and herring oils. 相似文献
9.
John D. Craske 《Journal of the American Oil Chemists' Society》1993,70(4):325-334
Thirty-five analysts studied the concept that, in the gas chromatographic (GC) analysis of fatty acid composition, errors
can be separated into those caused by poor chromatograph optimization and those related to inefficient conversion of triacylglycerols
(TAG) to fatty acid methyl esters (FAME). A primary standard mixture of FAME was used to determine how well the participants
had optimized their chromatographs. A primary standard of the equivalent TAG was used to determine total error of analysis.
“Chemistry error” was calculated as the difference between the absolute errors found for the FAME and the TAG standards. Grades
of analysis were computed for the FAME and TAG results and for the chemistry errors calculated from these analyses.
Only four analysts achieved grades of analysis for the FAME standard that can be considered excellent or good. These four
analysts used different injector/column configurations, indicating that, when properly optimized, a GC with a flame ionization
detector is an extremely accurate instrument. Conversely, it is evident that there is the potential for most analysts to improve
their instrumental optimization. In agreement with published information, AOCS method Ce 2-66 and AOAC method 969.33 gave
low chemistry grades, but a number of analysts used modifications of these methods, and some achieved much better grades.
It would appear that many of the standard methods that are in common use are capable of producing improved results, but that
critical parameters need to be better specified to ensure minimization of error. The concept of separating errors into those
of instrument origin and those caused by the chemical component of the total method would appear to be a useful concept for
the validation of analytical methods. 相似文献
10.
The products of the new information and communication technologies (NTIC), whose life often not exceed three years, became consumables to the computer image and other waste that contains neodymium and praseodymium (rare earths); in this field of management, treatment, and recycling of waste, we propose the recovery of elements such as neodymium and praseodymium, from the super-magnet Nd–Fe–B. Our study provides a simple and inexpensive process. The implementation scheme of our project consists of a first step in developing a plan of experience that has been made specifically to perform the optimization of operating conditions of the precipitation process. This experimental design was inspired by a statistical technique advanced design of experiments known factorial design. The method begins by embrittlement in liquid nitrogen (?196°C), dissolution in an acidic solution and recovered by a unit operation of chemical engineering, we add an oxalic acid solution to precipitate Nd as neodymium oxalate, followed by purification of neodymium and praseodymium. For characterization we used the following techniques. The neutron radiography, the neutron activation analysis (NAA) and the scanning electron microscope coupled with EDX. The identification of the most intense peaks in the XRD spectrum shows the presence of a single compound which hydrated neodymium oxalate chemical formula Nd2(C2O4)310H2O. The counting of γ spectrum shows that the purity of the precipitate is higher than 99%. Then, the thermal decomposition transforms this powder to neodymium oxide. After the reduction we obtain pure neodymium, the analytical balance shows that this magnet contains 26% of neodymium. 相似文献
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Summary Hypochlorous acid reagent has conveniently been used for the determination of total unsaturation in oils containing conjugated
double bonds. The use of 0.1 N HOCl reagent normally employed for oils with isolated double bonds leads to incomplete absorption,
and the increase in concentration and reaction period gives desirable results in the presence of mercuric acetate catalyst.
A 1-hr. reaction period with 0.3 N HOCl reagent in the presence of 2.5% solution of the catalyst is recommended. A sample
size varying between 0.07–0.1 g. and a 300–400% excess reagent should be employed to obtain reliable results. This procedure
can be effectively used for determining the total unsaturation of tung oil, isomerized fatty acids, and dehydrated castor
oil and can be employed for detecting the adulteration in commercial samples of tung oil, which cannot be ordinarily detected
by the determination of the partial iodine number with the help of conventional procedures. 相似文献
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Nylon 6,6 is an excellent material for the study of the diffusion mechanism and associated mechanical performance of polymers saturated with aqueous solutions of varying pH at different temperatures. The diffusion profile was studied for samples saturated at temperatures ranging from 20 to 90°C in solutions decreasing in pH from distilled water to 1.0M sulfuric acid. The presence of sulfuric acid molecules within the diffusing solutions acts to promote hydrolysis of the polyamide molecules. The degree of hydrolysis is dependent on saturation temperature and solution pH. The extent of degradation was evaluated via changes to mechanical performance and inherent viscosity and often results in a reduction of the stress at yield, flexural modulus, and inherent viscosity on increasing temperature and decreasing pH. The use of neutron activation analysis allowed for an evaluation of the sulfur content within the samples as a function of diffusing time. This demonstrated that although the mechanical performance decreases rapidly on initial exposure to the aqueous medium, this is likely due to plasticization. As diffusion time progresses, the sulfur content within the sample continues to rise to a level where the acid/water molar ratio is much higher in the sample than that of the bulk. This results in an enhancement of the degradation process as time progresses. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 97: 2476–2487, 2005 相似文献
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《Fuel》2006,85(10-11):1550-1558
Mercury, arsenic and selenium are trace elements well-known for their high volatility in underground coal gasification (UCG) which can lead to environmental and technical problems during gas utilization. In this paper, the volatilization of mercury, arsenic and selenium from coal in a seam during the process of UCG were investigated, based on comparison of their volatility during the transformation of coal to char and the conversion of char to ash. Three types of coal were involved in this study. The results indicate that the volatility of mercury, arsenic and selenium during UCG in the seam follows the sequence of Hg>Se>As. Mercury and selenium show volatility higher than 90% from coal to ash. The volatility of arsenic is lower than 60% as confirmed by arsenic enrichment in UCG ash. Arsenic volatilization during UCG is also enhanced by increasing temperature, which is different from the result during the combustion of crushed coal. Coal type has obvious effect on element volatilization. The higher the coal reactivity, the easier is the evaporation of the elements from coal in the seam. At the same time, thermodynamic equilibrium calculations using MTDATA program were performed to predict the possible species in UCG gas. With regard to UCG gas at the production well, mercury presents as Hg(g), H2Se(g) is the main gaseous species of selenium, whereas arsenic occurs in condensed phase as As2S3 and As. The effect of the pressure on the equilibrium composition of the gas results in major changes of the proportions of the species. High pressure leads to the formation and enhancement of the reduced species and increases the condensation temperature of the volatile elements. 相似文献
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Determination of mixtures in vegetable oils and milk fat by analysis of sterol fraction by gas chromatography 总被引:1,自引:0,他引:1
L. Alonso J. Fontecha L. Lozada M. Juárez 《Journal of the American Oil Chemists' Society》1997,74(2):131-135
A rapid gas-chromatographic (GC) procedure was developed for the analysis of the total sterol fraction of vegetable oils,
milk fat or mixtures, to detect possible admixtures of sunflower with olive oil and the addition of vegetable oils to milk
fat. The method, which employs alkali-catalyzed transesterification with KOH/methanol, was compared with saponification procedures
with and without transformation of sterols into silyl derivatives prior to analysis. Repeatability of the method was assessed,
and the coefficient of variation was 6.0 and 8.0% for β-sitosterol in olive and sunflower oils, respectively. Recovery of
β-sitosterol ranged from 92.6 to 95.8 for both oils. The GC method assayed in this work requires little analysis time and
eliminates the need for saponification, extraction, and derivatization steps. It offers good repeatability and recovery and
is thus well suited to routine use. 相似文献
17.
在1:1的盐酸介质中,以CuSO4为催化剂,Ca(H2PO2)2为还原剂,将砷还原为肉桂色单质胶体砷,砷在0~20ug/20ml范围内符合比耳定律。该方法应用于食品添加剂碳酸钠、碳酸氢钠和碳酸氢铵中微量砷的测定,结果良好。 相似文献
18.
Instrumental neutron activation analysis has become a standard technique for the study of the production and distributional patterns of archaeological pottery. Questions once framed within the context of long distance exchange are now focused on issues of subregional and even intrasite levels. The increasing specificity at which these questions are poised requires a high level of analytical precision as we seek to observe statistically and archaeologically significant differences among groups of pottery produced from geographically closely spaced resources or the compositional differences that arise from production behaviors of the producers of the pottery. 相似文献
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