Microstructures and thermoelectric properties of p-type pseudo-binary AgxBi0.5Sb1.5−xTe3 (x = 0.05–0.4) alloys prepared by cold pressing

The p-type pseudo-binary Ag_xBi_0.5Sb_1.5−xTe₃ (x = 0.05–0.4) alloys were prepared by cold pressing. The thermal conductivities (κ) were calculated from the values of heat capacities, densities and thermal diffusivities measured, and range approximately from 0.66 to 0.56 (W K^− 1 m^− 1) for the Ag_xBi_0.5Sb_1.5−xTe₃ alloy with molar fraction x being 0.4. Combining with the electrical properties obtained in the previous study, the maximum dimensionless figure of merit ZT of 1.1 was obtained at the temperature of 558 K.     

Effects of various environments on fatigue crack growth in Laser formed and IM Ti–6Al–4V alloys

The fatigue crack growth behaviors of Laser formed and ingot metallurgy (IM) Ti–6Al–4V alloys were studied in three environments: vacuum, air and 3.5% NaCl solution. Taking the Unified Fatigue Damage Approach, the fatigue crack growth data were analyzed with two intrinsic parameters, stress intensity amplitude ΔK and maximum stress intensity K_max, and their limiting values ΔK^* and . Fatigue crack growth rates da/dN were found increase with stress ratio R, highest in 3.5% NaCl solution, somewhat less in air and lowest in vacuum, and higher in IM alloy than in Laser formed one. In 3.5% NaCl solution, stress corrosion cracking (SCC) was superimposed on fatigue at R=0.9 for where K_max>K_ISCC, the threshold stress intensity for SCC. This and environment-assisted fatigue crack growth were evidenced by the deviation in fatigue crack growth trajectory (ΔK^* vs. curve) from the pure fatigue line where . Furthermore, the fractographic features, identified along the trajectory path, reflected the fatigue crack growth behaviors of both alloys in a given environment.     

Predicting fatigue transverse crack growth in cross-ply carbon–epoxy laminates from quasi static strength tests by using iso-damage curves

Cross-ply laminates made of carbon/epoxy IM7/977-2 system are investigated. The fatigue study is confined to ambient temperature conditions and zero loading ratio. Damage is characterized by the transverse crack density ρ in the central 90°-layer. The family of experimental fatigue cracking curves (ρ versus N, where N is the number of cycles, for each tensile test maximum stress amplitude) can be replaced with a set of “iso-damage curves”, i.e. contour curves of constant ρ in the σ–log (N) plane. The iso-damage curves approximately constitute a fan of straight lines that intersect at a common point (σ_e, log (N_s)), where N_s is a very large number of cycles beyond which no more crack appears, and σ_e is some fatigue limit.Our aim is to propose a simple method to predict fatigue cracking at an arbitrary maximum stress level loading by using data stemming from a constant strain rate test. This method essentially rests upon the construction of the above “iso-damage” curves, using very simple assumptions.     

Structural instabilities and superconductivity in La-214 compounds

In La_2–x Ba _x CuO₄ (LBCO) the transition to a low-temperature tetragonal phase and the suppression of superconductivity occur at the carrier concentration p 1/8 per copper. We will discuss the roles of various material parameters that control this instability. An unusual lattice softening has been found by ultrasonic measurement on La_2–x Sr _x CuO₄ (LSCO). This softening is present only in an in-plane shearing mode and is ascribed to the growth of structural fluctuations in the normal state.These phenomena are closely related because both the structural change in LBCO and the applied strain in LSCO lift the degeneracy of in-plane oxygen sites. They clarify the importance of strong coupling between the normal-state electronic system and the lattice by a Peierls-type mechanism.     

Fatigue resistance of silane-bonded epoxy/glass interfaces using neat and rubber-toughened epoxies

The influence that the energy absorbing ability of an epoxy has on the cyclic fatigue resistance of a silane-bonded epoxy/glass interface in moist air was studied using the double cleavage drilled compression (DCDC) test. The material properties of two epoxies with similar chemical structures were controlled through the manipulation of the molecular weight between cross-links, M _c, of the epoxy network. Two rubber-toughened epoxies with different nominal particle sizes (10–40 m and 1–2 m) were fabricated by adding a liquid butadiene/acrylonitrile copolymer to the epoxy resins. Mixtures of the silane-coupling agents 3-aminopropyltriethoxysilane (3-APES) and propyltriethoxysilane (PES) were used to treat the glass substrate in order to control the number of covalent bonds between epoxy and the glass. 3-APES has the ability to form primary bonds with both the epoxy and the glass, while PES forms primary bonds with only the glass. Experimental results showed that the manipulation of M _c had little effect on the cyclic fatigue resistance of the epoxy/glass interface. However, incorporation of rubber particles gave a significant improvement in the fatigue resistance. The rubber particles allowed the microscopic, non-linear deformation mechanisms of cavitation and shear yielding to dissipate energy during fatigue crack growth. Smaller particles gave the greatest improvement to fatigue resistance; about a 75% improvement compared to the neat (non-modified) epoxy. Adjustment of the number of silane bonds between the neat epoxies and the glass had little effect within experimental scatter on the fatigue resistance of the interfaces, suggesting that the energy dissipated through the breaking of bonds at the interface was insignificant compared to the energy dissipated through plastic and other inelastic deformation mechanisms in the epoxy.     

Effect of precipitates on damping capacity and mechanical properties of Ti–6Al–4V alloy

The present study was concerned with the effects of over-aging on damping property and fracture toughness in Ti–6Al–4V alloy. Damping property and toughness become important factors for titanium implants, which have big modulus difference between bone and implant, and need high damping capacity for bone-implant compatability. Widmanstätten, equiaxed, and bimodal microstructures containing fine α₂ (Ti₃Al) particles were obtained by over-aging a Ti–6Al–4V alloy. Over-aging heat treatment was conducted for 200 h at 545 °C. Fracture toughness, Charpy impact, and bending vibration tests were conducted on the unaged and the over-aged six microstructures, respectively. Charpy absorption energy and apparent fracture toughness decreased as over-aging was done, even if the materials were strengthened by precipitation of very fine and strong α₂-Ti₃Al particles. On the other hand, damping properties were enhanced by over-aging in Widmanstätten and equiaxed microstructures, but was weakened in bimodal microstructure due to the softening of tempered martensite and the decreasing of elastic difference between tempered martensite and α phase contained α₂ particles, etc. These data can provide effective information to future work about internal damping and fracture properties of Ti–6Al–4V alloy.     

Preparation of double-doped BaCeO3 and its application in the synthesis of ammonia at atmospheric pressure

Perovskite-type oxides BaCe_0.90Sm_0.10O_3−δ (BCS) and BaCe_0.80Gd_0.10Sm_0.10O_3−δ (BCGS) were synthesized by the sol–gel method and characterized by thermal analysis (TG-DTA), X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). Using the sintered samples as solid electrolytes and silver–palladium alloy as electrodes, ammonia was synthesized from nitrogen and hydrogen at atmospheric pressure in a solid-state proton-conducting cell reactor. The maximum rate of production of ammonia was 5.82×10⁻⁹ mol s⁻¹ cm⁻².     

Direct Observation of Fatigue Cracking in the Fuel Plate Using the Scanning Electron Microscope

Safety and environmental considerations play the important role in selecting and processing fusion materials. Fatigue impairs the reliability of the components utilized in the fusion reactor. In this paper, we described the fatigue cracking mechanism of the sandwich structure of dispersion U₃Si₂-Al fuel plates using the in situ scanning electron microscope. Direct observations indicated that the failure originates in the vicinal clad-meat interface under tensile-tensile cyclic and three points bending loading. The fatigue crack occurs in two typical fracture modes — Mode-I and the mixed-mode of I and II. The effect of the process of U₃Si₂-Al fuel meat on the fatigue behaviors of the sandwich structure is obvious.     

On assumptions associated with ΔKeff and their implications on FCG predictions

In this paper, an assessment of commonly used assumptions associated with ΔK_eff and their implications on FCG predictions in light of existing experimental and numerical data is presented. In particular, the following assumptions are examined: (1). ΔK_eff fully describes cyclic stresses and strains at the crack-tip vicinity. (2). K_op can be determined experimentally or numerically with certain accuracy. (3). Overload alters K_op but not K_max and associated σ_max at the crack-tip ‘process zone’. (4). Contact of crack faces curtails the crack driving force in terms of ΔK_eff.The analysis indicates that there is insufficient support to justify the above assumptions. In contrary, the analysis demonstrates that a two-parameter fatigue crack driving force in terms of ΔK and K_max, which accounts for both applied and the internal stresses should be used in FCG analyses and predictions.     

Fatigue Behavior of Ti-6Al-4V

Low-cycle-fatigue texts in vacuum and air were performed. Under cyclic loading the Ti-6Al-4V showed both cyclic hardening and cyclic softening depending on heat treatment, stress amplitude, and microstructure. Plastic deformation of the β-phase in the unaged condition due to stress induced martensitic transformation caused cyclic hardening. Cyclic softening was observed if the α-phase hardened by coherent Ti₃Al particles was plastically deformed. Equiaxed microstructures exhibited a stronger cyclic softening than lamellar structures. This behavior could be explained by the pronounced texture of the equiaxed microstructures, whereas the lamellar structures were texture-free. The fatigue life was influenced by the cyclic softening process mainly in the low-cycle-fatigue regime. The fatigue life at normalized stress amplitude (σ_a/σ_y) was shorter for microstructures with strong cyclic softening as compared to microstructures with lower cyclic softening.     

Study of (Bi4−x La x ) Ti3O12 Powders and Ceramics Prepared by Sol-Gel Method

La-modified (Bi_4–x La _x )Ti₃O₁₂ (abbreviated as BLT) powders were prepared by sol-gel processing methods. The powders were characterized by differential thermal analysis (DTA) and laser-diffraction particle-size analysis. The (Bi_4–x La _x )Ti₃O₁₂ ceramics were prepared from the powders and characterized by X-ray diffraction (XRD). The results indicate that the sol-gel method can be used to prepare nanometer powder for the new types of BLT ferroelectric ceramics. The solid reaction of BLT powders occurs at 730°C approximately resulting in the growth of BLT grain. The average grain size may be varied in the range 60–500 nm, depending on the calcination temperature of the powders. The (Bi_4–x La _x )Ti₃O₁₂ ceramics prepared from the powders were polycrystalline materials with completely monoclinic (Bi_4–x La _x )Ti₃O₁₂ phase.     

Current progress in ternary LREBa2Cu3Oy materials and their application

The J_c and H_irr values at 77 K of ternary light-rare-earth compounds, LREBa₂Cu₃O_y “LRE-123”, are usually high enough to serve in various applications. Several sources of vortex pinning can be in these composites tailored to fit the needs of the particular application. The list comprises LRE/Ba solid solution, oxygen vacancies, large particles of secondary phases, twin planes, nanoscale lamellas, etc. By means of the latter defects one can achieve a very high irreversibility field. Refinement of secondary phase particles and the optimal choice of their amount enhance the electromagnetic performance in a broad temperature range, up vicinity of T_c, allowing levitation at liquid oxygen, 90.2 K. An optimum content of MoO₃ doubles the self-field super-current at 77 K, H||c-axis. Altogether, the pinning tailoring in ternary LRE-123 materials provides a flexible and reliable way to fit the electromagnetic performance with the needs of sophisticated high-temperature and high-magnetic-field applications.     

Thermally activated rotation of Co1−xO particles within zirconia grains

Yttria partially stabilized zirconia (Y-PSZ) and Co_1−xO powders in 4:1 molar ratio were sintered and then annealed at 1300 and 1600°C to investigate the orientation change of Co_1−xO particles within Y-PSZ grains. Transmission electron microscopic observations indicated the Co_1−xO particles remained nonepitaxy in Y-PSZ grains after annealing at 1300°C for 300 h. When fired at 1600°C for 1–100 h, submicro-sized Co_1−xO particles (denoted as C) reached parallel epitaxy relationship, i.e. [100]_C//[100]_Z, [010]_C//[010]_Z and another relationship, i.e. [111]_C//[100]_Z, //[011]_Z with respect to the host zirconia grain (denoted as Z) nearly free of tetragonal precipitates. On the other hand, larger intragranular Co_1−xO particles (>1 μm in diameter) failed to reach epitaxial orientations even subject to prolonged annealing (100 h) at 1600°C. The temperature and size dependence of orientation change of the intragranular particle is in accordance with theoretical consideration of Brownian type rotation of the particle above a critical temperature for anchorage release at interface.     

Enhancement of Pinning Role by Nonstoichiometry in YBa2Cu3O7?y Superconductors

Considerably improved flux pinning and critical current density J c values have been achieved in Y-deficient Y-123 superconductors by directional solidification in air. In comparison with the regular Y-123 composition, Y-deficient one also has an orthorhombic structure and Y-123 main crystal phase remains in it. Whereas with the shortage of Y, Y_1–x Ba₂Cu₃O_7–y can be regarded as (YBa₂Cu₃)_1–x O_7–t(Ba₂Cu₃) _x O _t–y or (YBa₂Cu₃O_7–z )( _x ^YO _z–y ), so there may develop several kinds of microstructure defects as pinning sites in the system, such as highly dense, fine-scale, and faultlike defects, as well as localized superstructure, which are able to induce the increasing in flux pinning and J c values in higher external magnetic fields. This kind of simple nonstoichiometric route could lead to a commercial technique for flux-pinning enhancement in Y-123 bulk materials.     

Doping-induced microstructural, textural and optical properties of In2Ti1−xVxO5+δ semiconductors and their role in the photocatalytic splitting of water

The physicochemical properties of V-doped indium titanates (In₂Ti_1−xV_xO_5+δ, 0.0 ≤ x ≤ 0.2) were investigated by using XPS, powder XRD, UV–vis, SEM and luminescence spectroscopy techniques. The Rietveld refinement of XRD data revealed that even though the V-containing samples were isostructural with In₂TiO₅ (orthorhombic space group Pnma), a systematic x-dependent variation was noticeable in the Ti–O bond lengths in [TiO₆] octahedral units, cell parameters and in the value of δ. XPS results confirmed the coexistence of V⁵⁺ and V⁴⁺ states, leading thereby to an enhancement in oxygen non-stoichiometry in the doped samples. A loading-dependent progressive shift from 400 to 750 nm was also observed in the onset of the absorption edge, indicating a significant narrowing of the band gap. Furthermore, the samples with higher V-content were comprised of the grain clusters having larger size and an irregular shape. The UV–vis, photoluminescence and thermoluminescence studies indicate that the doping-induced lattice defects may give rise to certain closely spaced acceptor/donor energy levels in between the band gap of host matrix. The indium titanates are found to serve as stable photocatalysts for water splitting under visible light, where oxygen was the major reaction product. The role of microstructural and morphological properties in the photocatalytic activity is discussed.     

Preparation and characterisation of PPy/NanoGs/Fe3O4 conductive and magnetic nanocomposites

Nanocomposites composed of polypyrrole (PPy), graphite nanosheets (NanoGs), magnetite (Fe₃O₄) nanoparticles, have been successfully synthesised with a two-step process. First, we prepared NanoGs/Fe₃O₄ powder via wet chemical co-precipitation method. Next, pyrrole was polymerised in the suspension of NanoGs/Fe₃O₄ and then PPy/NanoGs/Fe₃O₄ nanocomposites were produced. The products were characterised by Fourier-transform infrared spectroscopy, Transmission electron microscopy, Thermogravimetric, conductivity and magnetisation analysis. The result showed that the conductivity of the PPy/NanoGs/Fe₃O₄ composites, compared with pure PPy, increased dramatically. And the saturation magnetisation of nanocomposites increased with the increase of the volume fraction of the Fe₃O₄ particles. In addition, according to the thermal gravimetric analysis, compared with PPy, nanocomposites exhibited enhanced thermal stability due to the introduction of NanoGs/Fe₃O_4. The PPy/NanoGs/Fe₃O₄ composites show potential applications in electric–magnetic shield materials.     

Luminescence properties of Sn2P2Se6 crystals

A large family of Sn_2yPb_2(1−y)P₂S_6xSe_6(1−x) semiconductor-ferroelectric crystals were obtained by the Bridgman technique. The photoluminescence properties of the Sn_2yPb_2(1−y)P₂S_6xSe_6(1−x) family crystals strongly depend on their chemical composition, excitation energy and temperature. The influence of the Pb → Sn and S → Se isovalent substitutions on the luminescence properties of a crystal with the Sn₂P₂Se₆ basic composition was investigated. A broad emission band observed in the Sn₂P₂Se₆ crystal with a maximum roughly at 600 nm (at T = 8.6 K) was assigned to a band-to-band electron-hole recombination, whereas broad emission bands, peaked near 785 nm (at T = 8.6 K) and 1025 nm (at T = 44 K) were assigned to an electron-hole recombination from defect levels localised within the bandgap. Possible types of recombination defect centres and specific mechanisms of luminescence in the Sn₂P₂Se₆ semiconductor-ferroelectric crystals were considered and discussed on the basis of the obtained results and the referenced data.     

Cyclic fatigue crack propagation of nanoparticle modified epoxy

An experimental study on the fatigue performance of nanoparticle modified epoxy was conducted. Seven material systems were examined which were: neat epoxy (E), 6 and 12 weight percent (wt.%) silica nanoparticle modified epoxy (S6, S12), 6 and 12 wt.% rubber nanoparticle modified epoxy (R6, R12), 3 wt.% each of silica and rubber nanoparticle modified epoxy (S3R3) and 6 wt.% each of silica and rubber nanoparticle modified epoxy (S6R6). Effects of those nanoparticles on the fatigue threshold (ΔG_th and ΔK_th) and fatigue crack propagation rates (da/dN) were studied. It was found that, compared to neat epoxy (E), nanosilica (S6, S12) increased ΔG_th (and ΔK_th) but nanorubber (R6 and R12) did not. However, a synergistic effect was observed on the fatigue threshold when both silica and rubber nanoparticles were added into epoxy. All these nanoparticles, individually or conjointly, decreased da/dN with silica the most effective. Morphology of the fracture surface was examined to understand the role of nanoparticles on toughening mechanisms under cyclic loading, which depended on the applied ΔG levels.     

Analyses of the fatigue crack propagation process and stress ratio effects using the two parameter method

In situ SEM observations (Zhang JZ. A shear band decohesion model for small fatigue crack growth in an ultra-fine grain aluminium alloy. Eng Fract Mech 2000;65:665–81; Zhang JZ, Meng ZX. Direct high resolution in-site SEM observations of very small fatigue crack growth in the ultra fine grain aluminium alloy IN 9052. Script Mater 2004;50:825–28; Halliday MD, Poole P, Bowen P. New perspective on slip band decohesion as unifying fracture event during fatigue crack growth in both small and long cracks. Mater Sci Technol 1999;15:382–90) have revealed that fatigue crack propagation in aluminium alloys is caused by the shear band decohesion around the crack tip. The formation and cracking of the shear band is mainly caused by the plasticity generated in the loading part of a load cycle. This shear band decohesion process has been observed to occur in a continuous way over the time period during the loading part of a cycle. Based on this observation, in this study, a new parameter has been introduced to describe fatigue crack propagation rate. This new parameter, da/dS, defines the fatigue crack propagation rate with the change of the applied stress at any moment of a stress cycle. The relationship between this new parameter and the conventional da/dN parameter which describes fatigue crack propagation rate per stress cycle is given.Using this new parameter, it is proven that two loading parameters are necessary in order to accurately describe fatigue crack propagation rate per stress cycle, da/dN. An analysis is performed and a general fatigue crack propagation model is developed. This model has the ability to describe the four general type of fatigue crack propagation behaviours summarised by Vasudevan and Sadananda (Vasudevan AK, Sadananda K. Fatigue crack growth in advanced materials. In: Fatigue 96, Proceedings of the sixth international conference on fatigue and fatigue threshold, vol. 1. Oxford: Pergamon Press; 1996. p. 473–8).