共查询到19条相似文献,搜索用时 125 毫秒
1.
2.
3.
4.
5.
2.1.3 聚合物基纳米复合材料的小结 除上述聚合物/无机纳米粒子复合材料、聚合物/有机插层改性无机纳米复合材料外,还有聚合物/聚合物分子复合材料。聚合物基纳米复合材料性能与用途见表5;聚合物基纳米复合材料的制法和应用汇总于图7;团聚的纳米粒子分散在聚合物基体中见图8;接技纳米粒子分散在聚合物基体中的可能结构见图9。2.2 在医药、生化、环保上应用前景2.2.1 在药物输运系统上应用 纳米技术导致药物制造和输运的根本改变,有望影响下个10年全世界价值3 800亿美元的药物市场的一半,其中美国公司的市场… 相似文献
6.
7.
8.
9.
无机/聚合物杂化纳米复合材料的研究综述 总被引:1,自引:0,他引:1
无机/聚合物杂化纳米复合材料是纳米材料发展的一个重要方面,本文介绍了纳米粒子效应,以及纳米复合材料的特殊性能,并详细介绍了无机/聚合物纳米复合材料的制备方法,最后对无机/聚合物纳米复合材料研究进行了展望. 相似文献
10.
11.
The present research focuses on a model system of a blend of two immiscible polymers containing an inorganic nanofiller, exploring the effect of various melt processing procedures on structuring and on the resulting properties. Binary polypropylene/alumina and ternary polypropylene/nylon/alumina composites were produced by batch compounding under various processing conditions and compositions. Several types of polypropylene and alumina grades were examined. The alumina nanoparticles vary primarily in their mean particle size (13, 50, 500 nm). The morphology of the nanocomposites produced and their thermal, and rheological properties were studied. It was found that under certain processing conditions the nanoparticles significantly affect the morphology of the polypropylene/nylon polymer blend causing compatibilization. Also, the alumina nanoparticles affect the melt viscosity of the polypropylene/nylon blends, whereas their effect on either polypropylene or nylon melts was found insignificant. POLYM. COMPOS., 27:425–430, 2006. © 2006 Society of Plastics Engineers 相似文献
12.
《塑料、橡胶和复合材料》2013,42(2):85-92
AbstractPolyethylene-based and polypropylene-based composites, incorporating silica nanoparticles and geopolymers, were prepared by melt compounding. Scanning electron microscope (SEM) images indicate that the silica nanoparticles do not distribute uniformly as fine particles in the matrix, but are unevenly distributed as clusters. As a result, the tensile properties of those composites are inferior to those of the matrix polymer. A novel concept of in situ formation of a reinforcing phase has been investigated as a method of resolving that problem. The reinforcing elements are microcrystalline phases developed during melt processing of mixtures of geopolymer precursors with polyethylene or polypropylene. Preliminary tensile test data on injection moulded specimens show some improvement in mechanical properties of both geopolymer–polyethylene and geopolymer–polypropylene composites relative to the matrix polymers. Scanning electron micrographs clearly show the presence in the composites of a nanoscale acicular crystalline structure that is thought to act as a fibre-like reinforcement. 相似文献
13.
This article presents a review of several research works on polypropylene/clay nanocomposites. In this study, we investigate the influence of preparation and treatment parameters of polypropylene/clay nanocomposite on the resulting thermomechanical properties. Compared to pure polymers and conventional composites, composites based on nanoclay particles are increasingly developed in industrial and academic fields as they promote an improvement of the starting polymers properties such as high modulus, heat resistance, gas impermeability, and biodegradability. The improvement of these properties depends on different parameters such as the content of clay and the nanoclay/polymer interaction. 相似文献
14.
综述了非常规新型导热粒子如纳米金刚石、碳化物、铁电陶瓷及其他无机功能粒子及其填充聚合物电介质的最新研究进展,重点探讨了新型导热粒子的含量、表面改性、加工方式等对聚合物复合材料的导热及介电性能的影响。介绍和分析了基于有机分子晶体为连续声子传递通路改性聚合物导热性能的研究及机理;在基体树脂内利用无机导热粒子及有机分子晶体可构筑连续的声子导热通路,从而达到降低界面热阻、提高体系热导率的目的。相比传统导热粒子,新型导热粒子在提高绝缘聚合物热导率的同时,还赋予体系其他物理性能如磁性、优良介电性能及储能等性能。 相似文献
15.
16.
Grafted inorganic nanoparticles can greatly improve the mechanical performance of polymers. To examine the effects of the interfacial characteristics generated by the grafting polymer bonded to nanoparticle surfaces, we chemically grafted nano‐silica with different polymers and then melt‐mixed it with polypropylene (PP). We extracted the homopolymers produced during the graft polymerization from the grafted products before the composites were manufactured to get rid of the side effects of the nongrafting polymers. We tailored the interfacial interaction between the grafted nano‐SiO2 and PP matrix by changing the amount of the grafting polymers on the nanoparticles, that is, the grafting percentage. Mechanical tests indicated that all the composites incorporated with grafted nano‐SiO2 particles possessed much higher impact strength than untreated SiO2/PP composites and neat PP. The greatest contribution of the particles was made at a low grafting percentage. Tensile measurements showed that the treated nanoparticles could provide PP with stiffening, strengthening, and toughening effects at a rather low filler content (typically 0.8 vol %) because of the enhanced interfacial adhesion resulting from molecular entanglement and interdiffusion between the grating polymers on the nanoparticles and matrix macromolecules. The presence of grafting polymers on the nanoparticles provided the composites with a tailorable interphase. The tensile performance of the composites was sensitive to the nature of the grafting polymers. Basically, a hard interface was beneficial to stress transfer, whereas a soft one hindered the development of cavities in the matrix. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 1771–1781, 2004 相似文献
17.
减摩耐磨用无机颗粒/高分子复合材料研究的进展 总被引:9,自引:1,他引:8
综述了减摩抗磨用无机颗粒/高分子复合材料的最新研究进展,重点阐述了不同类型无机颗粒的作用机理及其对复合材料最终性能的影响,指出这类材料的发展趋势在于应用纳米填料,通过发展适当的分散技术,同时加强粒子与基体的结合,有可能克服现有微米颗粒复合材料中存在的缺点,全面提高复合材料的综合性能。 相似文献
18.
The use of nanoparticulates in polymeric materials has become a potential alternative for organic–inorganic composite materials because of their versatility in property modification and ease of batch fabrication. This paper investigates the kneading and mechanical properties of polypropylene (PP) with added nano‐ZnO powder in sizes of 10–30 nm, through batch kneading and microinjection molding processes. The results show that the PP microgears with added ZnO nanoparticles are well replicated with clear structural definition. The resulting composites with a small amount of nanofiller added exhibit significant improvement in wear resistance and mechanical properties. The possible strengthening and wearing mechanisms is discussed based on the investigation of the worn and fractured surfaces of the composites. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 6009–6016, 2006 相似文献
19.
综述官能团化聚烯烃(FPO)在无机填料填充、增强、增韧,纤维增强、填充和阻燃等类型聚丙烯复合材料中的应用,并讨论了FPO改善复合材料界面粘结和提高力学性能的作用机理。 相似文献