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结合芜湖新兴铸管炼钢部RH自然脱碳冶炼低碳钢QD08的生产实际,从热力学和动力学的角度出发,考虑初始碳氧含量以及真空度变化等因素,研究RH的碳氧反应,系统分析和研究低碳钢QD08钢生产的工艺制度。RH真空处理过程中,随真空处理时间延长,真空度降低,真空室内PCO降低,碳氧浓度积呈降低的趋势,真空室内因发生碳氧反应进行脱碳,RH自然脱碳满足热力学条件;RH自然脱碳反应速度取决于:[C]、[O]元素在钢液内部的传质系数、真空处理时间、抽真空的速度和脱碳速率,并具有一定的规律。对RH自然脱碳及其反应机理进行探讨,并且为利用RH装置生产低碳钢提供了重要技术支持。 相似文献
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1 前言舞钢炼钢厂现有一台 90 t UHP电炉、两台 L F炉和一台 VD炉。按传统工艺 ,要生产 [C]≤0 .1 0 % ,尤其是 [C]≤ 0 .0 5 %的低碳钢是不能实现的。为满足市场对钢板品质的需要 ,我们试验开发了“真空自然氧脱碳”工艺 ,从而实现了低碳钢的生产。两年来 ,我们利用此工艺相继开发了WH70、X70、WDB62 0等低碳低合金高强高韧钢种。下面就对该工艺的理论基础和实际应用做简要陈述。2 真空自然氧脱碳机制真空自然氧脱碳原理与真空碳脱氧原理是一致的。换句话说 ,真空自然氧脱碳是根据真空碳脱氧原理反推出来的一种新的脱碳工艺 ,它们… 相似文献
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根据RH真空脱碳机理,结合本钢冶炼超低碳钢的生产实践,分析了脱碳时间和钢包等因素对钢水碳含量的影响,确定了超低碳钢的冶炼操作工艺以及降低钢液增碳的措施。 相似文献
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RH真空处理超低碳钢时脱碳速率的探讨 总被引:3,自引:0,他引:3
本文对RH真空处理冶炼超低碳钢时的脱碳速率进行了研究。通过对真空脱碳的基本速率方程的探讨,明确了影响真空脱碳速率的主要操作因素是环流气体流量和真空排气速度,并提出了加快RH脱碳速率的若干对策。 相似文献
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RH-KTB工艺生产超低碳钢 总被引:4,自引:0,他引:4
采用RH -KTB工艺大批量生产超低碳钢具有很多优越性。结合生产试验讨论了真空脱碳反应的机理及速率方程 ,分析了顶吹氧、真空度、钢水循环量等因素对脱碳速度的影响。 相似文献
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A novel three‐dimensional mathematical model proposed and developed for the non‐equilibrium decarburization process during the vacuum circulation (RH) refining of molten steel has been applied to the refining process of molten steel in a 90‐t multifunction RH degasser. The decarburization processes of molten steel in the degasser under the conditions of RH and RH‐KTB operations have been modelled and analysed, respectively, using the model. The results demonstrate that the changes in the carbon and oxygen contents of liquid steel with the treatment time during the RH and RH‐KTB refining processes can be precisely modelled and predicted by use of the model. The distribution patterns of the carbon and oxygen concentrations in the steel are governed by the flow characteristics of molten steel in the whole degasser. When the initial carbon concentration in the steel is higher than 400 · 10−4 mass%, the top oxygen blowing (KTB) operation can supply the oxygen lacking for the decarburization process, and accelerate the carbon removal, thus reaching a specified carbon level in a shorter time. Moreover, a lower oxygen content is attained at the decarburization endpoint. The average contributions at the up‐snorkel zone, the bath bulk and the free surface with the droplets in the vacuum vessel in the refining process are about 11, 46 and 42% of the overall amount of decarburization, respectively. The decarburization roles at the gas bubble‐molten steel interface in the up‐snorkel and the droplets in the vacuum vessel should not be ignored for the RH and RH‐KTB refining processes. For the refining process in the 90‐t RH degasser, a better efficiency of decarburization can be obtained using an argon blow rate of 417 I(STP)/min, and a further increase in the argon blowing rate cannot obviously improve the effectiveness in the RH refining process of molten steel under the conditions of the present work. 相似文献
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阐述了超纯铁素体不锈钢的超低碳氮的特点及其熔体降碳去氮困难的原因,利用真空降碳去氮的理论结合这方面的研究成果分析和讨论了影响VOD脱碳脱氮的影响因素,并利用VOD现场冶炼的具体数据进行了这些因素的统计分析,在此基础上提出了提高真空度、加强底吹氩搅拌强度、提高入炉钢液温度、提高人炉碳含量和降低人炉氮含量、增加VOD吹氧脱碳时的供氧量、高真空吹氩纯沸腾工艺、选用无碳、或低碳还原料等工艺技术措施,最后介绍了太钢这几年在VOD冶炼超纯铁素体不锈钢采取上述措施后所取得的效果。 相似文献
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在实验室利用石油液化气对钢中氧进行去除.研究结果表明:利用石油液化气对钢液脱氧是可行的,配合VD真空冶炼,可用于生产高碳、高质量洁净钢.钢液脱氧时,通入氩气和液化气两者的混合气体的脱氧效果优于单纯通入单一气体,钢中氧含量下降更明显,碳含量增加幅度更低.混合气体对钢液脱氧操作8 min后,钢中脱氧减慢,氧含量下降不明显.钢液脱氧的起始阶段,钢中碳含量增加较为缓慢,当钢中氧含量降低到一定水平后,钢中碳含量迅速增加.通入氩气,加强了钢液搅拌,在一定程度上抑制钢中氢含量的增加速度,促进了钢中氢的去除. 相似文献
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According to the analysis related to kinetic mechanism of vacuum denitrogenation and combining with the actual production of RH-MFB (a combination of Ruhstahl-Hausen vacuum degassing process with a multifunctional oxygen lance) at Liansteel, the limit step and model equation of vacuum denitrogenation are determined. Meanwhile, the influencing factors of nitrogen removal from liquid steel in vacuum of RH-MFB are analyzed. The results show that the limit step of vacuum denitrogenation in RH-MFB is the mass transfer of nitrogen in liquid boundary layer and the reaction follows first order kinetics. Keeping the necessary circulation time under the working pressure (67 Pa) is helpful to nitrogen removal from steel. The oxygen content in molten steel has little influence on the removal of nitrogen after deep deoxidation, while the sulphur content in liquid steel is always relatively low and has little effect on denitrogenation. The sharp decrease of carbon content in steel drives the process of denitrogenation reaction so as to exhibit a faster denitrogenation rate. The interfacial chemical reaction and argon blowing play a major role in the nitrogen removal when the carbon content in liquid steel is stable. 相似文献
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莱钢采用BOF-LF-CC工艺流程生产20CrMnTiH齿轮钢,在不经过VD炉真空处理的情况下,通过提高转炉终点碳命中率,使用组合式挡渣工艺,优化转炉底吹流量及钢包底吹氩模式,转炉全铝一次脱氧,调整精炼渣系,提高大包长水口密封性,避免钢水吸氧二次氧化,引进钢包下渣自动监测系统等工艺优化改进措施,有效降低了铸坯全氧含量,平均铸坯全氧含量达到了0.001 3%。 相似文献
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从转炉冶炼、LF精炼以及连铸工艺角度,对帘线钢盘条全氧含量控制技术进行了研究,形成了以转炉高碳出钢、夹杂物塑性化处理、钢液弱吹氩、增加连浇换包过程钢液重量和连铸保护浇注等为特点的控制技术,使鞍钢帘线钢盘条全氧含量控制在0.001 5%~0.002 0%。 相似文献