Sintered Sm2(Co, Fe,Cu,Zr)17 magnets withlight rare earth substitutions

The effects of partial substitution of light rare earths for Sm in (Sm_1-xR_x)₂ (Co,Fe,Cu,Zr)₁₇ have been investigated where R=Ce, Pr, Nd, Pr_0.5Nd _0.5, Ce_0.2Pr_0.4Nd_0.4 and x=0-0.5. Experiments show that both remanence and maximum energy product are improved for x=0.1-0.2, depending upon compositions and heat treatments. For a composition Sm_0.8R_0.2(Co_0.633Fe_0.286 Cu_0.061Zr_0.020)_7.59 with R =Ce_0.2Pr_0.4Nd_0.4, the authors obtained B_r=11.57 kG, _MH_c =15.5 kOe, _BH_c=10.33 kOe, H_k=10.03 kOe, and (BH)_max=30 MGOe     

Digital correction of A/D conversion error due to multiplexingdelay

A measurement channel which consists of a multiplexer, sample-and-hold circuit, and analog-to-digital (A/D) converter is studied. It is designed for the synchronous sampling and measurement of two or more voltage signals V₁(t), V ₂(t), . . ., but the finite time of A/D conversion (ΔT) makes it impossible to acquire consecutive samples closer in time than ΔT. This can become a source of measurement error if further processing of the measurement data is based on the assumption of ideal synchronism. It has been found that interpolation filters, developed from the Lagrange polynomial interpolation, are useful tools for solving the problem of correction. An illustrative example of their use is presented     

An uncertainty analysis for the measurement of intrinsic propertiesof materials by the combined transmission-reflection method

The uncertainty of measurements of the complex permittivity ϵ_r and permeability μ_r as a function of the normalized sample length l/Λ' due to the measured errors in the scattering coefficients S₁₁ and S ₂₁ is discussed. A simple analysis of ϵ_r and μ_r and some measured data are given, which allows one to determine the extent of l/Λ' and maximum uncertainty of the combined total transmission-reflection method in application to radar absorber measurements     

Annealing behavior of magnetic anisotropy in CoNbZr films

The effect of magnetic and nonmagnetic annealing on the magnetic anisotropy in CoNbZr films, formed by a DC opposing-targets sputtering method, was investigated. It was revealed that the origin of the magnetic anisotropy is the directional ordering of the magnetic atoms. The anisotropy fields and the direction of the easy axis obtained when the films are annealed in zero magnetic field are almost the same as those for the magnetic field parallel to the easy axis of the as-deposited films. When the films are annealed in a magnetic field perpendicular to the easy axis, the anisotropy field induced in parallel with the magnetic field, H_k(t), is well represented by the following formula: ln {1-H_k(t )/H_k(∞)∝-√Tt, where H_k(∞) is the thermal equilibrium value of the anisotropy field and D is the diffusion constant. The activation energy of the as-deposited film is 0.86 eV. Annealing the film increases the activation energy which is 2.1 eV when the film is annealed at a temperature of 450°C for 2 h     

NiTi substituted hexaferrites for magnetic recording

In order to obtain hexagonal ferrites with improved characteristics for application in the field of the magnetic recording, the ferrimagnetic Sr(NiTi)_x Fe_12-2xO₁₉ system is studied. Preliminary investigations suggested that NI is more effective than Co in reducing the magnetic anisotropy of hexaferrites. The system was analyzed as a function of the degree of substitution x and of the reaction temperature T_R and time τ. The reactivity of the mixtures and their magnetic characteristics (σ, H_c, H_A, T_c) were measured, and from the _χT(H) data it was possible to distinguish between single-domain or polydomain particles. The results are presented. The influence of the extraneous magnetic phases on the coercive field value was also studied and a preliminary investigation of the relation between coercive and anisotropy fields was carried out     

Automatic technique for measuring the Polder resonance in ferritespheres

An automatic technique for measuring the parameters of Polder resonance in polycrystalline ferrite spheres is proposed. The diagonal elements of the external susceptibility tensor versus DC magnetic field are calculated from the changes in resonance frequency and unloaded Q factor of a microwave cavity by perturbation theory. From these diagonal elements, all the elements of the intrinsic permeability tensor can be obtained. By fitting the theoretical curves to experimental data, the parameters of Polder resonance, ΔH M_s, and the g factor, are simultaneously calculated. The whole measurement procedure is controlled by a desktop computer. An accuracy of 5% is obtained in ΔH and M _s, and of 0.1% in the g factor     

Grain size dependence of coercivity and permeability innanocrystalline ferromagnets

Amorphous ribbons of composition Fe_74.5-xCu_xNb₃Si_13.5B₉ (x=0, 1 at.%) have been annealed between about 500°C and 900°C. This produced a series of crystallized samples with grain sizes between about 10 nm and 300 nm and with coercivities H _c and initial permeabilities μ_i varying over several orders of magnitude. The best soft magnetic properties (H _c≈0.01 A/cm and μ_i≈80×10³ ) were observed for the smallest grain sized of about 10 nm. With increasing grain size D, coercivity steeply increases following a D⁶-power law (up to D≈50 nm). H_c then runs through a maximum of H_c≈30 A/cm and decreases again for grain sizes above 150 nm according to the well-known 1/D law for polycrystalline magnets. The initial permeability was found to vary in a similar manner, essentially being inversely proportional to coercivity. The variation of the soft magnetic properties with the average grain size is discussed and compared with the predictions of the random anisotropy model and other theories for the magnetization reversal     

Magnetic properties of Sm2Fe17Nxpowder and bonded magnet

Sm₂Fe₁₇N_x powders were prepared through metallurgical processes such as melting, casting, pulverizing, and gas nitrogenation. Epoxy resin and zinc-bonded magnets were prepared from the powder by a compression molding process. The magnetic properties of magnetically aligned Sm₂Fe₁₇N_x powder were (BH)_max=170 kJ/m³ (21.4 MG-Oe), Br=1.20 T, and H_cJ=547 kA/m (6.87 kOe). Those of an epoxy-bonded magnet were (BH)_max =103 kJ/m³ (13.0 MG-Oe) and Br=0.835 T. H _cJ values in excess of 2 MA/m (25 kOe) were observed in the case of a zinc-bonded magnet     

Effect of stress on the law of approach to saturation magnetizationin carbon steels

In high fields where the magnetization is approaching saturation, the resolved magnetic polarization I can be expressed by a power series of the inverse of external field H as: I=I_s-b/H ²-c/H³ . . ., or alternatively in terms of the reversible permeability μ_rev=1+(2b/H³+3c/H⁴+ . . .)/μ₀ where I_s is the spontaneous magnetic polarization and b, c, are constants. These equations express the law of approach to saturation magnetization. The coefficient b for a cubic crystal has been deduced as b=0.0762/I_s[K+1.5(λ₁₀₀-λ ₁₁₁)σ]², where σ is the applied stress and others are magnetic constants. The values of reversible permeability μ_rev under biasing field H were measured for carbon steels with applied stresses. The results showed that the square root of 2b changed linearly with the applied stress, The values of magnetic constant K andλ₁₀₀ -λ₁₁₁ were calculated, They agreed with the standard values, but were affected by chemical composition and heat treatment of materials, especially in λ₁₀₀-λ₁₁₁     

A measurement of the NBS electrical watt in SI units

The National Bureau of Standards (NBS) electric watt in SI units to be: W_NBS/W=K_W =1-(16.69±1.33) p.p.m. The uncertainty of 1.33 p.p.m. has the significance of a standard deviation and includes the best estimate of random and known or suspected systematic uncertainties. The mean time of the measurement is May 15, 1988. Combined with the measurement of the NBS ohm in SI units: Ω_NBS/Ω=K_Ω =1-(1.593±0.022) p.p.m., this leads to a Josephson frequency/voltage quotient of E_J=E₀[1+(7.94±0.67) p.p.m.] where E₀=483, 594 GHz/V     

Properties of the W-type hexaferritePbZn2Fe16O27

W-type Pb-hexaferrites were prepared by standard ceramic methods. The lattice constants found by refinement were a=0.59140±0.00006 nm and c=3.29209±0.00041 nm. The X-ray density of a typical composition PbZn_1.9Fe_15.3O_25.8 was ρ=5.32 g/cm³ and the Vickers microhardness value h _v=6 kN/mm². A plot of the saturation magnetization versus temperature is given. The extrapolated value of the saturation magnetization (H→∞, T→0) was σ_s=108 emu×g^-1, and the Curie temperature was T_c=600±20 K     

Determination of overwrite specification in thin-film head/disksystems

A self-consistent write analysis using the Preisach model is presented and used to calculate overwrite in thin-film head/disk systems. Two overwrite characterization procedures are discussed, and for each of the procedures the calculated values are compared with measurements. Through a correlation of overwrite, nonlinear peak shifts, and readback output voltage the authors determine the overwrite requirement. They show that whereas -30 dB of overwrite will ensure a satisfactory overall performance of the recording system, a much lower overwrite, say -20 dB, can work in certain situations. An analytical implementation of the self-consistent model is presented and verified with measurements. The analytical approach can be used to determine the overwrite at any applied field for any head/disk combination. The authors introduce a normalized effective field h_n, which depends on M_rδ, H_c, and other head/disk parameters. It is shown that a value of h _n greater than 0.8 is needed for overwrite values of better than 25 dB. The importance of various head/disk parameters in optimizing the overwrite is also discussed     

Ta additive effect on RF magnetron sputtered CoCr films

Magnetic properties for sputtered CoCrTa films (18 at.% Cr and 2.0-3.0 at.% Ta), which were deposited under various background pressures P_i, and argon sputtering pressures, P _Ar, have been examined. The perpendicular anisotropy field H_k for CoCrTa films maintains high values of 5-6 kOe in a wide range of P_i and P_Ar , as compared with that for CoCr films. In order to optimize Ta composition, magnetic properties and crystalline microstructures for Ta additive content (0-4.0 at.%) have been investigated. H_k and perpendicular coercivity H_c⊥ increase with increasing Ta concentration above 2.0 at.% Ta. C-axis orientation is improved by adding Ta to CoCr films. However, above 3.0 at.% Ta, H_c⊥ steeply decreases and domain wall motion is observed, owing to the increase in crystalline grain size. The appropriate Ta composition is 2.0-3.0 at.%     

Free-space measurement of complex permittivity and complexpermeability of magnetic materials at microwave frequencies

A free-space measurement system operating in the 8.2-40-GHz frequency range is used to measure the reflection and transmission coefficients, S₁₁ and S₂₁, of planar samples. The complex electric permittivity and the magnetic permeability are calculated from the measured values of S₁₁ and S₂₁. The measurement system consists of transmit and receive horn lens antennas, a network analyzer, mode transitions, and a computer. Diffraction effects at the edges of the sample are minimized by using spot-focusing lens antennas. Errors due to multiple reflections between antennas via the surface of the sample are corrected by using a free-space TRL (thru, reflect, line) calibration technique. For thin, flexible samples, the sample had to be sandwiched between two half-wavelength (at mid-band) quartz plates to eliminate sagging. Results are reported in the frequency range of 8.6-13.4 GHz for materials such as Teflon, sodium borosilicate glass, and microwave-absorbing materials     

Computation of 3-D current driven skin effect problems using acurrent vector potential

A finite element formulation of current-driven eddy current problems in terms of a current vector potential and a magnetic scalar potential is developed. Since the traditional T-Ω method enforces zero net current in conductors, an impressed current vector potential T₀ is introduced in both conducting and nonconducting regions, describing an arbitrary current distribution with the prescribed net current in each conductor. The function T ₀ is represented by edge elements, while nodal elements are used to approximate the current vector potential and the magnetic scalar potential. The tangential component of T is set to zero on the conductor-nonconductor interfaces. The method is validated by computing the solution to an axisymmetric problem. Problems involving a coil with several turns wound around an iron core are solved     

Lateral magnetic inhomogeneities in Co-Cr layers detected by FMR

Co-Cr layers deposited on Ge underlayers were investigated with ferromagnetic resonance (FMR). The thickness of the Co-Cr layers and the substrate temperature (T_s) during deposition were varied. Measurements with a vibrating sample magnetometer showed that an increase of T_s results in an increase of both the bulk saturation magnetization M_s and the perpendicular coercivity H_c^⊥. The FMR spectra, obtained with the applied field perpendicular to the sample, showed two resonances for all layers. The effective anisotropy field is positive for both resonances. The difference in effective anisotropy field does not change with thickness of the layer, but increases with increasing T_s. From this it is clear that the two resonances are not due to magnetic inhomogeneities in the growth direction, but must be due to lateral magnetic inhomogeneities. Inhomogeneities in composition, resulting in different values of M _s, or in geometric structure, resulting in different values of the demagnetizing factor N_d, are the most probable causes of the observed effects     

Multirate polynomials prediction with unevenly spaced samples

A method for polynomial prediction with unevenly spaced samples is proposed for dynamic upsampling purposes, frequently needed in digital signal-processing applications. The procedure is based on Newton's divided-difference interpolation formula, which allows prediction along a polynomial of degree n if the samples are arbitrarily spaced. For this purpose, it is necessary to store n+1 latest values pairs (x_i, u_i) where x _i is the time instant when the sample y_i is available. Based on the (x_i, y_i ) pairs, the algorithm predicts y-samples for arbitrary values of x. Noise reduction techniques based on bandwidth limiting are discussed. As an application, a velocity measurement system is considered, based on pulse-width measuring, where the primary interest is in improving the accuracy at very low speeds     

Magnetic properties of GdBa2Cu3O7crystals in high magnetic field

The magnetic properties of single crystals of GdBa₂Cu ₃O₇ were investigated in a magnetic field of up to 20 T applied parallel to the c axis in the 1.7-300 K temperature range. In the superconducting state, the field and temperature dependences of the critical current densities were deduced from the hysteresis of the half-cycle using Bean's critical state model. The Gd³⁺ paramagnetic moment was then studied. Above about 20 K, the M(H) isotherms were found to be given, at different temperatures, by the Brillouin function of the free Gd³⁺ ion. Below 20 K, the average magnetization does not obey the Brillouin law. The normal-state susceptibility was described by the free-ion Curie-Weiss law     

Cr migration in CoNiTa/Cr films by annealing

CoNiTa/Cr double-layered films for longitudinal magnetic recording media have been prepared by using the facing targets sputtering apparatus. Substrate heating and postannealing were performed in order to increase the coercive force H_c. While the as-deposited film at the substrate temperature T_s of 400°C had H_c of 780 Oe, the films deposited at T_s of room temperature, exposed to atmosphere, and annealed at 400°C, had H_c as high as 1700 Oe. It has been found that the same amount of Cr atoms migrated from the underlayer to the magnetic layer and the vicinity of the film surface. Consequently, such a large increase of H_c seemed to be caused by isolation of magnetic grains by Cr atoms in their boundaries     

Quantized Hall resistance measurements

The quantized Hall resistances, R_H(4), of Si MOSFETs were measured at ≈0.5 K in a magnetic field of 15 T. The value of R_H(4) was determined in terms of the Commonwealth Scientific and Industrial Research Organization (CSIRO) realization of the SI ohm. A weighted mean of three determinations gave a value for the quantity R_H(4) of (6453.203,36(52)) Ω_SI-NML which can also be expressed as 6453.2(1.000,000,52(8)) Ω_SI-NML. This R_H (4) value gives a value for h/e² which is about 0.3 p.p.m. larger than the value for h/e² derived from the anomalous moment of the electron, using the quantum electrodynamics (QED) theory