碳材料在橡胶中的应用研究进展

综述各种碳材料复合橡胶的发展及研究进程,主要介绍石墨烯、氧化石墨烯、碳纳米管等碳系材料结构、功能化方式及橡胶复合材料加工方法。碳材料不仅能较大幅度地改善橡胶的各种基础性能,而且可赋予橡胶很多新的功能,如热量传导、电荷传输,因而能够提高橡胶制品性价比和档次。     

碳纳米材料在橡胶中的应用研究进展

介绍了新型零维碳纳米材料(富勒烯、炭黑-白炭黑双相粒子)、一维碳纳米材料(碳纳米纤维、碳纳米管)以及二维碳纳米材料(石墨烯、氧化石墨烯)在橡胶中的应用研究进展,指出了碳纳米材料今后的研发方向。     

碳纳米材料在橡胶材料中的应用研究进展

综述碳纳米材料在橡胶材料中的应用研究进展。介绍纳米石墨、碳纳米管、石墨烯、纳米金刚石以及炭黑-白炭黑双相纳米填料(CSDPF)的物化性质及其对橡胶材料性能的影响。碳纳米材料不仅能够改善橡胶材料的物理性能,而且能够赋予橡胶材料导电和导热等性能。碳纳米材料/橡胶复合材料的开发及应用发展潜力大,是功能性橡胶材料的一个重要发展方向。     

钾离子电池负极材料的研究现状

近年来,可充电钾离子电池(KIBs)的开发受到人们的广泛关注.碳基材料的来源丰富,廉价,无毒,安全,广泛的可行性研究表明,它们可以成为很有前途的KIBs负极材料.本文综述了石墨、石墨烯、硬碳材料和软碳材料等新型碳基材料的钾离子存储性能及其电化学性能,讨论了KIBs面临的关键问题,指出了KIBs的发展方向.     

碳材料增强PA复合材料的研究进展

综述了高性能碳材料对尼龙(PA)改性的研究成果。简要介绍了目前应用于PA改性上的高性能碳材料，包括碳纳米管、石墨烯、碳纤维及石墨等，介绍了高性能碳材料的结构与性质特点。分析了碳纳米管、石墨烯、碳纤维及石墨材料对改性后PA复合材料力学、热力学及电学等性能的影响。最后对高性能PA复合材料目前存在的问题及未来发展趋势进行了展望。     

石墨烯及其衍生物在有机硅材料中的应用研究进展

石墨烯是目前已知最轻薄的材料,其衍生物包括:氧化石墨烯、还原氧化石墨烯、石墨烯纳米片、三维石墨烯等,它们具有其它碳基材料不具备的超强特性,如高比表面积、高电子迁移率、高阻隔性、低密度等,在很多前沿领域(如高性能复合材料、光热纳米流体、储能电极、柔性显示屏)都可见其应用.本文介绍了石墨烯及其衍生物在硅橡胶、硅烷偶联剂、硅...     

轻质碳材料及其复合物在固体推进剂中的应用研究进展

从催化固体推进剂组分、调节推进剂燃烧性能等方面综述了轻质碳材料及其复合物在推进剂中的应用研究进展,分析了富勒烯、氧化石墨烯、碳纳米管等碳材料及其复合物对推进剂组分热分解的不同催化效果及对推进剂燃烧性能的调节作用。介绍了活性炭纤维、石墨等在推进剂制造、废旧推进剂处理等方面应用的研究进展,指出了今后轻质碳材料在固体推进剂中应用的重点研究方向。附参考文献40篇。     

新型碳纳米材料／聚合物吸波材料研究进展

传统的吸波材料由于密度大、吸收频带窄使其应用受到限制,新型吸波材料的探索和研究将成为吸波材料领域的主要发展方向。本文介绍了新型碳纳米材料（碳纳米管、碳纳米纤维、石墨烯）在聚合物吸波材料中的应用,展望了碳基吸波材料的发展前景。     

石墨烯复合材料的研究及其应用

综述了石墨烯复合材料的结构和分类,主要包括石墨烯-纳米粒子复合材料、石墨烯-聚合物复合材料和石墨烯-碳基材料复合材料,并简述石墨烯复合材料在催化领域、电化学领域、生物医药领域和含能材料领域的应用。     

聚氯乙烯和碳纳米材料复合研究进展

聚氯乙烯/碳纳米材料制成的复合材料具有良好的机械性能、耐磨性能、电磁性能、耐热性能,是近年来备受关注的新兴材料。本文综述了聚氯乙烯与石墨(GT)、石墨烯(GN)、氧化石墨烯(GO)和碳纳米管(CNT)等碳纳米材料复合的研究进展,阐述了各种复合材料的优势、劣势及研究开发进展情况,为将来拓宽碳纳米材料的用途提供了参考作用。     

Graphene/carbon black/natural rubber composites prepared by a wet compounding and latex mixing process

The extensively used latex mixing approach to prepare graphene can improve the graphene dispersion but meets some challenges in the preparation of high content carbon black filled rubber system like a rubber tire. Owing to the high melt viscosity of the rubber/graphene masterbatch, the dispersion of carbon black is not perfect during twin-roll mixing and some aggregates will be formed. Here we proposed a wet compounding process, combined with ultrasonically assisted latex mixing, named as the WCL method to prepare reduced graphene oxide/carbon black/natural rubber (rGO/CB/NR) composites. The morphological observations confirmed that both graphene and carbon black can be evenly dispersed in the rubber composites. The incorporation of rGO also improves the hardness, thermal conductivity and anti-aging properties of the composites. The rGO/CB/NR composites prepared by the WCL method possess better mechanical properties compared to conventional latex mixing. The entanglement-bound rubber tube model was utilised to understand the reinforcing mechanism.     

石墨烯/橡胶复合材料的结构设计与性能研究进展

综述了近年来石墨烯/橡胶复合材料结构设计的研究进展,介绍了石墨烯/橡胶复合材料的制备方法,重点阐述了石墨烯的不同改性方法及复合材料的界面结构对石墨烯/橡胶复合材料性能的影响,最后对石墨烯/橡胶复合材料的结构设计和性能研究面临的挑战和发展方向进行了展望。     

Aspects of producing hydrogenated nitrile butadiene rubber (HNBR) nanocomposites by melt compounding processing

Industry is constantly demanding for materials with differential properties that explores nanoscale fillers functionality. Unfortunately, most of the papers present processing methods that are hard to scale up. Effects in addition different amounts of multiwall carbon nanotubes (MWCNT) and few-layer graphene (FLG) on cure behaviour, viscoelastic, mechanical and electrical properties of a hydrogenated nitrile butadiene rubber (HNBR) are investigated and compared with those composites having carbon black (CB) as filler. Looking for scale up the produced nanocomposites, rubber composites were produced in a closed mixing chamber by melt mixing with unmodified fillers. Addition of nanotubes reduces curing time. Microstructural analyses indicate that FLG cannot be easily dispersed by this methodology. Significant improvement in mechanical properties is observed with MWCNT addition, with 940% modulus increment regarding to the pure polymer and also, in lower intensity, in HNBR/FLG composites. Moreover, HNBR/MWCNT composites presented a sharp reduction in electrical resistivity at low loading level.     

煤基石墨烯及复合材料在储能领域的应用

石墨烯及复合材料具有比表面积大、电导率高、导热性能和力学性能良好等优点,在电极材料、传感器、储氢材料等领域具有广泛的应用。但以高碳含量的天然资源煤为前体制备煤基石墨烯及复合材料达到煤炭清洁高效利用的研究目前报道有限,尤其是将其作为电极材料应用到储能领域的研究较少。本文重点总结了以不同煤质及衍生物为原料构建不同形貌和结构的煤基石墨烯及复合材料的方法以及存在的问题,详细介绍了煤基石墨烯及复合材料在储能领域,尤其是超级电容器、锂离子电池及钠离子电池领域的应用研究现状,最后提出了当前煤基石墨烯及复合材料的主要研究方向。该综述旨在为煤基新型石墨烯及复合材料的制备开发以及在储能领域的应用提供一定的思路。     

Mechanical and Barrier Properties of Bromo–Butyl Elastomers Filled with Electrochemically Exfoliated Graphene

In this paper, the effects of graphene loading and processing technique on the morphological, mechanical, thermal, rheological, and barrier properties of bromo–butyl rubber, are explored. Bromo–butyl rubber composites with electrochemically exfoliated graphene (EEG) nanosheet filler are prepared via solvent casting and/or melt blending techniques, and their properties are compared against a carbon black control sample. Even though analysis of the EEG composites via microscopy reveals agglomeration problems not present in the carbon black controls, EEG composite samples are observed to have improved barrier properties over carbon black samples in exchange for slightly reduced stress and strain at break. Extensional rheological analysis of the bromo–butyl rubber composites reveals strain hardening phenomena in all the samples and higher extensional modulus in solvent casted-melt blended (SCM) samples. As a result of better dispersion over the solely melt-blended samples, the SCM rubber composites exhibit superior tensile modulus and extensional modulus compared to the samples that are solely melt-blended.     

Functionalized graphene‐reinforced rubber composite: Mechanical and tribological behavior study

A functionalized graphene, fluorinated graphene nanosheets (FGS), and SiO₂ nanoparticles as reinforcing fillers were employed to improve the mechanical properties of the solution styrene butadiene and butadiene rubber composites (SSBR‐BR). The results showed that the mechanical properties of SSBR‐BR composite filled with FGS were substantially improved than those of the unfilled and equivalent filler loaded graphene oxide (GO) and reduced graphene oxide (rGO) filled SSBR‐BR composites. It can be ascribed to the fact that the hydrophobic surface of FGS can be endowed the good dispersion in rubber matrix and stronger interfacial interaction between rubber and fillers. The tribological properties of these composites are also investigated. The results reveal that incorporation of GO, rGO, and FGS in SSBR‐BR composites can decrease antiwear properties because the existence of layered graphene promotes to tear and peel off. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134, 44970.     

石墨烯类材料的应用及研究进展

石墨烯是碳原子以sp²杂化形成的单原子层厚度的具有二维空间结构的晶体,具有优异的力学性能、导电性能以及超大的比表面积,且耐高温和耐酸碱腐蚀,被认为是非常有潜力的新型碳材料.本文从石墨烯的特殊结构和性能出发,结合近几年国内外的研究发展现状,综述了石墨烯在生物材料、薄膜材料、催化材料、储能材料等领域的应用.对石墨烯类材料在实际应用中存在的一些问题进行了简单的分析,并对未来石墨烯在电子器件、复合材料等方面的发展进行了展望.     

Preparation and properties of styrene‐butadiene rubber nanocomposites blended with carbon black‐graphene hybrid filler

Graphene has become an attractive reinforcing filler for rubber materials, but its dispersion in rubber is still a big challenge. In this work, a novel carbon black‐reduced graphene (CB‐RG) hybrid filler was fabricated and blended with styrene‐butadiene rubber (SBR) via simple two‐roll mill mixing. The prepared CB‐RG hybrids had a microstructure with small CB agglomerates adsorbed onto graphene surfaces. CB acted as a barrier preventing the RG sheets from restacking even after drying. Homogeneous dispersion of graphene sheets in SBR matrix was observed by the mechanical mixing method based on the application of the CB‐RG hybrid fillers. Dynamic mechanical analysis showed that Tg of the SBR/CB‐RG blend was higher than that of the SBR/CB blend indicating strong interfacial interactions between RG and SBR due to the high surface area of graphene and the π‐π interaction between SBR and graphene. The tensile properties of SBR/CB‐RG composites improved significantly and the volume resistivity decreased compared with the SBR/CB blends. The thermal stability of SBR composites filled with CB and CB‐RG showed slight difference. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41309.     

Enhanced dispersion of carbon nanotube in silicone rubber assisted by graphene

We report a novel, scalable and inexpensive approach to fully disperse carbon nanotubes in silicone rubber by the addition of graphene. In comparison to graphene, the dispersion of multi-walled carbon nanotubes (MWNTs) in silicone rubber matrix is extremely difficult although both of them possess similar physical structure. The different dispersion behavior of graphene and MWNTs could be contributed to the difference in their interaction with polymer matrix and their geometry. Based on SEM, TEM and XRD analysis, we find that the dispersion of MWNTs in silicone rubber is dramatically improved by the addition of graphene. Graphene acts as a compatilizer since it shows strong interaction with both polymer matrix and MWNTs. This method provides a simple route to enhance the dispersion of carbon nanotubes and improve the electrical property of the polymer composites. The synergic effect of the hybrid materials may not to be limited to the applications in polymer composites.     

氟橡胶纳米复合材料的应用研究进展

简述了橡胶纳米复合材料疲劳失效机理和对包括了硅藻土、纳米氧化锌、凹凸棒土、二氧化铈、石墨烯和碳纳米管在内的纳米填料填充改性氟橡胶的研究进展。