稀土阻燃镁合金研究进展

综述了稀土阻燃镁合金的阻燃机理及其研究的最新进展。相比单一稀土元素的添加,混合稀土可以更好的提高镁合金的起燃温度。     

加入钙和稀土对AZ91D镁合金起燃温度的影响

镁合金在熔炼及压铸过程中易发生氧化燃烧。在众多的阻燃方法中,以合金化阻燃方法的效果最为明显。研究了加入混合轻稀土和Ca对AZ91D镁合金起燃温度的影响,观察了镁合金的金相组织,测试了各合金试样的起燃点,并进行了总结与比较。结果表明,Ca对提高AZ91D镁合金的起燃点有显著的作用,加入量为2％时,起燃点可提高至768℃;混合轻稀土对AZ91D镁合金的起燃点的影响与钙相比,效果更加明显,稀土加入量为2％左右,起燃点达到802℃。稀土更有利于提高AZ91D镁合金的起燃温度。     

稀土镁合金的摩擦磨损性能

采用MMS-2A型环块式摩擦磨损试验机对稀土镁合金GW103K进行了摩擦磨损试验.试验结果表明:GW103K体积磨损量随着磨损时间和外载荷的增大而增大,当磨损时间超过30min,外载荷超过400N时,体积磨损量增大明显;摩擦因数在0.26~0.28之间变化.对摩擦副环块,转速与体积磨损量成正比,与摩擦因数成反比.     

稀土对Mg合金组织及阻燃性能的影响

针对普通镁合金在熔铸和加工过程中易氧化燃烧的问题,研究了稀土对镁合金阻燃性能的影响.在溶剂保护条件下熔炼制备了含0.8%稀土的Mg-8Al-0.8Zn-0.2Mn合金,测定了合金的起燃温度,采用金相观察和XRD方法分析比较了合金在添加稀土前后的铸态显微组织.结果表明,稀土元素的加入可十分有效地提高镁合金的燃点,比未加RE时提高了175℃.同时,稀土的加入还使合金晶粒组织显著细化,强化相增多,从而导致合金的硬度也有明显提高.因此,作为合金元素,稀土不仅可改善镁合金的组织和力学性能,而且具有良好的阻燃作用效果,故含稀土的阻燃镁合金具有开发应用前景.     

镁合金的阻燃研究现状

介绍了镁合金阻燃的研究现状及进展,重点介绍了稀土合金化阻燃的研究。最后得出结论：混合稀土合金化阻燃镁合金是发展阻燃镁合金的方向。     

阻燃镁合金性能的研究

以AZ91D镁合金为例,论述添加起阻燃作用的金属元素之后,镁合金的阻燃性能、物理性能和化学性能的变化及其在生产中的实用价值.最后对阻燃镁合金的研究提出一些建议.     

CeO_2原矿制备含Ce稀土镁合金的组织和性能

将一定比例CeO2和精炼剂混合,在精炼过程中溶入到AM50镁合金中,制备成含Ce稀土镁合金。结果表明,当稀土的添加量为0.8wt%时,晶粒细化程度达到最大,有较多的Al11Ce3相析出,镁合金的抗拉强度和延伸率性能达到最好;当超过0.8wt%时,晶粒开始粗化,有更多的针状Al11Ce3相析出,镁合金力学性能会从高点下降。     

镁合金阻燃技术研究

镁合金具有比重小、比强度和比刚度高、阻尼性能好、易切削加工等优点,是目前工业上可应用的最轻的金属结构材料,它电磁屏蔽能力强,压铸工艺性能优异,易加工,可再生利用.因此镁合金被广泛应用于汽车、电子工业、航空航天等领域.但由于镁的化学性质活泼,非常容易氧化、燃烧,导致镁合金无法在大气条件下直接进行熔炼和浇注.因此,镁合金阻燃技术研究已经成为人们所关注的重要课题.     

镁合金在车用轻量化材料中的应用

车用轻量化材料的选择标准并非只要质轻就可以的,汽车材料必须满足的前提是在各种工况和环境下都保证能满足机械、热力、化学等各方面的要求,此外,还有抗腐蚀、抗老化、抗冲击变形等,用于轻量化的材料要满足的条件是十分苛刻的,介绍了镁合金在车用轻量化材料的实际应用。     

Ignition-proof mechanism of ZM5 magnesium alloy added with rare earth

The ignition-proof mechanism of ZM5 magnesium alloy added with 0.1% (mass fraction) rare earth (RE) was investigated. The oxide scales and substrates were characterized by scanning electronic microscope (SEM), X-ray diffraction (XRD), energy dispersive spectrometer (EDS) and tensile test. And an oxidation model of ZM5 alloy with RE was established. The results show that the ignition temperature of ZM5 alloy is particularly elevated from 654 to 823 ℃, the microstructure is refined, and the tensile strength i...     

Effects of rare earth elements on the microstructure and properties of magnesium alloy AZ91D

The effects of rare earth elements on the microstructure and properties of Magnesium alloy AZ91D alloy were studied.The different proportion of rare earth elements was added to the AZ91D and the tensile tests were carried out at different temperatures.The experimental results show that at room temperature or at 120℃ the AZ91D‘s decrease with the increasing amount of the rare earth elements.however,the ductility is improved.The influence of 0.14%Sb(mass fraction)on the AZ91D‘s strength is like that of rare earth elements(0.2%-0.4%)(mass fraction).Microstructure graphs demonstrate that appropriate amount of rare earth elements (0.1%-0.2%) can fine AZ91D‘s grain and improve its ductility.     

Effect of rare earth elements on the microstructure and property for magnesium alloy AM60B

The effects of rare earth elements on the microstructure and properties of magnesium alloy AM60B alloy were studied.Different proportions of rare earth elements were added to AM60B and the tensile tests were carried out under different temperatures.The experimental results show that at room temperature the tensile strength of AM60B can be improved with the addition of rare earth elements.The ductility of which at room or elevated temperature(120℃） can also be improved ,and the ductility is to some extent in proportion with the amount of rare earth elements.The ductility at 120℃ is better than that at room temperture,The microstructure graphs demonstrate that appropriate amount of rare earth elements (0.1%-0.2%,mass fraction)can fine AM60B‘s grain and improve its ductility.     

稀土镁球墨铸铁凸轮轴激光热处理的研究与应用

本文对稀土镁球墨铸铁凸轮轴激光热处理硬化层的组织耐磨性进行了探讨，并分析了磨损机理。研究结果表明；激光处理后的凸轮轴，变形小，而且具有良好的耐磨性，这对稀土镁球墨铸铁在实际中的应用有很大的意义。     

稀土元素Nd在热挤压AZ61镁合金中的作用

为了确定稀土元素Nd对热挤压AZ61镁合金显微组织和力学性能的影响，利用光学显微镜对不同含Nd量的AZ61+Nd镁合金进行了显微组织观察，并通过进行位移控制的拉伸试验测定了合金的室温和高温拉伸性能.结果表明，当热挤压AZ61+Nd镁合金中的Nd含量为0.5%时，其晶粒最细，力学性能最佳；随着Nd含量的增加，热挤压AZ61+Nd镁合金的强度有所降低，而伸长率则呈现先升高后降低的变化趋势；随着实验温度的升高，热挤压AZ61+Nd镁合金的抗拉强度和屈服强度均呈降低趋势，而伸长率则呈增加趋势.     

稀土Gd对Mg-5Al系镁合金显微组织与疲劳性能的影响

为了确定稀土元素Gd和时效处理对Mg-5Al系压铸镁合金显微组织及疲劳性能的影响,通过低周疲劳实验对压铸态和时效态Mg-5Al-x Gd镁合金的显微组织和疲劳性能进行了表征.结果表明,提高压铸态和时效态Mg-5Al-x Gd镁合金中Gd的含量,可使镁合金的显微组织得到细化.在总应变幅控制的低周疲劳加载条件下,压铸态和时效态Mg-5Al-x Gd镁合金均呈现出循环硬化和循环稳定特征,时效处理可以提高Mg-5Al-x Gd压铸镁合金的循环变形抗力.对于压铸态镁合金而言,Gd含量为1%时镁合金的循环变形抗力高于Gd含量为2%和3%的镁合金,而对于时效态镁合金而言,Gd含量为1%和2%时镁合金的循环变形抗力均高于Gd含量为3%的镁合金.     

稀土熔盐电解槽的热平衡计算

利用实测和文献提供的数据，对3kA钕电解槽进行了热平衡计算，并对结果进行了分析与讨论，提出了几项减少热损失，维持电解过程稳定性的措施。     

Plastic deformation behavior of ZK60 magnesium alloy with addition of neodymium

The hot deformation simulation of a ZK60 magnesiuln alloy at different temperatures from 373 to 673 K and different strain rates of 0.1, 0.01 and 0.002 s^-1 was studied by using the Gleebe-1500 simulator. The plastic deformation behavior was measured and the deformation activation energy was calculated. The microstructures of ZK60 magnesium alloy with an addition of neodymium during the deformation process were observed by using Polyvar-MET optical microscope and Tecnai G^2 20 TEM. The results show that the working hardening, the dynamic recovery and the dynamic recrystallization occur during the plastic deformation process at different temperatures and strain rates. The dynamic recrystallization starts when the temperature is over 473 K and the DRX grain size after hot deformation is only 5-10 μm. So the refined grains improve both the tensile strength and the elongation of alloys at room temperature. Neodymium is added into the alloy and a precipitate phase Mg12Nd that impedes the movement of dislocations is formed, which benefits to increasing mechanical properties of ZK60 magnesium alloy.     

稀土铈对AZ91镁合金表面腐蚀性能的影响

为解决镁合金表面处理工艺复杂、成本高且存在环境污染问题 ,采用气相扩渗法研究了稀土铈对AZ91镁合金表面的渗入及其耐腐蚀性能的影响 .结果表明 ,经过扩渗稀土铈表面处理的AZ91镁合金 ,腐蚀电阻增大近一倍 ,均匀腐蚀速率由 1.85 0mg/m2 ·s降为 0 .876mg/m2 ·s;腐蚀电位正移 ,同一电位下所对应的腐蚀电流密度明显降低 .利用X射线光电子能谱 (XPS)分析了经过扩渗稀土后AZ91镁合金表面的成分中 ,稀土铈是以化合态的形式存在于表层 ,渗入的稀土元素铈起到净化合金表面、微合金化的作用