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1.
采用真空蒸发-扩散镀的方法在金刚石表面镀钛,研究了镀覆温度和保温时间对金刚石表面形貌、镀层厚度、镀层物相的影响规律,分析了镀钛金刚石的抗氧化性能,研究了镀钛金刚石及其在铁基胎体中的结合状态。结果表明:在低温下(680℃)镀覆时,金刚石表面开始出现TiC;随镀覆温度升高或保温时间延长,镀层逐渐致密并增厚,在720℃镀覆时出现Ti沉积,在820℃镀覆时由于应力原因产生裂纹并导致镀层的破坏;镀层可隔绝金刚石与氧的直接接触,大幅度延缓氧对金刚石的侵蚀作用;镀钛后金刚石在胎体中可实现牢固的冶金键合。 相似文献
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复合镀覆Ti—Ni金刚石的钎焊应用 总被引:4,自引:2,他引:2
镀覆技术的研究进展表明:经过真空微蒸发镀钛、钨的金刚石单晶或聚晶,可以采用化学镀或电镀的方法在钛或钨镀层上进一步镀覆镍、钴、铬等金属,这种复合镀层与金刚石界面强力冶金结合,并且可以采用各种钎焊方法实现金刚石与多种金属基体的焊接。复合镀覆的金刚石可用于各类表镶工具的制造,获得高出刃、高磨粘结合强度,使金刚石表镶工具的使用寿命和加工效率大幅度提高。 相似文献
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以真空微蒸发镀覆技术为核心,围绕各类高性能超硬材料工具的不断开发应用,目前已经形成了超硬磨料镀覆金属化系列产品。包括镀覆单一金属的超硬磨料,如镀钛、镀钨的金刚石;镀覆合金的超硬磨料,如镀钛-铬合金的金刚石;真空微蒸发镀覆之后再经电镀形成的多层复合镀超硬磨料,如复合镀Ti-Ni具质量、降低制造成本和新产品开发有显作用。 相似文献
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《金刚石与磨料磨具工程》2014,(2)
<正>真空微蒸发镀覆技术和设备镀钛设备(单次镀钛5 000~20000克拉)3折销售,最低价格1.8万元低价供应超纯低温镀钛原料。镀钛原料包含了真空微蒸发镀钛的核心技术免费提供各类金刚石工具先进配方和工艺金刚石和CBN真空微蒸发镀钛技术和设备是提高超硬工具性能、降低成本的主要手段;我们对购进的高纯钛进一步高真空高温净化,用于镀钛专用原料,防止易挥发的杂质优先沉积在金刚石表面,损害镀层质量和结合力。最新推出超纯低温镀覆原料,镀覆的金刚石,镀层白亮悦目,进一步提高了工具的性能和稳定性,每克拉镀覆成本低至0.5分。 相似文献
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超硬材料系列镀覆产品及应用 总被引:14,自引:5,他引:14
以真空微蒸发镀覆技术为核心,围绕各类高性能超硬材料工具的不断开发应用,目前已经形成了超硬磨料镀覆系列产品。包括镀覆一层金属的超硬磨料,如镀钛、镀钨的金刚石;镀覆合金的超硬磨料,如镀钛-铬合金的金刚石;真空微蒸发镀覆之后再经电镀形成的多层复合超硬磨料,如复合镀Ti-Ni的金刚石等。这些系列镀覆产品分别适用于金属粉末烧结工具、钎焊工个和树脂结合剂工具,以于提高工具质量、降低制造成本和新产品开发有显著作用。新近研制成功的一种适用于树脂结合剂工具的刚玉涂覆的超硬磨料,克服了镀镍、镀铜超硬磨料镀覆成本高及使工具变钝的缺点,是树脂工具升级换代的新产品。 相似文献
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金刚石和立方氮化硼超硬磨料表面处理技术应用及发展 总被引:2,自引:0,他引:2
王艳辉 《金刚石与磨料磨具工程》2009,(1)
本文综合介绍了金刚石和立方氮化硼超硬磨料表面处理技术及应用情况及新的表面处理技术发展情况,包括真空微蒸发镀钛技术及应用进展;微粉专用真空微蒸发镀覆技术及应用;基于镀钛技术而发展的复合镀Ti-N i技术及应用;刚玉涂覆的超硬磨料及应用;基于原子层镀覆技术发展的超硬磨粒、微粉及纳米粉的镀硅镀钛技术及应用。 相似文献
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本文总结了近年来超硬材料工具厂家采用镀覆金刚石制造各类金刚石工具取得的技术进步和获得的良好经济效益.大规模工业化应用的结果表明:金刚石镀钛有两个重要作用,首先是实现了金刚石与结合剂之间的冶金结合,大幅度减少了金刚石脱落,因而采用镀钛金刚石制造各类金刚石工具,可以直接减少金刚石用量10%~20%;其次镀钛层对金刚石起到了... 相似文献
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镀钛超硬材料微粉及应用 总被引:1,自引:1,他引:0
本文报道了采用真空微蒸发镀覆技术进行工业化超硬材料微粉镀覆生产。镀覆钛和久合金的超硬材料(金刚石、立方氮化硼)微粉主要技术指标为;镀覆微粉的粒度最细达到5μ(W5),镀后无颗粒粘连,镀层均匀并且与超硬颗凿强力冶金结合,镀层光亮闪烁金属光泽。镀覆钛和钛合金的超硬材料微粉在各类精细超硬工具制造和超硬超晶材料领域有广泛应用前景。 相似文献
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在不同条件下镀覆金刚石并以其为磨料制备树脂砂轮,研究镀覆工艺及条件对镀覆金刚石性能的影响,并检测砂轮的平行度、硬度、耐磨性。实验结果表明:以镀覆金刚石为磨料制备的砂轮,与用未镀覆金刚石的砂轮相比,磨损程度最大可降低45.31%。在电镀镍工艺和镀层增重率相近时,用经过真空蒸发镀钛的镀覆磨料制备的砂轮耐磨性更好,磨损程度降低29.77%;使用高电流短时间的电镀工艺制备的镀覆金刚石作为磨料制备的砂轮,其磨损程度下降29.43%。镀层增重率影响镀覆金刚石表面镍刺的生长状态,用镀层增重率过大的镀覆金刚制备的砂轮耐磨性降低。砂轮的平行度、硬度受砂轮磨料镀覆工艺的影响很小。 相似文献
11.
用钛熔盐沉积及热处理工艺分别制备碳化钛涂覆的立方碳化硼颗粒(TiN/cBN)及碳化钛涂覆的金刚石颗粒(TiC/金刚石)。将cBN或金刚石颗粒分别与钛粉和KCl、NaCl和K2TiF6熔盐混合。将所得混合物在Ar气氛中加热至900°C,然后在H2气氛中于1000°C进行热处理。采用扫描电镜、X射线衍射和聚焦离子束技术对所制得颗粒进行表征。结果表明:cBN和金刚石颗粒表面已覆盖了纳米钛层。对Ti/cBN和TiC/金刚石涂层颗粒进行热处理后,颗粒表面沉积的Ti层与cBN和金刚石颗粒发生了原位化学反应,分别转化为钛化合物TiN和TiC。 相似文献
12.
C、Si、Mn、Cu对中锰球墨铸铁组织和性能的影响 总被引:1,自引:0,他引:1
应用湿砂铸型浇注中锰球墨铸铁,采用正交设计研究了C、Si、Mn、Cu对中锰球墨铸铁组织和力学性能的影响。结果表明,中锰球墨铸铁的铸态组织为奥氏体+碳化物+球状石墨,扫描照片中可见有大量细小均匀的韧窝。中碳、高硅、中锰和低铜有利于提高中锰球墨铸铁的硬度;低碳、高硅、中锰和中铜有利于提高其冲击韧度;低碳、中硅、低锰和低铜有利于提高其耐磨性。新开发的中锰球墨铸铁的硬度、冲击韧度和耐磨性远高于目前生产排沙潜水泵过流部件中所使用材料的各项性能,使用寿命是其2倍左右。 相似文献
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Toshihiko Hoshide Masato Hirano 《Journal of Materials Engineering and Performance》2010,19(4):562-567
The durability of coated materials with high performance should be adequately evaluated prior to their application. This study
aims at establishing a procedure to estimate the durability of such materials. In this study, a borosilicate glass was coated
with ceramic films by a radio-frequency (RF) magnetron sputtering method, and mechanical properties of materials coated with
single ceramic materials, alumina (Al2O3), silicon carbide (SiC), or titanium nitride (TiN), were investigated. Roughness and hardness were measured as surface characteristics
of coated glass. The strength of coated glass was evaluated under three-point bending mode. It was found that the strength
properties were improved by coating ceramic materials on glass. As for the strength properties, TiN-coated glass was superior
to Al2O3- or SiC-coated glass, although the surface of TiN-coated glass was rougher compared with that of Al2O3- or SiC-coated glass. A new procedure to estimate the strength of coated materials was proposed by incorporating relative
hardness and roughness variations with sputtering time. The strength in experiments was adequately estimated by using the
proposed procedure. 相似文献
14.
Rossana GaziaPietro Mandracci Federico MussanoStefano Carossa 《Surface & coatings technology》2011,206(6):1109-1115
Aluminium nitride thin films were deposited on titanium fixtures, while silicon oxide thin films were deposited on titanium fixtures and chromium-cobalt substrates, using the RF magnetron sputtering technique. Each coating showed different corrosion behaviours when electrochemical characterisations were made in a simulated biological environment, i.e. Hank's solution. Although aluminium nitride was more effective in reducing the localised corrosion on titanium implants, silicon oxide showed the best behaviour against general corrosion and results were consistent for the two kinds of substrates. Moreover the application of a SiO2/AlN bilayer onto the Ti fixtures improved the performances of each separate coating. When the coated surfaces were compared to uncoated substrates, there was no statistically significant difference in cell viability in the response of two different human osteoblastic cell lines — Saos-2 and MG-63. Field emission scanning electron microscopy assessed the surface morphology of coated and uncoated samples, whilst Fourier transform infrared spectroscopy was applied to investigate the bonding structure of barrier layers on silicon samples. On the basis of the data obtained, we are of the opinion that the tested materials show some promising characteristics for the fabrication of novel dental implants with reduced ion release properties. 相似文献
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H.B. Ji L.F. Xia X.X. Ma Y. Sun M.R. Sun School of Materials Science Engineering Harbin Institute of Technology Harbin China 《金属学报(英文版)》2000,13(4):967-973
1. IlltroductionThe high yield strength and toughness, moderate modules, low density, good corrosionresistance and exceptional biocompatibility of Ti-6Al--4V alloy have made it increasinglypopular in industrial and medical application. But the alloy does not have enough wearresistance, and so is restricted in surface, particularly tribological applications to a certain e.tent[1--2]. It has been demonstrated that plasma-based ion implalltation (PBll), anew cost-effective technique for improvi… 相似文献
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Donna D. Harbuck Charles F. Davidson Monte B. Shirts 《JOM Journal of the Minerals, Metals and Materials Society》1986,38(9):47-50
The Bureau of Mines investigated a procedure to produce fine-sized titanium nitride, carbide, and carbonitride powders. These powders, because of their high hardness and abrasion resistance, can be substituted for tungsten carbide in some cutting tool applications. Titanium nitride and carbide powders can be cemented together with nickel. The investigated approach produces titanium nitride by reducing titanium tetrachloride with magnesium or sodium vapor in a nitrogen atmosphere at temperatures between 750 and 1,050°C (1,382 and 1,922°F). Titanium carbide and titanium carbonitride can be formed by adding methane to the nitrogen atmosphere. Titanium tetrachloride reduction efficiencies as high as 98% are achieved. X-ray diffraction analyses showed that the powders contain no major impurities. Because the reactions occur in the gas phase, powders finer than 1 μm are produced. 相似文献
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《International Heat Treatment & Surface Engineering》2013,7(3-4):100-104
AbstractHot work tool steels are widely used for pressure die casting moulds, die inserts, extrusion tools for aluminium processing and for steel forging. Nitriding increases the lifetime of such tools in many cases, yet delivers disappointing results in others. To optimise performance and for knowledge based surface design, it is indispensable to understand the mechanisms which occur in the near surface zone during nitriding. Nitrogen and carbon profiles obtained for X38CrMoV51 (AISI H13) steels with two silicon levels (1·1 and 0·3%), together with high resolution microscopy and electron energy loss spectroscopy, revealed that the secondary carbides are gradually transformed into nitrides during nitriding. Thermodynamic calculations confirmed the experimental observations. The near surface zone can be divided into three subzones: (1) a nitrogen enriched, almost carbon free zone with high nitride precipitation density and high hardness; (2) a nitrogen enriched and carbon depleted zone where the carbide–nitride transformation occurs; (3) a carbon enriched zone where the displaced carbon from zones 1 and 2 reprecipitates. A correlation between microstructure and microhardness and residual stress profiles was observed for all three zones. It was found that silicon, although not directly participating in the formation of nitrides, has a strong impact on the properties of the near surface zone by stabilising the secondary carbides and retarding the carbide–nitride transformation. This results in homogeneous precipitation in the transformation zone, thus avoiding micrometre sized precipitates which can act as defects and promote crack propagation. The conclusions of the present work are in accordance with literature studies on the effect of silicon on the tempering behaviour and the secondary carbide structure of 5%Cr martensitic steels. 相似文献
18.
Micro-milling process is a direct and flexible fabrication method in producing functional three dimensional micro-products. The advance of micro-milling process ultimately depends on the development of micro cutting tools since it is a tool-based process. Therefore, in this study an attempt to improve the performance of carbide micro-end mills by applying cubic boron nitride (cBN) coating was carried out. Experiments and finite element method (FEM) based simulations were used to study the effect of cBN coated tool in micro-machining of Ti-6Al-4V titanium alloy. The experiments were conducted to compare the performance of cBN coated and uncoated micro-end mills in terms of surface roughness, burr formation and tool wear. FE simulations were employed to investigate chip formation process in micro-milling to reveal the effects of cBN coated micro-end mills with increased edge radius in terms of cutting force generation, tool temperature and contact pressure, sliding velocity and hence tool wear rate. The simulation results were further utilized for estimating tool life using a sliding wear rate model and compared with experiments. This study clearly showed that the cBN coated carbide tool outperformed the uncoated carbide tool in generation of tool wear and cutting temperature. 相似文献
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电子浆料作为一种性能优异的热界面材料,广泛应用于超高速电脑芯片、功率半导体器件以及高亮度LED中,可以通过低温固化方式实现芯片与热沉之间的机械连接、电连接和热连接并能满足高温环境下的使用要求。本文介绍了纳米银和碳纳米管应用于低温固化电子浆料提高导热性能的最新研究进展,基于二者对电子浆料导热结构的影响分别介绍了:1)纳米银尺寸、表面包覆剂以及烧结结构内部孪晶的形成对电子浆料导热性能的影响;2)制备定向碳纳米管阵列以及阵列连接界面改性修饰,在芯片与热沉之间形成高导热通路制备热界面材料; 3) 银修饰碳纳米管的界面效应以及其与银粉烧结键合形成三维复合导热结构对提升电子浆料导热性能的影响。并对未来纳米银与碳纳米管提高电子浆料导热性能的发展方向进行了展望。 相似文献
20.
《稀有金属材料与工程》2004,21(1):28-32
以对照原有钛渣工艺为切入点,从直流一空心电极电炉熔炼所产生的熔池流动特性可以抑制碳热还原过程的碳(氮)化钛生成,和能够气化除杂等几个方面做了简要论述。并着重指出,这些熔炼特性对提高我国钛渣生产技术水平的重要意义。 相似文献