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纳米结构的ZnO由于具有优异的光、电、磁、声等性能,已经成为光电、化学、催化、压电等领域中聚焦的研究热点之一.不同纳米结构的ZnO其制备方法不同,着重概述了采用化学气相沉积(CVD)工艺制备ZnO纳米材料,包括直接热分解、高温加热锌粉、碳热还原法以及金属有机气相沉积(MOCVD)4种方法,重点讨论了不同锌源和氧源对ZnO纳米结构的影响规律,并初步探讨了ZnO的VLS与VS生长机理,同时展望了ZnO在各领域中的最新应用. 相似文献
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ZnO是一种可用于室温或更高温度下的紫外发光材料,纳米结构的ZnO(如单晶薄膜、纳米粒子膜、纳米线和纳米带等)则更是在紫外激光发射领域显示了独到的优势,被认为是有望构造短波长半导体激光器的理想材料.本文对一维ZnO纳米结构(纳米线、纳米管和纳米带)的真空物理气相沉积制备技术及生长机理进行了初步探讨. 相似文献
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采用化学气相沉积(CVD)法制备了不同尺寸的四脚状纳米ZnO和ZnO纳米棒。采用X射线粉末衍射(XRD)、扫描电子显微镜(SEM)对纳米ZnO的晶型结构和形貌进行表征,研究结果表明CVD法制备的四脚状纳米ZnO具有三维空间结构,其最小平均臂宽约为70nm,臂长约300nm,制备的纳米棒直径约为84nm,长约2μm,且都为六方纤锌矿晶型结构。将ZnO纳米四脚状及纳米棒利用滚涂法在FTO导电玻璃上形成ZnO光阳极,经N719染料敏化后组装成染料敏化太阳能电池,光电性能结果表明,染料敏化小尺寸的四脚状纳米ZnO太阳能电池光电转换效率(η=1.88%)高于染料敏化大尺寸的四脚状纳米ZnO太阳能电池光电转换效率(η=1.18%),远高于染料敏化ZnO纳米棒太阳能电池的光电转换效率(η=0.7%)。 相似文献
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《Materials Chemistry and Physics》2005,89(2-3):326-331
ZnO nanowires, nanorods and nanoparticles through modulating the ratio of water to methanol have been synthesized by using a mild and simple solution method. The as-prepared ZnO nanostructures have been characterized by atomic force microscopy and X-ray photoelectron spectroscopy. With the increase of the ratio of water to methanol, the morphology of ZnO nanostructures varied form denser nanowires, to sparse nanowires, to nanorods, and then to nanoparticles. The ratio of water to methanol is supposed to play an important role in the formation of ZnO nanostructures. The mechanism of formation is related to the chemical potential, which is simply proportional to their surface ratio. 相似文献
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Zinc oxide nanostructures: synthesis and properties 总被引:3,自引:0,他引:3
This article provides a comprehensive review of the current research activities that focus on the ZnO nanostructure materials and their physical property characterizations. It begins with the synthetic methods that have been exploited to grow ZnO nanostructures. A range of remarkable characteristics are then presented, organized into sections describing the mechanical, electrical, optical, magnetic, and chemical sensing properties. These studies constitute the basis for developing versatile applications of ZnO nanostructures. 相似文献
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Zinc oxide’s (ZnO) physical and chemical properties make it a viable and extremely attractive compound to use in a variety of nanotechnology applications. Some of these applications include biomedical, energy, sensors, and optics. As the research in ZnO nanostructures continue to grow, it has inspired a whole host of new innovative applications. Complementing its unique chemical qualities, it also has a simple crystal-growth technology and offers significantly lower fabrication costs when compared to other semiconductors used in nanotechnology. Several processes have been developed in order to synthesize high quality ZnO nanostructures—specifically in the case of nanowires. Here we offer a comprehensive review on the growth methods currently employed in research, industry, and academia to understand what protocols are available to meet specific needs in nanotechnology. Methods examined include: the vapor–liquid–solid, physical vapor deposition, chemical vapor deposition, metal–organic chemical vapor deposition, and the hydrothermal-based chemical approach. Each of these methods is discussed and their strengths and weaknesses are analyzed with objective comparison metrics. In addition, we study the current state-of-the-art applications employing ZnO nanostructures at their core. A historical perspective on the evolution of the field and the accompanying literature are also presented. 相似文献
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Yufu Zhu Fei Deng Chaoying Ni Wenzhong Shen 《Journal of Materials Science: Materials in Electronics》2014,25(10):4547-4552
Novel ZnO core/shell nanostructures were constructed by depositing a porous ZnO layer directly on the surfaces of pre-fabricated ZnO nanowires through a facile chemical method. The morphology and structure of the obtained products have been investigated by field-emission scanning electron microscopy, high-resolution transmission electron microscopy and X-ray diffraction analysis. In these unique nanostructures, the porous overlayer exhibits a large surface area for sufficient dye loading to enhance light harvesting and the ZnO nanowire cores provide direct conduction pathways for the photogenerated electron transport to diminish the chance of electron recombination. The obtained ZnO nanostructures were used as photoanode material in dye-sensitized solar cell which showed an increase in performance of 141 % compared with an equivalent solar cell employing ZnO nanowire arrays as photoanode. This result was achieved mainly due to an increase in photogenerated current density directly resulting from improved light harvesting of the porous layer. 相似文献
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Xipeng Pu Dafeng Zhang Xiujie Yi Xin Shao Wenzhi Li Mingyan Sun Lei Li Xianhua Qian 《Advanced Powder Technology》2010,21(3):344-349
ZnO ellipsoidal nanostructures were rapidly synthesized using a chemical synthesis method at 90 °C without the assistance of aging procedure, calcination, sonication, microwave, laser or any organic additives. The effects of pH values and Zn2+ concentration on the morphologies of ZnO nanostructures were investigated. The instantaneous underdeveloped ZnO nanostructures were successfully obtained by using the electrophoretic deposition (EPD). Based on the experimental results, growth mechanism of ellipsoidal ZnO nanostructures was proposed. The ellipsoidal nanostructures are self-assembled by the oriented-attachment growth of primary nanoparticles, involving the end-to-end oriented-attachment along the major axis and the side-by-side oriented-attachment along the minor axis. Two half-ellipsoids of the ZnO nanostructures germinate in sequence. The UV–vis absorption and photoluminescence of the ellipsoidal nanostructures was also studied. This work presents a simple and ultra-fast route for large-scale fabrication of ZnO ellipsoidal nanostructures. 相似文献
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We fabricated the vertically-aligned zinc oxide (ZnO)/silicon (Si) double nanostructures by simple processes using the metal-assisted chemical etching and a subsequent hydrothermal synthesis, and their optical property was investigated. For efficient antireflection characteristics, Si nanostructures were optimized by changing the size of the dewetted silver (Ag) at different etching times. The thermally dewetted Ag nanoparticles or semi-island films as metal catalysts were controlled by the Ag film thickness and dewetting temperature. To form the ZnO/Si double nanostructures, ZnO nanorods were synthesized on the chemically etched Si nanostructures using a thin sputtered ZnO seed layer. The grown ZnO nanorod arrays (NRAs) exhibited good crystallinity and further reduced the surface reflection due to their antireflective property. The ZnO/Si double nanostructures showed the increased peak intensity of X-ray diffraction as well as the significantly reduced solar weight reflectance of 6.05% compared to 11.71% in the ZnO NRAs on the flat Si substrate. Also, the enhanced antireflection property of ZnO/Si double nanostructures was theoretically analyzed by performing the rigorous coupled wave analysis simulation. 相似文献
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Li KW Lian HB Cai JH Wang YT Lee KY 《Journal of nanoscience and nanotechnology》2011,11(12):11019-11022
The optimal carbon nanotube (CNT) bundles with a hexagonal arrangement were synthesized using thermal chemical vapor deposition (TCVD). To enhance the electron field emission characteristics of the pristine CNTs, the zinc oxide (ZnO) nanostructures coated on CNT bundles using another TCVD technique. Transmission electron microscopy (TEM) images showed that the ZnO nanostructures were grown onto the CNT surface uniformly, and the surface morphology of ZnO nanostructures varied with the distance between the CNT bundle and the zinc acetate. The results of field emissions showed that the ZnO nanostructures grown onto the CNTs could improve the electron field emission characteristics. The enhancement of field emission characteristics was attributed to the increase of emission sites formed by the nanostructures of ZnO grown onto the CNT surface, and each ZnO nanostructure could be regarded as an individual field emission site. In addition, ZnO-coated CNT bundles exhibited a good emission uniformity and stable current density. These results demonstrated that ZnO-coated CNTs is a promising field emitter material. 相似文献
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One-dimensional (1D) zinc oxide (ZnO) nanostructures have been extensively and intensively studied for several decades not only for their extraordinary chemical and physical properties, but also for their current and future different electronic and optoelectronic device applications. This review provides a brief overview of the progress of different synthesis methods and applications of 1D-ZnO nanostructures. Morphology of ZnO nanostructures grown by various methods and progress in the optical properties are briefly described. Using low-temperature photoluminescence (LTPL) study, detailed informations about the defect states and impurity of such nanostructures are reported. Improvement of field emission properties by modifying the edge of 1D-ZnO nanostructures is briefly discussed. Applications such as different sensors, field effect transistor, light-emitting diodes (LEDs), and photodetector are briefly reviewed. ZnO has large exciton binding energy (60 meV) and wide band gap (3.37 eV), which could lead to lasing action based on exciton recombination. As semiconductor devices are being aggressively scaled down, ZnO 1D nanostructures based resistive switching (RS) memory (resistance random access memory) is very attractive for nonvolatile memory applications. Switching properties and mechanisms of Ga-doped and undoped ZnO nanorods/NWs are briefly discussed. The present paper reviews the recent activities of the growth and applications of various 1D-ZnO nanostructures for sensor, LED, photodetector, laser, and RS memory devices. 相似文献
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One-dimensional (1D) zinc oxide (ZnO) hierarchical structures have been self-assembled on amorphous carbons using thermal chemical vapour transport and condensation. Three typical micro-?and nanostructures consisting of micrometre-sized rods and nanometre-sized needles were observed. Growth mechanisms were established to elucidate the growth properties of 1D ZnO hierarchical structures. 相似文献