The effect of mordant salts on antibacterial activity of wool fabric dyed with pomegranate and walnut shell extracts

Natural dyes have attracted increasing worldwide attention because of the carcinogenicity and environmental effects of synthetic dyes. In this study, wool fabric was treated with tannin‐rich extracts of Punica granatum peel and walnut shell in combination with some mordants. The effect of various mordants on the colorimetric and antibacterial properties of wool fabrics was investigated. The results showed that pretreatment with metallic mordants substantially improved the dyeing and fastness properties of wool fabrics. The extracts of Punica granatum peel and walnut shell showed a significant antibacterial activity at 5% concentration. In addition, antibacterial activity was dramatically enhanced using metallic salts. The antibacterial activity of samples dyed with natural dyes and without any mordant was not good, while the mordanted samples with copper, aluminum and tin salts obtained considerable antimicrobial properties following lightening and washing fastness. The extracts of Punica granatum peel and walnut shell can be considered as viable alternatives instead of artificial antibacterial agents for hospital textiles as well as an effective anti‐odour agent for sports and household textiles.     

Atmospheric pressure plasma‐induced decolorisation of cotton knitted fabric dyed with reactive dye

The aim of this study was to investigate the decolorisation effect of atmospheric pressure plasma treatment on knitted fabrics dyed with reactive dyes under different processing parameters, ie, air concentration, treatment duration and water content. The fabrics were dyed with reactive dye of a blue colour, and the colour depths were 0.5%, 1.5% and 3.0% on weight of fabric. The colour properties of untreated and plasma‐treated fabric samples were evaluated by means of reflectance, K/S and relative unlevelness index. The colour properties were evaluated instrumentally and quantitatively in order to study the decolorisation effect induced by atmospheric pressure plasma treatment. Experimental results revealed that the desired decolorisation effect was heavily influenced by the atmospheric pressure plasma treatment processing parameters. Although the desired decolorisation effect could be obtained by controlling the processing parameters of the atmospheric pressure plasma treatment, the treatment did not provide any significant reduction in the bursting strength of the fabric.     

Synthesis of sulfated β‐cyclodextrin/cotton/ZnO nano composite for improve the antibacterial activity and dyeability with Azadirachta indica

The sulfated β‐cyclodextrin (sb‐cd) was prepared from β‐cyclodextrin and the sb‐cd was crosslinked with cotton fabric using ethylenediaminetetraacetic acid (EDTA) as crosslinker. After crosslinking, the synthesized ZnO nanoparticles were padded on this fabric surface. Then, the treated fabrics were dyed with neem extract. The synthesized polymer, crosslinked and nanoparticle‐treated cotton fabrics were characterized using fourier transform infrared spectroscopy (FTIR), X‐ray diffraction (XRD), particle sized analyzer, and transmission electron microscopy (TEM) studies. The antibacterial test was done against Staphylococcus aureus and Escherichia coli bacterium. The composite coated with neem dyed cotton fabric has exhibited 71% of dye uptake with 2–3 fastness grade and it has 99% of antibacterial efficiency for S. aureus and 97% for E. coli bacterium. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013     

Assessment of the dyeing properties of pigments from five fungi and anti‐bacterial activity of dyed cotton fabric and leather

The present study was aimed to assess the anti‐bacterial activity and dyeing property of the pigments obtained from five fungal species. Cotton fabric and leather samples were dyed with the purified pigments and their anti‐bacterial activity was assayed under in‐vitro conditions. Post‐mordant cotton fabric and leather samples exhibited maximum bacterial reduction when compared with the pre‐mordant and dyed samples. Pigment exhaustion, colour coordinates and fastness properties of the dyed cotton fabric and leather samples were also assessed. The toxicity of the pigments was evaluated by seed germination assay.     

Electrostatic self‐assembly dyeing of cotton fabrics

A new approach to the dyeing of cotton fabrics using an electrostatic self‐assembly method was evaluated. Cotton fabrics were pretreated with 2,3‐epoxypropyltrimethylammonuium chloride and cationic charges were produced on the fabric surfaces. For the dyeing of cotton fabric, reactive and acid dyes were used. Oppositely charged anionic reactive/acid dyes and cationic poly(diallyldimethylammonium chloride) were alternately deposited on the surface of cationised cotton fabrics. Ten multilayer films of dye/poly(diallyldimethylammonium chloride) were deposited on the cotton fabric surfaces using a padder. The build‐up of the multilayer films and the level of colour strength (K/S) achieved are discussed. Samples of cotton fabrics were also dyed with the same dyes, but using the exhaust method, and both types of dyed samples were compared. The washing, rubbing and light fastness properties were evaluated for the dyed fabrics.     

Preparation and properties of Fe(II)‐ion‐sensitive colour‐changing fabric

Textile fabrics were dyed with complexometric indicators (ionochromic dyes) to develop Fe(II) ionochromic fabric. Three kinds of ionochromic dye were used to dye silk fabric, and they were evaluated for colour changes triggered by Fe(II) solution. The K/S values and photos of the fabrics were then recorded. It was found that 1,10‐phenanthroline was the most suitable ionochromic dye in these dyes. Colour change from white to red could be clearly seen when 1,10‐phenanthroline‐dyed silk fabric was triggered by Fe(II) solution, but it showed no colour change when triggered by Cu(II), Mg(II), or Ca(II) solution. Moreover, 1,10‐phenanthroline‐dyed nylon, polyester, and cotton fabrics showed no obvious colour changes after triggering by Fe(II) solution. Ion concentration, pH value, and reaction time could affect the colour changes. When triggered by 8 mg l^?1 of Fe(II) solution at neutral pH for about 15 min, the ionochromic fabric showed a clear colour change. In addition, three coloured fabrics in green, blue, and yellow were also dyed with 1,10‐phenanthroline. It was found that they could also show clear colour changes when triggered by Fe(II) solution. These ionochromic fabrics may find broad application in many fields, such as Fe(II) detection, magic toys, anticounterfeiting materials, and bionic silk flowers.     

Application of D‐optimal design in the analysis and modelling of dyeing of plasma‐treated wool with three natural dyes

Both the dyeing and finishing of textiles with natural compounds are gaining increasing attention because of various environmental and health problems associated with the use of synthetic reagents. In this study, wool fibres were dyed with three natural dyes, namely, Arnebia euchroma, cotton pods and harmal seeds. Alum was used as the mordant, and samples were mordanted by the premordanting method. Oxygen plasma was employed for the surface modification of wool. Plasma treatment time, alum concentration, dyebath temperature and pH were selected as the process variables, and their effects on the K/S of the dyed samples were analysed using D‐optimal design. The surface topography, morphology and chemistry of the wool fibres after plasma treatment were studied by atomic force microscopy (AFM), scanning electron microscopy (SEM) and Fourier Transform–infrared spectroscopy (FTIR), respectively. FTIR confirmed the creation of new oxygen‐containing groups on the surface of wool fibres after plasma treatment. SEM and AFM images confirmed the surface etching and increase in the roughness of plasma‐treated fibres. Increasing the dyebath pH and temperature increased the K/S of the dyed samples. Increasing the amount of alum mordant increased the K/S of samples dyed with cotton pods but decreased the K/S of samples dyed with A. euchroma and harmal seeds. Increasing the plasma treatment time improved the K/S of samples dyed with A. euchroma and cotton pods but had no significant effect on the K/S of samples dyed with harmal seeds.     

Durable antibacterial finish on cotton fabric by using chitosan‐based polymeric core‐shell particles

Cotton fabric with excellent antibacterial durability was obtained when treated with chitosan‐containing core‐shell particles without any chemical binders. These amphiphilic nanosized particles with antibacterial chitosan shells covalently grafted onto polymer cores were prepared via a surfactant‐free emulsion copolymerization in aqueous chitosan. Herein, two core‐shell particles, one with poly(n‐butyl acrylate) soft core and another with crosslinked poly(N‐isopropylamide) hard core, were synthesized and applied to cotton fabric by a conventional pad‐dry‐cure process. Antimicrobial activity was evaluated quantitatively using a Shake Flask Method in which the reduction of the number of Staphylococcus aureus cells was counted. The results showed that treated fabric had an excellent antibacterial property with bacterial reduction higher than 99%. The antibacterial activity maintained at over 90% reduction level even after 50 times of home laundering. The fabric surface morphology as well as the effect of latex particles with different core flexibilities on fabric hand, air permeability, break tensile strength, and elongation was investigated. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 1787–1793, 2006     

Application of polycarboxylic acid sodium salt in the dyeing of cotton fabric with reactive dyes

In this study, the effects of polycarboxylic acid sodium salt on the dyeing of cotton with reactive dyes were evaluated by measuring and comparing the K/S values and dyeing fastnesses of the dyed cotton fabric samples. Results showed that the K/S value and dyeing fastness of cotton fabrics dyed with polycarboxylic acid sodium salt, substituting inorganic salts as exhausting agent were close to that of with sodium chloride when dip‐dyeing process was used. While, in pad‐dry dyeing, the K/S value of cotton fabric samples dyed with polyacid salts as exhausting agent was higher than that of with sodium sulfate, and the dyeing fastnesses of these samples were nearly the same. The dyeing mechanism of cotton fabric with reactive dye, using polycarboxylic acid sodium salt as exhausting agent was analyzed. The dyeing exhausting mechanism of reactive dye seems different when the inorganic salt and polycarboxylic acid sodium salt were used as exhausting agent in the dyeing of cotton fabric with reactive dye. The polycarboxylic acid sodium salt, as weak electrolyte, increased the dye‐uptake of reactive dye on cotton fabric not only by screening negative charges on cotton surface, but also by the effect of salting‐out or hydrophobic combination. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007     

Eco‐friendly pretreatment of silk fabric for dyeing with Delonix regia extract

The flowers of Delonix regia have been evaluated for the natural dyeing of silk using a biomordant and enzymes. This is an eco‐friendly textile pretreatment that does not utilise metal mordanting. The aqueous extract obtained from the dried red flowers was used for the dyeing of silk fabrics. A bright reddish‐brown hue colour was observed when 30% owf Delonix extract was used on the pretreated silk material. The silk fabric was treated with either an enzyme or biomordant. The resulting dyed fabric showed resistance to fading. Finally, all dyed specimens were tested for wash and light fastness properties, making Delonix a viable alternative to synthetic red dyes. Through desorption studies, the order of reactivity of enzymes towards dye uptake in the one‐step process was found to be lipase > diasterase > protease–amylase = Pyrus(biomordant). For the two‐step process, the order of reactivity of enzymes was found to be protease–amylase > lipase > Pyrus (biomordant) > diasterase. Overall, it can be concluded that, treatments, the two‐step process was better in terms of larger colour yield values, fastness properties and both dye adherence ability.     

Novel feature of nano‐titanium dioxide on textiles: Antifelting and antibacterial wool

In this study, the antifelting and antibacterial features of wool samples treated with nanoparticles of titanium dioxide (TiO₂) were evaluated. To examine the antifelting properties of the treated samples, the fabric shrinkage after washing was determined. The antimicrobial activity was assessed through the calculation of bacterial reduction against Escherichia coli (Gram‐negative) and Staphylococcus aureus (Gram‐positive) bacteria. TiO₂ was stabilized on the wool fabric surface by means of carboxylic acids, including citric acid (CA) and butane tetracarboxylic acid (BTCA). Both oxidized samples with potassium permanganate and nonoxidized wool fabrics were used in this study. The relations between both the TiO₂ and carboxylic acid concentrations in the impregnated bath and the antifelting and antibacterial properties are discussed. With increasing concentration in the impregnated bath, the amount of TiO₂ nanoparticles on the surface of the wool increased; subsequently, lower shrinkage and higher antibacterial properties were obtained. The existence of TiO₂ nanoparticles on the surface of the treated samples was proven with scanning electron microscopy images and energy‐dispersive spectrometry. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011     

Effect of Silicone Nano,Nano/Micro and Nano/Macro‐Emulsion Softeners on Color Yield and Physical Characteristics of Dyed Cotton Fabric

The study of silicone nano‐emulsions and softeners to alter physical properties of undyed cotton fabric has recently gained a substantial interest. However, systematic investigation of silicon nano‐emulsion softeners on dyed cotton fabric has not so far been conducted. This paper deals with the application of silicone nano‐, micro‐, and macro‐emulsion softeners, and combinations of nano/micro and nano/macro, on dyed cotton fabric. We report the effect of silicon nano/micro‐ and nano/macro‐emulsion softeners on color yield and physical characteristics of dyed cotton fabric. All bleached fabrics were dyed with CI Reactive Black 5 and then treated with known concentrations of silicone softeners by the pad‐dry method. The silicone nano‐emulsion was combined with micro‐ and macro‐emulsion softeners using blending ratios of nano/micro (1:1) and nano/macro (1:1). Treated fabrics were compared in terms of physical properties such as fabric handling, wrinkle recovery angle, bending length, abrasion resistance and tensile strength. The color changes were evaluated by color yield (K/S) values and total color difference (ΔE_cmc). The results revealed that the silicon nano‐emulsion had better physical properties than micro‐, macro‐ and combination nano/micro‐ and nano/macro‐emulsion softeners. Among all treated samples, nano‐emulsion softeners showed better ΔE_cmc values. Scanning electron microscopy analysis suggests that the fiber morphology of treated fabrics was very smooth and uniform.     

Combining dyeing and wrinkle‐resistance finishing of cotton in a one‐step process using a hemicyanine fluorescent dye

Combining dyeing and wrinkle‐resistance finishing of cotton in a one‐step process using a hemicyanine fluorescent dye DHEASPBr‐C2 was investigated in this paper. Fourier transform infrared spectroscopy, a fixation test, extraction with boiling N,N‐dimethylformamide, and a colour fastness test certified that DHEASPBr‐C2 was linked to the cotton fibre through covalent bonds. The results showed that dyed cotton fabric using DHEASPBr‐C2 had an obvious fluorescent effect in the range 550–700 nm, and the emission peak location was 588–590 nm. In addition, the dyed fabric met the EN471:2003 standard for chromaticity and could be used in high‐visibility warning clothing.     

High‐performance liquid chromatography of some natural dyes: analysis of plant extracts and dyed textiles

In this study, wool fibre samples were mordanted by means of 25% alum mordant solution. The mordanted wool samples were dyed in 50%Reseda luteola L. (weld), 20%Rhamnus petiolaris Boiss (buckthorn) and 50%Datisca cannabina L. (bastard hemp) dyebaths. A reverse‐phase high‐performance liquid chromatography with diode‐array detection method was utilised for the identification of dyes in the dyed wool samples and the plant extracts. The extraction of dyes was carried out with a hydrogen chloride/methanol/water (2:1:1; v/v/v) mixture.     

Carrier‐free dyeing of radiation‐grafted polyester fabrics with disperse dyes

Carrier‐free dyeing of radiation‐grafted polyester fabrics with disperse red dye was studied in the temperature range 283–363 K. 1‐vinyl 2‐pyrrolidone (NVP), acrylic acid (AA) or their mixture was used to graft poly(ethylene terephthalate) (PET) fabric. The effects of pH of the dye solution, graft yield (GY), dyeing time (t), dye concentration (C), and dyeing temperature (T) on the colour difference (CD) of PET fabric were studied. The best dyeing condition was achieved at pH 5.5. CD increases linearly with the increase in GY, with slopes depending on the type of grafted copolymer. CD increased rapidly as the dyeing time increased; this was followed by a relatively slow dyeing rate within a few minutes. The initial dyeing rate (R) was found to increase with an increase in C and T. The dyeing rates for all grafted samples followed 0.35‐order kinetics and are temperature‐independent. Average activation energy 9.26 kJ mol^?1 is calculated for the dyeing process and is independent of the fabric treatment. Pre‐exponential rate constants 1976, 1839, and 1579 (CD/GY) s^?1 were calculated for dyeing PET samples grafted with AA/NVP mixture, NVP and AA, respectively, while 1074 CD s^?1 was evaluated for carrier dyeing of ungrafted fabric. Analysis of the kinetic parameters and the dyeing mechanism revealed that dyeing PET fabric was diffusion‐controlled. Grafting PET fabric improved significantly the dyeing affinity of the DR dye over ungrafted samples dyed in solutions containing a carrier. Copyright © 2005 Society of Chemical Industry     

Low‐temperature plasma processing for the enhancement of surface properties and dyeability of wool fabric

In the present investigation, wool fabric was treated with a low‐temperature air plasma. The plasma discharge power and treatment time were varied. The effect of plasma treatment on various fabric properties such as wettability, wickability, dyeability, crease recovery angle, breaking strength, and elongation at break was investigated. Surface morphology was studied using SEM micrographs. The fabric became substantially hydrophilic even with a short duration of air plasma treatment of 30 s with improvement in dye uptake and in the rate of dyeing when dyed at a lower temperature. Under these treatment conditions, aging was almost nil in a dry environment, even after 45 days, whereas some aging was observed in a humid (75% relative humidity) environment. A 20% increase in the breaking strength and 24% increase in the elongation at break were observed with reduction in wrinkle recovery angle to 133–144° from 169° for untreated fabric. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43097.     

Investigation on dye ability and antibacterial activity of nanolayer platinum coated polyester fabric using DC magnetron sputtering

In this research work, one side of polyester fabrics was coated by platinum using DC magnetron sputtering. The dye ability of coated and uncoated samples to different natural and synthetic dyes was evaluated. The antibacterial counting test was used for determination of antibacterial efficiency of both treated and untreated samples. The results show that, the existence of platinum nanolayer on the surface of PET fabrics causes improve the dyeability of fabrics. The improvement for natural dyes is more significant than for synthetic dye. According to antibacterial activity tests, platinum itself has no antibacterial effect against Staphylococcus aureus. However, the natural dyed Pt-coated samples show moderate antibacterial effect.     

Mechanism involved in the dyeing of wool with an oil‐in‐water microemulsion system

This article investigates the influence of oil‐in‐water (o/w) microemulsions, used as media for both dye solubilization and dye baths, on the dye uptake on fiber surfaces. An acetic acid solution/Synperonic L7/benzyl alcohol microemulsion system was used to solubilize a water‐insoluble antimicrobial natural dye (C.I. Natural Orange 2) and to dye wool fabric at an acidic pH. The results clearly show that the dye exhaustion on the fabric took place mainly when the temperature of the dye bath promoted a change in the molecular organization of the microemulsions with the liberation of the dye solubilized in the oil droplets of the microemulsions. Although uniformly and evenly dyed fabrics were obtained, they showed very low wash fastness. To confirm the mechanism involved and to achieve dyed fabrics with good wash‐fastness properties, two different dyeing methods were also studied. The first method was dyeing at a constant low temperature, at which the o/w microemulsion remained a monophase system; the second one was dyeing at a high temperature, at which it was transformed into a multiphase system. Both the dye exhaustion and wash fastness improved considerably for the fabrics dyed at a high temperature. Moreover, uniform and even dyeing was achieved. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Methyl methacrylate‐assisted dyeing of polyamide microfibre

Polyamide microfibres were dyed using disperse dye in the presence and absence of methyl methacrylate. The dye uptake and colour strength in the presence of methyl methacrylate were substantially higher than in its absence. Scanning electron microscope analysis showed that there was a dye layer on the microfibre surface formed by methyl methacrylate adsorption after dyeing. Differential scanning calorimetry measurement showed that the glass transition temperature of the polyamide microfibre reduced following methyl methacrylate treatment. The ultimate consequence of all these functions was to facilitate diffusion of dye molecules into the microfibre, thereby increasing the colour strength. The wash fastness of the dyed samples was identical for the two different dyebaths, although there were slight differences in the staining grades. The rub fastness of the methyl methacrylate‐treated samples was improved by ca. half a grade. The methyl methacrylate had no effect on light fastness.     

Effect of Dye‐Bath pH on Photostability of Dyed Nylon 66

Nylon 66 films were dyed in aqueous dye‐bath with C. I. Acid Blue 25 (1‐amino‐4‐(aminophenyl)‐2‐anthraquinone sodium sulfonate) at various pH values ranging from 2.0 to 7.0. Films were exposed to polychromatic irradiation (λ ⪈ 290 nm) at 60°C in air. The extent of photo‐oxidation was monitored by FT‐IR spectroscopy. Fading of dye with polychromatic irradiation was monitored by UV spectroscopy. We observed a peculiar effect of dye‐bath pH on the photostability of dyed nylon 66. Samples were more stable when dyed at pH 3 and above that (up to pH 7), whereas the samples dyed at pH < 3.0 showed sensitized photo‐oxidative degradation in nylon 66. Formation of quaternary ammonium salt on dye‐chromophore was considered responsible for the pH‐controlled behavior of anthraquinone acid dyes. The dyeing pH significantly effects the photofading behavior of dyed samples. The effect of dye‐bath pH on photofading of the dyed samples was more pronounced at lower dyeing pH and prevailed up to pH 4. The hydronium ion concentration was considered to be responsible for the enhanced fading of dye for the samples dyed at the lower pH.