Compression fracture of organic fibre reinforced plastics

To measure the fibre strength _f a new method was used and the value _f=450±70 MPa was obtained. The compression strength dependence of unidirectional organic fibre reinforced plastics on the fibre volume fraction may be described by the well known mixture law. The compression strength of polyparaphenilenterephtalamid and polyparaamidobenzimidazol fibres practically coincide in spite of differences in chemical structures, tensile strengths and Young moduli. Epoxy matrix constrains the plastic fibre yield in composite and the fibre yield limit in composite is greater than the isolated fibre strength. The higher the matrix content the greater the effect. The fracture process begins with the appearance of a net of fine shear microlines, only after that do shear macrolines (so-called kinks) appear. At elevated temperatures the formation of yield macrolines is also observed but the fibre bend in the lines is symmetrical due to the symmetrical mode of fibre stability loss. The strength of organic fibre reinforced plastics is insensitive to the stress concentration effect and to the test method due to the plasticity of the composite.     

Excellent heat resistance of Si-Zr-C-O fibre

In order to obtain the high heat-resistant fibre, Si-Zr-C-O fibre has been developed. Si-Zr-C-O fibre was produced by the use of polyzirconocarbosilane as the precursor polymer. In this paper, the difference in heat-resistance between Si-Ti-C-O and Si-Zr-C-O fibres was clarified. Si-Zr-C-O fibre showed excellent heat resistance (up to 1773 K) compared with Si-Ti-C-O fibre (up to 1573 K). Generally speaking, decomposition reaction of this type of fibre proceeds accompained by the release of CO gas which was formed by the reaction between excess carbon and oxygen included in the fibre. In the case of Si-Zr-C-O fibre, Zr can strongly capture the oxygen atoms, so that the aforementioned decomposition hardly proceeds up to 1873 K (ZrO2 + 3C = ZrC + 2CO; G<0 at over 1906 K).     

Fibre orientation effects on the fracture of short fibre polymer composites: on the existence of a critical fibre orientation on varying internal material variables

The dependence of fracture toughness on fibre orientation, in short fibre reinforced polymers, was investigated using materials with different polymer matrix (polyamide 6.6, polyarylamide and polyoxymethylene), fibre sizing, fibre content, mean fibre length and fibre length distribution.To assess the dependence on fibre orientation, plates with unidirectionally oriented fibres were prepared and cut at various angles with respect to the direction of the aligned fibres. The fracture behaviour was investigated by single-edge notch three-point bending tests. In addition the stress-strain behaviour was examined by performing uniaxial tension and compression tests.Both the critical stress intensity factor K _C and the fracture energy G _C measured at fracture initiation were found to present a bi-linear relationship to the factor characterizing fibre orientation, with different slopes over different ranges of the orientation factor. This suggested the occurrence of a transition between different failure mechanisms with varying fibre orientation, namely matrix fracture and fibre debonding at low values of the fibre orientation factor, fibre breakage and pull-out at high values of the fibre orientation factor. This interpretation is supported by the observation of the crack growth direction (which varies with varying fibre orientation) and the analysis of the fracture surfaces. The slopes of the two linear branches of the toughness vs. fibre-orientation-factor plot and the critical fibre orientation angle depend on all internal variables investigated: constituent polymer matrix, degree of fibre-matrix adhesion, fibre content, mean fibre length and fibre length distribution.     

Chemically-assisted fracture of thermoplastic PET reinforced with short E-glass fibre

The study of the stress-rupture lifetime of a PET/glass fibre system by means of fracture mechanics methods indicates the degradation of lifetime under an aggressive environment (10% HCl solution). The SEM-EDAX analysis reveals the depletion of calcium and aluminium elements from the fibre, and this is believed to be the cause of multiple fibre fractures. The fracture toughness is decreased because the role of fibre pull-out, which is the significant energy-consuming process, is negligible. A statistical analysis, from which the lifetime behaviour can be predicted, is carried out.     

The fracture energy of hybrid carbon and glass fibre composites

The fracture energy of a model carbon fibre/glass fibre/epoxy resin hybrid composite system has been evaluated as a function of the carbon fibre/glass fibre ratio. Work of fracture measurements were less than a rule of mixtures prediction and a pronounced negative synergistic effect was observed at high carbon fibre and high glass fibre contents. Fibre debonded lengths and fibre pull-out lengths for the carbon and glass fibres were accurately measured using a projection microscope technique. Models of microscopic fracture behaviour, together with these measurements, were successful in quantitatively describing the observed fracture behaviour of the hybrid fibrous composites. It was found that post-debond friction energy provided a major contribution to the fracture energy of the glass fibres. The post debond sliding mechanism was also shown to be primarily responsible for the non-linear behaviour of the work of fracture of the hybrid composite.     

Effect of fibre angle on fracture properties of unidirectional flyash filled FRP composites

The fracture properties of unidirectional flyash filled and unfilled glass fibre and carbon fibre reinforced epoxy resin composites are studied in relation to the variation of width ratio (a/W) and fibre angle. The results indicate that the fracture toughness, fracture surface energy and change in elastic strain energy are dependent on the width ratio but the effect of fibre angle between 30 and 60° is not very dependent on fracture properties due to the arrest of the crack path in fibre composites by flyash particles.     

Mixed mode fracture behaviour of steel fibre reinforced concrete

In this paper, results are reported for a series of discrete end hooked and straight fibre pullout tests subjected to mixed mode action with the results compared to that of discrete fibres pulled out in Mode I (tensile) and Mode II (shear) fracture. As has been previously observed from Modes I and II fracture tests, the snubbing effect dominates the behaviour of fibres at large fibre bending angles. At large fibre bending angles, considerable slip and crack separation occurred prior to the fibres being engaged in taking load and fibres that are inclined close to the cracked surface are ineffective in carrying load. The results of the test were compared with the fibre engagement and bond stress models in the Unified Variable Engagement Model (UVEM). A good correlation is observed for the UVEM model with the test data and provides further confirmation of the validity of the UVEM model to predict the mix mode fracture of steel fibre reinforced concrete.     

Influence of fibre taper on the work of fibre pull-out in short fibre composite fracture

A model has been formulated to determine the work of pull-out, U, of an elastic fibre as it shear-slides out of a plastic matrix in a fractured composite. The fibres considered in the analysis have the following shapes: uniform cylinder and ellipsoidal, paraboloidal or conical tapers. Energy transfer at the fibre–matrix interface is described by an energy density parameter which is defined as the ratio of U to the fibre surface area. The model predicts that the energy required to pull out a tapered fibre is small because the energy transfer at the fibre–matrix interface to overcome friction is small. In contrast, the pull-out energy of a uniform cylindrical fibre is large because the energy transfer is large. The pull-out energies of the paraboloidal and ellipsoidal fibres lay between those for the uniform cylindrical and the conical fibres. With the exception of the uniform cylindrical fibre which yields a constant energy density, tapered fibres yield expressions for the energy density which depend on the fibre axial ratio, q. In particular, the energy density increases as q increases but converges at large q. By defining the critical axial ratio, q ₀, as the limit beyond which u is independent of the fibre slenderness, our model predicts the value of q ₀ to be about 10. These results are applied to explain the mechanisms regulating fibre composite fracture.     

The elevated-temperature dependence of fracture energy mechanisms of hybrid carbon-glass fibre reinforced composites

The fracture energy of a model hybrid carbon-glass-epoxy resin composite system has been evaluated at room temperature and three elevated temperatures. Values of the work of fracture increased with temperature and glass fibre content with an especially dramatic increase for the high temperature-high glass fibre content specimens. Evaluation of existing microstructural fracture energy mechanisms of fibre debonding, post-debond sliding and fibre pull-out were successful in quantitatively accounting for the work of fracture at room temperature. For the elevated-temperature tests of glass fibres in epoxy resin, it was shown that extensive frictional energy of the nature of the post-debond sliding mechanism is also dissipated after fibre failure.     

Interlaminar fracture toughness and associated fracture behaviour of bead-filled epoxy/glass fibre hybrid composites

To investigate enhancement of matrix-dominated properties (such as interlaminar fracture toughness) of a composite laminate, two different bead-filled epoxies were used as matrices for the bead-filled epoxy/glass fibre hybrid composites. The plane strain fracture toughness of two different bead-filled epoxies have been measured using compact tension specimens. Significant increases in toughness were observed. Based on these results the interlaminar fracture toughness and fracture behaviour of hybrid composites, fabricated using bead-filled epoxy matrices, have been investigated using double cantilever beam and end notch flexure specimens for Mode I and Mode II tests, respectively. The hybrid composites based on carbon bead-filled matrix shows an increase in both G _IC initiation and G _IIC values as compared to a glass fibre reinforced plastic laminate with unmodified epoxy matrix. The optimum bead volume fraction for the hybrid composite is between 15% and 20%. However, the unmodified epoxy glass-fibre composite shows a higher G _IC propagation value than that of hybrid composites, due to fibre bridging, which is less pronounced in the hybrids as the presence of the beads results in a matrix-rich interply region.     

Characterization of Nicalon fibres with varying diameters: Part I Strength and fracture studies

Experimental studies have been conducted to examine the strength and fracture behaviour of monofilament Nicalon SiC fibres with diameters ranging from 8 to 22 m. The effects of varying fibre diameter, flaw location and flaw population on the mechanical response of individual fibres were investigated by recourse to extensive fractographic analysis performed on fibres fractured under tensile loading. Results indicate that variations in fibre diameter influence the apparent fibre fracture toughness (K1c), with higher K1c values observed for decreasing fibre diameters. Observations also suggest that the location of the critical flaw may play a role in the fracture of Nicalon fibres. Tensile strength values are shown to increase as the normalized distance of the critical flaw from the fibre centre increases, while critical flaw population appears to be strongly dependent on location. The ratio of K1c to geometry factor (Y) is observed to remain constant with varying flaw location. In addition to surface flaws, three distinct internal flaw populations are seen to cause fracture in Nicalon fibres. Based on these experimental findings, a statistical characterization of the strength of Nicalon fibres with varying diameters is presented in Part II of this paper. © 1998 Chapman & Hall     

Effects of fibre content on mechanical properties and fracture behaviour of short carbon fibre reinforced geopolymer matrix composites

Geopolymer matrix composites reinforced with different volume fractions of short carbon fibres (C_f/geopolymer composites) were prepared and the mechanical properties, fracture behaviour and microstructure of as-prepared composites were studied and correlated with fibre content. The results show that short carbon fibres have a great strengthening and toughening effect at low volume percentages of fibres (3·5 and 4·5 vol.%). With the increase of fibre content, the strengthening and toughening effect of short carbon fibres reduce, possibly due to fibre damage, formation of high shear stresses at intersect between fibres and strong interface cohesion of fibre/matrix under higher forming pressure. The property improvements are primarily based on the network structure of short carbon fibre preform and the predominant strengthening and toughening mechanisms are attributed to the apparent fibre bridging and pulling-out effect.     

Relationships between microstructures and fracture energies in carbon fibre/PEEK composites

The aim of this investigation was to characterize the fracture surfaces of a series of similar composites, and to relate the features observed to the fracture modes. The materials used in this study were based on the ICI material APC-2, being uniaxially aligned composites of carbon fibre in a matrix of poly-ether-ether-ketone, peek. The fracture method chosen for this comparative study was to propagate cracks in the weakest plane of the materials, so that the samples split under the wedging action of a blade driven into the material. The fracture surfaces are thus representative of cracks propagating parallel to the fibres and normal to the prepreg layers. Fracture energies were obtained from analysis of the geometry of the crack without the need for any load measurements using a specially developed technique, the razor blade test^1,2. The fracture surfaces were prepared from the slivers of material split off in the test, and were examined in the scanning electron microscope (sem). They were thus taken from the same region of material which yielded the data on fracture energy. The principal microstructural factors identified as being significant were the matrix ductility and the fibre/matrix adhesion.     

Production of alumina fibre through jute fibre substrate

Alumina fibre has been produced using jute fibre as substrate material at temperatures lower than 1600 C in a reducing atmosphere. Processed jute fibre was chemically pretreated by saturation with Al₂Cl₆ · 12H₂O, coked and then pyrolysed to obtain alumina fibre. Chemical pretreatment conditions have been determined by following weight loss measurements of the jute fibre at 0.1 to 0.6 N solutions of NaOH, KOH, NH₄OH, Na₂CO₃, K₂CO₃, HCl and acetic acid. The effect of heat treatment on the jute fibre and jute fibre + aluminium salt has been studied from 150 to 1600 C. Trace elements present (Fe₂O₃, SiO₂, K₂O, Na₂O, CaO, MgO, ZnO, MnO, V₂O₅, P₂O₅, CuO) on heat-treated products have been determined by atomic absorption spectrometry. Optical and scanning electron micrographs of representative samples showing growth mechanism are presented. The effect of copper, nickel and platinum catalysts and fluxing agents such as K₂O and Na₂O in fibre formation has also been examined. Particle size and surface area analyses of intermediate and final products have been carried out. Changes in 2 values are plotted for various products from X-ray diffraction studies. It is conceived that the porous surface of cellulosic fibrils in the jute fibre adsorbs the AlCl₃ molecules which decompose to oxide and are gradually shaped to the fibrous form during the course of thermal treatment in a reducing atmosphere and due to the high surface area.     

Strength and fracture toughness of carbon fibre polyester composites

Fracturing of carbon fibre/polyester composites has been studied by means of mechanical testing and scanning electron microscopy. Carbon fibres were surface-treated in several ways so as to vary the interlaminar shear strength of the composites, and the effect of this variation on the work of fracture was determined by means of Charpy V-notch impact tests and slow three-point bend tests on notched specimens of triangular cross-section. The effect of moisture on the fracture toughness was also studied by measuring toughness and interlaminar shear strength after exposure to steam. Improvement of the fibre/resin bond results, as expected, in an increase in the brittleness of composites and it appears that a purely mechanical bond, such as might be obtained by acid-etching the fibre surface, is less proof against deterioration in humid atmospheres than a chemical bond, such as can be obtained by the use of coupling agents. Estimates of the magnitude of various contributions to the fracture toughness show that in carbon-fibre-reinforced resins the effect of increasing the stiffness or load-bearing ability of the matrix and the work done against friction in pulling broken fibres out of the matrix contribute approximately one fifth and four fifths, respectively, of the total work of fracture.     

Investigation of mixed-mode fracture of aligned steel fibre reinforced cementitious composites

International Journal of Fracture - Mixed-mode fracture experiments were conducted on aligned steel fibre reinforced cementitious composite (ASFRC) and ordinary steel fibre reinforced cementitious...     

Effect of fibre content on the interlaminar fracture toughness of unidirectional glass-fibre/polyamide composite

In this paper, the effects of fibre content on the interlaminar fracture in continuous glass-fibre/polyamide 12 composite have been investigated under model I (DCB) loading condition. The specimens were fabricated with different fibre volume contents (21%, 26%, 34% and 39%) by using a powder impregnation method. It was observed that the values of G_IC(NL) and G_IC(PROP) of this material have a dropping tendency with increasing fibre volume content in the range of 21%–39%, while no general trends in G_IC(5%) and G_IC(VIS). Results show that the glass-fibre/polyamide 12 composites possess high mode I fracture toughness, which is mainly attributed to the high ductility of the polyamide 12 matrix, and the increased fibre bridging caused by the increasing of the fibre volume content can not change the decrease tendency of G_IC(PROP). The fracture surfaces of the specimens were observed by scanning electron microscopy, and the fracture mechanism was analysed.     

Discrete fracture in high performance fibre reinforced concrete materials

In this paper a simple, but effective methodology to simulate opening mode fracture in high performance fibre reinforced concrete is presented. The main contribution of the paper is a technique to extrapolate the load displacement curves of three point bending experiments on fibre reinforced concrete. The extrapolation allows the full work of fracture to be determined, from which the fracture energy may be obtained. The fracture energy is used in the definition of a cohesive softening function with crack tip singularity. The softening relation is implemented in an embedded discontinuity method, which is employed for the numerical simulation of three point bending experiments. The experimental work includes a size effect study on three point bending specimens. The numerical simulation provides a satisfactory prediction of the flexural behaviour and the size effect observed in the experiments.     

Shear strength and fracture toughness of carbon fibre/epoxy interface: effect of surface treatment

Textile-reinforced composites have become increasingly attractive as protection materials for various applications, including sports. In such applications it is crucial to maintain both strong adhesion at fibre–matrix interface and high interfacial fracture toughness, which influence mechanical performance of composites as well as their energy-absorption capacity. Surface treatment of reinforcing fibres has been widely used to achieve satisfactory fibre–matrix adhesion. However, most studies till date focused on the overall composite performance rather than on the interface properties of a single fibre/epoxy system. In this study, carbon fibres were treated by mixed acids for different durations, and resulting adhesion strength at the interface between them and epoxy resin as well as their tensile strength were measured in a microbond and microtensile tests, respectively. The interfacial fracture toughness was also analysed. The results show that after an optimum 15–30 min surface treatment, both interfacial shear strength and fracture toughness of the interface were improved alongside with an increased tensile strength of single fibre. However, a prolonged surface treatment resulted in a reduction of both fibre tensile strength and fracture toughness of the interface due to induced surface damage.     

Mixed-mode fracture performance of fibre reinforced concrete under impact loading

A test procedure developed to determine the mixed-mode impact resistance of fibre reinforced concrete materials is described. Results are presented from a series of experiments using a repeated drop-weight impact apparatus for the impact resistance of both polypropylene and steel fibre reinforced concrete. The behaviour of the mixed-mode specimen geometry was investigated under impact loading condition. The effect of the fibre types and contents on the impact fracture energy of the specimens was investigated. A close investigation was made of the positions and formations of the crack patterns. The fracture performance of the plain and fibre reinforced concrete was investigated with the proposed geometry using 1.0, 2.0 and 3.0% by weight in the case of steel fibre, and 0.1, 0.2 and 0.3% by weight in the case of polypropylene fibre.

---

Resume Aux charges statiques auxquelles les structures en béton sont soumises s'ajoutent souvent des charges dynamiques, parfois significatives, qu'il convient de prendre en compte dans le calcul. Cet article décrit un mode opératoire visant à déterminer la résistance au choc en mode mixte de béton renforcé de fibres (FRC). On y présente les résultats d'une série d'essais utilisant une machine d'essai au choc à répétition (mouton) pour évaluer la résistance de béton renforcé de fibres d'acier et de fibres de polypropylène. On a mis au point une géométrie d'éprouvettes en mode mixte qu'on a soumises à des essais au choc, et on a étudié l'effet des types et des pourcentages de fibres sur la résistance des éprouvettes à la rupture par choc. On s'est aussi livré à une étude précise des emplacements et de la formation des fissures. On a examiné la résistance à la rupture de béton ordinaire et de béton de fibres dans la géométrie proposée avec des pourcentages de 1, 2 et 3% en poids de fibres d'acier, et de 0,1, 0,2 et 0,3% pour les fibres de polypropylène.