共查询到17条相似文献,搜索用时 140 毫秒
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反应烧结碳化硅陶瓷的制备及烧结机理 总被引:7,自引:2,他引:5
用溶胶-凝胶法合成的无机/有机杂化材料结合SiC+C混合粉料制成了反应烧结碳化硅陶瓷素坯,并对由这种素坯制成的碳化硅陶瓷进行了物相鉴定和显微结构观察;借助Si-C相图对反应烧结碳化硅的烧结机理进行了研究,分析表明其主要烧结机理为溶解-再沉淀型。 相似文献
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探索一种制备无机基质/有机杂化光功能材料的途径,采用溶胶-凝胶法在无机基质溶胶中分别掺杂自制的5种有机发光材料,制备出透明、均匀的有机-无机杂化发光薄膜,研究其发光行为,探讨发光行为的规律。 相似文献
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王国祥 《化学工业与工程技术》2008,29(6):7-10
以丙烯酰胺为有机相,通过钛酸正丁酯的水解引入二氧化钛无机相,采用溶胶-凝胶法制备了聚丙烯酰胺(PAM)/二氧化钛(TiO2)水溶性高聚物杂化材料。讨论了二氧化钛溶胶质量分数、单体质量分数对聚合反应转化率的影响;对合成的杂化材料进行了红外、热性能表征。实验结果表明,二氧化钛包裹在聚丙烯酰胺内部,同时,合成的杂化材料耐热性能有所提高。 相似文献
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Summary A type of hybrid material incorporating poly(methyl methacrylate) with tetraethoxysilane (TEOS) has been successfully prepared by using the in-situ sol-gel process. The bonding between the organic phase and inorganic phase involved (3-trimethoxysilyl) propyl methacrylate. The thermal properties of the hybrid materials varied with the acid content, the TEOS content and the molecular weight of polymer were investigated by thermal gravimetric analysis. 相似文献
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Inorganic/organic hybrid materials have considerable promise and are beginning to become a major area of research for many
coating usages, including abrasion and corrosion resistance. Our primary approach is to prepare the inorganic phase in situ
within the film formation process of the organic phase. The inorganic phase is introduced via sol-gel chemistry into a thermosetting
organic phase. By this method, the size, periodicity, spatial positioning, and density of the inorganic phase can be controlled.
An important aspect of the inorganic/organic hybrid materials is the coupling agent. The initial task of the coupling agent
is to provide uniform mixing of the oligomeric organic phase with the sol-gel precursors, which are otherwise immiscible.
UV-curable inorganic/organic hybrid systems have the advantages of a rapid cure and the ability to be used on heat sensitive
substrates such as molded plastics. Also, it is possible to have better control of the growth of the inorganic phase using
UV curing. It is our ultimate goal to completely separate the curing of inorganic and organic phases to gain complete control
over the morphology, and hence optimization of “all” the coating properties. Thus far, it has been found that concomitant
UV curing of the inorganic and organic phases using titanium sol-gel precursors afforded nanocomposite coatings which completely
block the substrate from UV light while maintaining a transparent to visible light. Also, it has been found that the morphology
of the inorganic phase is highly dependent on the concentration and reactivity of the coupling agent.
Presented at the 82nd Annual Meeting of the Federation of Societies for Coatings Technology, October 27–29, 2004, in Chicago,
IL. 相似文献
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Epoxidized soybean oil-based ceramer coatings 总被引:3,自引:2,他引:1
New inorganic/organic hybrid coating containing epoxidized soybean oil were prepared. Three sol-gel precursors [titanium (IV)
i-propoxide, titanium (IV) di-i-propoxide bis-acetoacetonate, and zirconium n-propoxide] were utilized as the inorganic phase. Various coating properties, including adhesion, hardness, impact resistance,
flexibility and tensile properties, were investigated as a function of sol-gel precursor type and concentration. All ceramer
coatings exhibited excellent flexibility and hardness. Tensile strength and hardness increased with sol-gel precursor concentration.
A slight decrease in adhesion and impact resistance was observed with increasing precursor content. 相似文献
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Self-assembled organic/inorganic hybrid materials were created via domain targeted sol-gel reactions of tetraethylorthosilicate in solution with sulfonated poly(styrene-b-[ethylene-co-butylene]-b-styrene) (sSEBS) copolymers. Dynamic mechanical analyses (DMA) of these hybrid materials suggest that the silicate component preferentially incorporates within the sulfonated polystyrene (PS) domains. An irreversible order-order transition (OOT) for unmodified SEBS, sSEBS, and the organic/inorganic hybrids was identified using DMA in shear mode. The OOT temperature increases with sulfonation as well as by adding a silicate phase by the sol-gel process. The DMA results imply a morphological shift with sulfonation, and reflect modified interactions within and between phases. Atomic force microscopy (AFM) indicated a shift from hexagonally packed cylinders in unmodified SEBS to a lamellar morphology in the sulfonated materials, but silicate incorporation did not affect the morphology or domain dimensions. The latter result is evidence for sol-gel polymerization templating in a self-assembly process. The phase-separated morphology is stable up to the degradation temperature of the polymer and thermogravimetric analysis revealed that the degradation temperature is unaffected by silicate incorporation. Small angle X-ray scattering data are in harmony with the structures revealed by AFM in terms of degree of order and scale of features. These results are largely rationalized in terms of chain mobility restrictions due to hydrogen-bonding interactions between different sulfonated PS blocks, an increase in the PS-ethylene/butylene block mixing parameter, increased interfacial surface tension and chain restrictions posed by inserted silicate nanostructures in the case of the hybrid materials. 相似文献
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金属涂装预处理技术一些进展 总被引:1,自引:0,他引:1
叙述了利用溶胶-凝胶技术制备无机-有机杂化复合涂层的原理和过程,及用于铝合金、不锈钢、镀锌铁板等金属涂装的预处理,革除磷化、铬钝化等污染工序,获得很好效果。并介绍了对汽车、铝型材等涂装实例。对低表面处理涂料发展简况和应用实例也作了简介。 相似文献