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合成并鉴定了二安替比林基─(2─溴)苯基甲烷(DAOBM),研究了它与钒(Ⅴ)的显色条件。在Tween─80和Mn(Ⅱ)存在下,DAOBM与V(Ⅴ)在H3PO4(1+10)介质中生成橙色产物,λmax=490nm,ε=1.55×106L·mol-1·cm-1,V(Ⅴ)的浓度在0.1~0.9μg/25ml范围内符合比尔定律。方法用于中草药和矿样中钒的测定,结果满意。 相似文献
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新型热作模具钢(JM)的研究与应用 总被引:1,自引:1,他引:0
5Cr4W4MoVNb钢(JM)是一种新型加钒、铌的Cr-W-Mo热作模具钢。应用结果表明,该钢具有良好的锻造性能和机械加工性能,用该钢制作的精锻齿模和扳手模的使用寿命比3Cr2W8V钢提高1倍以上。 相似文献
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镧系元素高氯酸盐苯丁基亚砜配合物的合成与表征 总被引:7,自引:0,他引:7
本文以稀土高氯酸盐RE(ClO_4)_3nH_2O(RE=La~(3+)、Ce~(3+)、Pr~(3+)、Nd~(3-)、Sm~(3-)、Eu(3+),n=6~7)与苯丁基亚砜PBSO(C_6H_5C_4H_9)在无水乙醇体系中合成出六个新配合物,并对配合物进行了元素分析,稀土离子含量测定,配体PBSO含量测定ClO_4~-含量测定、IR谱、导电、TG-DTA分析及X-射线粉末衍射。确定了配合物的组成为[RE(BPSO)_7(ClO_4)](ClO_4)_2,配位数为8,电解质类型为1:2。 相似文献
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矿样经Na2O2,NaOH熔融后碱过滤分离大量钛、铁等杂质,在PH4.5的乙酸一乙酸钠介质中,V(Ⅳ)柯还原Fe(Ⅲ)-phen据此建立了钛铁矿中微量钒的光度测定方法。最大吸收波长为512nm,间接摩尔吸光系为1.1×10^4。 相似文献
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热作模具钢4Cr5Mo2NiVRE(R88)的研制 总被引:2,自引:0,他引:2
通过加钒-钼和镍-稀土使新研制的钢种4Cr5Mo2NiVRE(R88)在高温下具有高的热稳定性、抗氧化性和高的强韧性。应用结果表明,R88钢制成的热作模具寿命比3Cr2W8V钢模具提高一倍。 相似文献
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2-(2-苯并噻唑偶氮)-5-磺丙氨基苯酚高效液相色谱法测定钢中钒、钴和镍 总被引:1,自引:0,他引:1
在KIO_4存在下,研究了2-(2-苯并噻唑偶氮)-5-磺丙氨基苯酚(BTASPAP)与V(Ⅴ),Co(Ⅱ)和Ni(Ⅱ)形成稳定络合物的反应,在Cl8柱上,以含0.2mol/L的乙酸-乙酸钠缓冲溶液(pH3.5)和1.0×10-3mol/L,溴化四丁基铵的乙腈-丙酮-水(36+1+63)为流动相洗脱液,在565nm处检测。V(Ⅴ),CD(Ⅱ)和Ni(Ⅱ)的络合物在6min内获得完全分离,检测限分别为15.0ng/ml,15.0ng/ml和40.0mg/ml.该方法已用于合金钢中钒、钴和镍的测定。 相似文献
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在微酸性介质中痕量V(Ⅴ)对重铬酸钾氧化偶氮胂Ⅲ褪色的反应有显著的催化作用,催化反应的表观活化能为2172kJ·mol-1。据此建立了测定痕量钒的催化动力学分析法。线性测定范围为002~020μg·ml-1,方法检出限为002μg·ml-1V。本法重现性较好,用于测定人发、马铃薯、茶叶和废水中钒的含量,结果满意。 相似文献
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Cr2O3和铬铁矿能溶于H2SO4-Li2SO4Ce(SO4)2(20/10/1V/W/V),H2SO4-Li2SO4-MnO2(20/10/1V/W/W)或H2SO4-Li2SO4-KIO4(20/10/2/V/W/W)中,生成的混浊溶解可用H2O2处理或溶剂萃取使之变得清亮,而后用分光光度法在614nm处测定铬。 相似文献
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<正>Minmetals Resources acquired the world’s largest copper mine under construction for USD5.85 billion.One after another,listed companies Jien Nickle,China Molybdenum and Chihong Zinc and Germanium raised money to get involved in overseas mining projects…SOEs and private enterprises are engaged in a frenzy of overseas mine purchasing.A reporter with Economic 相似文献
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正Judging from China’s copper consumption field,the biggest consumption unit is electric power,which accounts for 47%of total consumption;it is followed by light industry sector,including household electrical appliance,machinery,durable goods and hardware etc,which accounts for 22%of total consumption;followed by transportation field, 相似文献
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《China Nonferrous Metals Monthly》2014,(10)
正In 2013,the Central Geological Prospecting Fund(CGPF)Project newly discovered 15 ore fields,including 3 large above ore fields,and 5medium sized ore fields.The reporter learned from the recently published"Annual Report of Central Geological Prospecting Fund Project(2013)"that,from 2006 to 2013 the CGPF 相似文献
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《China Nonferrous Metals Monthly》2014,(10)
正This year,the investment growth rate of real estate industry continued to slow down,sold area of commercial housing also dropped significantly,which brought huge pressure to the domestic air conditioning manufactures.In the first half of the year,by relying on high growth in national financial expenditure,along with investment in public infrastructure 相似文献
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《China Nonferrous Metals Monthly》2014,(10)
正Kang Yi,Honorary Chairman of China Nonferrous Metals Industry Association,said recently at the Forum on Development of the Non-ferrous Metals Industry in Central and Western China held in Zhengzhou that,as more and more electrolytic aluminum factories in Xinjiang came into operation,the electrolytic aluminum output of Xinjiang had reached2,275,000 tons in the first 7 months this year, 相似文献
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《China Nonferrous Metals Monthly》2014,(12)
正"Xinjiang project has been completed according to schedule,but total completion and total start of production are two different concepts,after completion it still needs a gradual process of reaching production target."On the morning of November 3,Shenhuo Coal Industry and Electricity Power told investors the above statement on the investor interaction platform. 相似文献
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正The reporter learned from Guangdong Province Precious Metal Transaction Center that in 2013the Center maintained healthy development momentum,and had become the second largest precious metal transaction platform in China in terms of market size;currently Guangdong is quickening steps of financial innovation for the Center,aiming to build a transaction center with international core competitiveness. 相似文献
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正On May 22,Baotou Rare Earth Industry Cooperation Consultation MeetingProject Agreement-signing Ceremony was held in Ningbo,nearly 40 enterprises from Ningbo,Guangdong,Hunan,and Shanxi participated in project consultation.After multi-lateral communication,agreements were signed for a total of 7 rare earth projects successfully. 相似文献