热作模具钢热处理工艺研究

本文以热作模具钢H13为主要研究对象,从其使用条件出发,简述了合金元素在工件当中的作用,并详细阐述了热处理工艺的控制要点。认为,正火应采用高温空冷正火,用以消除大部分碳化物;球化退火应采用等温球化退火,均匀冷却工件,减少其变形和开裂的倾向;淬火应采用1 010℃左右的高温淬火,以获得足够的晶粒度,保证工件的热强性;回火应在600℃左右回火三次较为适合。     

大截面热作模具钢45Cr2NiMoVSi中残余奥氏体为的研究

研究了大截面热作模具钢４５Ｃｒ２ＮｉＭｏＶＳｉ中残余奥氏体（以下简称Ａｒ）的回火转变动力学、Ａｒ的热稳定性和机械稳定性、Ａｒ的分布形态以及Ａｒ对材料性能的影响。提出了热模钢回火新工艺的两种可能性。     

H13热作模具钢热处理工艺研究

以热作模具钢的代表——H13热作模具钢的使用条件作为热处理工艺设定参数的主要考虑对象,采用合金化的角度简述合金元素在工件当中的作用,并分析现阶段H13热作模具钢的热处理过程中正火、球化退火、淬火、回火等工艺,以此为出发点,制定并完善了传统的热作模具钢的热处理工艺.     

H13热作模具钢的热处理

测定了Ｈ１３钢的临界点和退火用ＴＴＴ曲线,研究了热处理工艺对Ｈ１３组织和性能的影响,试验结果表明,Ｈ１３钢在８４０￣８６０℃退火,软化效果最好,在１０２０￣１０４０℃加热淬火,５８０￣６００℃回火,可满足热作模具钢的硬度要求。     

4Cr5Mo2V热作模具钢组织和性能研究

研究了不同热处理工艺对新型热作模具钢4Cr5Mo2V钢的组织和性能的影响,并与H13钢作了对比。结果表明：经1030℃淬火,4Cr5M02V钢硬度可达到57．7HRC,晶粒度达到9级;经1030℃淬火,600℃回火两次后该钢保持与H13钢硬度相同的情况下具有更好的冲击韧性。     

含氮热作模具钢的成分与热处理工艺优化分析

现代金属制造工艺较以往出现了多种变化,技术持续进步,从进一步提升材料质量的角度出发,也有必要继续加强研究。本文以含氮热作模具钢的成分与热处理工艺优化为目标,首先分析含氮热作模具钢的质量影响因素、控制思路等内容,再以此为基础,通过模拟实验的方式,从钒和氮含量控制、淬火和回火温度控制等方面,做材料质量对比分析,服务后续工作。     

H13热作模具钢的应用

H13(4Cr5MoSiV1)热作模具钢是首钢特殊钢公司根据美国标准钢号H13开发的一种使用温度在600℃以下的中碳中铬热作模具钢。H13既具有3Cr2W8V钢的高温性能,又具有5CrMnMo钢高韧性的特点,也具有一般热作模具钢要求的较高的热硬性、热强性、抗回火稳定性、耐磨性、抗冷热疲劳性等。现已在锤锻模、挤压模、压铸模、模锻模等     

热作模具钢H13开坯工艺研究

H13(4Cr5MoSiV1)是目前国内较常用的热作模具钢品种之一,由于该钢种碳含量特别是合金含量较高,过去该钢种的生产一直沿袭炼钢铸小钢锭——锻钢生产的工艺路线,限制了该品种的发展,本文从开发H13轧材工艺的关键初轧开坯入手,对H13在初轧工序的加热、轧制、精整等工艺进行试验研究取得成功,为打通H13轧材生产工艺打下了坚实的基础。     

新型热作模具钢的试验研究

对新型热作模具钢4Cr2Mo2MnVNbB作了全面性能试验,并与老钢种3Cr2W8V进行对比及应用考核,证明本钢种的综合性能较高,使用寿命长,可以更替3Cr2W8V钢,其应用价值显著,可供有关部门选用。     

Effect of Deep Cryogenic Treatment on Formation of Reversed Austenite in Super Martensitic Stainless Steel

The effect of deep cryogenic treatment on the formation of reversed austenite(RA)in super martensitic stainless steel was investigated.RA was found to form in steels without(A)and with(B)deep cryogenic treatment.The volume fraction of RA initially increased and then decreased with increasing tempering temperature over 550-750 ℃for the two steels,which were quenched at 1 050 ℃.In addition,for both with and without deep cryogenic treatment,the RA content reached a maximum value at 650 ℃ although the RA content in steel B was greater than that in steel A over the entire range of tempering temperatures.Furthermore,the hardness(HRC)of steel B was greater than that of steel A at tempering temperatures of 550-750 ℃.From these results,the basic mechanism for the formation of RA in steels A and B was determined to be Ni diffusion.However,there were more Ni-enriched points,a lower degree of enrichment,and a shorter diffusion path in steel B.It needed to be noted that the shapes of the RA consisted of blocks and stripes in both steels.These shapes resulted because the RA redissolved and transformed to martensite along the martensitic lath boundaries when the tempering temperature was 650-750 ℃,and a portion of RA in the martensitic lath divided the originally wider martensitic laths into a number of thinner ones.Interestingly,the RA redissolved more rapidly in steel B and consequently resulted in a stronger refining effect.     

H13改进型热作模具钢的组织与性能

 研究了高锰型马氏体热作模具钢SDH3-Mod的室温冲击韧性、回火稳定性和热疲劳性能,并结合透射电镜(TEM)分析了锰对其微观组织的影响。结果表明：SDH3-Mod钢回火组织中残余奥氏体以薄膜状存在于马氏体板条间,提高冲击韧性,延缓裂纹扩展;同时,锰在高温时阻碍碳化物粗化长大和延迟基体的回复再结晶,提高抗回火软化能力和热疲劳性能,使SDH3-Mod性能优于H13。     

Microstructure and Properties of Hot Working Die Steel H13MOD

Compared with H13 steel, the influences of different heat treatment process on the microstructure and properties of the new type of hot working die steel H13MOD were studied. The results show that the complete austenitizing temperature of H13MOD is around 1030 °C and the quenching hardness achieves the maximum value at this temperature. While for H13, the complete austenitizing temperature is above 1100 °C and the quenching hardness rise constantly with the quenching temperature increasing. In quenching process, the undissolved MC carbides can prevent the coarsening of grain in both steels. With the rise of quenching temperature, when MC carbides dissolve completely, the grain grows quickly. The hardness and strength of H13MOD at higher tempering temperature (above 570 °C) are nearly the same as those of H13, but its toughness is higher than that of H13. Mo₂ C carbide is the main strengthening phase in H13MOD, which is attributed to the higher content of Mo. The quantity of VC eutectic carbides is reduced because of lower content of V in H13MOD, which plays an important role in enhancing the impact toughness of H13MOD. Under a certain strength condition, H13MOD steel can be used in the environment that higher toughness is required and the service life of die casting mold can be improved.     

深冷处理对H13钢组织结构和热稳定性的影响

 为了研究深冷处理对H13热作模具钢热稳定性的影响及组织演化规律,利用洛氏硬度计、X射线衍射仪、扫描电子显微镜及透射电子显微镜等对经不同热处理工艺处理后H13热作模具钢的热稳定性及显微组织进行了表征。结果表明,深冷处理促使部分残余奥氏体转变为马氏体,导致深冷处理后试验钢的硬度高于淬火态试验钢的硬度。经深冷处理后试验钢在540 ℃回火20 h过程中其硬度均比常规热处理的试验钢硬度高,深冷处理的试验钢具有更好的热稳定性。与常规热处理的试验钢相比,深冷处理促使钢中碳原子偏聚并在回火过程中以碳化物的形式析出,导致深冷处理的试验钢回火后马氏体基体中碳的质量分数降低。透射电镜结果显示,试验钢在回火过程中析出的大量弥散分布的纳米级M₂₃C₆型碳化物,经长时间回火后碳化物粗化致使试验钢硬度随着回火时间的增加而下降。     

Influence of Shallow and Deep Cryogenic Treatment on Tribological Behavior of En 19 Steel

 The influence of cryogenic treatment on the wear resistance of En 19 steel was studied. Furthermore, a comparative analysis on the effect of Deep Cryogenic Treatment (DCT, -196 ℃×24 h), Shallow Cryogenic Treatment (SCT, -80 ℃×5 h) and Conventional Heat Treatment (CHT) was done through dry sliding wear testing. The microstructures of CHT, SCT and DCT samples were also examined through scanning electron microscopy. The results indicated that the wear resistance of shallow and deep cryogenically treated samples is higher when compared to that of conventionally treated samples. X-ray diffraction pattern revealed that the transformation of retained austenite into martensite is responsible for the wear resistance improvement.     

热作模具钢的硬韧性因子

 根据热作模具钢的服役条件,基于均匀设计试验方法,设计了6种不同成分的热作模具钢,同时设计了对应的热处理工艺。测定了这6种钢的室温冲击韧性和二次回火后的硬度,提出了硬韧性因子(HT),并利用二次型逐步回归分析方法得到了硬韧性因子与化学成分及热处理工艺之间的关系。     

深冷处理在金属材料中的应用及研究进展

概述了金属材料深冷处理技术的发展历程,介绍了深冷处理的工艺、机理,并对深冷处理技术的应用发展趋势作了探讨。     

深冷处理后W18Cr4V高速钢的显微组织

 用X射线衍射和透射电子显微镜研究了W18Cr4V高速钢循环深冷处理前后的显微组织。结果表明,与一次长时间深冷处理相比,多次循环深冷处理后马氏体轴比和碳含量明显下降,奥氏体含量进一步减少,有大量新的超细弥散碳化物颗粒沿马氏体孪晶带和位错线析出,表明高速钢多次循环深冷处理效果好于一次长时间深冷处理。     

Comparison of Microstructures and Properties Obtained After Different Heat Treatment Strategies of High Strength Low Alloyed Steel

The influence of different heat treatment strategies on the microstructure and properties of 42SiCr steel was investigated.To compare the benefit of innovative treatment methods with more conventional ones,several strategies based on a new quenching and partitioning (Q-P) process were designed together with several strategies using more traditional quenching and tempering process.Different combinations of mechanical properties were obtained with ultimate strengths in the range of 1818-2120 MPa and ductility between 10% and 24%.Resulting microstructures were martensitic with 0-12% of retained austenite and they were analyzed by laser scanning confocal microscopy,transmission electron microscopy and X-ray diffraction phase analysis.