立式双辊铸轧镁合金薄带微观组织分析

在实验室的立式双辊铸机上进行了AZ31B镁合金薄带的铸轧试验.研究了不同工艺下铸轧薄带微观组织,并对不同冷却方式下铸轧镁合金薄带微观组织进行了分析.结果表明,双辊铸轧镁合金晶粒细小、无共析现象发生.铸轧速度对板带的显微组织影响显著,当铸轧速度达到20 m/min时,镁合金薄带组织为理想等轴晶.对铸轧态镁合金薄带进行油冷,既防止了薄带表面氧化,又阻止了冷却过程晶粒长大.     

薄带双辊铸轧过程凝固组织的数值模拟

采用有限元方法计算铸轧过程中的宏观传输现象,用元胞自动机方法模拟微观凝固组织,将二者耦合模拟了双辊铸轧薄带凝固过程中晶粒的形核与长大过程,实现了对双辊铸轧薄带凝同过程组织演变的模拟;并以镁合金AZ31B为对象,研究了薄带铸轧工艺过程中的主要工艺参数(浇注温度、铸轧速度等)对镁合金薄带凝固组织的影响规律,从而为通过工艺优化来控制铸轧薄带的凝固组织提供了理论依据.     

双辊铸轧法生产变形镁合金薄带新工艺的研究

面对开发新一代变形镁合金产品的迫切要求，东北大学国家重点实验室与吉林临江镁业股份有限公司合作，用双辊铸轧法成功生产出1mm～3mm厚的AZ31镁合金薄带，并获得了良好的薄带组织和塑性性能，为企业实现变形镁合金薄带的工业化生产提出了新的技术路线。     

AZ31镁合金薄带铸轧温度场的数值模拟

借助ANSYS软件下的Fluent模块模拟了AZ31镁合金铸轧区的温度场,研究了AZ31镁合金薄带铸轧时不同工艺参数下铸轧区的三维温度场的分布,分析了温度场的分布对薄带铸轧过程稳定性的影响。通过对比分析模拟结果,给出在所选取范围内最佳工艺参数是,浇注温度为853K,铸轧速度为9m/min,冷却水流速为3m/s。     

双辊快速凝固AZ31镁合金薄带试验研究

在等径双辊连铸机上进行了AZ31镁合金薄带连铸的试验研究，掌握了诸如浇铸温度、铸辊转速、辊缝和侧封等合理的工艺参数，成功地铸出了AZ31镁合金薄带并对其显微组织进行了分析。     

双辊铸轧镁合金板坯微观组织特征

利用自行开发的镁合金双辊铸轧设备，通过镁合金铸轧工艺试验，制备出AZ31镁合金铸轧板坯。研究了双辊铸轧镁合金板坯显微组织特征及铸轧温度对板坯微观组织影响规律。结果表明，镁合金双辊铸轧板坯晶粒细小，均匀圆整，显微组织具有快速凝固和半固态组织特征；铸轧温度对板坯显微组织的影响显著，当铸轧温度为685℃时，镁合金铸轧板坯获得理想的显微组织。     

铸轧Al-Si系镁合金组织性能的研究

近终形双辊铸轧镁合金薄带是目前国内外研究的热点之一,本文中以AS系镁合金为研究对象,利用双辊铸轧法成功铸轧出了厚度5mm的AS系镁合金板材,并研究了镁合金铸轧薄带组织和后续热轧工艺对镁合金板材组织性能的影响。研究表明,As系镁合金铸轧薄带组织均匀,铸轧的亚共晶组织（Mg．3％A1-0．75％Si）主要由细小的蔷薇状枝晶组成;而铸轧的共晶与过共晶组织（Mg-5．52％A1-1．4％Si和Mg-6％A1-1．6％Si）主要由蔷薇状枝晶和等轴晶组成。热轧后,再结晶程度、晶粒细化效果和抗拉强度随压下量的增加而提高。     

铸轧镁合金薄带组织演变实验研究与模拟

以镁合金薄带双辊铸轧新技术为背景,开展了铸轧成形过程中组织性能的模拟研究。镁合金薄带双辊铸轧是以液态镁合金为原料,用两个反向转动的水冷铸辊为结晶器,直接制备1．5～3．0mm镁合金薄带的短流程新工艺。对双辊铸轧轻合金薄带的凝固组织演化过程进行数值模拟,用以优化和指导制备技术,具有重要的理论意义和应用前景。项目研究组通过对双辊铸轧过程动态凝固成形的有限元数值模拟研究、镁合金薄带铸轧实验研究以及后续加工过程中的组织演变规律研究,得到了主要工艺参数对铸轧工艺稳定性及组织性能的影响规律。     

AZ31B镁合金电磁铸轧实验研究

在自行设计、安装的水平式双辊连续铸轧机上进行了AZ31B镁合金电磁铸轧试验,成功试制出3mm×200mm×Lmm的AZ31B镁合金铸轧板,研究了电磁场对铸轧板组织及力学性能的影响。结果表明,在AZ31B镁合金铸轧过程中施加电磁场能显著细化铸轧板的晶粒组织,晶粒平均尺寸由不加电磁场的28～30μm减小至12μm左右;板坯力学性能也得到有效改善,抗拉强度、屈服强度、伸长率和硬度分别提高了16.3%、28.7%、50%和17.1%。     

Al-Ti-C对AZ61镁合金铸轧及热轧后组织的影响

研究了Al-Ti-C对双辊铸轧镁合金薄带的组织影响,并利用铸轧坯直接进行热轧,研究了细化有剂对镁合金微观组织的影响。结果表明,添加了细化剂Al-Ti-C的薄带铸轧组织基本为等轴晶,晶粒明显细化。     

Effects of Post-weld Heat Treatment on Microstructure,Mechanical Properties and the Role of Weld Reinforcement in 2219 Aluminum Alloy TIG-Welded Joints

In as-welded state, each region of 2219 aluminum alloy TIG-welded joint shows diff erent microstructure and microhardness due to the diff erent welding heat cycles and the resulting evolution of second phases. After the post-weld heat treatment, both the amount and the size of the eutectic structure or θ phases decreased. Correspondingly, both the Cu content in α-Al matrix and the microhardness increased to a similar level in each region of the joint, and the tensile strength of the entire joint was greatly improved. Post-weld heat treatment played the role of solid solution strengthening and aging strengthening. After the post-weld heat treatment, the weld performance became similar to other regions, but weld reinforcements lost their reinforcing eff ect on the weld and their existence was more of an adverse eff ect. The joint without weld reinforcements after the post-weld heat treatment had the optimal tensile properties, and the specimens randomly crack in the weld zone.     

The First Phase of the SRIF Industrialized Base in ＂West Area＂ Has Been Put into Operation

After nearly two years＇ tense construction, the first phase of industrialized base of Shenyang Research Institute of Foundry （SRIF）, located at the Tiexi Casting and Forging Industrial Park in the west of Tiexi District, has now been completed and formally put into operation.     

Thermodynamics Study on the Decomposition of Chromite with KOH

Institute of Process Engineering, Chinese Academy of Sciences, China, has proposed a method for oxidative leaching of chromite with potassium hydroxide. Understanding the mechanism of chromite decomposition, especially in the potassium hydroxide fusion, is important for the optimization of the operating parameters of the oxidative leaching process. A traditional thermodynamic method is proposed and the thermal decomposition and the reaction decomposition during the oxidative leaching of chromite with KOH and oxygen is discussed, which suggests that chromite is mainly destroyed by reactions with KOH and oxygen. Meanwhile, equilibrium of the main reactions of the above process was calculated at different temperatures and oxygen partial pressures. The stable zones of productions, namely, K2CrO4 and Fe2O3, increase with the decrease of temperature, which indicates that higher temperature is not beneficial to thermodynamic reactions. In addition, a comparison of the general alkali methods is carried out, and it is concluded that the KOH leaching process is thermodynamically superior to the conventional chromate production process.     

Influence of Heat Treatment on Damping Behaviour of the Magnesium Wrought Alloy AZ61

The effect of isochronal heat treatments for 1h on variation of damping, hardness and microstructural change of the magnesium wrought alloy AZ61 was investigated. Damping and hardness behaviour could be attributed to the evolution of precipitation process. The influence of precipitation on damping behaviour was explained in the framework of the dislocation string model of Granato and Lücke.     

Effect of Rare Earth Doping on Impedance,Modulus and Conductivity Properties of Multiferroic Composites:0.5(BiLa_xFe_(1-x)O_3)–0.5(PbTiO_3)

The Lanthanum-doped bismuth ferrite–lead titanate compositions of 0.5(Bi LaxFe1-xO3)–0.5(Pb Ti O3)(x = 0.05,0.10,0.15,0.20)(BLxF1-x-PT) were prepared by mixed oxide method.Structural characterization was performed by X-ray diffraction and shows a tetragonal structure at room temperature.The lattice parameter c/a ratio decreases with increasing of La(x = 0.05–0.20) concentration of the composites.The effect of charge carrier/ion hopping mechanism,conductivity,relaxation process and impedance parameters was studied using an impedance analyzer in a wide frequency range(102–106Hz) at different temperatures.The nature of Nyquist plot confirms the presence of bulk effects only,and non-Debye type of relaxation processes occurs in the composites.The electrical modulus exhibits an important role of the hopping mechanism in the electrical transport process of the materials.The ac conductivity and dc conductivity of the materials were studied,and the activation energy found to be 0.81,0.77,0.76 and 0.74 e V for all compositions of x = 0.05–0.20 at different temperatures(200–300 °C).     

Quantitative Analysis of the Crystallographic Orientation Relationship Between the Martensite and Austenite in Quenching–Partitioning–Tempering Steels

The orientation relationships(ORs)between the martensite and the retained austenite in low-and medium-carbon steels after quenching–partitioning–tempering process were studied in this work.The ORs in the studied steels are identified by selected-area electron diffraction(SAED)as either K–S or N–W ORs.Meanwhile,the ORs were also studied based on numerical fitting of electron backscatter diffraction data method suggested by Miyamoto.The simulated K–S and N–W ORs in the low-index directions generally do not well coincide with the experimental pole figure,which may be attributed to both the orientation spread from the ideal variant orientations and high symmetry of the low-index directions.However,the simulated results coincide well with experimental pole figures in the high-index directions{123}_(bcc).A modified method with simplicity based on Miyamoto’s work was proposed.The results indicate that the ORs determined by modified method are similar to those determined by Miyamoto’method,that is,the OR is near K–S OR for the low-carbon Q–P–T steel,and with the increase of carbon content,the OR is closer to N–W OR in medium-carbon Q–P–T steel.     

Using Finite Element and Contour Method to Evaluate Residual Stress in Thick Ti-6Al-4V Alloy Welded by Electron Beam Welding

This work was to reveal the residual stress profile in electron beam welded Ti-6Al-4V alloy plates(50 mm thick) by using finite element and contour measurement methods.A three-dimensional finite element model of 50-mmthick titanium component was proposed,in which a column–cone combined heat source model was used to simulate the temperature field and a thermo-elastic–plastic model to analyze residual stress in a weld joint based on ABAQUS software.Considering the uncertainty of welding simulation,the computation was calibrated by experimental data of contour measurement method.Both test and simulated results show that residual stresses on the surface and inside the weld zone are significantly different and present a narrow and large gradient feature in the weld joint.The peak tensile stress exceeds the yield strength of base materials inside weld,which are distinctly different from residual stress of the thin Ti-6Al-4V alloy plates presented in references before.     

Microstructures and Tensile Properties of Ultrafine-Grained Ni–(1–3.5) wt% SiC_(NP) Composites Prepared by a Powder Metallurgy Route

Silicon carbide nanoparticle-reinforced nickel-based composites(Ni–Si CNP),with a Si CNPcontent ranged from1 to 3.5 wt%,were prepared using mechanical alloying and spark plasma sintering.In addition,unreinforced pure nickel samples were also prepared for comparative purposes.To characterize the microstructural properties of both the unreinforced pure nickel and the Ni–Si CNPcomposites transmission electron microscopy(TEM) was used,while their mechanical behavior was investigated using the Vickers pyramid method for hardness measurements and a universal tensile testing machine for tensile tests.TEM results showed an array of dislocation lines decorated in the sintered pure nickel sample,whereas,for the Ni–Si CNPcomposites,the presence of nano-dispersed Si CNPand twinning crystals was observed.These homogeneously distributed Si CNPwere found located either within the matrix,between twins or on grain boundaries.For the Ni–Si CNPcomposites,coerced coarsening of the Si CNPassembly occurred with increasing Si CNPcontent.Furthermore,the grain sizes of the Ni–Si CNPcomposites were much finer than that of the unreinforced pure nickel,which was considered to be due to the composite ball milling process.In all cases,the Ni–Si CNPcomposites showed higher strengths and hardness values than the unreinforced pure nickel,likely due to a combination of dispersion strengthening(Orowan effects) and particle strengthening(Hall–Petch effects).For the Ni–Si CNPcomposites,the strength increased initially and then decreased as a function of Si CNPcontent,whereas their elongation percentages decreased linearly.Compared to all materials tested,the Ni–Si CNPcomposite containing 1.5% Si C was found more superior considering both their strength and plastic properties.     

Directional Growth of Tin Crystals Controlled by Combined Solute Concentration Gradient Field and Static Magnetic Field

A new method was introduced to achieve directional growth of Sn crystals. Microstructures in liquid(Pb)/liquid(Sn) diffusion couples were investigated under various static magnetic fields. Results show that the β-Sn crystals mainly reveal an irregular dendritic morphology without or with a relatively low static magnetic field(B0.3 T). When the magnetic field is increased to 0.5 T, the β-Sn dendrites close to the final stage of growth begin to show some directional character. With a further increase in the magnetic field to a higher level(0.8–5 T), the β-Sn dendrites have an enhanced directional growth character, but the dendrites show a certain deflection. As the magnetic field is increased to 12 T, the directional growth of the β-Sn dendrites in the center of the couple is severely destroyed. The mechanism of the directional growth of the β-Sn crystals and the deflection of the β-Sn crystals with the application of static magnetic field was tentatively discussed.     

电化学噪声数据处理方法概述

综述了常见的电化学噪声数据处理方法,介绍了直流趋势剔除、统计分析、快速傅立叶变换(FFT)法计算功率谱密度(PSD)以及小波变换处理电化学噪声信号的基本过程,并阐释了各种数学处理及所得参数的物理意义。