共查询到20条相似文献,搜索用时 78 毫秒
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长余辉材料在安全指示、防伪和生物成像等领域具有广泛应用前景,但其缺陷调控及余辉机理尚不清晰。自激活长余辉材料以其物质组成及晶体结构简单,便于研究余辉机理而受到关注。本研究以自激活长余辉材料锗酸锌为基质,采用高温固相反应合成得到了一系列钙掺杂的长余辉材料Zn2–xCaxGeO4(x=0、0.1、0.2、0.3、0.4、0.5)。实验表明,在锗酸锌中掺杂钙元素后,使用376nm紫外光激发时,观察到锗酸锌基质样品的黄色发光峰;同时在267 nm激发下, Zn1.5Ca0.5GeO4荧光强度增强了6.2倍。从余辉光谱和余辉衰减曲线上看, Zn1.5Ca0.5GeO4初始余辉强度增强了25.1倍;并且在所考察的300 s余辉时间里,与锗酸锌相比, Zn1.5Ca0.5GeO4保持了近5倍的余辉强度。进一步热释曲线表征显示,材料主要陷阱的... 相似文献
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长余辉发光材料研究进展 总被引:1,自引:0,他引:1
第一次观察到Sm~(3 )、Tm~(3 )、Yb~(3 )的红色和橙红色长余辉发光;首次在含镉的氧化物中观察到红、绿、蓝等多种颜色的新型长余辉发光,特别第一次观察到非稀土离子如Pb~(2 )、Bi~(3 )、Sn~(2 )、Sb~(3 )的长余辉发光现象;首先发现在一种基质中由一种稀土离子(Dy~(3 ))激活产生的发白色光的长余辉发光材料;第一次观察到Er~(3 )、Ho~(3 )的绿色长余辉发光;在掺Tm~(3 )的材料中发现迄今为止未见国内外报道的800nm最长波长的长余辉发射;在掺Tm~(3 )的材料中初步观察到既有上转换发光又具有长余辉发射的新的发光现象;开展了长余辉发光材料的纳米组装,以及开拓这类材料在环境和生物医学领域的应用研究。研究的能产生长余辉发光的激活离子和基质化合物已有较大扩展,并发现了一些变化规律及用现有模型和规则难以说明和解释的新的现象。迄今,文献报道的具有长余辉发光的基质和离子主要是铝酸盐、硅酸盐、硫氧化钇等基质和Eu~(2 )、Eu~(3 )、Ce~(3 )、Tb~(3 )、Pr~(3 )、Mn~(2 )等离子,拓展到锗酸盐、钨酸盐、镓酸盐、石榴石、含镉的氧化物以及稀土硫氧化物等... 相似文献
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长余辉发光材料的研究进展 总被引:1,自引:0,他引:1
长余辉发光材料因其具有特殊的储能发光性能,是一类绿色环保型材料.综述了主要体系长余辉发光材料的研究历程,总结了长余辉材料的制备方法和余辉效应,概括了长余辉发光研究上存在的问题,提出了今后研究和应用的发展方向. 相似文献
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系统地分析和概括了稀土离子激活硅酸盐体系长余辉发光材料的种类、特性、组成、结构、发光机理和制备技术。并根据长余辉发光材料研究现状,探讨了硅酸盐长余辉发光材料的研究方向与发展前景。 相似文献
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长余辉发光材料是一种在外在激发源(紫外线-可见光,X射线,β射线等)停止后仍能在相当时间内(几秒到十几个小时)维持肉眼可见的荧光余辉的材料,在应急照明、警示标识等方面开始得到广泛的应用。然而,长余辉材料的力致发光现象却是近几年来在国际上得到相关领域研究人员重视的一个研究方向,在力学传感器、材料应力分析、建筑物安全、地震及火山爆发预测等方面具有重要的应用前景。本文简单介绍了长余辉发光材料的力致发光现象及其发光机制、研究现状和应用等方面研究进展,供有关研究人员参考。 相似文献
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Zhanjun Li Nuo Yu Juanjuan Zhou Yang Li Yuanwei Zhang Ling Huang Kai Huang Yang Zhao Sharon Kelmar Jinyi Yang Gang Han 《Advanced materials (Deerfield Beach, Fla.)》2020,32(49):2003881
Afterglow nanoparticles (AGNPs) possessing inherently long lifetime with tailorable emission colors and uniform size have long been sought due to their time-gating-free high-contrast multiplexing imaging. Herein, via a straightforward template method, it is reported that such multicolor AGNPs can be accomplished. The resultant AGNPs exhibit a series of tunable afterglow emissions, including blue, yellow, green, and white. These multicolor AGNPs are found to be highly bright, enabling them to perform high-contrast multichannel afterglow imaging in vitro and in vivo without the use of any complicated time-gating algorithms or systems, which existing tools are unable to do. 相似文献
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Shen Xu Runfeng Chen Chao Zheng Wei Huang 《Advanced materials (Deerfield Beach, Fla.)》2016,28(45):9920-9940
Organic afterglow materials, developed recently by breaking through the difficulties in modulating ultrafast‐decayed excited states, exhibit ultralong‐lived emission for persistent luminescence with lifetimes of several orders of magnitude longer than traditional fluorescent and phosphorescent emissions at room temperature. Their exceptional properties, namely ultralong luminescent lifetime, large Stokes shifts, facile excited state transformation, and environmentally sensitive emission, have led to a diverse range of advanced optoelectronic applications. Here, the organic afterglow is reviewed from the perspective of fundamental concepts on both phenomenon and mechanism, examining the technical challenges in relation to excited state tuning and lifetime elongation. In particular, the advances in material design strategies that afford a large variety of organic afterglow materials for a broad utility in optoelectronics including lighting and displays, anti‐counterfeiting, optical recording, chemical sensors and bio‐imaging are highlighted. 相似文献
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烧成条件对长余辉蓄光玻璃光学性能的影响 总被引:8,自引:0,他引:8
以SrAl2O4:Eu,Dy长余辉发光粉体和低熔点硼硅酸盐玻璃为原料,在一定条件下合成了长余辉蓄光玻璃.研究结果表明,烧成温度和保温时间对该玻璃的发光效果影响较大.温度越高,保温时间越长,由于空气的氧化作用,蓄光玻璃的发光效果越差,本试验控制烧成温度在750~800℃间,保温时间在 10min以内,能合成性能较好的蓄光玻璃.余辉衰减曲线表明蓄光玻璃的发光性能较之原始发光粉体有所下降.SEM分析表明,低温合成的蓄光玻璃中,所含能继续保持发光性质的粉体料,明显比高温合成样要多. 相似文献
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Nian Liu Junpeng Shi Qiang Wang Jingru Guo Zhenyu Hou Xinhui Su Hongwu Zhang Xiaolian Sun 《Small (Weinheim an der Bergstrasse, Germany)》2020,16(26)
Persistent luminescence nanoparticles (PLNPs) with rechargeable near‐infrared afterglow properties attract much attention for tumor diagnosis in living animals since they can avoid tissue autofluorescence and greatly improve the signal‐to‐background ratio. Using UV, visible light, or X‐ray as excitation sources to power up persistent luminescence (PL) faces the challenges such as limited tissue penetration, inefficient charging capability, or tissue damage caused by irradiation. Here, it is proved that radiopharmaceuticals can efficiently excite ZnGa2O4:Cr3+ nanoparticles (ZGCs) for both fluorescence and afterglow luminescence via Cerenkov resonance energy transfer as well as ionizing radiation. 18F‐FDG, a clinically approved tumor‐imaging radiopharmaceutical with a short decay half‐life around 110 min, is successfully used as the internal light source to in vivo excite intravenously injected ZGCs for tumor luminescence imaging over 3 h. The luminescence with similar decay time can be re‐obtained for multiple times upon injection of 18F‐FDG at any time needed with no health concern. It is believed this strategy can not only provide tumor luminescence imaging with high sensitivity, high contrast, and long decay time at desired time, but also guarantee the patients much less radiation exposure, greatly benefiting image‐guided surgery in the future. 相似文献
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本文描述了国内外防伪领域标准化工作的情况,介绍了防伪国家标准对于提升我国防伪技术整体水平、促进我国防伪行业技术进步、提高企业核心竞争力所发挥的作用。根据防伪技术的发展趋势,对我国防伪标准化工作提出了一些建议。 相似文献
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目的建立一种光变防伪商标的微镜像素模型。方法基于色光反射,利用双余弦函数所构成的微镜曲面,满足反射光亮度和反射光强稳定度的雅可比行列式判据特性。结果构建出了适用于商标的RGBS结构型印刷防伪微镜模型,模拟并分析了函数表面形状随参数变化的情况。结论该模型利用余弦函数的周期性,可通过调节结构参量达到防伪的效果。 相似文献
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长余辉(寿命)发光材料研究的最新进展 总被引:7,自引:0,他引:7
综述了近几年来长余辉发光材料研究的最新进展,包括三方面:新材料研制,新应用领域的开拓和发光机理研究的模型.材料方面,主要介绍了红光、蓝光研究的进展与获得长余辉发光的关键因素-结构缺陷形成的陷阱态,以及稀土掺杂的作用.为促进新材料的研究着重概述了对长余辉发光机理研究的新进展,除了载流子传输与隧穿效应外,还介绍了两种最新观点;双光子吸收与VK中心模型,并对其存在的问题作了评述.应用方面,除了已有的弱光照明与显示领域外,还在向光电信息功能,特别是二维图像存储,高能粒子射线探测方面发展. 相似文献
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Design,Properties, and In Vivo Behavior of Superparamagnetic Persistent Luminescence Nanohybrids
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Eliott Teston Yoann Lalatonne Dan Elgrabli Gwennhael Autret Laurence Motte Florence Gazeau Daniel Scherman Olivier Clément Cyrille Richard Thomas Maldiney 《Small (Weinheim an der Bergstrasse, Germany)》2015,11(22):2696-2704
With the fast development of noninvasive diagnosis, the design of multimodal imaging probes has become a promising challenge. If many monofunctional nanocarriers have already proven their efficiency, only few multifunctional nanoprobes have been able to combine the advantages of diverse imaging modalities. An innovative nanoprobe called mesoporous persistent luminescence magnetic nanohybrids (MPNHs) is described that shows both optical and magnetic resonance imaging (MRI) properties intended for in vivo multimodal imaging in small animals. MPNHs are based on the assembly of chromium‐doped zinc gallate oxide and ultrasmall superparamagnetic iron oxide nanoparticles embedded in a mesoporous silica shell. MPNHs combine the optical advantages of persistent luminescence, such as real time imaging with highly sensitive and photostable detection, and MRI negative contrast properties that ensure in vivo imaging with rather high spatial resolution. In addition to their imaging capabilities, these MPNHs can be motioned in vitro with a magnet, which opens multiple perspectives in magnetic vectorization and cell therapy research. 相似文献